KR20190069181A - Perfume compostion comprising fragrances of citrus - Google Patents

Abstract

The present invention relates to a perfume composition including a citrus-based fragrance component with improved fragrance persistence. The perfume composition comprises 4.2 to 21 wt% of a citrus-based fragrance component and 5.8 to 29 wt% of a non-citrus-based fragrance component with respect to the total weight of the perfume composition.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition comprising a citrus-based perfume ingredient.

TECHNICAL FIELD The present invention relates to a perfume composition containing a perfume ingredient of a citrus series, and more particularly to a perfume composition which has an effect of maintaining a long-time perfume while imparting a perfume of a citrus series.

Considering that the fragrance ingredient contained in the cosmetic market and the sustainability of the cosmetics market are the main purchasing factors of consumers in recent years, it is important to realize the desired fragrance and improve the persistence of the fragrance, . Not only in the fragrance in which the fragrance is the main component but also in the cosmetics, the feeling of use of the user is improved and the user is prevented from having a sense of rejection of the effectiveness of the cosmetic having the unique fragrance.

On the other hand, citrus means citrus including citrus fruits such as lemon, grapefruit, and bergamot. The fruit of citrus has a sour and refreshing taste, and the citrus flavor also has a sour and refreshing flavor.

In particular, such a citrus-based fragrance gives a refreshing feeling, so it is used in various cosmetics including fragrance, and has a very high flavor. However, since the fragrance of the citrus series is generally small in molecular weight, it is more volatile than other fragrances, and the fragrance spreads rapidly, while the persistence is poor.

Accordingly, when the perfume of the citrus series is applied to the perfume, it is disadvantageous that the perfume is repeatedly applied every 1-2 hours by the user or even when the perfume is used as a diffuser, the perfume is blown away and can not be used for a long time.

Further, in order to solve the problem of persistence, there has been attempted to develop a scent component that suppresses volatility or to add other additives, but it has not been able to realize the citrus scent as it is.

For this reason, there is an urgent need to develop a technology capable of satisfying the consumer's preference and enhancing the flavor of the citrus series at the same time.

SUMMARY OF THE INVENTION It is an object of the present invention to solve the above-mentioned problems of the prior art and the technical problems required from the past.

The inventors of the present invention have recognized and solved the above problems and have repeated numerous experiments and studies to find that when a citrus-based flavor ingredient and a non-citrus flavor ingredient are used together, the perfume of the citrus flavor is fully realized And at the same time, the present invention has been completed on a perfume composition in which the fragrance persistency is remarkably improved as compared with the case of containing only the perfume ingredients of the existing citrus series.

It is another object of the present invention to provide a cosmetic composition comprising a perfume composition with improved persistence.

Accordingly, in order to accomplish the above object, the perfume composition according to the present invention comprises a perfume composition of a citrus series and a perfume composition of a non-citrus series.

The fragrance composition according to the present invention may contain 4.2 to 21% by weight of the fragrance component of the citrus based on the total weight of the perfume composition, and 5.8 to 29% by weight of the fragrance component of the non-citrus series.

In the perfume composition according to the present invention, the fragrance component of the citrus series may be at least one selected from the group consisting of Claritone, Hydrocitronitrile and Mandaril.

In detail, the fragrance component of the citrus series according to the present invention may be a mixture of Claritone, Hydrocitronitrile and Mandaril.

In addition, the fragrance component of the citrus series may contain 1.5 to 7.5% by weight of Claritone, 0.75 to 3.75% by weight of hydrocitronitrile, and Mandaril, based on the total weight of the perfume composition. 0.5 to 5% by weight.

On the other hand, the fragrance component of the non-citrus series may be at least one selected from the group consisting of muguet alcohol, Brahmanol, Madranol, Palisandin and Vetikon.

In detail, the perfume ingredients of the non-citrus series include 2.45 to 12.25% by weight of muguet alcohol, 1.3 to 6.5% by weight of Brahmanol based on the total weight of the perfume composition, Madranol) in an amount of 0.75 to 3.75% by weight, Palisandin in an amount of 0.25 to 1.25% by weight, and Victon in an amount of 1.05 to 5.25% by weight.

