KR20140118735A - Intermittent coating apparatus and coating film forming system - Google Patents

Abstract

Provided is an intermittent coating apparatus in which vibration transferred from a switching unit to a nozzle may be reduced. A coating nozzle (11) ejects a coating liquid onto a substrate (5). A supply pipe (30) is connected to the coating nozzle (11) and the coating liquid flows toward the coating nozzle (11). A switching unit (32) repeatedly switches opening/closing of the supply pipe (30) so that the coating liquid is intermittently ejected from the coating nozzle (11). The coating nozzle (11) is placed on a nozzle base (50). A base (60) of the switching unit is a body separated from the nozzle base (50), and the switching unit (32) is placed thereon.

Description

TECHNICAL FIELD [0001] The present invention relates to an intermittent coating apparatus and a coating film forming system,

The present invention relates to an intermittent coating apparatus for intermittently coating a coating liquid from a nozzle toward a substrate and a coating film forming system having the intermittent coating apparatus.

Conventionally, in the production of a chemical cell such as a lithium ion battery, a coating apparatus for discharging a coating solution of an electrode material having a relatively high viscosity from a nozzle onto a metal foil as a base material to form a coating film is used. Such a coating apparatus includes intermittently coating an electrode material intermittently to form a coating region and a non-coating region alternately (see, for example, Patent Document 1).

In the apparatus for performing intermittent coating disclosed in Patent Document 1, the coating liquid is intermittently discharged from a slot die having a discharge port of a small slit shape. In this apparatus, a relief path is provided by branching from the liquid feed path connected to the slot die from the liquid storage means, and the intermittent coating is performed by repeatedly switching the path by the three-way valve. The coating liquid flowing into the relief path at the time of non-coating is refluxed to the coating liquid storing means.

Patent Document 2 is disclosed as a technique related to the present invention.

Japanese Unexamined Patent Publication No. 2012-30193 Japanese Patent Application Laid-Open No. 11-83719

When performing intermittent coating, it is important to precisely maintain the interval between the discharge port of the slot die and the substrate. This is because, if the discharge port varies with respect to the substrate, a coating region can not be formed with a desired shape with high accuracy.

However, since the intermittent coating is performed by, for example, repeatedly switching the path by the three-way valve, the switching of the path involves a mechanical operation (opening and closing of the pipe). When this vibration is transmitted to the discharge port, the interval between the discharge port and the substrate may vary. This is not preferable as described above.

SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and it is an object of the present invention to provide an intermittent coating apparatus capable of reducing vibration transmitted from a switching means to a nozzle.

According to a first aspect of the present invention, there is provided an intermittent coating apparatus for intermittently coating a coating liquid from a nozzle toward a substrate, the apparatus comprising: a nozzle; a supply pipe connected to the nozzle, Switching means for intermittently discharging the coating liquid from the nozzle toward the substrate by repeatedly switching on / off the supply pipe, a nozzle base on which the nozzle is mounted, And a switching means base on which the means is mounted.

According to a second aspect of the present invention, there is provided a coating apparatus according to the first aspect of the invention, comprising: nozzle moving means for moving the nozzle base to adjust the position of the nozzle with respect to the base material; And a switching means for moving the switching means in the same direction as the moving direction of the switching means.

According to a third aspect of the present invention, in the intermittent coating apparatus according to the second aspect, the nozzle moving means moves the nozzle base in the horizontal direction, and the switching moving means freely moves the switching means in an arbitrary horizontal direction And the movement of the nozzle is transmitted through the supply pipe, thereby moving the switching means in the same direction as the moving direction.

According to a fourth aspect of the present invention, in the intermittent coating apparatus according to any one of the first to fourth aspects, the vibration suppressing means provided in the switching means base for suppressing transmission of vibration from the switching means to the nozzle .

According to a fifth aspect of the present invention, there is provided an intermittent coating apparatus comprising: the intermittent coating apparatus according to any one of claims 1 to 5; and a heat treatment apparatus for performing a heat treatment on the substrate coated with the coating liquid by the intermittent coating apparatus, Drying means, and conveying means for conveying the substrate to the intermittent coating apparatus and the drying means in order.

