KR20230077103A - Shampoo composition including graphene and making method for the same - Google Patents
Shampoo composition including graphene and making method for the same Download PDFInfo
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- KR20230077103A KR20230077103A KR1020210164001A KR20210164001A KR20230077103A KR 20230077103 A KR20230077103 A KR 20230077103A KR 1020210164001 A KR1020210164001 A KR 1020210164001A KR 20210164001 A KR20210164001 A KR 20210164001A KR 20230077103 A KR20230077103 A KR 20230077103A
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Landscapes
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- Cosmetics (AREA)
Abstract
본 발명은 그래핀 함유 샴푸 조성물 및 그의 제조방법에 관한 것이며, 보다 구체적으로는 그래핀 옥사이드를 함유하는 샴푸 조성물에 추가적으로 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물을 함유하는 그래핀 함유 샴푸 조성물 및 그의 제조방법에 관한 것이다. The present invention relates to a graphene-containing shampoo composition and a method for preparing the same, and more specifically, to a shampoo composition containing graphene oxide, in addition to plant extracts such as leaf leaf extract, medicinal wheat extract, ginseng extract, Astragalus extract, Rehmannia Root extract, and Cham. The present invention relates to a graphene-containing shampoo composition containing angelica root extract, golden extract, barberry root extract, and hwangbyeok bark extract, and a method for preparing the same.
Description
본 발명은 그래핀 함유 샴푸 조성물 및 그의 제조방법에 관한 것이며, 보다 구체적으로는 그래핀 옥사이드를 함유하는 샴푸 조성물에 추가적으로 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물을 함유하는 그래핀 함유 샴푸 조성물 및 그의 제조방법에 관한 것이다. The present invention relates to a graphene-containing shampoo composition and a method for preparing the same, and more specifically, to a shampoo composition containing graphene oxide, in addition to plant extracts such as leaf leaf extract, medicinal wheat extract, ginseng extract, Astragalus extract, Rehmannia Root extract, and Cham. The present invention relates to a graphene-containing shampoo composition containing angelica root extract, golden extract, barberry root extract, and hwangbyeok bark extract, and a method for preparing the same.
모발은 외부의 충격으로부터 완충작용을 하며, 일광, 기온 변화 및 마찰 등의 외부 자극으로부터 인체를 보호하며, 인체에 불필요한 비소, 수은 및 아연 등의 중금속을 흡수하여 체외로 배출하는 기능을 한다. 현재에는 이러한 기본적인 기능뿐만 아니라, 새로운 이미지를 연출하고 자기만의 개성과 자신감을 창출하는 미용적인 측면의 기능이 더욱 중요시되고 있다.Hair acts as a buffer from external shocks, protects the human body from external stimuli such as sunlight, temperature change, and friction, and absorbs heavy metals such as arsenic, mercury, and zinc unnecessary for the human body and discharges them outside the body. Currently, not only these basic functions, but also cosmetic functions that create a new image and create one's own personality and confidence are becoming more important.
한편, 모발은 샴푸, 건조, 스타일링, 주변 환경 등 다양한 외적 요인에 의해 손상 받거나 또한, 샴푸로 세정시 두피의 과도한 마찰이나 천연 보습성분의 제거로 인해 건조 내지 거칠고 윤기 없는 상태를 유지하게 된다. 그러나, 유전적 요인, 내분비 질환, 영양결핍, 약물사용, 출산, 발열, 수술, 심한 신체적, 정신적 스트레스 등 다양한 요인으로 인해 최근에는 남여노소를 불문하고 탈모(Alopecia) 현상이 증가될 뿐 아니라, 탈모 시작 연령이 점차 낮아지고 있는 추세이다. 따라서 모발의 부드러움, 유연성, 윤기, 정전기방지, 빗질 용이성 등의 헤어컨디셔닝에 있어서는 이들 비결정질 영역을 근본적으로 보호하거나 회복시키는 것이 중요하다.On the other hand, hair is damaged by various external factors such as shampooing, drying, styling, surrounding environment, etc. Also, when washing with shampoo, excessive friction of the scalp or removal of natural moisturizing ingredients makes it dry or rough and maintains a non-glossy state. However, recently, due to various factors such as genetic factors, endocrine diseases, nutritional deficiencies, drug use, childbirth, fever, surgery, and severe physical and mental stress, not only the phenomenon of alopecia has increased, but also hair loss The starting age is gradually decreasing. Therefore, it is important to fundamentally protect or restore these amorphous regions in hair conditioning such as softness, flexibility, gloss, antistatic, and ease of combing of hair.
따라서, 두피로부터 생성되는 노폐물과 두피에 잔존하는 각종 이물질 등을 효과적으로 제거하는 세정력의 확보는 물론, 비듬 또는 가려움증과 같은 두피 트러블의 완화 또는 예방을 위한 항균, 항염 및 피부진정 기능의 향상과 더불어, 탈모 방지 및 발모 촉진을 강화하기 위한 복합 기능성 샴푸의 개발이 요구되고 있다. Therefore, in addition to securing cleaning power that effectively removes wastes generated from the scalp and various foreign substances remaining on the scalp, as well as improving antibacterial, anti-inflammatory and skin soothing functions for mitigating or preventing scalp troubles such as dandruff or itching, There is a demand for the development of complex functional shampoos for preventing hair loss and promoting hair growth.