The present invention also provides a cosmetic composition comprising the perfume composition.

Specifically, the cosmetic composition may be contained in an amount of 0.5 to 5% by weight based on the total weight of the cosmetic composition, and the formulation of the cosmetic composition may be a solution, a current liquid, an emulsion, a paste, a lotion, a gel, , Basic cosmetic formulations of surfactant-containing cleansing, oil, oil-in-water (O / W) type, basic cosmetic formulations of w / o type, skin, lotion, eye cream, Formulation of color cosmetics consisting of formulations, body lotion formulations, peeling gel, underwater type make-up base, in-water make-up base, foundation, skin cover, lipstick, lip gloss, face powder, two way cake, eye sachet, cheek color, eyebrow pencil , Sunscreen, baboon cream, and scalp.

INDUSTRIAL APPLICABILITY As described above, the perfume composition according to the present invention has the effect of realizing the original flavor of the citrus and improving the persistence of the citrus flavor.

In addition, the cosmetic composition containing the perfume composition according to the present invention has an effect that the citrus flavor lasts for a long time.

Hereinafter, each configuration will be described in more detail, but this is only an example, and the scope of the present invention is not limited by the following contents.

The fragrance can be classified into various types according to the flavor characteristics, such as a floral, a citrus, an oriental, a sipre, a fuzer, a fruity, a woody, and the like. It is the molecular weight of the fragrance particles that greatly affects the persistence and flavor of the fragrance. A molecule having a small molecular weight has a high volatility, and thus has a problem that the smell resistance is excellent but the persistence of the smell is greatly deteriorated.

The most typical cosmetic composition utilizing fragrance is fragrance, which is in the order of top note, middle note, and base note in order of smell. The citrus flavor is often a compound having a small molecular weight, and has a high volatility, and thus has excellent dispersibility of fragrant particles at the time of fragrance, but has a problem of poor continuity. Accordingly, in a cosmetic composition such as a perfume containing a perfume of a citrus series, the citrus fragrance constitutes a top note.

However, despite the high preference of the citrus flavor which gives a refreshing and refreshing feeling, there is a problem that the durability is greatly lowered. However, the perfume composition according to the present invention has a citrus flavor, And also has an excellent smell diffusion property.

Specifically, the perfume composition according to the present invention comprises a perfume composition of a citrus series and a perfume composition of a non-citrus series. In the perfume composition according to the present invention, the fragrance component of the citrus series may be contained in an amount of 4.2 to 21% by weight, preferably 8 to 15% by weight, based on the total weight of the perfume composition, By weight, and 10 to 13% by weight. At this time, the non-citrus flavor component may contain 5.8 to 29% by weight, preferably 10 to 22% by weight, and most preferably 15 to 19% by weight.

When the fragrance component of the citrus series is added in a smaller amount than the above content, there is a problem that the fragrance of the citrus series is not sufficiently realized. When the component is added in an excess amount, There is a problem in that the persistence of the fragrance is deteriorated.

When the fragrance component of the non-citrus type is added in a smaller amount than the above-mentioned content, there is a problem that the persistence of the citrus flavor is remarkably deteriorated due to the early volatility as in the case of adding only the fragrance component of the citrus type, , There is a problem that the original incense-making ability of the citrus deteriorates and the mixed flavor is felt.

The fragrance component of the above-mentioned citrus series is not particularly limited as long as it gives a citrus flavor, but it is preferably selected from the group consisting of Claritone, Hydrocitronitrile and Mandaril It can be more than one.

The Claritone is a citrus family, also known as 2,4,4,7-tetramethyloct-6-en-3-one (2,4,4,7-tetramethyloct- Lt; / RTI > The hydrocitronitrile is a citrus-based fragrance component also called 5-cyclohexyl-3-methylpentanenitrile, and Mandaril is a (2E) -tri Deca-2, 12-dienenitrile ((2E) -trideca-2,12-dienenitrile).

The fragrance component of the citrus series is preferably composed of a mixture of a plurality of components rather than a single component, and in particular, a mixture of Claritone, Hydrocitronitrile and Mandaril Is most preferable.