In the intermittent coating apparatus, the supply pipe between the nozzle and the switching means is set short. This is to quickly reflect the switching of the opening and closing of the supply pipe by the switching means into the intermittent discharge (i.e., discharge / stop) in the nozzle. The members disposed in close proximity to each other are usually placed in the base shape of the same body.

On the other hand, according to the invention of Claims 1 and 5, the nozzles and the switching means disposed in such proximity are placed on the separate nozzle base and switching means base, respectively. The switching of the opening and closing of the supply pipe by the switching means is accompanied by a mechanical change, so that the vibration is hardly transmitted to the nozzle through the base. Vibration of the nozzle deteriorates the precision of the intermittent coating, so that the deterioration in accuracy of such intermittent coating can be suppressed.

According to the invention of claim 2, since the positional relationship between the nozzle and the switching means is unlikely to change, the stress generated in the supply pipe can be reduced. Particularly, in the intermittent coating apparatus, the distance between the nozzle and the switching means is short. Therefore, if the position of the switching means is fixed, a stress is generated in a relatively large supply pipe with the movement of the nozzle. Therefore, the invention of Claim 2 capable of reducing the stress is particularly suitable for the intermittent coating apparatus.

On the other hand, in the invention of claim 2, the switching means moves. Therefore, the relative position between the member on the upstream side (the side opposite to the nozzle) of the switching means, for example, the storing means for storing the coating liquid, and the switching means can be changed. However, from the viewpoint of improving the precision of intermittent coating, it is not necessary to shorten the pipe length on the upstream side of the switching means. Therefore, the pipe length can be set long. If the length of the piping is set long, the stress of the piping due to the movement of the switching means is small, which is not a problem.

According to the invention of claim 3, since the switching means can freely move the switching means in an arbitrary horizontal direction, the positioning of the switching means can be made unnecessary for the nozzle moving means.

Further, when the position of the nozzle is fixed and the intermittent coating is performed, the switching means can move in the horizontal direction due to the switching operation of the switching means, so that the vibration to the nozzle through the switching means base is hardly transmitted.

According to the invention of claim 4, transmission of vibration can be further suppressed.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a diagram showing the overall configuration of a coating film forming system equipped with an intermittent coating apparatus according to the present invention; Fig.
Fig. 2 is a diagram showing a schematic configuration of an intermittent coating apparatus according to the present invention.
3 is a perspective view showing a schematic structure of a part of an intermittent coating apparatus according to the present invention.
4 is a perspective view showing a schematic structure of a part of an intermittent coating apparatus according to the present invention.
5 is a diagram showing a schematic configuration of a part of an intermittent coating apparatus according to the present invention.

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

≪ Overall Construction of Coating Film Forming System >

 1 is a diagram showing the entire configuration of a coating film forming system 1 equipped with an intermittent coating apparatus according to the present invention. In Fig. 1 and the subsequent figures, for ease of understanding, the dimensions and the number of each part are exaggerated or simplified as necessary.

This coating film forming system 1 is an apparatus for manufacturing a lithium ion secondary battery by coating a coating liquid of an active material, which is an electrode material, on a metal foil as a base material and drying the coating liquid. The coating film forming system 1 includes an intermittent coating apparatus 10, a drying unit 70, and a transport mechanism 80. The coating film forming system 1 also includes a control unit 90 for managing the entire system.

The base material 5 is a metal foil that functions as a current collector of the lithium ion secondary battery. In the case of producing the anode of the lithium ion secondary battery in the coating film forming system 1, for example, an aluminum foil (Al) can be used as the base material 5. [ In the case of manufacturing the negative electrode in the coating film forming system 1, copper foil (Cu), for example, can be used as the base material 5. The substrate 5 is a long metal foil and its width and thickness are not particularly limited. For example, the width may be 600 mm to 700 mm and the thickness may be 10 m to 20 m.

