KR20200078557A - 황화물 및 이황화물을 인-시튜로 생산하면서 수소화처리 촉매를 활성화하기 위한 통합 공정 - Google Patents

황화물 및 이황화물을 인-시튜로 생산하면서 수소화처리 촉매를 활성화하기 위한 통합 공정 Download PDF

Info

Publication number
KR20200078557A
KR20200078557A KR1020207014483A KR20207014483A KR20200078557A KR 20200078557 A KR20200078557 A KR 20200078557A KR 1020207014483 A KR1020207014483 A KR 1020207014483A KR 20207014483 A KR20207014483 A KR 20207014483A KR 20200078557 A KR20200078557 A KR 20200078557A
Authority
KR
South Korea
Prior art keywords
integrated process
sulfur
catalyst
temperature
iiib
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1020207014483A
Other languages
English (en)
Korean (ko)
Inventor
오메르 레파 코세오글루
로버트 피터 호지킨스
Original Assignee
사우디 아라비안 오일 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사우디 아라비안 오일 컴퍼니 filed Critical 사우디 아라비안 오일 컴퍼니
Publication of KR20200078557A publication Critical patent/KR20200078557A/ko
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/12—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one alkaline treatment step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
    • B01D11/043—Counter-current multistage extraction towers in a vertical or sloping position with stationary contacting elements, sieve plates or loose contacting elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0484—Controlling means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0488—Flow sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0492—Applications, solvents used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/08—Recovery of used refining agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/30—Controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • C10G29/10—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
KR1020207014483A 2017-10-25 2018-09-11 황화물 및 이황화물을 인-시튜로 생산하면서 수소화처리 촉매를 활성화하기 위한 통합 공정 Withdrawn KR20200078557A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US15/793,351 2017-10-25
US15/793,351 US10240096B1 (en) 2017-10-25 2017-10-25 Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and disulphides
PCT/US2018/050423 WO2019083627A1 (en) 2017-10-25 2018-09-11 INTEGRATED METHOD FOR THE ACTIVATION OF HYDROTREATMENT CATALYSTS WITH SULFIDES AND DISULFIDES PRODUCED IN SITU

Publications (1)

Publication Number Publication Date
KR20200078557A true KR20200078557A (ko) 2020-07-01

Family

ID=63794619

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020207014483A Withdrawn KR20200078557A (ko) 2017-10-25 2018-09-11 황화물 및 이황화물을 인-시튜로 생산하면서 수소화처리 촉매를 활성화하기 위한 통합 공정

Country Status (7)

Country Link
US (2) US10240096B1 (enExample)
EP (1) EP3692114B1 (enExample)
JP (1) JP2021501232A (enExample)
KR (1) KR20200078557A (enExample)
CN (1) CN111247230A (enExample)
SG (1) SG11202002111VA (enExample)
WO (1) WO2019083627A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10851314B2 (en) * 2019-04-17 2020-12-01 Saudi Arabian Oil Company Method to improve the efficiency of pipeline transportation of heavy oils
US11261386B2 (en) 2020-05-20 2022-03-01 Saudi Arabian Oil Company Conversion of MEROX process by-products to useful products in an integrated refinery process
US11603499B2 (en) * 2021-06-30 2023-03-14 Saudi Arabian Oil Company Hydroprocess integrating oxidized disulfide oil compounds
WO2025141383A1 (en) * 2023-12-28 2025-07-03 Reliance Industries Limited Process for removal of sodium from di-sulfide oil using activated carbon as adsorbent
WO2025141385A1 (en) * 2023-12-28 2025-07-03 Reliance Industries Limited Process for removal of sodium from di-sulfide oil using zeolite adsorbent