On the other hand, in the case of containing the fragrance component of the citrus type as described above, each component contains 1.5 to 7.5% by weight, preferably 2.2 to 6.0% by weight of Claritone, based on the total weight of the perfume composition By weight, and most preferably 4.8 to 5.5% by weight. Hydrocitronitrile may be contained in an amount of 0.75 to 3.75% by weight, preferably 1.6 to 3.3% by weight, and most preferably 2.0 to 2.5% by weight. In the case of Mandaril, it may contain 0.5 to 5% by weight, preferably 2.2 to 4.5% by weight, and most preferably 3.2 to 4% by weight.

In the perfume composition according to the present invention, the perfume ingredient of the non-citrus series is not particularly limited as long as it is not a perfume ingredient of a citrus series, but may be a perfume ingredient such as a floral, oriental, .

Preferably, it may be at least one of a floral series scent component and a woody series scent component, and is most preferably a mixture of a floral series scent component and a woody series scent component.

The fragrance component of the floral series may be at least one selected from the group consisting of muguet alcohol and hydroxy citronellal.

The mugu alcohol is also referred to as 3-cyclohexyl-2,2-dimethylpropan-1-ol, and is a fragrance component of lilies of the valley.

The woody series flavoring component may be at least one member selected from the group consisting of Brahmanol, Madranol, Palisandin and Vetikon, preferably two or more flavor components May be mixed and most preferably a mixture of Brahmanol, Madranol, Palisandin and Vetikon.

The Brahmanol is a 2-methyl-4- (2,2,3-trimethyl-1-cyclopent-3-enyl) 1-ol), Madranol is also referred to as 3-methyl-4- (2,2,6-trimethylcyclohexyl) butan-2-ol 3-methyl-4- (2,2,6-trimethylcyclohexyl) butan-2-ol, and Palisandin and Vetikon are components corresponding to methoxycyclododecane and 4 4-methyl-4-phenyl-2-pentanone.

In the perfume composition according to the present invention, when the non-citrus flavor component is composed of a mixture of a fragrance component of a floral series and a fragrance component of a woody series, muguet alcohol, Brahmanol, Madranol, Palisandin and Vetikon. ≪ / RTI >

More specifically, based on the total weight of the perfume composition, it may comprise 2.45 to 12.25 wt%, preferably 3.3 to 8.5 wt%, and most preferably 6.1 to 7.5 wt% of muguet alcohol And Brahmanol in an amount of 1.3 to 6.5% by weight, preferably 3.7 to 5.75% by weight, most preferably 4.9 to 5.25% by weight, and Madranol in an amount of 0.75 to 3.75% By weight, preferably 1.2 to 3.25% by weight, and most preferably 1.5 to 2.5% by weight. Palisandin may be contained in an amount of 0.25 to 1.25% by weight, preferably 0.5 to 1% by weight, more preferably 0.6 to 0.75% by weight. In the case of Vecton, it may be contained in an amount of 1.05 to 5.25% by weight, preferably 1.3 to 3.5% by weight, and most preferably 1.9 to 2.75% by weight.

The present invention also provides a cosmetic composition comprising the perfume composition. Specifically, the cosmetic composition may contain 0.5 to 5% by weight, based on the total weight of the cosmetic composition.

The formulation of the cosmetic composition according to the present invention is not limited to a particular type, but may be in the form of solutions, suspensions, emulsions, pastes, lotions, gels, water-soluble liquids, creams, essences, surfactant-containing cleansing oils, A makeup base for underwater type makeup base, a makeup base for underwater type makeup base, a makeup base for underwater type makeup base, a makeup base for underwater type makeup base , A cream, a cream, a cream, a cream, a cream, a cream, a foundation cream, a skin cover, a lipstick, a lip gloss, a face powder, a two-way cake, have.

Hereinafter, the present invention will be described in more detail by way of examples, but the scope of the present invention is not limited thereto.

Preparation of cosmetic composition

A perfume composition prepared from the ingredients of Tables 1 to 3 below was prepared and a body lotion was prepared containing 2% by weight, based on the total weight of the cosmetic composition, of a perfume composition.

