KR20200023818A - Method Of Transfer Printing Of Fabrics Using Mineral Pigments - Google Patents
Method Of Transfer Printing Of Fabrics Using Mineral Pigments Download PDFInfo
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- KR20200023818A KR20200023818A KR1020180100220A KR20180100220A KR20200023818A KR 20200023818 A KR20200023818 A KR 20200023818A KR 1020180100220 A KR1020180100220 A KR 1020180100220A KR 20180100220 A KR20180100220 A KR 20180100220A KR 20200023818 A KR20200023818 A KR 20200023818A
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- South Korea
- Prior art keywords
- weight
- knitted fabric
- transfer paper
- mineral pigment
- transfer
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 42
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 29
- 239000011707 mineral Substances 0.000 title claims abstract description 29
- 239000000049 pigment Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000010023 transfer printing Methods 0.000 title claims abstract description 13
- 238000012546 transfer Methods 0.000 claims description 43
- 229920005989 resin Polymers 0.000 claims description 19
- 239000011347 resin Substances 0.000 claims description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 16
- 239000004840 adhesive resin Substances 0.000 claims description 13
- 229920006223 adhesive resin Polymers 0.000 claims description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 229920003002 synthetic resin Polymers 0.000 claims description 5
- 239000000057 synthetic resin Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 229920006163 vinyl copolymer Polymers 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 239000003086 colorant Substances 0.000 abstract description 7
- 150000001450 anions Chemical class 0.000 abstract description 5
- 238000005338 heat storage Methods 0.000 abstract description 5
- 230000005855 radiation Effects 0.000 abstract description 5
- 238000009413 insulation Methods 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 4
- 238000007639 printing Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000008451 emotion Effects 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F16/00—Transfer printing apparatus
- B41F16/02—Transfer printing apparatus for textile material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F19/00—Apparatus or machines for carrying out printing operations combined with other operations
- B41F19/02—Apparatus or machines for carrying out printing operations combined with other operations with embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F31/00—Inking arrangements or devices
- B41F31/002—Heating or cooling of ink or ink rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
Abstract
Description
본 발명은 보는 각도에 따라 다양한 빛깔을 발현하는 미네랄안료를 직편물의 표면에 전사함으로써 화려한 무늬의 발현과 함께 음이온, 원적외선방사 및 축열, 보온효과와 비침방지효과를 가지는 의류용 제품을 제공하는 것이다.The present invention is to provide a garment product having an anion, far-infrared radiation and heat storage, thermal insulation effect and anti-impregnation effect with the appearance of colorful patterns by transferring the mineral pigments expressing various colors according to the viewing angle on the surface of the knitted fabric. .
직물을 아름답게 장식하기 위해 직물에 무늬를 형성하기 위해서는, 자수에 의한 방법, 직조에 의한 조직 또는 패턴의 형성방법, 그리고 직물에 날염 등에 의한 염색방법 등이 전통적으로 사용되어 왔다.In order to form a pattern on a fabric for beautifully decorating the fabric, a method by embroidery, a method of forming a tissue or pattern by weaving, and a dyeing method by printing or the like on a fabric have traditionally been used.
최근에는 소비자들의 다양한 요구를 충족시키기 위해 이들 종래의 방법들에 서 탈피하여, 좀 더 다양한 감성을 표현할 수 있는 디자인에 대한 연구가 지속되고 있다. Recently, researches on designs that can express more diverse emotions have been continued from these conventional methods in order to satisfy various demands of consumers.
한편, 전사날염은 염료와 친화성이 낮은 전사지에 무늬를 프린팅 하고 상기 전사지의 무늬가 하방으로 향하도록 하여 직물지에 밀착시킨 후, 상기 종이의 상부를 압착하면서 열을 가하여 상기 염료가 직물지에 인쇄되도록 하는 기술이다. 이때 염료는 승화성 염료로서 직물지와 친화성이 높은 것을 사용한다.On the other hand, the transfer printing is printed on the transfer paper having a low affinity with the dye, the transfer paper pattern is directed downward to adhere to the fabric paper, and then press the heat while pressing the top of the paper so that the dye is printed on the fabric paper It is a technique to do. In this case, a dye having a high affinity with textile paper is used as a sublimable dye.