The elongated base material 5 is transported in the order of the intermittent coating apparatus 10 and the drying unit 70 by being discharged from the take-up roller 81 and wound up by the take-up roller 82. [ The conveying mechanism 80 is constituted by the take-up roller 81 and the take-up roller 82 and a plurality of auxiliary rollers 83. The number and position of the auxiliary rollers 83 are not limited to those shown in Fig. 1, and can be increased or decreased as necessary.

The drying section 70 performs drying treatment of the coating film of the coating liquid formed on the base material 5 in the intermittent coating apparatus 10. The drying section 70 heats the substrate 5 conveyed by the conveying mechanism 80 to evaporate the solvent from the coating liquid to perform the drying treatment. The drying section 70 is provided with a preheating section for gently raising the coating film of the coating liquid, a main drying section for heating the coating film up to a predetermined temperature to perform the main heating, An annealing portion for removing stress, a cooling portion for cooling the heated coating film, and the like.

<Coating device>

Fig. 2 is a view showing a schematic structure of an intermittent coating apparatus 10 according to the present invention. The intermittent coating apparatus 10 is provided with a coating nozzle 11, a storage tank 20, supply pipes 30 and 37 and a circulation pipe 40 as main elements. The storage tank 20 stores a solution of an active material, which is an electrode material of a lithium ion secondary battery, as a coating solution. In the case of producing the positive electrode in the coating film forming system 1, for example, lithium cobalt oxide (LiCoO ₂ ) as a positive electrode active material, carbon (C) as a conductive additive, polyvinylidene fluoride PVDF) and N-methyl-2-pyrrolidone (NMP) as a solvent are stored. Lithium nickel oxide (LiNiO ₂ ), lithium manganese oxide (LiMn ₂ O ₄ ), lithium iron phosphate (LiFePO ₄ ), or the like may be used as the positive electrode active material in place of lithium cobalt oxide.

On the other hand, when the negative electrode is manufactured in the coating film forming system 1, a mixed liquid of graphite (graphite) as a negative electrode active material, PVDF as a binder, and NMP as a solvent is used as a coating material for a negative electrode material in the storage tank 20 It keeps. Instead of graphite, hard carbon, lithium titanate (Li ₄ Ti ₅ O ₁₂ ), silicon alloy, tin alloy, or the like may be used as the negative electrode active material. Styrene-butadiene rubber (SBR) or the like may be used instead of PVDF as a binder in both the positive electrode material and the negative electrode material, and water (H ₂ O) or the like may be used instead of NMP as a solvent. When SBR is used as a binder and water is used as a solvent, carboxymethyl cellulose (CMC) may be used in combination as a thickening agent. The coating liquid of the cathode material and the cathode material is a slurry in which solid (fine particles) are dispersed and has a viscosity of 1 Pa · s (Pascal second) or more, and generally has thixotropy.

The storage tank 20 may be provided with a stirrer and an air pressure unit. The agitator stirs the coating solution stored in the storage tank 20 to make the concentration distribution uniform. The air pressurizing unit feeds the high pressure air into the vapor phase portion in the storage tank 20 to pressurize the liquid level of the stored coating liquid.

The reservoir tank 20 and the coating nozzle 11 are communicatively connected by supply pipes 30 and 37. The supply pipe 37 supplies the coating liquid stored in the storage tank 20 toward the supply valve 32. The supply piping 30 supplies the coating liquid from the supply valve 32 toward the coating nozzle 11. As the supply pipes 30 and 37, a stainless pipe or a resin pipe (including a flexible pipe, hereinafter the same) can be used. A pump 31 is inserted in the path of the supply pipe 37 and a filter 33 and a syringe 36 are inserted in the path of the supply pipe 30. In addition, the circulation pipe 40 is branched from the path of the supply pipe 37. The proximal end side of the circulation pipe 40 is connected to the supply pipe 37 at a position on the downstream side of the pump 31 (on the side closer to the coating nozzle 11) and the distal end side is connected to the reservoir tank 20.