Compound name Example 1 Comparative Example 1 Comparative Example 2 Claritone 5 10 8 Hydrocitronitrile 2.3 9 8 Mandaril 3.5 8.5 8 Muguet alcohol 6.5 - One Brahmanol 5 - 0.8 Madranol 2 - 0.5 Palisandin 0.7 - 0.45 Vetikon 2.5 - 0.75

Compound name Comparative Example 3 Comparative Example 4 Comparative Example 5 Claritone 10.8 8 8 Hydrocitronitrile - 2.8 0.6 Mandaril - - 2.2 Muguet alcohol 6.5 6.5 6.5 Brahmanol 5 5 5 Madranol 2 2 2 Palisandin 0.7 0.7 0.7 Vetikon 2.5 2.5 2.5

Compound name Comparative Example 6 Comparative Example 7 Comparative Example 8 Claritone 5 5 5 Hydrocitronitrile 2.3 2.3 2.3 Mandaril 3.5 3.5 3.5 Muguet alcohol 15.7 15.1 15 Brahmanol One One 2 Madranol - 0.5 0.5 Palisandin - 0.1 0.1 Vetikon - - 0.1

Experimental Example 1 - Persistence confirmation experiment

The evaluation of the reverberation persistence of the body lotion according to the examples and the comparative examples was conducted on 20 ordinary people.

After washing the left arm of the subject cleanly, 0.1 g of the body lotion according to the examples and the comparative examples was taken and rubbed 10 times in a circular shape in a region of a size of a size of five hundreds won and rubbed lightly. After 30 seconds, the initial sensory evaluation was performed .

After 1 hour, the body lotion was applied to the other part of the left arm in the same manner, and the reverberation after 30 seconds was compared with the reverberation at the initial application site, and the sensory evaluation was performed by the questionnaire shown in Table 4 below.

survey One Almost no odor 2 I feel very weak smell 3 I feel a weak smell 4 Smell of medium intensity 5 I feel a little strong smell 6 Strong smell 7 Very strong smell

After 4 hours, the body lotion was applied to the new site as in the above experiment, and the reverberation after 30 seconds was compared with the reverberation at the initial application site, and the sensory evaluation was carried out by the following questionnaire.

In the same manner, reverberant sensory evaluation was performed after 8 hours and 12 hours, respectively, and the number of people who were scored according to the results of the questionnaire was measured as shown in the following table.

score Example 1 (number of persons) 1h 4h 8h 12h One 0 0 0 0 2 0 0 0 0 3 0 0 0 One 4 0 One 5 6 5 6 7 4 4 6 6 6 7 5 7 8 6 4 4

score Comparative Example 1 (number of persons) Comparative Example 2 (number of persons) 1h 4h 8h 12h 1h 4h 8h 12h One 0 0 5 8 0 0 0 0 2 0 4 6 7 0 0 0 8 3 0 5 7 5 0 4 6 7 4 0 4 2 0 0 4 5 2 5 0 3 0 0 3 5 6 One 6 3 2 0 0 5 4 2 One 7 17 2 0 0 12 3 One One score Comparative Example 3 (number of persons) Comparative Example 4 (number of persons) 1h 4h 8h 12h 1h 4h 8h 12h One 0 0 5 9 0 0 0 0 2 0 4 4 4 0 0 0 6 3 0 5 5 4 0 2 4 4 4 0 4 6 3 0 3 2 6 5 0 7 0 0 3 5 7 4 6 5 0 0 0 7 10 7 0 7 15 0 0 0 10 0 0 0 score Comparative Example 5 (number of persons) Comparative Example 6 (number of persons) 1h 4h 8h 12h 1h 4h 8h 12h One 0 0 0 One 0 0 0 0 2 0 0 One 4 0 2 4 10 3 0 5 8 4 0 5 7 7 4 4 7 3 6 0 4 7 3 5 5 3 8 5 0 4 2 0 6 5 5 0 0 7 3 0 0 7 6 0 0 0 13 2 0 0 score Comparative Example 7 (number of persons) Comparative Example 8 (number of persons) 1h 4h 8h 12h 1h 4h 8h 12h One 0 0 0 0 0 0 0 0 2 0 One 3 7 0 0 2 4 3 0 2 7 9 0 0 7 9 4 0 5 7 3 0 6 4 6 5 5 4 3 One 4 4 7 One 6 5 7 0 0 7 7 0 0 7 10 One 0 0 9 3 0 0

Experimental Example 2 - Expert sensory evaluation

The aroma of the body lotion according to the examples and comparative examples was evaluated for 15 professional steerers. Based on the reference example in which the fragrance component of the citrus series is contained as a single component, a value of 0 to 9 is assigned depending on the degree of similarity with the citrus flavor.