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2428623A (en) 1942-12-22 1947-10-07 Standard Oil Dev Co Method of regenerating spent caustic alkali solution
US2693442A (en) 1948-08-11 1954-11-02 Standard Oil Co Mercaptan extraction process
US3104157A (en) 1961-03-21 1963-09-17 Exxon Research Engineering Co Universal caustic regeneration process
US4626341A (en) * 1985-12-23 1986-12-02 Uop Inc. Process for mercaptan extraction from olefinic hydrocarbons
SU1395628A1 (ru) 1986-07-07 1988-05-15 Волго-Уральский научно-исследовательский и проектный институт по добыче и переработке сероводородсодержащих газов Способ выделени меркаптанов из высокосернистого газоконденсата
US4705620A (en) * 1986-12-16 1987-11-10 Uop Inc. Mercaptan extraction process
NL9202282A (nl) 1992-12-29 1994-07-18 Gastec Nv Werkwijze voor het ontzwavelen van een gas en absorbens geschikt voor deze werkwijze.
WO2001096499A1 (en) * 2000-06-10 2001-12-20 Sk Corporation The method for using disulfide mixture as a sulfiding agent
CN101275085B (zh) * 2007-03-30 2012-01-25 中国石油化工股份有限公司 一种汽油脱硫的组合方法
US8308957B2 (en) 2007-06-14 2012-11-13 Merichem Company Process for separating mercaptans from caustic
US7875185B2 (en) * 2007-09-10 2011-01-25 Merichem Company Removal of residual sulfur compounds from a caustic stream
CA2698461A1 (en) * 2007-09-18 2009-03-26 Shell Internationale Research Maatschappij B.V. Process for the deep desulfurization of heavy pyrolysis gasoline
FR2935142B1 (fr) * 2008-08-20 2010-11-19 Arkema France Dimethyldisulfure issu au moins partiellement de matieres renouvellables
US8586801B2 (en) * 2008-09-04 2013-11-19 Albemarle Corporation Cobalt-molybdenum sulfide catalyst materials and methods for stable alcohol production from syngas
RU2015119652A (ru) * 2012-10-26 2016-12-20 Сименс Энерджи, Инк. Способы и системы для обработки использованной щелочи и регенерируемой среды
EP2806015B1 (en) 2013-05-24 2016-03-02 Total SA Integrated process for dialkyldisulfides treatment
US20150034529A1 (en) 2013-07-31 2015-02-05 Uop Llc Processes and apparatuses for removing mercaptans from a feed stream
US20150057477A1 (en) * 2013-08-23 2015-02-26 Uop Llc Systems and methods for producing fuel from a renewable feedstock
US20150094506A1 (en) * 2013-09-27 2015-04-02 Uop Llc Systems and methods for producing fuel from a renewable feedstock
EP3116853B1 (en) 2014-03-14 2019-01-09 Reliance Industries Limited A process for the removal of sodium from di-sulfide oil
US9580661B2 (en) 2014-11-24 2017-02-28 Saudi Arabian Oil Company Integrated hydrocarbon desulfurization with oxidation of disulfides and conversion of SO2 to elemental sulfur
CN105175296A (zh) 2015-08-14 2015-12-23 湖北兴发化工集团股份有限公司 一种甲硫醇盐溶液氧化生产二甲基二硫的方法及装置

Also Published As

Publication number Publication date
US10400183B2 (en) 2019-09-03
WO2019083627A1 (en) 2019-05-02
US20190194555A1 (en) 2019-06-27
SG11202002111VA (en) 2020-05-28
US10240096B1 (en) 2019-03-26
CN111247230A (zh) 2020-06-05
JP2021501232A (ja) 2021-01-14
EP3692114A1 (en) 2020-08-12
EP3692114B1 (en) 2021-11-10

Similar Documents

Publication Publication Date Title
US7790021B2 (en) Removal of sulfur-containing compounds from liquid hydrocarbon streams
US10400183B2 (en) Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and disulphides
US20210002562A1 (en) Ultrasonic oxidative desulfurization of heavy fuel oils
KR20210097745A (ko) 통합된 정제 공정에서의 생산물에 의한 머록스 공정의 제어된 촉매적 산화방법
CN113195687A (zh) 用于芳烃萃取过程的溶剂
US20030127362A1 (en) Selective hydroprocessing and mercaptan removal
KR102167636B1 (ko) 통합 설폰 분해로 산화적 탈황하는 방법
JP6526179B2 (ja) ジスルフィドの酸化およびｓｏ２の元素硫黄への変換を伴う統合された炭化水素脱硫
CN101611119A (zh) 石油的氧化脱硫和脱氮
CN103313956A (zh) 使用气态氧化剂的烃原料流的脱硫
CN102851068B (zh) 一种汽油脱硫的方法
RU2535212C2 (ru) Способ удаления сульфонов из углеводородного топлива
JP2021501232A5 (enExample)
JP2020510719A (ja) Ｆｃｃを使用する石油留分の酸化脱硫及びスルホン処理
CN102851069B (zh) 一种汽油脱硫的方法
EP0076100B1 (en) A method of refining sour hydrocarbon distillates
WO2018140620A1 (en) Oxidative desulfurization of oil fractions and sulfone management using an fcc
KR20240155726A (ko) 폐플라스틱 열분해유로부터 정제 탄화수소의 제조 방법 및 제조 시스템
RU2541315C1 (ru) Способ очистки жидких моторных топлив от серосодержащих соединений
MXPA04008358A (es) Eliminacion de compuestos con contenido de azufre de corrientes de hidrocarburos liquidos.
KR101068994B1 (ko) 디벤조티오펜설폰의 이산화황 제거용 촉매 및 이를 이용한 비페닐의 제조방법
Akhmadullin et al. Desulphurization of petroleum products and sewage decontamination using polymeric KSM catalyst
JP5420843B2 (ja) 炭化水素の硫黄分低減方法

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20200520

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20210820

Comment text: Request for Examination of Application

PC1202 Submission of document of withdrawal before decision of registration

Comment text: [Withdrawal of Procedure relating to Patent, etc.] Withdrawal (Abandonment)

Patent event code: PC12021R01D

Patent event date: 20220715

WITB Written withdrawal of application