본 발명의 그래핀 함유 샴푸 조성물 및 그의 제조방법에는 상술한 문제점을 해결하기 위해, 머리결 개선, 머리카락이 상대적으로 덜 빠지는 탈모 작용 완화, 두피의 가려움이나 트러블의 완화, 두피의 진정 작용의 효과가 있는 그래핀 함유 샴푸 조성물 및 그의 제조방법을 제공한다. In order to solve the above-mentioned problems, the graphene-containing shampoo composition and method for preparing the same of the present invention have the effects of improving hair quality, relieving hair loss, relieving itchiness or trouble of the scalp, and soothing the scalp. A graphene-containing shampoo composition and method for preparing the same are provided.
본 발명의 일 실시형태인 그래핀 함유 샴푸 조성물은, 정제수 20 중량부 내지 40 중량부, 글리세린 1 중량부 내지 10중량부, 식물 추출물 1 중량부 내지 10 중량부, 올리브 오일 0.4 중량부 내지 0.6 중량부 및 쌀겨 오일 0.1 중량부 내지 0.4 중량부를 포함하는 오일, 향료 0.1 중량부 내지 0.5 중량부, 계면활성제 1 내지 10 중량부, 암모늄라우레스설페이트 15 중량부 내지 25중량부, 암모늄라우릴설페이트 15 중량부 내지 25중량부 및 그래핀 옥사이드 0.01 중량부 내지 0.1 중량부를 함유한다. The graphene-containing shampoo composition according to an embodiment of the present invention contains 20 parts by weight to 40 parts by weight of purified water, 1 part by weight to 10 parts by weight of glycerin, 1 part by weight to 10 parts by weight of a plant extract, and 0.4 parts by weight to 0.6 parts by weight of olive oil. 0.1 to 0.4 parts by weight of rice bran oil, 0.1 to 0.5 parts by weight of perfume, 1 to 10 parts by weight of surfactant, 15 to 25 parts by weight of ammonium laureth sulfate, 15 parts by weight of ammonium lauryl sulfate part to 25 parts by weight and 0.01 part by weight to 0.1 part by weight of graphene oxide.
또한, 상기 식물 추출물은 소엽잎 추출물 1 중량부 내지 2 중량부, 약모밀 추출물 1 중량부 내지 2 중량부, 인삼 추출물 1 중량부 내지 2 중량부을 포함하며, 또한 상기 식물 추출물은 황기 추출물 0.01 중량부 내지 0.05 중량부, 지황 추출물 0.01 중량부 내지 0.05 중량부, 참당귀 뿌리 추출물 0.01 중량부 내지 0.05 중량부, 황금 추출물 0.01 중량부 내지 0.05 중량부, 황련 뿌리 추출물 0.01 중량부 내지 0.05 중량부, 황벽 나무 껍질 추출물 0.01 중량부 내지 0.05 중량부을 더욱 포함한다. In addition, the plant extract includes 1 part by weight to 2 parts by weight of leaf leaf extract, 1 part by weight to 2 parts by weight of medicinal buckwheat extract, and 1 part by weight to 2 parts by weight of ginseng extract, and the plant extract contains 0.01 part by weight to 0.01 part by weight of astragalus extract. 0.05 part by weight, Rehmannia Root extract 0.01 part by weight to 0.05 part by weight, Angelica gigas root extract 0.01 part by weight to 0.05 part by weight, Golden extract 0.01 part by weight to 0.05 part by weight, Barberry root extract 0.01 part by weight to 0.05 part by weight, Hwangbyeok tree bark It further comprises 0.01 part by weight to 0.05 part by weight of the extract.
본 발명의 일 실시형태인 그래핀 함유 샴푸물 조성물의 제조방법은 상기 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 비수리 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물은 소엽잎, 약모밀, 인삼, 황기, 지황, 참당귀 뿌리, 황금, 황련 뿌리, 황벽 나무 껍질을 혼합하는 제1 단계; 상기 제1 단계의 혼합물을 75℃ 내지 85℃의 추출온도, 5시간 내지 7시간의 추출시간, 에탄올 농도 50wt% 내지 60wt%에서 추출하는 제2 단계; 상기 제2 단계의 추출물을 샴푸 조성물에 혼합하는 제3 단계;를 포함한다. One embodiment of the present invention, a method for producing a graphene-containing shampoo water composition, is a leaf extract of the plant extract, medicinal buckwheat extract, biscuits extract, ginseng extract, Astragalus extract, Rehmannia Root extract, Angelica root extract, Golden extract, Barberry root The extract, Hwangbyeok bark extract, is a first step of mixing leaflets, medicinal wheat, ginseng, Astragalus, Rehmannia Root, Angelica root, golden, Barberry root, and Hwangbyeok bark; A second step of extracting the mixture of the first step at an extraction temperature of 75° C. to 85° C., an extraction time of 5 hours to 7 hours, and an ethanol concentration of 50 wt% to 60 wt%; A third step of mixing the extract of the second step with the shampoo composition; includes.
본 발명의 그래핀 함유 샴푸 조성물 및 그의 제조방법에 의하면, 그래핀 옥사이드를 함유하는 샴푸 조성물에 추가적으로 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물을 함유하여 머리결 개선, 머리카락이 상대적으로 덜 빠지는 탈모 작용 완화, 두피의 가려움이나 트러블의 완화, 두피의 진정 작용의 효과가 있다. According to the graphene-containing shampoo composition and method for manufacturing the same of the present invention, in addition to the graphene oxide-containing shampoo composition, plant extracts such as leaf leaf extract, medicinal buckwheat extract, ginseng extract, Astragalus extract, Rehmannia Root extract, Angelica gigas root extract, Golden It contains extract, barberry root extract, and hwangbyeok bark extract to improve hair quality, relieve hair loss, relieve itching or trouble of the scalp, and soothe the scalp.