The scores of the professional steerers were collected and the average scores were as follows.

Distinction Example 1 Comparative Example One 2 3 4 5 6 7 8 Average score 8.0 8.3 8.0 6.6 6.6 7.0 7.6 7.3 7.3

Referring to Tables 5 to 7, it can be seen that when the body lotion of the embodiment is applied, the best reverberation persistence is shown even after 12 hours have elapsed. In addition, in the case of the examples, high scores were shown in the sensory evaluation by the experts, and it was found that the citrus flavor was sufficiently realized and the durability was excellent.

In comparison with Comparative Example 1, in the case of containing only the citric fragrance, the citrus flavor component contained the largest amount of the fragrance component and the high volatility as the general property of the citrus flavor component, Is most fully implemented. However, in the reverberation persistence, all of the fragrance was initially flashed, and after 12 hours, the reverberation was estimated to remain very weak.

In the case of Comparative Example 2, although the citrus component was contained in an excess amount as compared with the examples, it was found that the degree of perfume was the same in the sensory evaluation of the expert, while the persistence of the reverberation was low.

Referring to Comparative Examples 3 to 5, it can be seen that the reverberation persistence is lower than that of the Examples. Furthermore, it was found that the sensory evaluation by the expert was evaluated with a significantly lower score. Particularly, in some professional irrigation companies, there was a case where the user could appreciate that the fragrance can be appreciated by other fragrances than the citrus fragrance.

With reference to Comparative Examples 6 to 8, it was evaluated that the score of sensory evaluation by experts was not so high and the reverberation persistence was not excellent.

Claims (9)

A citrus-based perfume ingredient and a non-citrus-based perfume ingredient. The method according to claim 1,
Based on the total weight of the perfume composition, the fragrance component of the citrus series comprises 4.2 to 21% by weight,
And 5.8 to 29% by weight of the fragrance component of the non-citrus type. The method according to claim 1,
Wherein the fragrance component of the citrus series is at least one selected from the group consisting of Claritone, Hydrocitronitrile and Mandaril. The method according to claim 1,
Wherein the fragrance component of the citrus series is a mixture of Claritone, Hydrocitronitrile and Mandaril. The method according to claim 1,
Wherein the non-citrus flavor component is characterized by at least one selected from the group consisting of muguet alcohol, Brahmanol, Madranol, Palisandin and Vetikon Perfume composition. 5. The method of claim 4,
The fragrance component of the citrus series is based on the total weight of the perfume composition,
Characterized in that it comprises 1.5 to 7.5% by weight of Claritone, 0.75 to 3.75% by weight of hydrocitronitrile and 0.5 to 5% by weight of Mandaril. 6. The method of claim 5,
The perfume ingredients of the non-citrus series are based on the total weight of the perfume composition,
From 2.45 to 12.25% by weight of muguet alcohol, from 1.3 to 6.5% by weight of Brahmanol, from 0.75 to 3.75% by weight of Madranol, from 0.25 to 1.25% by weight of palisandin, And 1.05 to 5.25% by weight of Vecton. 8. A cosmetic composition comprising a perfume composition according to any one of claims 1 to 7,
Wherein the perfume composition comprises 0.5 to 5% by weight based on the total weight of the cosmetic composition. 9. The method of claim 8,
The formulation of the cosmetic composition may be in the form of a solution, suspension, emulsion, paste, lotion, gel, water-soluble liquid, cream, essence, cosmetic containing cleansing oil, oil, A makeup base, a foundation, a skin cover, a lipstick, a lipstick, a lipstick, a lipstick, a lipstick, Wherein the cosmetic composition is one selected from the group consisting of lip gloss, face powder, two-way cake, eye sachet, cheek color, color cosmetic formulations comprising eyebrow pencils, sunscreen, baboon cream and scalp.