The pump 31 is provided on the upstream side (the side near the storage tank 20) with respect to the connecting portion of the circulation pipe 40 and is controlled by the control unit 90 to store the pump 31 in the storage tank 20 And the coating liquid of the electrode material is fed to the supply pipe 37. The supply valve 32 is controlled by the control unit 90 to repeatedly open and close the flow path of the supply pipe 30. As a result, supply / stop of the coating liquid to the coating nozzle 11 is repeatedly switched. The filter 33 is sandwiched between the supply valve 32 and the connection portion between the circulation pipe 40 in the path of the supply pipe 30 and flows toward the coating nozzle 11 of the supply pipe 30 The foreign substance is removed from the coating liquid. A syringe 36 is provided between the supply valve 32 and the coating nozzle 11. The syringe 36 is controlled by the control unit 90 to suck the coating liquid from the supply pipe 30 when the supply valve 32 is closed. Thus, the discharge of the coating liquid from the coating nozzle 11 can be quickly stopped.

The coating nozzle 11 is a slit nozzle provided with a discharge port 11a having a slit shape along the width direction of the substrate 5. [ The coating nozzle 11 is coated on the surface of the substrate 5 running from the discharge port 11a while the coating liquid fed via the supply lines 37 and 30 is pressed and supported by the backup roller 12. The pouring nozzle 11 is provided with a nozzle moving mechanism 51 for adjusting the distance between the backup roller 12 and the ejection opening 11a and an attitude adjusting mechanism (not shown) for defining the attitude.

The distal end side of the circulation pipe 40 branched from the path of the supply pipe 37 is connected to the reservoir tank 20. Like the supply pipes 30 and 37, a stainless pipe or a resin pipe can also be used as the circulation pipe 40. The circulation piping 40 conveys the coating liquid discharged from the storage tank 20 and flowing from the supply piping 30 to the storage tank 20. A circulation valve (41) and a filter (43) are fitted in the circulation pipe (40). The circulation valve (41) is controlled by the control unit (90) to open and close the flow path of the circulation pipe (40). The filter 43 is provided between the circulation valve 41 and the reservoir tank 20 to remove foreign matter from the coating solution flowing toward the reservoir tank 20 of the circulation pipe 40.

When the supply valve 32 is opened while the circulation valve 41 is closed, the coating liquid delivered from the storage tank 20 flows over the entire supply piping 37 and 30 and is supplied to the coating nozzle 11.

On the other hand, when the circulation valve 41 is opened while the supply valve 32 is being closed, the coating liquid delivered from the storage tank 20 flows to the middle of the supply pipe 37 and flows into the circulation pipe 40, And is returned to the tank 20. That is, the supply valve 32 repeatedly switches the supply / stop of the coating liquid fed from the storage means to the coating nozzle 11 through the supply pipe 30 so that the coating liquid is supplied from the coating nozzle 11 intermittently As shown in Fig.

The syringe 36 draws the coating liquid from the supply pipe 30 in accordance with the disposal of the supply valve 32. As a result, the coating liquid on the discharge port 11a is sucked to the supply valve 32 side, thereby suppressing the coating liquid from falling off.

The timings of the opening and closing of the supply valve 32 and the circulation valve 41 are appropriately controlled by the control unit 90 so that the coating liquid is intermittently .

In the example of Fig. 2, a pressure gauge 35 is provided. The pressure gauge 35 is installed in the supply pipe 37 at a position between the connection portion with the circulation pipe 40 and the pump 31, for example. The measurement value measured by the pressure gauge 35 is output to the control unit 90. [ The control unit 90 can control the driving speed (rotation speed) of the pump 31 so that the pressure becomes a desired value, for example.

In the intermittent coating apparatus, as described above, by opening and closing the supply valve 32 provided at the base end of the supply pipe 30, the intermittent supply from the paint nozzle 11 provided at the tip of the supply pipe 30 Control the coating. When the supply valve 32 is closed, the syringe 36 sucks the coating liquid from the supply piping 30 to quickly stop the discharge from the coating nozzle 11.

