KR20140108054A - Aromatic composition for expressing the fragrance of Dendrobium moniliforme - Google Patents

Abstract

The present invention relates to an aromatic composition for expressing fragrances of dendrobium moniliforme including propylene glycol, limonene,transocimene, linalool, dimethyl hydroquinone and methyl salicylate. The aromatic composition of the present invention can increase demand for fragrances by expressing the unique fragrance of dendrobium moniliforme and improving preference, thereby leading to useful application in the fragrance industry.

Description

[0001] The present invention relates to a fragrance composition for reproducing the fragrance of a bamboo curtain (Dendrobium moniliforme)

The present invention relates to perfume compositions which reproduce fragrance of Dendrobium moniliforme . More particularly, the present invention relates to a perfume composition having superior palatability while reproducing the inherent fragrance of bamboo.

Gingko is a perennial plant belonging to the orchidaceae (orchidae). Its scientific name is Dendrobium moniliforme Sw. Several roots are lowered from rootstock and several stems are gathered up to 20cm height. Stems are bumps and nodes. Leaves are 2 ~ 3 year old, slanting, lanceolate and glossy. The surface is dark green and the base is connected to the sheath. Leaves do not run on old stems. From May to June, one or two white or pinkish-scented flowers hang from the upper nodes of old stems. The central calyx leaf is lanceolate and the petal is similar in length to calyx. The color of flower changes much. It is an evergreen perennial plant that grows on the rocky surface of the southern provinces or on the surface of exposed dead trees. It is distributed in China, Japan, and Taiwan.

The flower has one or two white or pinkish-scented flowers at the upper node of the old stem. The central calyx leaf is lanceolate and the petal is similar in length to calyx. The color of flower changes much.

In herbal medicine, all plants except roots are used as medicinal materials. They have antipyretic analgesic effect, are effective for cataracts, and are used as tonic tonic. Dendrobine, mucin, and starch can be included in the bark.

The floral fragrance of the gingko leaves a unique sweet fragrance, but it is loved by many people with its rich and sweet fragrance. Therefore, various methods for reproducing such superior scent incense have been attempted.

In order to reproduce the fragrance of the herbaceous flower, there is usually a solvent extraction method in which the fragrance component is prepared into a concrete state by using a solvent, and the components that are dissolved in the alcohol are selected and re-concentrated to an absolute form. In addition, there is a steam distillation method which can break the cell wall of a plant by using hot water or steam and extract the oil and obtain it as an essential oil type.

However, the above methods must apply heat in the extraction process, and the loss of the fragrance due to this is inevitable, and there may be many differences from the original fragrance of flowers. In addition, the fragrance prepared from the scent of the bamboo leaves has a somewhat metallic smell and does not actually reach the fragrance of natural aroma. Therefore, there has been a continuing need for a perfume composition which can reproduce the scent of bamboo.

As a background of the present invention, Korean Patent Laid-Open Publication No. 10-2010-0031118 (Mar. 19, 2010) discloses an external preparation for skin containing herbal extracts, which can be used for the treatment of atopic dermatitis, contact dermatitis, (Korean Patent Registration No. 10-0539298 (2005.12.28) discloses a skin external preparation containing a herb extract or an extract of Chinese primate as an agent for promoting senescence due to inflammation The present invention relates to a composition for improving inflammation and preventing skin aging, which has an effect of improving inflammation, improving wrinkles and improving elasticity, and having no side effects. However, there is no description of a perfume composition that reproduces the natural fragrance of the ginkgo fragrance as it is.

Korean Patent Publication No. 10-2010-0031118 (Mar. 19, 2010) Korean Patent No. 10-0539298 (December 28, 2005)

Therefore, the present inventors tried to reproduce the fragrance of the bamboo grove by analyzing the directional components of the bark by using the SPME (Solid Phase Micro Extraction) method, which is effective for analyzing the fragrance of living natural products, and recombining the bamboo fragrance to have a favorable feeling. Unlike the conventional extraction method, the SPME method can analyze the fragrance of a living flower without requiring a solvent or heat, so that a smell closer to natural can be obtained, The present invention has been completed.