하기에 설명되는 실시예는 단지 예시적인 것에 불과하며, 이러한 실시예로부터 다양한 변형이 가능하다. 이하에서, 용어들은 하나의 구성요소를 다른 구성요소로부터 구별하는 목적으로만 사용된다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 또한 어떤 부분이 어떤 구성 요소를 "포함"한다고 할 때, 이는 특별히 반대되는 기재가 없는 한 다른 구성요소를 제외하는 것이 아니라 다른 구성요소를 더 포함할 수 있는 것을 의미한다. The embodiments described below are merely illustrative, and various modifications are possible from these embodiments. In the following, terms are used only for the purpose of distinguishing one component from another. Singular expressions include plural expressions unless the context clearly dictates otherwise. In addition, when a certain component is said to "include", this means that it may further include other components without excluding other components unless otherwise stated.
하기에서 본 발명의 그래핀 함유 샴푸 조성물에 대하여 구체적으로 설명한다. 즉, 본 발명의 그래핀 함유 샴푸 조성물은 정제수 20 중량부 내지 40 중량부, 글리세린 1 중량부 내지 10중량부, 식물 추출물 1 중량부 내지 10 중량부, 올리브 오일 0.4 중량부 내지 0.6 중량부 및 쌀겨 오일 0.1 중량부 내지 0.4 중량부를 포함하는 오일, 향료 0.1 중량부 내지 0.5 중량부, 계면활성제 1 내지 10 중량부, 암모늄라우레스설페이트 15 중량부 내지 25중량부, 암모늄라우릴설페이트 15 중량부 내지 25중량부 및 그래핀 옥사이드 0.01 중량부 내지 0.1 중량부를 함유한다. The graphene-containing shampoo composition of the present invention will be described in detail below. That is, the graphene-containing shampoo composition of the present invention includes 20 parts by weight to 40 parts by weight of purified water, 1 part by weight to 10 parts by weight of glycerin, 1 part by weight to 10 parts by weight of a plant extract, 0.4 parts by weight to 0.6 parts by weight of olive oil, and rice bran. Oil containing 0.1 to 0.4 parts by weight of oil, 0.1 to 0.5 parts by weight of perfume, 1 to 10 parts by weight of surfactant, 15 parts to 25 parts by weight of ammonium laureth sulfate, 15 parts by weight to 25 parts by weight of ammonium lauryl sulfate part by weight and 0.01 part by weight to 0.1 part by weight of graphene oxide.
여기서, 글리세린은 1 중량부 내지 5중량부 함유되며, 구조상 히드록시기(-OH)를 3개를 가지고 있어서 샴푸 후에 두피에 수분 흡수력이 강하며, 두피에 대한 윤활 작용과 보습 작용을 한다.Here, glycerin is contained in an amount of 1 part by weight to 5 parts by weight, and has three hydroxyl groups (-OH) in its structure, so that the scalp has a strong moisture absorption ability after shampooing, and has a lubricating and moisturizing effect on the scalp.
본 발명의 오일은 올리브 오일 0.4 중량부 내지 0.6 중량부 및 쌀겨 오일 0.1 중량부 내지 0.4 중량부을 포함한다. 올리브 오일은 항산화 작용을 하며, 올리브 오일에는 비타민E. 폴리페놀, 식물 스테롤 등의 항산화 작용을 갖는 성분을 포함하고 있으므로 두피 내의 항균 효과를 기대할 수 있다. 그리고, 올리브 오일의 하이드록시타이로솔 성분은 활성 산소로부터 손상된 모발을 보호하는 작용을 할 수 있다. 다만, 상기 범위를 초과하는 경우 올리브 오일은 단일 불포화 지방산이기 때문에 바람직하지 않다. 쌀겨 오일은 쌀의 씨앗에서 제거된 쌀겨로 제조되며, 쌀겨 오일에는 미네랄, 아미노산, 필수지방산과 산화방지제를 포함하고 있으므로 두피에 대한 영양 공급과 함께 산화 방지에 대한 효과를 갖는다. 한편, 쌀겨 오일은 30℃ 내지 35℃의 저온에서 5일 내지 10일 발효시키면 보습 효과를 향상하는 효과를 갖는다. The oil of the present invention includes 0.4 to 0.6 parts by weight of olive oil and 0.1 to 0.4 parts by weight of rice bran oil. Olive oil has antioxidant properties, and vitamin E in olive oil. Since it contains components having antioxidant action such as polyphenols and plant sterols, an antibacterial effect in the scalp can be expected. In addition, the hydroxytyrosol component of olive oil can act to protect damaged hair from active oxygen. However, if it exceeds the above range, it is not preferable because olive oil is a monounsaturated fatty acid. Rice bran oil is made from rice bran removed from rice seeds, and since rice bran oil contains minerals, amino acids, essential fatty acids and antioxidants, it has an antioxidant effect as well as a nutritional supply to the scalp. On the other hand, rice bran oil has the effect of improving the moisturizing effect when fermented for 5 to 10 days at a low temperature of 30 ° C to 35 ° C.
