WO2019083627A1 - INTEGRATED METHOD FOR THE ACTIVATION OF HYDROTREATMENT CATALYSTS WITH SULFIDES AND DISULFIDES PRODUCED IN SITU - Google Patents

INTEGRATED METHOD FOR THE ACTIVATION OF HYDROTREATMENT CATALYSTS WITH SULFIDES AND DISULFIDES PRODUCED IN SITU

Info

Publication number
WO2019083627A1
WO2019083627A1 PCT/US2018/050423 US2018050423W WO2019083627A1 WO 2019083627 A1 WO2019083627 A1 WO 2019083627A1 US 2018050423 W US2018050423 W US 2018050423W WO 2019083627 A1 WO2019083627 A1 WO 2019083627A1
Authority
WO
WIPO (PCT)
Prior art keywords
carrying
catalyst
temperature
iiib
sulfur containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2018/050423
Other languages
English (en)
French (fr)
Inventor
Omer Refa Koseoglu
Robert Peter HODGKINS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Arabian Oil Co
Original Assignee
Saudi Arabian Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Co filed Critical Saudi Arabian Oil Co
Priority to CN201880064635.4A priority Critical patent/CN111247230A/zh
Priority to SG11202002111VA priority patent/SG11202002111VA/en
Priority to KR1020207014483A priority patent/KR20200078557A/ko
Priority to JP2020523287A priority patent/JP2021501232A/ja
Priority to EP18783186.2A priority patent/EP3692114B1/en
Publication of WO2019083627A1 publication Critical patent/WO2019083627A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/12—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one alkaline treatment step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
    • B01D11/043—Counter-current multistage extraction towers in a vertical or sloping position with stationary contacting elements, sieve plates or loose contacting elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0484—Controlling means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0488—Flow sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0492—Applications, solvents used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/08—Recovery of used refining agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/30—Controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • C10G29/10—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Definitions

  • Figure 2 shows one embodiment of the invention, where DSO is produced and purified, then used to activate catalysts.
  • the caustic alkaline solution which contains various thiolates of formula X-S-R, where X is an alkaline ion such as IC, or Na + , or some other component of an alkaline compound and R is as discussed supra, moves "8" to a second reaction vessel "9," which contains a catalyst "10,” and to which oxygen containing air "1 1" is introduced.
  • the contact preferably takes place at a temperature of from 20 °C to 300 °C, more preferably at a temperature from 20 °C to 80 °C, Following oxidation, a minor proportion of sulfides and a major proportion of disulfides "12" are produced, and are treated as discussed infra,
  • reaction vessel was pressurized to 45 bars, using hydrogen followed by a 30 minute purge.
  • the hydrogen flow was 27.5 NL/h and the temperature was increased to 175 °C, in 25 °C/hr increments.
  • This example compares commercially available DMDS suifiding to DSO obtained using the invention.
  • the DSO was obtained by combining the DSOs from propane and butane MEROX units, as described supra.
  • the vessel was pressurized to 45 bars, with hydrogen gas, and purged for 30 minutes.
  • the rate of hydrogen flow was set at 27.5 NL/h, and the reactor temperature was increased to 175 °C, at a rate of 25 °C/hour.
  • alkalis including, but not being limited to KOH, LiOH, other alkali hydroxides, and other alkali materials.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
PCT/US2018/050423 2017-10-25 2018-09-11 INTEGRATED METHOD FOR THE ACTIVATION OF HYDROTREATMENT CATALYSTS WITH SULFIDES AND DISULFIDES PRODUCED IN SITU Ceased WO2019083627A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201880064635.4A CN111247230A (zh) 2017-10-25 2018-09-11 用原位产生的硫化物和二硫化物活化加氢加工催化剂的集成方法
SG11202002111VA SG11202002111VA (en) 2017-10-25 2018-09-11 Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and disulphides
KR1020207014483A KR20200078557A (ko) 2017-10-25 2018-09-11 황화물 및 이황화물을 인-시튜로 생산하면서 수소화처리 촉매를 활성화하기 위한 통합 공정
JP2020523287A JP2021501232A (ja) 2017-10-25 2018-09-11 系中で生成される硫化物および二硫化物で水素化処理触媒を活性させるための統合方法
EP18783186.2A EP3692114B1 (en) 2017-10-25 2018-09-11 Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and mercaptans