Therefore, the piping length of the supply pipe 30 affects the responsiveness of the intermittent coating. The responsiveness referred to herein refers to the temporal responsiveness from the opening / closing of the supply valve 32 to the discharge / stop of the coating liquid from the coating nozzle 11. This response is lowered with longer pipe length. The reason for this is explained in more detail. Micro-bubbles are included in the coating liquid flowing through the supply pipe 30, and the micro-bubbles act as a cushion to suck the coating liquid falling from the coating nozzle 11 It is difficult. The longer the piping length is, the more microbubbles are contained, so that it becomes more difficult to inhale the coating liquid. Therefore, even if the syringe 36 sucks the coating liquid when the supply valve 32 is closed, if the pipe length is long, the coating liquid may fall from the coating nozzle 11. As a result, the responsiveness is deteriorated.

The pressure change of the coating liquid accompanying opening and closing of the supply valve 32 provided at the base end of the supply pipe 30 is time-consuming to be transmitted to the paint nozzle 11 provided at the tip of the supply pipe 30 Can be considered as a factor of deterioration of response. Even in this point of view, the longer the supply pipe 30 is, the worse the responsiveness is.

In the intermittent coating apparatus, the timing of dispensing / stopping the coating liquid from the coating nozzle 11 affects the formation position and shape of the coating film, so that it is preferable that the response is high. Therefore, in the intermittent coating apparatus, the distance between the supply valve 32 and the coating nozzle 11 is set to be short.

As described above, in the intermittent coating apparatus, since the distance between the supply valve 32 and the coating nozzle 11 is set short, the supply valve 32 and the coating nozzle 11 are usually placed on the same base.

3 is a schematic perspective view showing an example of a part of the intermittent coating apparatus. 3, the reservoir tank 20, the pump 31, the filters 33 and 43, the pressure gauge 35, the syringe 36, and the moving mechanisms 51 and 61 are omitted .

3, the supply valve 32 and the coating nozzle 11 are placed on the separate valve base 60 and the nozzle base 50, respectively, in the present embodiment, have. The nozzle base 50 and the valve base 60 are spaced from each other.

However, since the opening and closing of the supply valve 32 involves a mechanical operation, the supply valve 32 generates vibration due to repeated opening and closing operations. This switching of the opening and closing is performed for several seconds or more, for example, for one second, so that a vibration of several Hz or more occurs.

In the present embodiment, however, the valve base 60 on which the supply valve 32 is mounted is separate from the nozzle base 50 on which the coating nozzle 11 is placed. Therefore, as compared with the structure in which the supply valve 32 and the coating nozzle 11 are placed on the same base, vibration transmitted from the supply valve 32 to the coating nozzle 11 through the base can be suppressed.

If the pouring nozzle 11 vibrates, the accuracy with respect to the shape of the coating film (also referred to as a coating film) is lowered. In this embodiment, therefore, the vibration of the coating nozzle 11 can be suppressed, can do. In other words, in order to improve the accuracy of the shape of the coating film, it is possible to reduce the necessity of employing a valve that is difficult to be vibrated as the supply valve 32, so that a more inexpensive valve can be employed.

As described above, the circulation valve 41 is closed when the supply valve 32 is opened and is opened when the supply valve 32 is closed. Therefore, the circulation valve 41 is also oscillated in the same oscillation as the supply valve 32 . Therefore, as shown in Fig. 3, it is preferable that the circulation valve 41 is also placed on the base separate from the nozzle base 50. [ Thus, the vibration from the supply valve 32 and the circulation valve 41 can be prevented from being transmitted to the coating nozzle 11. In the example of FIG. 3, the supply valve 32 and the circulation valve 41 are placed on the same valve base 60.

The nozzle base 50 and the valve base 60 may be attached to a common base or may be attached to a separate base, respectively. The nozzle base 50 and the hopper 50 are separate from each other and the valve base 60 and the hopper 60 are separate from each other so that the supply nozzle 32 or the circulation valve 41 is provided with the coating nozzle 11, It is possible to further suppress the vibration transmitted to the vehicle.

The syringe 36 may be provided on either the nozzle base 50 or the valve base 60. From the viewpoint of responsiveness, it is preferable that the syringe 36 is provided in the nozzle base 50 because it is preferable to be disposed near the coating nozzle 11. [ On the other hand, suction of the coating liquid by the syringe 36 is also accompanied by a mechanical operation, so that the syringe 36 may be provided in the valve base 60 from the viewpoint of vibration suppression.

