KR20140057285A - 내부 전자 공여체로서 유용한 치환된 페닐렌 디벤조에이트의 제조 및 중합체 제조용 전촉매 - Google Patents
내부 전자 공여체로서 유용한 치환된 페닐렌 디벤조에이트의 제조 및 중합체 제조용 전촉매 Download PDFInfo
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- KR20140057285A KR20140057285A KR1020147004787A KR20147004787A KR20140057285A KR 20140057285 A KR20140057285 A KR 20140057285A KR 1020147004787 A KR1020147004787 A KR 1020147004787A KR 20147004787 A KR20147004787 A KR 20147004787A KR 20140057285 A KR20140057285 A KR 20140057285A
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- RNHXTCZZACTEMK-UHFFFAOYSA-N methyl 4-ethoxybenzoate Chemical compound CCOC1=CC=C(C(=O)OC)C=C1 RNHXTCZZACTEMK-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- USJZIJNMRRNDPO-UHFFFAOYSA-N tris-decylalumane Chemical compound CCCCCCCCCC[Al](CCCCCCCCCC)CCCCCCCCCC USJZIJNMRRNDPO-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229940035658 visco-gel Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/220,910 US9133286B2 (en) | 2011-08-30 | 2011-08-30 | Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same |
| US13/220,910 | 2011-08-30 | ||
| PCT/US2012/049935 WO2013032651A1 (en) | 2011-08-30 | 2012-08-08 | Production of substituted phenylene dibenzoate for use as internal electron donor and procatalyst for polymer preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140057285A true KR20140057285A (ko) | 2014-05-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147004787A Withdrawn KR20140057285A (ko) | 2011-08-30 | 2012-08-08 | 내부 전자 공여체로서 유용한 치환된 페닐렌 디벤조에이트의 제조 및 중합체 제조용 전촉매 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9133286B2 (enExample) |
| EP (1) | EP2751063A1 (enExample) |
| JP (1) | JP2014529624A (enExample) |
| KR (1) | KR20140057285A (enExample) |
| CN (1) | CN103732571A (enExample) |
| BR (1) | BR112014000860A2 (enExample) |
| MX (1) | MX2014002503A (enExample) |
| RU (1) | RU2014111829A (enExample) |
| WO (1) | WO2013032651A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112016012033B1 (pt) * | 2013-11-27 | 2021-02-09 | W.R. Grace & Co.-Conn | processo de polimerização para copolímeros de impacto |
| EP3596140B1 (en) * | 2017-03-17 | 2024-03-20 | SABIC Global Technologies B.V. | Process for preparing a procatalyst for polymerization of olefins |
| CN120483875B (zh) * | 2025-07-10 | 2025-10-21 | 营口市向阳催化剂有限责任公司 | 取代亚苯基芳族二酯的制备方法及其在催化剂制备中的应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0269453B1 (en) * | 1986-11-28 | 1993-03-17 | Takeda Chemical Industries, Ltd. | A process for producing carboxylic acid esters |
| GB9300318D0 (en) | 1993-01-08 | 1993-03-03 | Oxford Analytical Instr Ltd | Improvements relating to sample monitoring |
| US5948212A (en) | 1996-10-21 | 1999-09-07 | Union Carbide Chemicals & Plastics Technology Corporation | Titanium separation process |
| US6841598B2 (en) * | 2002-08-16 | 2005-01-11 | General Electric Company | Antistatic and antidust agents, compositions thereof, and methods of manufacture |
| KR20060099512A (ko) * | 2003-09-23 | 2006-09-19 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션 | 혼합된 선택성 조절제를 갖는 촉매 조성물 및 프로필렌중합 방법 |
| CN101318886B (zh) * | 2008-07-04 | 2011-05-04 | 浙江理工大学 | 一种邻羟基苯基烷基酮的合成方法 |
| JP6046349B2 (ja) * | 2008-12-31 | 2016-12-14 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 置換フェニレン芳香族ジエステルの製造 |
| US8507717B2 (en) | 2008-12-31 | 2013-08-13 | Dow Global Technologies Llc | Production of substituted phenylene aromatic diesters |
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
-
2011
- 2011-08-30 US US13/220,910 patent/US9133286B2/en not_active Expired - Fee Related
-
2012
- 2012-08-08 BR BR112014000860A patent/BR112014000860A2/pt not_active IP Right Cessation
- 2012-08-08 MX MX2014002503A patent/MX2014002503A/es unknown
- 2012-08-08 JP JP2014528414A patent/JP2014529624A/ja active Pending
- 2012-08-08 WO PCT/US2012/049935 patent/WO2013032651A1/en not_active Ceased
- 2012-08-08 EP EP12750660.8A patent/EP2751063A1/en not_active Withdrawn
- 2012-08-08 KR KR1020147004787A patent/KR20140057285A/ko not_active Withdrawn
- 2012-08-08 RU RU2014111829/04A patent/RU2014111829A/ru not_active Application Discontinuation
- 2012-08-08 CN CN201280039564.5A patent/CN103732571A/zh active Pending
-
2015
- 2015-08-07 US US14/821,171 patent/US20150344597A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US9133286B2 (en) | 2015-09-15 |
| MX2014002503A (es) | 2014-05-28 |
| BR112014000860A2 (pt) | 2017-02-21 |
| WO2013032651A1 (en) | 2013-03-07 |
| US20130053525A1 (en) | 2013-02-28 |
| CN103732571A (zh) | 2014-04-16 |
| RU2014111829A (ru) | 2015-10-10 |
| US20150344597A1 (en) | 2015-12-03 |
| JP2014529624A (ja) | 2014-11-13 |
| EP2751063A1 (en) | 2014-07-09 |
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