KR20210096610A

KR20210096610A - 말단캡핑된 경화성 폴리오르가노실록산

말단캡핑된 경화성 폴리오르가노실록산 Download PDF

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Publication number: KR20210096610A
Authority: KR; South Korea
Prior art keywords: group; formula; ethyl; silane; substituted
Prior art date: 2018-11-30
Legal status : Ceased

Application number

KR1020217015923A

Other languages

English (en)

Korean (ko)

Inventor

테레제 헤메리

아드리안 두라쿠

요한 클라인

Original Assignee

헨켈 아게 운트 코. 카게아아

Priority date

2018-11-30

Filing date

2019-11-22

Publication date

2021-08-05

2019-11-22 Application filed by 헨켈 아게 운트 코. 카게아아 filed Critical 헨켈 아게 운트 코. 카게아아

2021-08-05 Publication of KR20210096610A publication Critical patent/KR20210096610A/ko

Status Ceased legal-status Critical Current

Links

239000000203 mixture Substances 0.000 claims abstract description 159
239000003054 catalyst Substances 0.000 claims abstract description 60
239000002318 adhesion promoter Substances 0.000 claims abstract description 44
229910052710 silicon Inorganic materials 0.000 claims abstract description 20
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 18
125000000217 alkyl group Chemical group 0.000 claims description 143
-1 amino, oximino Chemical group 0.000 claims description 141
125000004432 carbon atom Chemical group C* 0.000 claims description 96
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 88
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 74
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 73
125000003118 aryl group Chemical group 0.000 claims description 68
229910052739 hydrogen Inorganic materials 0.000 claims description 67
239000001257 hydrogen Substances 0.000 claims description 67
229910000077 silane Inorganic materials 0.000 claims description 65
125000003342 alkenyl group Chemical group 0.000 claims description 57
150000001875 compounds Chemical class 0.000 claims description 52
125000000304 alkynyl group Chemical group 0.000 claims description 51
125000001072 heteroaryl group Chemical group 0.000 claims description 36
229920002554 vinyl polymer Polymers 0.000 claims description 36
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 32
229920000642 polymer Polymers 0.000 claims description 25
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 23
125000005842 heteroatom Chemical group 0.000 claims description 23
125000002947 alkylene group Chemical group 0.000 claims description 22
239000000463 material Substances 0.000 claims description 21
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 20
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 19
239000004014 plasticizer Substances 0.000 claims description 19
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
229910052757 nitrogen Inorganic materials 0.000 claims description 17
239000000945 filler Substances 0.000 claims description 16
150000001412 amines Chemical class 0.000 claims description 15
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 15
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 15
CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 14
229910052736 halogen Inorganic materials 0.000 claims description 14
150000002367 halogens Chemical class 0.000 claims description 14
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 13
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
125000002252 acyl group Chemical group 0.000 claims description 12
150000002148 esters Chemical class 0.000 claims description 12
229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 claims description 11
239000004205 dimethyl polysiloxane Substances 0.000 claims description 11
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 11
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
125000004423 acyloxy group Chemical group 0.000 claims description 10
125000006413 ring segment Chemical group 0.000 claims description 10
FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 10
WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
125000004104 aryloxy group Chemical group 0.000 claims description 9
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 9
238000000034 method Methods 0.000 claims description 9
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
239000000853 adhesive Substances 0.000 claims description 8
230000001070 adhesive effect Effects 0.000 claims description 8
LZCLXQDLBQLTDK-UHFFFAOYSA-N lactic acid ethyl ester Natural products CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 claims description 8
150000003606 tin compounds Chemical class 0.000 claims description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
150000001298 alcohols Chemical class 0.000 claims description 7
238000000576 coating method Methods 0.000 claims description 7
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 7
229940116333 ethyl lactate Drugs 0.000 claims description 7
229940005667 ethyl salicylate Drugs 0.000 claims description 7
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 7
125000006832 (C1-C10) alkylene group Chemical group 0.000 claims description 6
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
239000011248 coating agent Substances 0.000 claims description 6
125000004122 cyclic group Chemical group 0.000 claims description 6
150000002170 ethers Chemical class 0.000 claims description 6
125000005647 linker group Chemical group 0.000 claims description 6
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 6
WYMSENKWVCCQGJ-UHFFFAOYSA-N n,n-dimethyl-1-triethoxysilylmethanamine Chemical compound CCO[Si](CN(C)C)(OCC)OCC WYMSENKWVCCQGJ-UHFFFAOYSA-N 0.000 claims description 6
AQIQPUUNTCVHBS-UHFFFAOYSA-N n,n-dimethyl-3-triethoxysilylpropan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCN(C)C AQIQPUUNTCVHBS-UHFFFAOYSA-N 0.000 claims description 6
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
238000007789 sealing Methods 0.000 claims description 6
