CN113710633A - 用于催化链烷烃脱氢和催化剂回收的方法 - Google Patents

用于催化链烷烃脱氢和催化剂回收的方法 Download PDF

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Publication number
CN113710633A
CN113710633A CN202080028734.4A CN202080028734A CN113710633A CN 113710633 A CN113710633 A CN 113710633A CN 202080028734 A CN202080028734 A CN 202080028734A CN 113710633 A CN113710633 A CN 113710633A
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China
Prior art keywords
oxide
reactor
catalyst
metal oxide
effluent stream
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Pending
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CN202080028734.4A
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English (en)
Chinese (zh)
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M·J·塔尔曼
M·纳格维卡
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Kellogg Brown and Root LLC
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Kellogg Brown and Root LLC
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Publication of CN113710633A publication Critical patent/CN113710633A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/048—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by liquid-liquid extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/14—Packed scrubbers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN202080028734.4A 2019-03-21 2020-03-19 用于催化链烷烃脱氢和催化剂回收的方法 Pending CN113710633A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962821672P 2019-03-21 2019-03-21
US62/821,672 2019-03-21
PCT/US2020/023627 WO2020191192A1 (en) 2019-03-21 2020-03-19 Processes for catalytic paraffin dehydrogenation and catalyst recovery

Publications (1)

Publication Number Publication Date
CN113710633A true CN113710633A (zh) 2021-11-26

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Country Link
US (1) US20200299212A1 (enExample)
EP (1) EP3941893A4 (enExample)
JP (1) JP2022526905A (enExample)
KR (1) KR20210142677A (enExample)
CN (1) CN113710633A (enExample)
SG (1) SG11202110419TA (enExample)
WO (1) WO2020191192A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117019022A (zh) * 2023-08-09 2023-11-10 上海润和盛建工程科技有限公司 一种移动床低碳烷烃脱氢系统

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3990422B1 (en) 2019-06-28 2023-07-19 Dow Global Technologies LLC Methods for forming light olefins that include use of cooled product as a recycled quench stream
US11117108B2 (en) 2019-09-13 2021-09-14 Kellogg Brown & Root Llc Use of a fuel oil wash to remove catalyst from a fluidized-bed propane dehydrogenation reactor effluent
CN117794887A (zh) * 2021-08-11 2024-03-29 埃克森美孚化学专利公司 烷烃和烷基芳族烃的脱氢方法
KR20240034226A (ko) * 2021-08-11 2024-03-13 엑손모빌 케미칼 패턴츠 인코포레이티드 알칸 및 알킬 방향족 탄화수소의 탈수소화 방법
WO2023212497A1 (en) * 2022-04-25 2023-11-02 Kellogg Brown & Root Llc Processes for catalytic paraffin dehydrogenation and catalyst recovery

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB815332A (en) * 1955-04-25 1959-06-24 Exxon Research Engineering Co Dehydrogenation of hydrocarbons
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
US20010049461A1 (en) * 1998-05-18 2001-12-06 Nobuji Kishimoto Lower alkane oxidative dehydrogenation catalysts and a process for producing olefins
WO2003026787A2 (en) * 2001-09-24 2003-04-03 Conocophillips Company Oxidative dehydrogenation of alkanes to olefins using an oxide surface
US20040069684A1 (en) * 2002-10-10 2004-04-15 Kellogg Brown & Root, Inc. Catalyst recovery from light olefin FCC effluent
CN101568379A (zh) * 2006-12-28 2009-10-28 环球油品公司 用于轻质烷烃脱氢的具有返混的流化床反应器
US20090325791A1 (en) * 2008-06-27 2009-12-31 Wei Pan Hydrocarbon Dehydrogenation with Zirconia
US20100236985A1 (en) * 2009-03-19 2010-09-23 Lin Luo Dehydrogenation process and catalyst
CN103119131A (zh) * 2010-09-21 2013-05-22 环球油品公司 循环脱氢方法与fcc的联合用于炼油厂链烷烃脱氢
US20140371504A1 (en) * 2013-06-18 2014-12-18 Uop Llc Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation
US20170210685A1 (en) * 2014-10-15 2017-07-27 Nova Chemicals (International) S.A. High conversion and selectivity odh process
US20200101445A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Mixed Metal Oxide Catalyst useful for Paraffin Dehydrogenation

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB815332A (en) * 1955-04-25 1959-06-24 Exxon Research Engineering Co Dehydrogenation of hydrocarbons
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
US20010049461A1 (en) * 1998-05-18 2001-12-06 Nobuji Kishimoto Lower alkane oxidative dehydrogenation catalysts and a process for producing olefins
WO2003026787A2 (en) * 2001-09-24 2003-04-03 Conocophillips Company Oxidative dehydrogenation of alkanes to olefins using an oxide surface
US20040069684A1 (en) * 2002-10-10 2004-04-15 Kellogg Brown & Root, Inc. Catalyst recovery from light olefin FCC effluent
CN101568379A (zh) * 2006-12-28 2009-10-28 环球油品公司 用于轻质烷烃脱氢的具有返混的流化床反应器
US20090325791A1 (en) * 2008-06-27 2009-12-31 Wei Pan Hydrocarbon Dehydrogenation with Zirconia
US20100236985A1 (en) * 2009-03-19 2010-09-23 Lin Luo Dehydrogenation process and catalyst
CN103119131A (zh) * 2010-09-21 2013-05-22 环球油品公司 循环脱氢方法与fcc的联合用于炼油厂链烷烃脱氢
US20140371504A1 (en) * 2013-06-18 2014-12-18 Uop Llc Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation
US20170210685A1 (en) * 2014-10-15 2017-07-27 Nova Chemicals (International) S.A. High conversion and selectivity odh process
US20200101445A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Mixed Metal Oxide Catalyst useful for Paraffin Dehydrogenation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117019022A (zh) * 2023-08-09 2023-11-10 上海润和盛建工程科技有限公司 一种移动床低碳烷烃脱氢系统
WO2025030766A1 (zh) * 2023-08-09 2025-02-13 上海润和盛建设备科技有限公司 一种移动床低碳烷烃脱氢系统
CN117019022B (zh) * 2023-08-09 2026-02-27 上海润和盛建设备科技有限公司 一种移动床低碳烷烃脱氢系统

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US20200299212A1 (en) 2020-09-24
EP3941893A4 (en) 2023-01-11
SG11202110419TA (en) 2021-10-28
EP3941893A1 (en) 2022-01-26
WO2020191192A1 (en) 2020-09-24
JP2022526905A (ja) 2022-05-27
KR20210142677A (ko) 2021-11-25

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