본 발명의 그래핀 옥사이드는 0.01 중량부 내지 0.1 중량부 함유되며, 탄소 동소체 중 하나인 그래핀(graphene)에 있어서 탄소 원자들은 육각형의 꼭짓점에 존재하며 넓게 퍼진 육각형 벌집 모양의 2차원 평면 결정 구조를 이룬다. 그래핀은 원자 한 개 두께로 이루어진 막으로 안정적인 구조로 존재한다. 그래핀 옥사이드를 사용함으로써 두피 내의 항균력을 증가시켜 두피 각질 개선, 모발 탄력 개선, 두피 유분 유지, 두피 탄력 개선되는 효과를 기대할 수 있다. 이는 그래핀 옥사이드가 갖고 있는 두피 내에 미세하게 침투되는 것으로 인하여 피부 내 흡수 효과가 높아지는 것으로 여겨진다.The graphene oxide of the present invention is contained in an amount of 0.01 part by weight to 0.1 part by weight, and in graphene, one of the carbon allotropes, carbon atoms exist at the vertices of the hexagon and form a two-dimensional planar crystal structure in a widely spread hexagonal honeycomb shape. achieve Graphene is a film with a thickness of one atom and exists in a stable structure. By using graphene oxide, antibacterial power in the scalp is increased, and the effects of improving scalp dead skin cells, hair elasticity, maintenance of scalp oil, and improvement of scalp elasticity can be expected. It is believed that this is because the absorption effect in the skin is increased due to fine penetration into the scalp of graphene oxide.
본 발명에 사용되는 그래핀 옥사이드는 물리적 박리법, 화학적 증착법, 화학적 박리법, 에피텍샬 성장법 등을 사용하여 제조될 수 있다. 물리적 박리법은 여러 층으로 구성된 흑연 결정에서 기계적인 힘으로 한 층을 벗겨내어 그래핀을 만드는 방법이다. 물리적 힘을 이용해 흑연 결정으로부터 한 겹씩 그래핀을 생성시킨다. 상대적으로 필요한 에너지가 낮지만, 넓은 면적으로 만드는 것이 어렵고, 결함 비율이 높고 대량 생산이 어려운 단점을 갖는다. 화학 증착법(chemical vapor deposition)은 뛰어난 결정질을 갖는 단층 내지 수층 정도의 그래핀을 넓은 면적으로 얻는 방법이다. 그래핀을 성장시키고자 하는 기판 표면에 높은 운동 에너지를 가진 기체 또는 증기 형태 탄소 전구체를 흡착-분해(또는 반응)하여 탄소 원자를 분해하고 탄소 원자들이 서로 결합하게 만들어 그래핀으로 성장시키는 방법이다. 촉매 없이 흑연과 같은 sp2 결합구조를 가진 탄소 구조체를 합성하기 위해서는 매우 높은 온도와 압력이 필요하다. 높은 결정질의 그래핀을 낮은 온도(~1273K)에서 합성하기 위해서는 촉매가 필요하며, 가장 많이 사용되는 전이 금속 촉매는 구리와 니켈이며, 그 외 금, 백금, 루테늄, 철, 이리듐 등이 사용된다. 화학적 박리법은 흑연의 산화-환원 특성을 활용한 방법이다. 흑연을 강산과 산화제 등으로 산화시켜 산화 흑연(graphite oxide)을 만든다. 산화 흑연은 강한 친수성이어서 물 분자가 면 사이에 쉽게 끼어들기 때문에 물과 닿으면 잘 침투한다. 이 결과 면 사이 간격이 커져 교반이나 초음파 분쇄기를 장시간 이용하면 쉽게 박리시킬 수 있다. 화학반응 과정은 먼저 미세한 흑연 결정을 강한 황산과 질산 혼합물에 넣어 그래핀의 가장자리에 카복실 화합물(graphene-COOH)을 결합한다. 이를 그래핀 아마이드로 만들고 테트라하이드로푸란, 테트라클로로메탄, 다이클로로에탄 같은 용액을 이용해 회수하면 그래핀이 생성된다. 에피텍셜 성장법(epitaxial growth)은 실리콘 카바이드(SiC)와 같이 탄소가 결정에 흡착되거나 포함된 재료를 약 1,500℃에서 열처리하여 그래핀을 만드는 방법이다. 열처리 공정 중 탄소가 실리콘 카바이드 표면의 결을 따라 성장하면서 그래핀이 형성된다. 에피텍셜 합성법은 직접 원하는 위치에 그래핀을 성장시킬 수 있는 장점이 있지만, 재료가 비싸고 제작이 어렵다는 단점이 있다. 따라서, 본 발명의 화학적 박리법을 사용하여 그래핀을 바람직하게 제조할 수 있다. Graphene oxide used in the present invention may be prepared using a physical exfoliation method, a chemical vapor deposition method, a chemical exfoliation method, an epitaxial growth method, or the like. The physical exfoliation method is a method of producing graphene by mechanically peeling off one layer from a graphite crystal composed of several layers. Graphene is created layer by layer from graphite crystals using physical force. Although the energy required is relatively low, it is difficult to make it in a large area, and the defect rate is high and mass production is difficult. Chemical vapor deposition is a method of obtaining single to several layers of graphene having excellent crystalline quality over a large area. It is a method of growing graphene by adsorbing and decomposing (or reacting) a gaseous or vapor-type carbon precursor with high kinetic energy on the surface of a substrate to grow graphene to decompose carbon atoms and make carbon atoms bond with each other. In order to synthesize a carbon structure having an sp2 bonding structure like graphite without a catalyst, very high temperature and pressure are required. A catalyst is required to synthesize high-crystalline graphene at a low temperature (~1273K), and the most commonly used transition metal catalysts are copper and nickel, while gold, platinum, ruthenium, iron, and iridium are also used. The chemical exfoliation method utilizes the oxidation-reduction properties of graphite. Graphite is oxidized with a strong acid and an oxidizing agent to produce graphite oxide. Graphite oxide is highly hydrophilic, so water molecules can easily get between the surfaces, so it penetrates well when it comes in contact with water. As a result, the gap between the surfaces increases, so that it can be easily separated by stirring or using an ultrasonic mill for a long time. In the chemical reaction process, fine graphite crystals are first put into a mixture of strong sulfuric acid and nitric acid to bind a carboxyl compound (graphene-COOH) to the edge of graphene. When this is made into graphene amide and recovered using solutions such as tetrahydrofuran, tetrachloromethane, and dichloroethane, graphene is produced. Epitaxial growth is a method of producing graphene by heat-treating a material in which carbon is adsorbed or contained in a crystal, such as silicon carbide (SiC), at about 1,500 ° C. During the heat treatment process, graphene is formed as carbon grows along the grain of the silicon carbide surface. The epitaxial synthesis method has the advantage of being able to directly grow graphene at a desired location, but has the disadvantage of being expensive and difficult to manufacture. Therefore, graphene can be preferably prepared using the chemical exfoliation method of the present invention.