125000003302 alkenyloxy group Chemical group 0.000 claims description 5
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
229920006395 saturated elastomer Polymers 0.000 claims description 5
SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 4
229910003849 O-Si Inorganic materials 0.000 claims description 4
229910003872 O—Si Inorganic materials 0.000 claims description 4
125000005133 alkynyloxy group Chemical group 0.000 claims description 4
125000005553 heteroaryloxy group Chemical group 0.000 claims description 4
150000004658 ketimines Chemical class 0.000 claims description 4
BVBBZEKOMUDXMZ-UHFFFAOYSA-N n,n-diethyl-3-triethoxysilylpropan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCN(CC)CC BVBBZEKOMUDXMZ-UHFFFAOYSA-N 0.000 claims description 4
UMXXGDJOCQSQBV-UHFFFAOYSA-N n-ethyl-n-(triethoxysilylmethyl)ethanamine Chemical compound CCO[Si](OCC)(OCC)CN(CC)CC UMXXGDJOCQSQBV-UHFFFAOYSA-N 0.000 claims description 4
KPIIDEIURMTGCD-UHFFFAOYSA-N n-ethyl-n-(trimethoxysilylmethyl)ethanamine Chemical compound CCN(CC)C[Si](OC)(OC)OC KPIIDEIURMTGCD-UHFFFAOYSA-N 0.000 claims description 4
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
ROWWCTUMLAVVQB-UHFFFAOYSA-N triethoxysilylmethanamine Chemical compound CCO[Si](CN)(OCC)OCC ROWWCTUMLAVVQB-UHFFFAOYSA-N 0.000 claims description 4
150000001408 amides Chemical class 0.000 claims description 3
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
230000007062 hydrolysis Effects 0.000 claims description 3
238000006460 hydrolysis reaction Methods 0.000 claims description 3
125000005702 oxyalkylene group Chemical group 0.000 claims description 3
IYXFDAOFSCZADY-UHFFFAOYSA-N 2-phenylethyl 2-hydroxypropanoate Chemical compound CC(O)C(=O)OCCC1=CC=CC=C1 IYXFDAOFSCZADY-UHFFFAOYSA-N 0.000 claims description 2
HXLAEGYMDGUSBD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN HXLAEGYMDGUSBD-UHFFFAOYSA-N 0.000 claims description 2
YNMSDIQQNIRGDP-UHFFFAOYSA-N Phenethyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCCC1=CC=CC=C1 YNMSDIQQNIRGDP-UHFFFAOYSA-N 0.000 claims description 2
125000000732 arylene group Chemical group 0.000 claims description 2
235000013877 carbamide Nutrition 0.000 claims description 2
ZWTJVXCCMKLQKS-UHFFFAOYSA-N diethoxy(ethyl)silicon Chemical compound CCO[Si](CC)OCC ZWTJVXCCMKLQKS-UHFFFAOYSA-N 0.000 claims description 2
GAURFLBIDLSLQU-UHFFFAOYSA-N diethoxy(methyl)silicon Chemical compound CCO[Si](C)OCC GAURFLBIDLSLQU-UHFFFAOYSA-N 0.000 claims description 2
BODAWKLCLUZBEZ-UHFFFAOYSA-N diethoxy(phenyl)silicon Chemical compound CCO[Si](OCC)C1=CC=CC=C1 BODAWKLCLUZBEZ-UHFFFAOYSA-N 0.000 claims description 2
XMKVMJPCDLDMTQ-UHFFFAOYSA-N ethenyl(diethoxy)silane Chemical compound CCO[SiH](C=C)OCC XMKVMJPCDLDMTQ-UHFFFAOYSA-N 0.000 claims description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
150000003949 imides Chemical class 0.000 claims description 2
INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 2
PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims description 2
NHBRUUFBSBSTHM-UHFFFAOYSA-N n'-[2-(3-trimethoxysilylpropylamino)ethyl]ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCNCCN NHBRUUFBSBSTHM-UHFFFAOYSA-N 0.000 claims description 2
MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 claims description 2
ZLDHYRXZZNDOKU-UHFFFAOYSA-N n,n-diethyl-3-trimethoxysilylpropan-1-amine Chemical compound CCN(CC)CCC[Si](OC)(OC)OC ZLDHYRXZZNDOKU-UHFFFAOYSA-N 0.000 claims description 2
QIOYHIUHPGORLS-UHFFFAOYSA-N n,n-dimethyl-3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN(C)C QIOYHIUHPGORLS-UHFFFAOYSA-N 0.000 claims description 2
KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 claims description 2
VNBLTKHUCJLFSB-UHFFFAOYSA-N n-(trimethoxysilylmethyl)aniline Chemical compound CO[Si](OC)(OC)CNC1=CC=CC=C1 VNBLTKHUCJLFSB-UHFFFAOYSA-N 0.000 claims description 2
LZWFTMZUDLGKMY-UHFFFAOYSA-N n-[3-[dimethoxy(methyl)silyl]propyl]-n',n'-dimethylpropane-1,3-diamine Chemical compound CO[Si](C)(OC)CCCNCCCN(C)C LZWFTMZUDLGKMY-UHFFFAOYSA-N 0.000 claims description 2
230000000269 nucleophilic effect Effects 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims description 2
QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 2
ARKBFSWVHXKMSD-UHFFFAOYSA-N trimethoxysilylmethanamine Chemical compound CO[Si](CN)(OC)OC ARKBFSWVHXKMSD-UHFFFAOYSA-N 0.000 claims description 2
150000003672 ureas Chemical class 0.000 claims description 2
150000003673 urethanes Chemical class 0.000 claims description 2
150000002431 hydrogen Chemical class 0.000 claims 13
239000002585 base Substances 0.000 claims 1
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
238000003860 storage Methods 0.000 abstract description 13
239000010703 silicon Substances 0.000 abstract description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 42
239000003795 chemical substances by application Substances 0.000 description 14
238000009472 formulation Methods 0.000 description 14
229910052760 oxygen Inorganic materials 0.000 description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
239000003085 diluting agent Substances 0.000 description 13
229910052717 sulfur Inorganic materials 0.000 description 12
239000010936 titanium Substances 0.000 description 12
238000004132 cross linking Methods 0.000 description 11
239000003431 cross linking reagent Substances 0.000 description 11
239000002274 desiccant Substances 0.000 description 11
229910052719 titanium Inorganic materials 0.000 description 11
235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
125000000524 functional group Chemical group 0.000 description 10
125000003545 alkoxy group Chemical group 0.000 description 9
125000000753 cycloalkyl group Chemical group 0.000 description 9
239000012948 isocyanate Substances 0.000 description 9
150000002513 isocyanates Chemical class 0.000 description 9