<Movement mechanism>

 As described above, the coating nozzle 11 is provided with a nozzle moving mechanism 51 for adjusting the position with respect to the backup roller 12 (see Fig. 2). As the nozzle moving mechanism 51, for example, a known moving mechanism capable of biaxial movement and being actively controlled can be employed. The nozzle moving mechanism 51 is attached to the nozzle base 50 to move the nozzle base 50. As a result, the coating nozzle 11 fixed to the nozzle base 50 is also moved. For example, by moving the pouring nozzle 11 away from the backup roller 12, the space between the pouring nozzle 11 and the backup roller 12 is widened to perform maintenance of the pouring nozzle 11. [

In order to improve the responsiveness in the intermittent coating apparatus, it is necessary to shorten the distance between the supply valve 32 and the coating nozzle. That is, the pipe length of the supply pipe 30 is set to be short. However, in order to allow the pouring nozzle 11 to move smoothly while the position of the supply valve 32 is fixed, a flexible piping can be considered as the supply piping 30, but a flexible piping having a short piping length is generally Low flexibility. Therefore, the kind of piping that can be employed as the supply piping 30 is narrowed, resulting in an increase in cost.

4 is a perspective view showing an example of a part of the intermittent coating apparatus. In FIG. 4, like in FIG. 3, the respective components are appropriately omitted in order to make the drawings easy to see. In this embodiment, as exemplified in Figs. 1 and 4, it is preferable that a valve moving mechanism 61 for moving the supply valve 32 is provided. The moving mechanism 61 for the valve is attached to, for example, the valve base 60 and makes the valve base 60 movable. As a result, the supply valve 32 fixed to the valve base 60 is also movable.

The valve moving mechanism 61 moves the supply valve 32 in the same direction as the moving direction of the nozzle moving mechanism 51. In other words, the valve moving mechanism 61 follows the movement of the coating nozzle 11 to move the supply valve 32. As a result, the coating nozzle 11 can be moved while suppressing the fluctuation of the relative position between the coating nozzle 11 and the supply valve 32. Therefore, the bending stress of the supply pipe 30 caused by the movement of the coating nozzle 11 can be suppressed.

Therefore, for example, a pipe (for example, stainless steel pipe) having a fixed shape can be employed as the supply pipe 30. [ Even flexible piping can be employed that has a short piping length and is relatively difficult to bend. That is, it is possible to increase the kinds of piping that can be adopted.

Also, for example, in the example of Fig. 4, the supply pipe 30 is bent at a substantially right angle. In this intermittent coating apparatus, since the distance between the coating nozzle 11 and the supply valve 32 is short, it is necessary to bend the supply pipe 30 to a very small radius of curvature. It is difficult to bend the flexible pipe with such a small radius of curvature in general flexible pipe. Therefore, in this case, it is preferable to adopt a pipe which is formed into a bent shape in advance, for example, a pipe having a fixed shape such as stainless steel. In other words, by using the valve moving mechanism 61, it is possible to employ a pipe whose shape is fixed as the supply pipe 30, so that the supply valve 32, And the coating nozzle 11 can be increased.

In the present embodiment, since the supply valve 32 is moved, the upstream component (for example, the storage tank 20 or the pump 31) of the supply pipe 30 and the position of the supply valve 32 The relationship is changed. Therefore, it is preferable to adopt a flexible piping for the piping between the element and the supply valve 32. On the upstream side of the supply valve 32, there is little need to limit the length of the piping from the viewpoint of improving the responsiveness in the intermittent coating. Therefore, the length of the flexible pipe employed on the upstream side of the supply valve 32 can be set sufficiently long. Since the pipe length in the initial state can be set long, the bending stress generated in the flexible pipe is small even if the supply valve 32 moves. Therefore, there is no problem even if the position of this element is fixed.