본 발명의 계면활성제는 1 내지 10 중량부 함유되며, 정제수와 글리세린, 식물 추출물, 올리브 오일 및 쌀겨 오일을 포함하는 오일, 향료, 그래핀 옥사이드 등의 성분을 잘 혼합하고, 혼합된 상태가 유지되어 샴푸 성분으로서 사용되게 하는 역할을 한다. 특히, 계면활성제와 세정성을 갖는다는 점에서 계면활성제로서 하기 화학식 1로 표시되는 화합물 5 내지 10 중량부를 사용할 수 있다. The surfactant of the present invention is contained in an amount of 1 to 10 parts by weight, and components such as purified water, glycerin, plant extract, oil including olive oil and rice bran oil, fragrance, and graphene oxide are well mixed and the mixed state is maintained. It plays a role to be used as a shampoo ingredient. In particular, 5 to 10 parts by weight of the compound represented by Formula 1 may be used as a surfactant in that it has surfactant and detergency.
[화학식 1] [Formula 1]
본 발명의 그래핀 함유 샴푸 조성물은 암모늄라우레스설페이트 15 중량부 내지 25중량부, 암모늄라우릴설페이트 15 중량부 내지 25중량부를 더욱 함유한다. 암모늄라우레스설페이트은 코코넛에서 추출한 성분으로서 세정력이 우수하다. 암모늄라우릴설페이트는 올리브 오일 또는 쌀겨 오일과 정제수가 혼합되게 하여 샴푸 세정시에 두피에 남아 있는 먼지를 올리브 오일 또는 쌀겨 오일과 정제수에 씻겨 내려가게 함으로써 두피와 모발을 깨끗하게 한다. The graphene-containing shampoo composition of the present invention further contains 15 parts by weight to 25 parts by weight of ammonium laureth sulfate and 15 parts by weight to 25 parts by weight of ammonium lauryl sulfate. Ammonium laureth sulfate is an ingredient extracted from coconut and has excellent cleaning power. Ammonium lauryl sulfate is mixed with olive oil or rice bran oil and purified water to clean the scalp and hair by washing away the dust remaining on the scalp with olive oil or rice bran oil and purified water during shampoo washing.
본 발명의 식물 추출물은 소엽잎 추출물(Perilla Frutescens Leaf Extract) 1 중량부 내지 2 중량부, 약모밀 추출물(Houttuynia Cordata Extract) 1 중량부 내지 2 중량부, 인삼 추출물(Panax Ginseng Root Extract) 1 중량부 내지 2 중량부을 포함한다. 소엽잎 추출물은 비타민 K와 미네랄 성분을 함유하고 있어서 두피의 트러블 개선에 도움이 되고, 두피 진정 작용을 갖는다. 약모밀 추출물은 두피에 대하여 항균 작용을 하고, 아토피의 두피에 개선 효과를 갖는다. 인삼 추출물은 바람직하게 홍삼 추출물을 사용할 수 있다. 홍삼 추출물에는 페놀성 화합물과 말코스가 두피의 노화 방지에 좋고, 두피 내에 침투하여 혈류 증가에 따른 탄력 향상의 효과를 갖는다. 또한, 본 발명의 식물 추출물은 비수리 추출물 1 중량부 내지 2 중량부을 더 포함할 수 있다. 비수리 추출물을 사용하여 두피의 지방질 산화를 억제하고, 항산화 물질로 작용할 수 있다. The plant extract of the present invention contains 1 to 2 parts by weight of Perilla Frutescens Leaf Extract, 1 to 2 parts by weight of Houttuynia Cordata Extract, and 1 part to 2 parts by weight of Panax Ginseng Root Extract. 2 parts by weight. Leaf extract contains vitamin K and minerals, so it helps to improve scalp troubles and has a scalp soothing effect. The medicinal buckwheat extract has an antibacterial effect on the scalp and has an improving effect on the atopic scalp. Ginseng extract may preferably use red ginseng extract. In red ginseng extract, phenolic compounds and malcose are good for preventing aging of the scalp, and have an effect of improving elasticity due to increased blood flow by penetrating into the scalp. In addition, the plant extract of the present invention may further include 1 part by weight to 2 parts by weight of the periwinkle extract. Visuri extract can be used to inhibit lipid oxidation in the scalp and act as an antioxidant.