Accordingly, an object of the present invention is to provide a fragrance composition which can reveal a main component of a scent of scallops, produce a combined scent using the same, reproduce scent of scallops, and have excellent palatability.

Another object of the present invention is to provide a cosmetic composition or composition for external application for skin which contains the above-mentioned perfume composition as a constituent.

Other objects and advantages of the present invention will become more apparent from the following detailed description of the invention, claims and drawings.

According to one aspect of the present invention, there is provided a process for the preparation of propylene glycol, Limonene, trans Ocimene, Linalool, Dimethyl Hydroquinone, Wherein the fragrance composition is reproducible including a scaly musk containing a methyl salicylate.

According to another aspect of the present invention, there is provided a cosmetic composition comprising the perfume composition.

According to still another aspect of the present invention, there is provided an external preparation for skin comprising the above-described perfume composition.

Hereinafter, the present invention will be described in detail.

The present inventors analyzed directional components using the SPME technique (SUPELCO international, Vol. 13, No. 4, p. 9-10) and analyzed the delicate flavor of bamboo flowers. Unlike conventional extraction methods, SPME does not require any solvent or heat, and the adsorbed components on the fiber can be quickly desorbed and injected into the GC-MS column without any special pretreatment. And the analysis time is greatly shortened, so that a smell closer to natural can be obtained.

As a result of analyzing the fragrance components of the gypsum by the SPME technique, it was found that the fragrance of the gypsum was composed of propylene glycol, limonene, trans Ocimene, Linalool, Dimethyl Hydroquinone, and Methyl Salicylate were the main components.

Accordingly, the perfume composition according to the present invention may contain at least one selected from the group consisting of Propylene Glycol, Limonene, trans Ocimene, Linalool, Dimethyl Hydroquinone, Methyl Salicylate).

The perfume composition of the present invention may further comprise at least one selected from the group consisting of Aldehyde C-6, cis-3-Hexenol, Methyl Phenyl Ether, alpha Pinene, Beta pinene, para Cresol Methyl Ether, para Cymene, benzyl alcohol, cis Ocimene, methyl benzoate, phenyl ethyl ketone, (Phenyl Ethyl Alcohol), and beta-Caryophyllene (beta-Caryophyllene).

According to a preferred embodiment of the present invention, the perfume composition of the present invention comprises 7-10% by weight of propylene glycol, 5-10% by weight of limonene, 60 to 75% by weight of trans Ocimene, 3-5% by weight of Linalool, 2-4% by weight of Dimethyl Hydroquinone and 2-4% by weight of Methyl Salicylate 1 to 2 wt.% Of Aldehyde C-6, 0.5 to 1.5 wt.% Of cis-3-hexenol, 0.2 to 0.5 wt.% Of Methyl Phenyl Ether, 0.5 to 1 wt% of alpha pinene, 0.1 to 0.5 wt% of beta pinene, 0.1 to 0.5 wt% of para cresol methyl ether, 0.2 to 0.6 wt% of para cymene, 0.5 to 1% by weight of benzyl alcohol, 0.5 to 2% by weight of cis ocimene, 0.1 to 0.5% by weight of methyl benzoate, 0.1 to 5% by weight of phenyl ethyl alcohol, 0.5-1% by weight, and 0.3 to 0.8% by weight of beta-caryophyllene, and at least one component selected from the group consisting of 0.3 to 0.8% by weight of beta-caryophyllene.

When used in a range outside the above range to reproduce the fragrance of scent, the fragrance similarity of the scent may be lowered and the palatability of the fragrance may be lowered. However, other components are preferably used within the above-mentioned range, but they may be contained in an amount outside the above-described range, so long as they do not significantly affect the fragrance of the bamboo grove and do not affect the reproduction of the bamboo fragrance.