<Specific Example of Moving Mechanism for Valve>

 The valve moving mechanism 61 may employ any moving mechanism that performs a tracking function following the movement of the nozzle moving mechanism 51. [ The follow function of the valve moving mechanism 61 is controlled by the controller 90 when the nozzle moving mechanism 51 and the valve moving mechanism 61 are known moving mechanisms controlled by the controller 90. [ . Alternatively, the nozzle moving mechanism 51 and the valve moving mechanism 61 mechanically interlock with each other, so that the valve moving mechanism 61 may be realized.

It is preferable that the nozzle moving mechanism 51 moves the nozzle base 50 in the horizontal direction and the valve moving mechanism 61 is free to move the supply valve 32 in any horizontal direction. The movement of the coating nozzle 11 is transmitted to the supply valve 32 through the supply pipe 30 so that the supply valve 32 is moved in the direction of movement of the coating nozzle 11 And moves in the same direction.

As the valve moving mechanism 61, a roller structure can be employed. Such a roller structure has a predetermined rolling member (for example, a sphere or the like), and this rolling member is provided between the valve base 60 and the base 63. This rolling member is rotatably fixed to the valve base 60. This rolling member is rotatable so that the valve base 60 is freely movable in any horizontal direction with respect to the base 63. [ The rolling member may be rotatably fixed to the base 63.

When such a valve moving mechanism 61 is used, the supply valve 32 freely moves in the horizontal direction in accordance with the opening / closing operation of itself when the intermittent coating is performed. Therefore, since the vibration energy accompanying the opening and closing of the supply valve 32 is consumed as the horizontal movement of the supply valve 32, the vibration transmitted to the supply pipe 30 side is also suppressed. However, since flexible piping may be employed from the viewpoint of suppressing vibration transmission through the supply piping 30, vibration transmitted to the supply piping 30 is suppressed as described above, and therefore, for example, A pipe formed of stainless steel or the like may be employed.

Since the supply valve 32 freely moves in the horizontal direction, the supply valve 32 is transmitted from the supply valve 32 to the valve base 60 side (and further to the base 63 side) as compared with the case where the supply valve 32 is fixed Vibration is also suppressed. Therefore, the transmission of vibration to the coating nozzle 11 through the base 63 can be further reduced. It is also possible to add a configuration in which the nozzle base 50 and the valve base 60 are connected and connected by a flexible support member.

In addition, it is unnecessary to align the nozzle moving mechanism 51 and the valve moving mechanism 61 with each other. To explain in more detail, for example, a moving mechanism capable of moving in one direction is adopted as the nozzle moving mechanism 51 and the valve moving mechanism 61. At this time, in order to move the pouring nozzle 11 without changing the relative positions of the pouring nozzle 11 and the supply valve 32, the nozzle moving mechanism 51 and the valve moving mechanism 61 are precisely parallel . However, in the example of Fig. 4, the valve moving mechanism 61 is freely movable in any horizontal direction. Therefore, when the coating nozzle 11 is moved, the moving force is transmitted to the supply valve 32 through the supply pipe 30, so that the supply valve 32 is moved in the same direction as the coating nozzle 11 . Therefore, the workability in attaching the valve moving mechanism 61 can be improved.

In the example of Fig. 4, three valve moving mechanisms 61 are provided, and the three valve moving mechanisms 61 support the valve base 60 at three positions. If the valve base 60 is supported at four or more positions, since the valve base 60 is rattled due to a variation in the height of the valve moving mechanism 61, the valve base 60 is supported at three positions here, It is possible to avoid stuttering.

The valve moving mechanism 61 is not limited to the roller structure, and may have a pair of plate members slidable sideways in the horizontal direction. For example, the abutment surfaces of the pair of plate members are brought into contact with each other with a low friction coefficient, so that the pair of plate members can slide relatively sideways. One of the plate members is fixed to the lower surface of the valve base 60, and the other is fixed to the upper surface of the base 63. As a result, the valve base 60 can freely move in any horizontal direction with respect to the base 63.

If the single roller structure is employed, since the contact area between the rolling elements and the valve base 60 or the base 63 is small, they are hard to be worn. Therefore, the life span is relatively long.