본 발명의 식물 추출물은 황기 추출물(Astragalus Membranaceus Root Extract) 0.01 중량부 내지 0.05 중량부, 지황 추출물(Rehmannia Chinensis Root Extract) 0.01 중량부 내지 0.05 중량부, 참당귀 뿌리 추출물(Angelica Gigas Root Extract) 0.01 중량부 내지 0.05 중량부, 황금 추출물(Scutellaria Baicalensis Root Extract) 0.01 중량부 내지 0.05 중량부, 황련 뿌리 추출물(Coptis Chinensis Root Extract) 0.01 중량부 내지 0.05 중량부, 황벽 나무 껍질 추출물(Phellodendron Amurense Bark Extract) 0.01 중량부 내지 0.05 중량부을 더욱 포함할 수 있다. 황기 추출물은 두피에 대한 항산화 효과와 보습 효과가 있다. 지황 추출물은 두피에 유분 밸런스를 유지하여 두피에 지나친 유분의 방출이나 건조하게 되는 것을 방지하는 효과를 갖는다. 참당귀 뿌리 추출물은 혈액순환을 활발하게 도와주기 때문에 두피의 탄력을 유지하는 효과를 갖는다. 황금 추출물에 함유된 바이칼린, 카데킨 성분은 두피 염증을 가라않히는 효과를 갖는다. 황련 뿌리 추출물에 함유된 베르베린 성분은 두피에 대하여 소염, 항균 작용을 한다. 황벽 나무 껍질 추출물은 두피의 활성을 억제하여 피부 산화적 손상을 방지하고, 피부 활력에 도움을 준다. The plant extract of the present invention contains 0.01 part by weight to 0.05 part by weight of Astragalus Membranaceus Root Extract, 0.01 part by weight to 0.05 part by weight of Rehmannia Chinensis Root Extract, and 0.01 part by weight of Angelica Gigas Root Extract. Part to 0.05 part by weight, Scutellaria Baicalensis Root Extract 0.01 part to 0.05 part by weight, Coptis Chinensis Root Extract 0.01 part to 0.05 part by weight, Phellodendron Amurense Bark Extract 0.01 part by weight It may further include 0.05 parts by weight to 0.05 parts by weight. Astragalus extract has antioxidant and moisturizing effects on the scalp. Rehmannia glutinosa extract maintains the oil balance on the scalp and has an effect of preventing excessive oil release or drying of the scalp. Angelica gigas root extract helps blood circulation actively, so it has the effect of maintaining the elasticity of the scalp. Baicalin and catechin components contained in golden extract have the effect of calming scalp inflammation. The berberine component contained in barberry root extract has anti-inflammatory and antibacterial effects on the scalp. Hwangbyeok tree bark extract inhibits the activity of the scalp to prevent oxidative damage to the skin and helps to revitalize the skin.
본 발명의 그래핀 함유 샴푸 조성물은 하기 화학식 2의 화합물 1 중량부 내지 2 중량부를 더욱 포함하여 샴푸 조성물을 물에 희석하여 거품 형성을 촉진한다. The graphene-containing shampoo composition of the present invention further includes 1 part by weight to 2 parts by weight of a compound represented by Formula 2 below, and dilutes the shampoo composition in water to promote foam formation.
[화학식 2] [Formula 2]
본 발명의 그래핀 함유 샴푸 조성물은 실리콘계 고분자로 유기화합물 계열 화합물 0.1 중량부 내지 1 중량부을 더욱 포함할 수 있다. 예를 들어, 폴리디메틸실록산(polydimethylsiloxane)을 사용하여 보습 작용을 하며, 두피에 수분을 촉촉하게 유지하는 효과를 갖는다. The graphene-containing shampoo composition of the present invention may further include 0.1 part by weight to 1 part by weight of an organic compound-based compound as a silicon-based polymer. For example, polydimethylsiloxane is used to moisturize and has an effect of keeping the scalp moist.
본 발명의 그래핀 함유 샴푸 조성물은 글리콜 화합물을 포함할 수 있다. 예를 들어, 화학식 3으로 표시되는 화합물 1 중량부 내지 5 중량부 함유하여 습윤제의 역할을 하며, 화학식 4로 표시되는 화합물 0.1 중량부 내지 0.5 중량부 함유하여 두피 항균력과 함께 스킨 컨디셔닝 효과를 갖는다. The graphene-containing shampoo composition of the present invention may include a glycol compound. For example, 1 part by weight to 5 parts by weight of the compound represented by Formula 3 is contained to act as a humectant, and 0.1 part by weight to 0.5 parts by weight of the compound represented by Formula 4 is contained to have a scalp antibacterial activity and skin conditioning effect.
[화학식 3] [화학식 4] [Formula 3] [Formula 4]
본 발명의 그래핀 함유 샴푸 조성물은 하기 화학식 5로 표시되는 화합물을 포함할 수 있다. 화학식 5로 표시되는 화합물 0.1 중량부 내지 0.5 중량부을 포함하여 두피의 염증을 완화하는 효과를 가질 수 있다. The graphene-containing shampoo composition of the present invention may include a compound represented by Formula 5 below. Including 0.1 part by weight to 0.5 part by weight of the compound represented by Formula 5 may have an effect of alleviating inflammation of the scalp.
[화학식 5] [Formula 5]
본 발명의 그래핀 함유 샴푸 조성물은 에칠헥실글리세린(Ethylhexylglycerin) 0.1 중량부 내지 0.3 중량부을 포함할 수 있다. 에칠헥실글리세린을 포함하여 샴푸 조성물의 방부 효과와 함께 탈취 효과, 피부 컨디셔닝의 효과를 가질 수 있다. The graphene-containing shampoo composition of the present invention may include 0.1 part by weight to 0.3 part by weight of ethylhexylglycerin. Including ethylhexyl glycerin, the shampoo composition may have a deodorizing effect and a skin conditioning effect along with an antiseptic effect.
