KR20210142677A - 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 - Google Patents

촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 Download PDF

Info

Publication number
KR20210142677A
KR20210142677A KR1020217033232A KR20217033232A KR20210142677A KR 20210142677 A KR20210142677 A KR 20210142677A KR 1020217033232 A KR1020217033232 A KR 1020217033232A KR 20217033232 A KR20217033232 A KR 20217033232A KR 20210142677 A KR20210142677 A KR 20210142677A
Authority
KR
South Korea
Prior art keywords
metal oxide
effluent stream
reactor
oxide catalyst
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1020217033232A
Other languages
English (en)
Korean (ko)
Inventor
마이클 제이 톨맨
마노즈 나그베카르
Original Assignee
켈로그 브라운 앤드 루트 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 켈로그 브라운 앤드 루트 엘엘씨 filed Critical 켈로그 브라운 앤드 루트 엘엘씨
Publication of KR20210142677A publication Critical patent/KR20210142677A/ko
Ceased legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/048—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by liquid-liquid extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/14—Packed scrubbers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020217033232A 2019-03-21 2020-03-19 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 Ceased KR20210142677A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962821672P 2019-03-21 2019-03-21
US62/821,672 2019-03-21
PCT/US2020/023627 WO2020191192A1 (en) 2019-03-21 2020-03-19 Processes for catalytic paraffin dehydrogenation and catalyst recovery

Publications (1)

Publication Number Publication Date
KR20210142677A true KR20210142677A (ko) 2021-11-25

Family

ID=72514227

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217033232A Ceased KR20210142677A (ko) 2019-03-21 2020-03-19 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법

Country Status (7)

Country Link
US (1) US20200299212A1 (enExample)
EP (1) EP3941893A4 (enExample)
JP (1) JP2022526905A (enExample)
KR (1) KR20210142677A (enExample)
CN (1) CN113710633A (enExample)
SG (1) SG11202110419TA (enExample)
WO (1) WO2020191192A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3990422B1 (en) 2019-06-28 2023-07-19 Dow Global Technologies LLC Methods for forming light olefins that include use of cooled product as a recycled quench stream
US11117108B2 (en) 2019-09-13 2021-09-14 Kellogg Brown & Root Llc Use of a fuel oil wash to remove catalyst from a fluidized-bed propane dehydrogenation reactor effluent
CN117794887A (zh) * 2021-08-11 2024-03-29 埃克森美孚化学专利公司 烷烃和烷基芳族烃的脱氢方法
KR20240034226A (ko) * 2021-08-11 2024-03-13 엑손모빌 케미칼 패턴츠 인코포레이티드 알칸 및 알킬 방향족 탄화수소의 탈수소화 방법
WO2023212497A1 (en) * 2022-04-25 2023-11-02 Kellogg Brown & Root Llc Processes for catalytic paraffin dehydrogenation and catalyst recovery
CN117019022B (zh) * 2023-08-09 2026-02-27 上海润和盛建设备科技有限公司 一种移动床低碳烷烃脱氢系统

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB815332A (en) * 1955-04-25 1959-06-24 Exxon Research Engineering Co Dehydrogenation of hydrocarbons
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
JP3678335B2 (ja) * 1998-05-18 2005-08-03 株式会社日本触媒 低級アルカン酸化脱水素用触媒およびオレフィンの製造方法
US20030065235A1 (en) * 2001-09-24 2003-04-03 Allison Joe D. Oxidative dehydrogenation of alkanes to olefins using an oxide surface
US7011740B2 (en) * 2002-10-10 2006-03-14 Kellogg Brown & Root, Inc. Catalyst recovery from light olefin FCC effluent
WO2008082866A1 (en) * 2006-12-28 2008-07-10 Uop Llc Fluidized bed reactor with back-mixing for dehydrogenation of light paraffins
US20090325791A1 (en) * 2008-06-27 2009-12-31 Wei Pan Hydrocarbon Dehydrogenation with Zirconia
US8653317B2 (en) * 2009-03-19 2014-02-18 Dow Global Technologies Llc Dehydrogenation process and catalyst
US9150465B2 (en) * 2010-09-21 2015-10-06 Uop Llc Integration of cyclic dehydrogenation process with FCC for dehydrogenation of refinery paraffins
US9963407B2 (en) * 2013-06-18 2018-05-08 Uop Llc Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation
CA2867731C (en) * 2014-10-15 2022-08-30 Nova Chemicals Corporation High conversion and selectivity odh process
CA3114440A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation

Also Published As

Publication number Publication date
US20200299212A1 (en) 2020-09-24
EP3941893A4 (en) 2023-01-11
CN113710633A (zh) 2021-11-26
SG11202110419TA (en) 2021-10-28
EP3941893A1 (en) 2022-01-26
WO2020191192A1 (en) 2020-09-24
JP2022526905A (ja) 2022-05-27

Similar Documents

Publication Publication Date Title
US20200299212A1 (en) Processes for catalytic paraffin dehydrogenation and catalyst recovery
KR101631398B1 (ko) 공역 디올레핀의 제조방법
RU2508282C2 (ru) Способ получения дегидрированных углеводородных соединений
RU2698107C2 (ru) Способ получения легких олефинов
TWI385140B (zh) A method for producing olefins and a manufacturing apparatus thereof
RU2712274C1 (ru) Реактор с турбулентным псевдоожиженным слоем, устройство и способ, в котором используют кислородсодержащее соединение для производства пропена и c4 углеводорода
JP5518727B2 (ja) 連続的な２段階反応を利用した合成ガスからの軽質オレフィンの製造方法
JP2022526905A5 (enExample)
CN101563306A (zh) 用于处理来自氧合物-到-烯烃的反应的催化剂的方法中的淬灭物流的中和
US20220250049A1 (en) Processes for catalytic paraffin dehydrogenation and catalyst recovery
US11117108B2 (en) Use of a fuel oil wash to remove catalyst from a fluidized-bed propane dehydrogenation reactor effluent
US12404171B2 (en) Alternating fixed and fluidized bed reactor systems and processes
RU2612305C1 (ru) Способ окислительной конверсии этана в этилен
JP2006291182A5 (enExample)
WO2023212497A9 (en) Processes for catalytic paraffin dehydrogenation and catalyst recovery
RU2549187C2 (ru) Способ конверсии синтез-газа с использованием кобальтового катализатора на первой стадии и рутениевого катализатора на носителе на второй стадии
EP0182811A1 (en) Process for converting methane into high hydrocarbon products.
US5474960A (en) Process for reactivating a fluid bed catalyst in a reactor dipley
US9732015B2 (en) Process for the selective hydrogenation of acetylene to ethylene
JP5910341B2 (ja) １，３−ブタジエンの製造方法
US20150353449A1 (en) Process for the selective hydrogenation of acetylene to ethylene
RU2021130478A (ru) Способы каталитического дегидрирования парафинов и извлечения катализатора
KR20070107057A (ko) 탈수소화에 의해 알킬화 촉매 독물들의 처리

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

B15 Application refused following examination

Free format text: ST27 STATUS EVENT CODE: N-2-6-B10-B15-EXM-PE0601 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0601 Decision on rejection of patent

St.27 status event code: N-2-6-B10-B15-exm-PE0601