이 경우 그라비아 인쇄기로 인쇄하게 되는데, 이는 동판에 문양이 요철로 형성되고 상기 요철에 인쇄를 도포하여 인쇄하는 방식이므로 다양한 색상으로 인쇄할 경우, 여러 개의 실린더를 통과시켜야 하므로 생산이 지연되고 정확한 무늬의 발현이 어려운 문제점이 있었다.In this case, the gravure printing machine is used, which is a pattern formed by the unevenness of the copper plate and the printing is applied by printing the unevenness. There was a difficult problem of expression.
그러므로 본 발명에 의하면, 보는 각도에 따라 다양한 빛깔을 발현하는 미네랄안료를 직편물의 표면에 전사함으로써 화려한 무늬의 발현과 함께 음이온, 원적외선방사 및 축열, 보온효과와 비침방지효과를 가지는 의류용 제품을 간단한 방법으로 제공하는 것을 기술적과제로 한다.Therefore, according to the present invention, by transferring the mineral pigment expressing a variety of colors according to the viewing angle on the surface of the knitted fabric, a garment product having anion, far-infrared radiation and heat storage, thermal insulation effect and anti-impregnation effect with the appearance of colorful patterns Providing in a simple way is a technical task.
그러므로 본 발명에 의하면, 합성수지필름으로 이루어진 전사용지에 그라비아용 투명잉크와 이형제가 혼합된 수지액층을 형성시켜 전사용지를 만드는 단계(301);Therefore, according to the present invention, a step of making a transfer paper by forming a resin liquid layer in which a transparent ink for gravure and a release agent are mixed on a transfer paper made of a synthetic resin film;
상기 전사용지의 수지액층에 미네랄안료를 분산시키는 단계(302);Dispersing the mineral pigment in the resin liquid layer of the transfer paper (302);
접착용 수지액이 묻은 엠보무늬를 가진 로울러에 상기 전사용지를 통과시켜 상기 전사용지의 수지액층상에 접착용 수지액을 코팅하는 단계(304); Coating (304) the adhesive resin solution on the resin liquid layer of the transfer paper by passing the transfer paper through a roller having an embossed pattern on which the adhesive resin solution is attached;
상기 전사용지와 직편물을 밀착시키고 열롤러를 통과시켜 합지하여 열전사하는 단계(305);Contacting the transfer paper and the knitted fabric and passing the heat roller to lamination to thermal transfer (305);
상기 합지된 전사용지와 직편물을 45~50℃에서 숙성시키는 단계(306); 및Aging the laminated transfer paper and the knitted fabric at 45 ~ 50 ℃ (306); And
상기 합지된 전사용지와 직편물을 분리하는 단계(306)로 이루어진 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법이 제공된다.There is provided a transfer printing method of a knitted fabric using a mineral pigment, comprising the step 306 of separating the laminated transfer paper and the knitted fabric.
이하 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명은 미네랄안료를 이용한 직편물의 전사 인쇄 방법에 관한 것으로서 보는 각도에 따라 다양한 빛깔을 발현하는 미네랄안료를 직편물의 표면에 전사함으로써 화려한 무늬의 발현과 함께 음이온, 원적외선방사 및 축열, 보온효과와 비침방지효과를 가지는 의류용 제품을 제공하는 것이다. The present invention relates to a transfer printing method of a knitted fabric using a mineral pigment, by transferring a mineral pigment expressing a variety of colors according to the viewing angle on the surface of the knitted fabric, with the appearance of colorful patterns, anion, far-infrared radiation and heat storage, heat retention effect And to provide a product for clothing having a non-impregnation effect.
본 발명의 미네랄안료를 이용한 직편물의 전사 인쇄 방법은 크게 전사용지를 만드는 단계(301); 미네랄안료를 분산시키는 단계(302); 접착용 수지액을 코팅하는 단계(304); 합지·열전사하는 단계(305); 숙성단계(306); 및 분리단계(306)로 이루어진다.The transfer printing method of the knitted fabric using the mineral pigment of the present invention comprises the steps of making a transfer paper large (301); Dispersing the mineral pigment (302); Coating an adhesive resin solution (304); Laminating and thermally transferring (305); Aging step 306; And a separation step 306.
먼저, 합성수지필름으로 이루어진 전사용지에 그라비아용 투명잉크와 이형제가 혼합된 수지액층을 형성시켜 전사용지를 만드는 단계(301)를 행하여 수지액층에 미네랄안료를 부착시킬 수 있도록 준비한다. First, a step (301) of preparing a transfer paper by forming a resin liquid layer in which a gravure transparent ink and a release agent are mixed on a transfer paper made of a synthetic resin film is prepared to attach a mineral pigment to the resin liquid layer.