본 발명의 그래핀 함유 샴푸 조성물은 폴리쿼터늄-73 0.1 중량부 내지 0.8 중량부을 더욱 포함하여 샴푸 시에 두피에 얇은 피막을 형성하여 보습 효과를 높일 수 있다. The graphene-containing shampoo composition of the present invention may further include 0.1 part by weight to 0.8 part by weight of polyquaternium-73 to form a thin film on the scalp during shampooing to enhance the moisturizing effect.
본 발명의 그래핀 함유 샴푸 조성물은 코카마이드엠이에이(cocamide monoethanolamine) 1 중량부 내지 3 중량부를 더욱 포함하여 샴푸의 거품 형성에 사용될 수 있다. The graphene-containing shampoo composition of the present invention may further include 1 part by weight to 3 parts by weight of cocamide monoethanolamine to be used for foaming of shampoo.
한편, 본 발명의 그래핀 함유 샴푸 조성물의 제조 방법은, 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 비수리 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물은 소엽잎, 약모밀, 비수리, 인삼, 황기, 지황, 참당귀 뿌리, 황금, 황련 뿌리, 황벽 나무 껍질을 혼합하는 제1 단계; 상기 제1 단계의 혼합물을 75℃ 내지 85℃의 추출온도, 5시간 내지 7시간의 추출시간, 에탄올 농도 50wt% 내지 60wt%에서 추출하는 제2 단계; 상기 제2 단계의 추출물을 샴푸 조성물에 혼합하는 제3 단계;를 포함한다. 바람직하게는, 80℃의 추출온도, 6시간의 추출시간, 에탄올 농도 50wt% 서 추출하여 사용할 수 있다. 여기서, 상기 제3 단계의 샴푸 조성물에 함유되는 쌀겨 오일은 30℃ 내지 35℃의 저온에서 5일 내지 10일 발효시키는 단계를 포함한다. On the other hand, the manufacturing method of the graphene-containing shampoo composition of the present invention is a plant extract, leaf extract, medicinal buckwheat extract, daffodil extract, ginseng extract, astragalus extract, Rehmannia Root extract, Angelica root extract, golden extract, barberry root extract, hwangbyeok The bark extract is a first step of mixing leaflets, medicinal wheat, birch, ginseng, astragalus, rehmannia, angelica root, golden, barberry root, and hwangbyeok tree bark; A second step of extracting the mixture of the first step at an extraction temperature of 75° C. to 85° C., an extraction time of 5 hours to 7 hours, and an ethanol concentration of 50 wt% to 60 wt%; A third step of mixing the extract of the second step with the shampoo composition; includes. Preferably, it can be extracted and used at an extraction temperature of 80 ° C., an extraction time of 6 hours, and an ethanol concentration of 50 wt%. Here, the rice bran oil contained in the shampoo composition of the third step includes fermenting for 5 to 10 days at a low temperature of 30 ° C to 35 ° C.
(실시예) (Example)
정제수 28.79중량부, 글리세린 6중량부, 올리브 오일 0.5 중량부 및 쌀겨 오일 0.3 중량부를 포함하는 오일, 향료 0.3 중량부, 화학식 1로 표시되는 화합물 9 중량부, 암모늄라우레스설페이트 22 중량부, 암모늄라우릴설페이트 20 중량부, 화학식 2로 표시되는 화합물 1.5 중량부, 코카마이드엠이에이 2.5 중량부, 화학식 3로 표시되는 화합물 3 중량부, 화학식 4로 표시되는 화합물 0.15 중량부, 그래핀 옥사이드 0.05 중량부, 에칠헥실글리세린 0.15 중량부, 화학식 5로 표시되는 화합물 0.2 중량부, 폴리쿼터늄-73 0.5 중량부, 폴리디메틸실록산 0.5 중량부, 소엽잎 추출물 1.5 중량부, 약모밀 추출물 1.5 중량부, 인삼 추출물 1.5 중량부, 황기 추출물 0.01 중량부, 지황 추출물 0.01 중량부, 참당귀 뿌리 추출물 0.01 중량부, 황금 추출물 0.01 중량부, 황련 뿌리 추출물 0.01 중량부, 황벽 나무 껍질 추출물 0.01 중량부를 혼합하여 샴푸 조성물을 제조하였다. 여기서 중량부는 kg을 의미한다. 28.79 parts by weight of purified water, 6 parts by weight of glycerin, oil containing 0.5 parts by weight of olive oil and 0.3 parts by weight of rice bran oil, 0.3 parts by weight of perfume, 9 parts by weight of the compound represented by Formula 1, 22 parts by weight of ammonium laureth sulfate, ammonium la 20 parts by weight of uryl sulfate, 1.5 parts by weight of the compound represented by Formula 2, 2.5 parts by weight of Cocamide MEA, 3 parts by weight of the compound represented by Formula 3, 0.15 part by weight of the compound represented by Formula 4, 0.05 part by weight of graphene oxide 0.15 parts by weight of ethylhexylglycerin, 0.2 parts by weight of the compound represented by Formula 5, 0.5 parts by weight of polyquaternium-73, 0.5 parts by weight of polydimethylsiloxane, 1.5 parts by weight of leaf extract, 1.5 parts by weight of wild wheat extract, 1.5 parts by weight of ginseng extract Shampoo composition was prepared by mixing 0.01 parts by weight of Astragalus root extract, 0.01 part by weight of Rehmannia tuber extract, 0.01 part by weight of Angelica gigas root extract, 0.01 part by weight of Golden extract, 0.01 part by weight of Barberry root extract, and 0.01 part by weight of Hwangbyeok bark extract. . Here, weight part means kg.