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/793,351 2017-10-25
US15/793,351 US10240096B1 (en) 2017-10-25 2017-10-25 Integrated process for activating hydroprocessing catalysts with in-situ produced sulfides and disulphides

Publications (1)

Publication Number Publication Date
WO2019083627A1 true WO2019083627A1 (en) 2019-05-02

Family

ID=63794619

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/050423 Ceased WO2019083627A1 (en) 2017-10-25 2018-09-11 INTEGRATED METHOD FOR THE ACTIVATION OF HYDROTREATMENT CATALYSTS WITH SULFIDES AND DISULFIDES PRODUCED IN SITU

Country Status (7)

Country Link
US (2) US10240096B1 (enExample)
EP (1) EP3692114B1 (enExample)
JP (1) JP2021501232A (enExample)
KR (1) KR20200078557A (enExample)
CN (1) CN111247230A (enExample)
SG (1) SG11202002111VA (enExample)
WO (1) WO2019083627A1 (enExample)

Families Citing this family (5)

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US10851314B2 (en) * 2019-04-17 2020-12-01 Saudi Arabian Oil Company Method to improve the efficiency of pipeline transportation of heavy oils
US11261386B2 (en) 2020-05-20 2022-03-01 Saudi Arabian Oil Company Conversion of MEROX process by-products to useful products in an integrated refinery process
US11603499B2 (en) * 2021-06-30 2023-03-14 Saudi Arabian Oil Company Hydroprocess integrating oxidized disulfide oil compounds
WO2025141383A1 (en) * 2023-12-28 2025-07-03 Reliance Industries Limited Process for removal of sodium from di-sulfide oil using activated carbon as adsorbent
WO2025141385A1 (en) * 2023-12-28 2025-07-03 Reliance Industries Limited Process for removal of sodium from di-sulfide oil using zeolite adsorbent

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US4705620A (en) * 1986-12-16 1987-11-10 Uop Inc. Mercaptan extraction process
US20090065434A1 (en) * 2007-09-10 2009-03-12 Tiejun Zhang Removal of residual sulfur compounds from a caustic stream
US20150284264A1 (en) * 2012-10-26 2015-10-08 Siemens Energy, Inc. Methods and systems for treating spent caustic and regenerating media
US20160108333A1 (en) 2013-05-24 2016-04-21 Total Sa Integrated process for dialkyldisulfides treatment

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US2428623A (en) 1942-12-22 1947-10-07 Standard Oil Dev Co Method of regenerating spent caustic alkali solution
US2693442A (en) 1948-08-11 1954-11-02 Standard Oil Co Mercaptan extraction process
US3104157A (en) 1961-03-21 1963-09-17 Exxon Research Engineering Co Universal caustic regeneration process
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FR2935142B1 (fr) * 2008-08-20 2010-11-19 Arkema France Dimethyldisulfure issu au moins partiellement de matieres renouvellables
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US4705620A (en) * 1986-12-16 1987-11-10 Uop Inc. Mercaptan extraction process
US20090065434A1 (en) * 2007-09-10 2009-03-12 Tiejun Zhang Removal of residual sulfur compounds from a caustic stream
US20150284264A1 (en) * 2012-10-26 2015-10-08 Siemens Energy, Inc. Methods and systems for treating spent caustic and regenerating media
US20160108333A1 (en) 2013-05-24 2016-04-21 Total Sa Integrated process for dialkyldisulfides treatment

Also Published As

Publication number Publication date
US10400183B2 (en) 2019-09-03
US20190194555A1 (en) 2019-06-27
SG11202002111VA (en) 2020-05-28
US10240096B1 (en) 2019-03-26
CN111247230A (zh) 2020-06-05
KR20200078557A (ko) 2020-07-01
JP2021501232A (ja) 2021-01-14
EP3692114A1 (en) 2020-08-12
EP3692114B1 (en) 2021-11-10

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