In addition, the perfume composition according to the present invention can be incorporated into a cosmetic composition or a composition for external application for skin, and the present invention provides a cosmetic composition or composition for external application for skin containing the perfume composition according to the present invention.

The blending amount of the perfume composition according to the present invention may be suitably selected and mixed in order to achieve the desired effect according to the conventional techniques in the art, and the formulation of the composition is not particularly limited, and the solution, emulsion, Shape can be taken.

The cosmetic composition includes cosmetics such as various creams, lotions, skins, shampoos, rinses, cleansing, cleansers, soaps, treatments, and essences. Examples of the composition for external application for skin include perfume, But are not limited to, and may be compounded with any of the bases known in the art, including, but not limited to, lotions, soluble powders, suspensions, emulsions, creams, gels, That is, the composition according to the present invention can be applied to various kinds of paper products such as toilet paper, paper towels, napkins, notebooks, notepads and the like, and other products such as mops, toothpaste powder, mask, medical gauze, fabric softener, medical detergent, kitchen detergent, It is also applicable to daily use goods and foods.

In addition, the cosmetic composition and the composition for external application for skin may be mixed with other ingredients without difficulty by those skilled in the art depending on other formulations or use purposes.

As described above, the fragrance composition according to the present invention recovers the inherent natural fragrance of the bark by recombining the fragrance so as to have a favorable feeling by analyzing the directional component of the living flower fragrance by utilizing the SPME technique, Palatability can also be improved. Therefore, according to the present invention, it is possible to produce a large amount of excellent fragrance composition of bamboo fragrance, and the present invention can be very usefully used in fragrance industry field by increasing fragrance demand.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood by those skilled in the art that these embodiments are only for describing the present invention in more detail and that the scope of the present invention is not limited by these embodiments in accordance with the gist of the present invention .

[ Example  One] SPME Analysis of fragrance of gravel by using the law

A fragrant component was adsorbed to a polyacrylate fiber coated with 85 탆 polyacrylate for 2 hours to pick up a fragrant component.

After capturing the fragrance components, the fiber was sealed, transferred to the inlet of GC / MS, desorbed for 2 minutes, and subjected to GC / MS analysis. GC / MS analysis conditions are as follows.

Analysis condition

- Analytical instrument: Agilent 6890 GC

Detector: Agilent 5973N MSD

- Column: DB-5ms (30m * 0.25mm * 0.25μm)

- Mobile phase gas: He

- Injection temperature: 240 ℃

- Detector temperature: 280 ℃

- Oven temperature: 40 to 300 캜 (5 캜 / min)

- Ionization voltage: 70 eV

- Removal time: 5 minutes

As a result, the fragrance components of the bark analyzed by the SPME method are shown in Table 1 below.

Flavor Name Content (% by weight) Propylene Glycol 7.3 Aldehyde C-6 < RTI ID = 0.0 > 1.1 Cis-3-hexenol < / RTI > 0.6 Methyl phenyl ether (Methyl Phenyl Ether) 0.2 Alpha pinene 0.6 Betapinen ( beta Pinene ) 0.1 Para Cresol Methyl Ether < RTI ID = 0.0 > 0.1 Paracimen ( money Cymene ) 0.2 Limonene ( Limonene ) 5.1 Benzyl alcohol ( Benzyl Alcohol ) 0.6 Cis omen cis Ocimene ) 0.9 Transoceanic ( trans Ocimene ) 67.4 Methylbenzoate ( Methyl Benzoate ) 0.1 Rina Rule ( Linalool ) 3.0 Phenyl ethyl alcohol ( Phenyl Ethyl Alcohol ) 0.5 Dimethylhydroquinone ( Dimethyl Hydroquinone ) 2.3 Methyl salicylate ( Methyl Salicylate ) 2.9 Beta Calypso Fillen ( beta Caryophyllene ) 0.4 Etc 6.6 Total content 100

As shown in Table 1, the bark is composed of propylene glycol, limonene, trans Ocimene, Linalool, Dimethyl Hydroquinone, methyl salicylate (Methyl Salicylate) and the like, and these main components account for 88% by weight of the total.