샴푸 조성물의 효과를 확인하여 위하여, 30명에게 본 실시예에서 제조한 샴푸 조성물을 사용한 결과를 조사하였다. 샴푸 조성물의 효과는 머리결 개선, 머리카락이 상대적으로 덜 빠지는 탈모 작용, 두피의 가려움이나 트러블의 완화, 두피의 진정 작용에 대하여 구체적으로 조사였다. In order to confirm the effect of the shampoo composition, the results of using the shampoo composition prepared in this example were investigated on 30 people. The effects of the shampoo composition were specifically investigated for hair texture improvement, hair loss with relatively less hair falling out, relief of itching or troubles of the scalp, and soothing effect of the scalp.
본 실시예에 의하면, 머리결 개선(97%), 머리카락이 상대적으로 덜 빠지는 탈모 작용 완화(94%), 두피의 가려움이나 트러블의 완화(94%), 두피의 진정 작용(91%)의 효과가 있음을 확인하였다. According to this embodiment, the effects of hair texture improvement (97%), hair loss relief (94%), scalp itchiness or trouble relief (94%), scalp soothing effect (91%) confirmed that there is
본 발명은 상기 실시예들에 한정되는 것이 아니라 서로 다른 다양한 형태로 제조될 수 있으며, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자는 본 발명의 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.The present invention is not limited to the above embodiments, but can be manufactured in a variety of different forms, and those skilled in the art to which the present invention pertains may take other specific forms without changing the technical spirit or essential features of the present invention. It will be understood that it can be implemented as. Therefore, the embodiments described above should be understood as illustrative in all respects and not limiting.
Claims (3)
상기 식물 추출물은 소엽잎 추출물 1 중량부 내지 2 중량부, 약모밀 추출물 1 중량부 내지 2 중량부, 인삼 추출물 1 중량부 내지 2 중량부을 포함하며, 또한 상기 식물 추출물은 황기 추출물 0.01 중량부 내지 0.05 중량부, 지황 추출물 0.01 중량부 내지 0.05 중량부, 참당귀 뿌리 추출물 0.01 중량부 내지 0.05 중량부, 황금 추출물 0.01 중량부 내지 0.05 중량부, 황련 뿌리 추출물 0.01 중량부 내지 0.05 중량부, 황벽 나무 껍질 추출물 0.01 중량부 내지 0.05 중량부을 더욱 포함하는 것을 특징으로 하는 그래핀 함유 샴푸 조성물. The method of claim 1,
The plant extract includes 1 part by weight to 2 parts by weight of leaf leaf extract, 1 part by weight to 2 parts by weight of medicinal wheat extract, 1 part by weight to 2 parts by weight of ginseng extract, and the plant extract contains 0.01 part by weight to 0.05 part by weight of Astragalus extract. 0.01 part by weight to 0.05 part by weight of Rehmannia glutinosa extract, 0.01 part by weight to 0.05 part by weight of Angelica gigas root extract, 0.01 part by weight to 0.05 part by weight of Golden extract, 0.01 part by weight to 0.05 part by weight of Rhododendron root extract, 0.01 part by weight to 0.05 part by weight of Hwangbyeok tree bark extract A graphene-containing shampoo composition further comprising 0.05 parts by weight to 0.05 parts by weight.
상기 식물 추출물인 소엽잎 추출물, 약모밀 추출물, 인삼 추출물, 황기 추출물, 지황 추출물, 참당귀 뿌리 추출물, 황금 추출물, 황련 뿌리 추출물, 황벽 나무 껍질 추출물은 소엽잎, 약모밀, 인삼, 황기, 지황, 참당귀 뿌리, 황금, 황련 뿌리, 황벽 나무 껍질을 혼합하는 제1 단계; 상기 제1 단계의 혼합물을 75℃ 내지 85℃의 추출온도, 5시간 내지 7시간의 추출시간, 에탄올 농도 50wt% 내지 60wt%에서 추출하는 제2 단계; 상기 제2 단계의 추출물을 정제수, 글리세린, 올리브 오일 및 쌀겨 오일를 포함하는 오일, 향료, 계면활성제, 암모늄라우레스설페이트, 암모늄라우릴설페이트 및 그래핀 옥사이드를 함유하는 그래핀 함유 샴푸조성물에 혼합하는 제3 단계;를 포함하는 것을 특징으로 하는 그래핀 함유 샴푸물 조성물의 제조방법. A method for producing the graphene-containing shampoo water composition according to claim 3,
The plant extracts, lobular leaf extract, medicinal buckwheat extract, ginseng extract, astragalus extract, rehmannia extract, angelica root extract, golden extract, barberry root extract, hwangbyeok bark extract, are leafy leaf extract, medicinal buckwheat extract, ginseng, astragalus extract, rehmannia root, angelica chinensis. A first step of mixing the root, golden, yellow lotus root, and yellow wall bark; A second step of extracting the mixture of the first step at an extraction temperature of 75° C. to 85° C., an extraction time of 5 hours to 7 hours, and an ethanol concentration of 50 wt% to 60 wt%; An agent for mixing the extract of the second step with a graphene-containing shampoo composition containing purified water, glycerin, oil including olive oil and rice bran oil, fragrance, surfactant, ammonium laureth sulfate, ammonium lauryl sulfate and graphene oxide Step 3; Method for producing a graphene-containing shampoo water composition comprising a.
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| KR20210120567A (en) | 2020-03-27 | 2021-10-07 | (주)네이처앤트리 | Hair coating agent using silk fibroin protein having stability in water-soluble phase |
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| KR20210120567A (en) | 2020-03-27 | 2021-10-07 | (주)네이처앤트리 | Hair coating agent using silk fibroin protein having stability in water-soluble phase |
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