150000004756 silanes Chemical class 0.000 description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
229910052782 aluminium Inorganic materials 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
125000005442 diisocyanate group Chemical group 0.000 description 7
229920005989 resin Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
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239000012963 UV stabilizer Substances 0.000 description 6
229920004482 WACKER® Polymers 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
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229910052799 carbon Inorganic materials 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 6
229910052742 iron Inorganic materials 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229920003023 plastic Polymers 0.000 description 6
239000004033 plastic Substances 0.000 description 6
239000000565 sealant Substances 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
229910052726 zirconium Inorganic materials 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
125000002950 monocyclic group Chemical group 0.000 description 5
239000005056 polyisocyanate Substances 0.000 description 5
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238000002360 preparation method Methods 0.000 description 5
239000000047 product Substances 0.000 description 5
125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 5
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125000001424 substituent group Chemical group 0.000 description 5
150000003505 terpenes Chemical class 0.000 description 5
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 4
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 4
239000007983 Tris buffer Substances 0.000 description 4
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
229910052796 boron Inorganic materials 0.000 description 4
239000011575 calcium Substances 0.000 description 4
150000001721 carbon Chemical group 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
239000013522 chelant Substances 0.000 description 4
238000009833 condensation Methods 0.000 description 4
230000005494 condensation Effects 0.000 description 4
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
239000011521 glass Substances 0.000 description 4
150000002430 hydrocarbons Chemical group 0.000 description 4
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000005259 measurement Methods 0.000 description 4
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150000002923 oximes Chemical class 0.000 description 4
125000003367 polycyclic group Chemical group 0.000 description 4
229920001223 polyethylene glycol Polymers 0.000 description 4
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150000003077 polyols Chemical class 0.000 description 4
230000009257 reactivity Effects 0.000 description 4
239000002904 solvent Substances 0.000 description 4
239000000758 substrate Substances 0.000 description 4
239000002023 wood Substances 0.000 description 4
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
239000005058 Isophorone diisocyanate Substances 0.000 description 3
JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
125000005370 alkoxysilyl group Chemical group 0.000 description 3
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
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239000000835 fiber Substances 0.000 description 3
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150000002739 metals Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
239000005011 phenolic resin Substances 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
230000001698 pyrogenic effect Effects 0.000 description 3
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
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CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
150000003459 sulfonic acid esters Chemical class 0.000 description 1
239000003760 tallow Substances 0.000 description 1
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125000003831 tetrazolyl group Chemical group 0.000 description 1
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229920001169 thermoplastic Polymers 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
125000000335 thiazolyl group Chemical group 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
229950006389 thiodiglycol Drugs 0.000 description 1
125000003396 thiol group Chemical group [H]S* 0.000 description 1
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VCDLLOVEJODESP-UHFFFAOYSA-L tin(2+);diphenoxide Chemical compound [Sn+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 VCDLLOVEJODESP-UHFFFAOYSA-L 0.000 description 1
SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical compound [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 description 1
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HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
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KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
125000005369 trialkoxysilyl group Chemical group 0.000 description 1
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CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
OCANZHUXNZTABW-UHFFFAOYSA-N triethoxy(pent-4-enyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCC=C OCANZHUXNZTABW-UHFFFAOYSA-N 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
239000013638 trimer Substances 0.000 description 1
UWSYCPWEBZRZNJ-UHFFFAOYSA-N trimethoxy(2,4,4-trimethylpentyl)silane Chemical compound CO[Si](OC)(OC)CC(C)CC(C)(C)C UWSYCPWEBZRZNJ-UHFFFAOYSA-N 0.000 description 1
NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
125000002348 vinylic group Chemical group 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000002025 wood fiber Substances 0.000 description 1
125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
150000003754 zirconium Chemical class 0.000 description 1