상기 합성수지필름은 폴리에스테르필름, 폴리에틸렌필름, 폴리프로필렌필름 중 어느 하나를 사용할 수 있으며, 합성수지필름으로 이루어진 전사용지에 수지액층을 형성한다.The synthetic resin film may be any one of a polyester film, polyethylene film, and polypropylene film, and forms a resin liquid layer on a transfer paper made of a synthetic resin film.
상기 그라비아용 투명잉크와 이형제의 중량비는 40:60~50:50인 것이 작업에 바람직하다.The weight ratio of the transparent ink for gravure and the release agent is preferably 40:60 ~ 50:50 for the operation.
상기 그라비아용 투명잉크는 비닐코폴리머 25~55중량%, 톨루엔 20~40중량%, 메틸에틸케톤 20~30중량%, 잔부로서 폴리에틸렌왁스로 이루어진 것이 바람직하다. The gravure transparent ink is preferably 25 to 55% by weight of vinyl copolymer, 20 to 40% by weight of toluene, 20 to 30% by weight of methyl ethyl ketone, and the balance of polyethylene wax.
이형제는 N,N-다이메틸폼아마이드 30~40중량%, 톨루엔 10~20중량%, 메틸에틸케톤 20~30중량%, 잔부로서 폴리우레탄으로 이루어진 것을 사용하는 것이 직편물과 전사용지의 분리가 용이하도록 할 수 있다.The release agent used was 30-40% by weight of N, N-dimethylformamide, 10-20% by weight of toluene, 20-30% by weight of methyl ethyl ketone, and the remainder of polyurethane as the remainder. It can be done easily.
상기와 같이 준비된 전사용지의 수지액층에 미네랄안료를 분산시키는 단계(302)를 행하여 전사용지의 수용액층에 미네랄안료를 분포시킨다.Dispersing the mineral pigment in the resin liquid layer of the transfer paper prepared as described above (302) to distribute the mineral pigment in the aqueous solution layer of the transfer paper.
상기 미네랄안료는 입경 3~5㎛인 산화아연, 산화티타늄, 산화철, 코발트블루 및 크롬의 조합으로 이루어진 군 중 어느 하나인 미네랄안료를 사용하는 것이 다양한 색상과 광물특유의 광택을 발현할 수 있어 완성된 직물에 화려한 무늬와 색상을 부여할 수 있으며, 원단접착력이 우수하여 효과적이다. The mineral pigment is one of the group consisting of a combination of zinc oxide, titanium oxide, iron oxide, cobalt blue and chromium having a particle diameter of 3 ~ 5㎛ that can express a variety of colors and mineral-specific gloss finished It can give a colorful pattern and color to the finished fabric and it is effective because of its excellent adhesive strength.
이후 상기 전사용지에 접착용 수지액을 코팅하게 되는데, 접착용 수지액이 묻은 엠보무늬를 가진 로울러에 상기 전사용지를 통과시켜 상기 전사용지의 수지액층상에 접착용 수지액을 코팅하는 단계(304)를 행한다.Then, the adhesive resin is coated on the transfer paper, and the transfer paper is passed through a roller having an embossed pattern on which the adhesive resin is deposited to coat the adhesive resin on the resin liquid layer of the transfer paper (304). ).
상기 접착용 수지액은 방향족폴리이소시아네이트 수지 70~80중량%, 아세트산 에틸 20~30중량%로 이루어진 것을 사용하는 것이 미네랄안료의 직물에 대한 접착력이 향상되고, 직편물의 촉감이 뻣뻣해지지 않아 바람직하다. It is preferable that the adhesive resin solution is composed of 70 to 80% by weight of aromatic polyisocyanate resin and 20 to 30% by weight of ethyl acetate because the adhesion of the mineral pigment to the fabric is improved and the texture of the knitted fabric is not stiff. .