[ Example  2] The results of the analysis showed that the fragrance and natural scent of fragrance Comparative sensory evaluation

The sensory evaluation was performed on 25 normal male and female twenty to forty-five year olds, and the fragrance of the natural incense sample A and the combined fragrance sample B according to the present invention was taken respectively, Question 1) and palatability (question 2). The results are shown in Table 2 below.

Rating agent
Question 1 (similarity) Question 2 (palatability) A B A B CYB Similarity ○ YJS Similarity ○ LHY x ○ JYJ Similarity ○ JHS x ○ KUJ Similarity ○ NSH x ○ OSJ x ○ LYU Similarity ○ YH Similarity ○ JHJ Similarity ○ JHJ Similarity ○ GYJ x ○ KUJ x ○ PAN Similarity ○ NIY x ○ YYJ Similarity ○ CUJ Similarity ○ JMH x ○ BKR Similarity ○ KYJ Similarity ○ PSY Similarity ○ PSY x ○ RYS Similarity ○ NHN x ○ synthesis Similar 15 X 10 6 19 total 25 25

[ Manufacturing example ]

The fragrance composition as shown in Table 3 below was prepared by blending the fragrance composition having similarity to the scent of fragrance as described above.

Perfume containing fragrance compositions recreating the scent of bamboo Content (% by weight) Scent recipe combination fragrance 15 water 5 Pigment Suitable amount Sunscreen Suitable amount Alcohol (Ethyl Alcohol) To 100

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art. It is therefore intended that the scope of the present invention be defined by the appended claims and their equivalents.

Claims (6)

And is characterized by the presence of a bamboo flavor including Propylene Glycol, Limonene, trans Ocimene, Linalool, Dimethyl Hydroquinone, and Methyl Salicylate. ≪ / RTI > The composition of claim 1, wherein the composition is selected from the group consisting of Aldehyde C-6, cis-3-Hexenol, Methyl Phenyl Ether, alpha Pinene, beta Pinene, para Cresol Methyl Ether, para Cymene, Benzyl Alcohol, cis Ocimene, Methyl Benzoate, Phenyl Ethyl Alcohol), and beta-Caryophyllene. The fragrance composition according to claim 1, wherein the fragrance composition further comprises at least one component selected from the group consisting of Phenyl Ethyl Alcohol (Phenyl Ethyl Alcohol) and Beta Calyophyllene. The perfume composition of claim 1, further comprising 7-10% by weight of propylene glycol, 5-10% by weight of limonene, 60-75% by weight of trans ocimene, Characterized in that the scent of the bark is reproduced, including 3-5% by weight of Linalool, 2-4% by weight of Dimethyl Hydroquinone and 2-4% by weight of Methyl Salicylate ≪ / RTI > 4. The composition of claim 3, wherein each of the components comprises 1-2% by weight of Aldehyde C-6, 0.5-1.5% by weight of cis-3-hexenol, 0.2-0.5 wt% of methyl phenyl ether, 0.5-1 wt% of alpha pinene, 0.1-0.5 wt% of beta pinene, 0.1-0.5 wt% of para cresol methyl ether, 0.2 to 0.6 wt% of para cymene, 0.5 to 1 wt% of benzyl alcohol, 0.5 to 2 wt% of cis ocimene, 0.1 to 0.5 wt% of methyl benzoate, 0.5-1% by weight of phenyl ethyl alcohol, and 0.3-0.8% by weight of beta-caryophyllene, to reproduce the scent of bark ≪ / RTI > A cosmetic composition comprising a perfume composition according to any one of claims 1 to 4. A composition for external application for skin containing a perfume composition according to any one of claims 1 to 4.