<Vibration Suppression Member>

 A vibration suppressing member for suppressing transmission of vibration from the supply valve 32 to the coating nozzle 11 may be provided. For example, as the vibration suppressing member 64, a member formed of rubber, a gel-like material, foamed styrol or the like and absorbing vibration can be used. Fig. 5 is a view schematically showing a schematic configuration of a portion for supporting the supply valve 32. Fig. 5, the vibration suppressing member 64 has a plate-like shape and is sandwiched between the supply valve 32 and the valve base 60. [ This suppresses the transmission of vibration from the supply valve 32 to the valve base 60 and further suppresses the transmission of the vibration from the supply valve 32 to the coating nozzle 11. [ Alternatively, the vibration suppressing member may be disposed between the valve base 60 and the base 63 (between the valve base 60 and the valve moving mechanism 61, or between the valve moving mechanism 61 and the base 63) Or the like). This also makes it possible to suppress the vibration.

The valve moving mechanism 61 freely movable in any horizontal direction as shown in Figs. 4 and 5 can also be regarded as one type of vibration suppressing member since vibration transmission is suppressed.

In the example of Fig. 4, the supply pipe 30 is constituted by a plurality of pipes. The joints of these pipes may be fitted with, for example, rubber, a gel-like material, or a vibration suppressing member formed of foamed styrol or the like to absorb vibration. As a result, the vibration of the supply valve 32 can be prevented from being transmitted to the coating nozzle 11 through the supply pipe 30.

The installation position of the filter in the piping is not limited to the example of the embodiment described above. The connection position of the circulation pipe 40 in the path of the supply pipe 30 and the connecting portion of the pump 31, (32) and the coating nozzle (11). In addition, the filter is not essential and may not be installed.

The coating nozzle 11 is not limited to a slit nozzle having one slit-shaped discharge port 11a, and may have a plurality of slits, or may be a nozzle for discharging a coating liquid from a generally circular discharge port.

The coating liquid to be subjected to the coating process using the technique related to the present invention is not limited to the electrode material of the lithium ion secondary battery. For example, the coating liquid of the solar cell material (electrode material, sealing material) Or a coating liquid containing an insulating film of an electronic material or a protective film, or a catalyst for a fuel cell. The technique relating to the present invention can be suitably applied to the coating of a coating liquid having a relatively high viscosity. Therefore, the technique related to the present invention may be used to apply the coating solution of the pigment or the adhesive.

1: Coating system 5: Base
10: intermittent coating apparatus 11: coating nozzle
30: supply pipe 32: switching means (supply valve)
50: nozzle base 51: nozzle moving means (moving mechanism for nozzle)
60: Switching device base (valve base)
61: switching transfer means (valve transfer mechanism)
70: dryer 80: conveying mechanism

Claims (5)

An intermittent coating apparatus for intermittently coating a coating liquid from a nozzle toward a substrate,
A nozzle,
A supply pipe connected to the nozzle, through which the coating liquid flows toward the nozzle,
Switching means for intermittently discharging the coating liquid from the nozzle toward the substrate by repeatedly switching on / off the supply piping,
A nozzle base on which the nozzle is placed,
And a switching means base which is separate from the nozzle base and on which the switching means is mounted. The method according to claim 1,
Nozzle moving means for moving the nozzle base to adjust a position of the nozzle relative to the base material;
Further comprising a switching means for moving the switching means in the same direction as the moving direction of the nozzle base by the nozzle moving means. The method of claim 2,
The nozzle moving means moves the nozzle base in a horizontal direction,
Wherein the switching means is capable of freely moving the switching means in an arbitrary horizontal direction and the switching means is moved in the same direction as the moving direction by the movement of the nozzle being transmitted through the supply pipe Intermittent coating device. The method according to any one of claims 1 to 3,
Further comprising vibration suppressing means provided in the switching means base for suppressing transmission of vibration from the switching means to the nozzle. An intermittent coating apparatus according to any one of claims 1 to 3,
Drying means for performing a heat treatment on the substrate to which the coating liquid is applied by the intermittent coating apparatus to dry the coating liquid;
And a conveying means for sequentially conveying the substrate to the intermittent coating device and the drying means.

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