이후 전사용지와 직편물을 밀착시키고 80~90℃의 열롤러를 통과시켜 합지하여 열전사하는 단계(305)를 행하는데, 상기 코팅단계(304)에서 엠보무늬를 가진 로울러에 의해 전사용지에 생긴 무늬가 직편물의 표면에 형성되게 된다. 이렇게 수지액층이 형성된 필름에 무늬를 안착 시켜 원단에 무늬를 입히고 필름은 분리됨으로써 무늬가 원단에 접착력이 강하게 형성된다.Thereafter, the transfer paper and the knitted fabric are brought into close contact with each other and passed through a thermal roller at 80 to 90 ° C. to perform thermal transfer (305), which is formed on the transfer paper by an roller having an embossed pattern in the coating step 304. A pattern is formed on the surface of the knitted fabric. Thus, the pattern is placed on the film on which the resin liquid layer is formed to coat the fabric, and the film is separated, so that the pattern is strongly formed on the fabric.
이후 상기 합지된 전사용지와 직편물을 45~50℃에서 숙성시키는 단계(306)를 행한다. Thereafter, the step of aging the laminated transfer paper and knitted fabric at 45˜50 ° C. is performed.
이후 상기 합지된 전사용지와 직편물을 분리하는 단계(306)를 거쳐 전사용지에 형성된 무늬와 색상이 직편물의 표면에 형성된다. After the step 306 of separating the laminated transfer paper and the knitted fabric is a pattern and color formed on the transfer paper is formed on the surface of the knitted fabric.
그러므로 본 발명에 의하면, 보는 각도에 따라 다양한 빛깔을 발현하는 미네랄안료를 직편물의 표면에 전사함으로써 화려한 무늬의 발현과 함께 음이온, 원적외선방사 및 축열, 보온효과와 비침방지효과를 가지는 의류용 제품을 제공할 수 있으며, 특히 블랙색상의 히잡제품에 화려한 색상과 무늬를 발현할 수 있는 효과가 있다.Therefore, according to the present invention, by transferring the mineral pigment expressing a variety of colors according to the viewing angle on the surface of the knitted fabric, a garment product having anion, far-infrared radiation and heat storage, thermal insulation effect and anti-impregnation effect with the appearance of colorful patterns It can provide, especially in the hijab product of the black color has the effect of expressing colorful colors and patterns.
도 1은 본 발명의 미네랄안료를 이용한 직편물의 전사 인쇄 방법에 의해 제조된 실시예 1의 직편물의 표면사진이다.1 is a surface photograph of the knitted fabric of Example 1 prepared by the transfer printing method of the knitted fabric using the mineral pigment of the present invention.
이하 다음의 실시 예에서는 본 발명의 미네랄안료를 이용한 직편물의 전사 인쇄 방법에 대한 비한정적인 예시를 하고 있다.The following examples are given as non-limiting examples of the transfer printing method of the knitted fabric using the mineral pigment of the present invention.
[실시예 1]Example 1
폴리에스테르필름으로 이루어진 전사용지에 비닐코폴리머 55중량%, 톨루엔 20중량%, 메틸에틸케톤 23.5중량%, 폴리에틸렌왁스 1.5중량%로 이루어진 그라비아용 투명잉크와 N,N-다이메틸폼아마이드 33중량%, 톨루엔 10중량%, 메틸 에틸 케톤 27중량%, 폴리우레탄 30중량%로 이루어진 이형제가 중량비 50:50으로 혼합된 수지액층을 형성시켜 전사용지를 만드는 단계(301)를 거친 후, 상기 전사용지의 수지액층에 입경 4.5㎛인 미네랄안료를 분산시키켜 표면에 분포시키는 단계(302)를 거치고, 방향족폴리이소시아네이트 수지 80중량%, 아세트산 에틸 20중량%로 이루어진 접착용 수지액이 담겨진 접착용 수지액욕조에 엠보무늬를 가진 로울러를 일부 담그고 로울러 상부로 상기 전사용지를 통과시켜 상기 전사용지의 수지액층상에 접착용 수지액을 코팅하는 단계(304)를 거치고, 상기 전사용지의 접착용 수지액이 코팅된 면에 직편물을 밀착시키고 80℃의 열롤러를 통과시켜 합지하여 열전사하는 단계(305)를 거친 후, 상기 합지된 전사용지와 직편물을 45~50℃에서 24시간동안 숙성시키는 단계(306)를 거친 후, 상기 합지된 전사용지와 직편물을 분리하여 미네랄안료를 이용한 직편물의 전사 인쇄 방법을 완료하였다.Gravure transparent ink consisting of 55% by weight of vinyl copolymer, 20% by weight of toluene, 23.5% by weight of methyl ethyl ketone, and 1.5% by weight of polyethylene wax and 33% by weight of N, N-dimethylformamide on a transfer paper made of polyester film After forming the transfer paper by forming a resin liquid layer in which a release agent composed of 10% by weight of toluene, 27% by weight of methyl ethyl ketone, and 30% by weight of polyurethane was formed at a weight ratio of 50:50, Dispersing the mineral pigment having a particle diameter of 4.5㎛ in the resin liquid layer and distributing it on the surface (302), the adhesive resin bath containing the adhesive resin liquid consisting of 80% by weight of aromatic polyisocyanate resin, 20% by weight of ethyl acetate Immersing a roller having an embossed pattern and passing the transfer paper over the roller to coat the adhesive resin solution on the resin liquid layer of the transfer paper (304). After contacting, the knitted fabric is in close contact with the surface of the transfer resin adhesive coating, and passed through a thermal roller at 80 ℃ to pass the step of thermal transfer (305), then the laminated transfer paper and the knitted fabric After the aging step 306 for 24 hours at 45 ~ 50 ℃ 306, the laminated transfer paper and the knitted fabric is separated to complete the transfer printing method of the knitted fabric using a mineral pigment.
Claims (5)
상기 전사용지의 수지액층에 미네랄안료를 분산시키는 단계(302);
접착용 수지액이 묻은 엠보무늬를 가진 로울러에 상기 전사용지를 통과시켜 상기 전사용지의 수지액층상에 접착용 수지액을 코팅하는 단계(304);
상기 전사용지와 직편물을 밀착시키고 열롤러를 통과시켜 합지하여 열전사하는 단계(305);
상기 합지된 전사용지와 직편물을 45~50℃에서 숙성시키는 단계(306); 및
상기 합지된 전사용지와 직편물을 분리하는 단계(306)로 이루어진 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법.Making a transfer paper by forming a resin liquid layer in which a transparent ink for gravure and a release agent are mixed on a transfer paper made of a synthetic resin film (301);
Dispersing a mineral pigment in the resin liquid layer of the transfer paper (302);
Coating (304) the adhesive resin solution on the resin liquid layer of the transfer paper by passing the transfer paper through a roller having an embossed pattern on which the adhesive resin solution is attached;
Contacting the transfer paper and the knitted fabric and passing the heat roller to lamination to thermal transfer (305);
Aging the laminated transfer paper and the knitted fabric at 45 ~ 50 ℃ (306); And
Separation (306) of the laminated transfer paper and the knitted fabric, characterized in that the transfer printing method of the knitted fabric using a mineral pigment.
상기 그라비아용 투명잉크와 이형제의 중량비는 40:60~50:50인 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법.The method of claim 1,
The weight ratio of the transparent ink for gravure and the release agent is 40:60 ~ 50:50 Transfer printing method of the knitted fabric using a mineral pigment, characterized in that.
상기 그라비아용 투명잉크는 비닐코폴리머 25~55중량%, 톨루엔 20~40중량%, 메틸에틸케톤 20~30중량%, 잔부로서 폴리에틸렌왁스로 이루어지고, 이형제는 N,N-다이메틸폼아마이드 30~40중량%, 톨루엔 10~20중량%, 메틸에틸케톤 20~30중량%, 잔부로서 폴리우레탄으로 이루어진 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법.The method of claim 1,
The transparent ink for gravure is 25 to 55% by weight of vinyl copolymer, 20 to 40% by weight of toluene, 20 to 30% by weight of methyl ethyl ketone, and the balance is made of polyethylene wax, and the release agent is N, N-dimethylformamide 30 -40% by weight, 10 to 20% by weight of toluene, 20 to 30% by weight of methyl ethyl ketone, and the balance of polyurethane as a balance.
상기 미네랄안료는 입경 3~5㎛인 미네랄안료인 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법.The method of claim 1,
The mineral pigment is a transfer printing method of a knitted fabric using a mineral pigment, characterized in that the mineral pigment having a particle size of 3 ~ 5㎛.
상기 접착용 수지액은 방향족폴리이소시아네이트 수지 70~80중량%, 아세트산 에틸 20~30중량%로 이루어진 것을 특징으로 하는 미네랄안료를 이용한 직편물의 전사 인쇄 방법.The method of claim 1,
The adhesive resin solution is 70 to 80% by weight of aromatic polyisocyanate resin, 20 to 30% by weight of ethyl acetate transfer printing method of a knitted fabric using a mineral pigment.
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