KR20120124398A - 비닐아민 포함 중합체 및 아크릴아미드 포함 중합체로 처리하여 종이의 건조 강도를 향상시키는 방법 - Google Patents
비닐아민 포함 중합체 및 아크릴아미드 포함 중합체로 처리하여 종이의 건조 강도를 향상시키는 방법 Download PDFInfo
- Publication number
- KR20120124398A KR20120124398A KR1020127016776A KR20127016776A KR20120124398A KR 20120124398 A KR20120124398 A KR 20120124398A KR 1020127016776 A KR1020127016776 A KR 1020127016776A KR 20127016776 A KR20127016776 A KR 20127016776A KR 20120124398 A KR20120124398 A KR 20120124398A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer
- acrylamide
- daltons
- propyl
- vinylamine
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 319
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 title claims abstract description 129
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims description 36
- 230000008569 process Effects 0.000 title claims description 12
- 230000002708 enhancing effect Effects 0.000 title 1
- 125000002091 cationic group Chemical group 0.000 claims abstract description 65
- 239000000178 monomer Substances 0.000 claims abstract description 44
- 239000007864 aqueous solution Substances 0.000 claims abstract description 37
- 125000000129 anionic group Chemical group 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000000123 paper Substances 0.000 claims description 81
- 239000007787 solid Substances 0.000 claims description 28
- 229920000867 polyelectrolyte Polymers 0.000 claims description 16
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 13
- -1 3- (diethylamino) propyl Chemical group 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 12
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 12
- 230000007062 hydrolysis Effects 0.000 claims description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims description 9
- 239000004815 dispersion polymer Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 claims description 6
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 claims description 6
- ADTJPOBHAXXXFS-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]prop-2-enamide Chemical compound CN(C)CCCNC(=O)C=C ADTJPOBHAXXXFS-UHFFFAOYSA-N 0.000 claims description 6
- GFOCCLOYMMHTIU-UHFFFAOYSA-N n-[3-(diethylamino)propyl]prop-2-enamide Chemical compound CCN(CC)CCCNC(=O)C=C GFOCCLOYMMHTIU-UHFFFAOYSA-N 0.000 claims description 5
- 239000005518 polymer electrolyte Substances 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 3
- WWJCRUKUIQRCGP-UHFFFAOYSA-N 3-(dimethylamino)propyl 2-methylprop-2-enoate Chemical compound CN(C)CCCOC(=O)C(C)=C WWJCRUKUIQRCGP-UHFFFAOYSA-N 0.000 claims description 3
- UFQHFMGRRVQFNA-UHFFFAOYSA-N 3-(dimethylamino)propyl prop-2-enoate Chemical compound CN(C)CCCOC(=O)C=C UFQHFMGRRVQFNA-UHFFFAOYSA-N 0.000 claims description 3
- WIYVVIUBKNTNKG-UHFFFAOYSA-N 6,7-dimethoxy-3,4-dihydronaphthalene-2-carboxylic acid Chemical compound C1CC(C(O)=O)=CC2=C1C=C(OC)C(OC)=C2 WIYVVIUBKNTNKG-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims description 3
- VNLHOYZHPQDOMS-UHFFFAOYSA-N n-[3-(diethylamino)propyl]-2-methylprop-2-enamide Chemical compound CCN(CC)CCCNC(=O)C(C)=C VNLHOYZHPQDOMS-UHFFFAOYSA-N 0.000 claims description 3
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims description 3
- AJURYMCOXVKKFB-UHFFFAOYSA-M trimethyl(3-prop-2-enoyloxypropyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCOC(=O)C=C AJURYMCOXVKKFB-UHFFFAOYSA-M 0.000 claims description 3
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims description 3
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- NFUDTVOYLQNLPF-UHFFFAOYSA-M trimethyl-[3-(2-methylprop-2-enoyloxy)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCCC[N+](C)(C)C NFUDTVOYLQNLPF-UHFFFAOYSA-M 0.000 claims description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 239000000047 product Substances 0.000 description 49
- 239000013055 pulp slurry Substances 0.000 description 15
- 229920002472 Starch Polymers 0.000 description 12
- 239000000654 additive Substances 0.000 description 12
- 235000019698 starch Nutrition 0.000 description 12
- 239000008107 starch Substances 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 8
- 229920006317 cationic polymer Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 239000012452 mother liquor Substances 0.000 description 6
- 229920002401 polyacrylamide Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 229920006318 anionic polymer Polymers 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 4
- 150000003141 primary amines Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920002488 Hemicellulose Polymers 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001408 amides Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000008394 flocculating agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical class N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 235000019463 artificial additive Nutrition 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002801 charged material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 1
- IUWVWLRMZQHYHL-UHFFFAOYSA-N n-ethenylpropanamide Chemical compound CCC(=O)NC=C IUWVWLRMZQHYHL-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 229920000885 poly(2-vinylpyridine) Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- WZAPMUSQALINQD-UHFFFAOYSA-M potassium;ethenyl sulfate Chemical compound [K+].[O-]S(=O)(=O)OC=C WZAPMUSQALINQD-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XVIGJPONQXWIOK-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoyloxy)propyl]azanium Chemical compound CC(=C)C(=O)OCCC[N+](C)(C)C XVIGJPONQXWIOK-UHFFFAOYSA-N 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/35—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
- D21H17/375—Poly(meth)acrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/56—Polyamines; Polyimines; Polyester-imides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29067009P | 2009-12-29 | 2009-12-29 | |
| US61/290,670 | 2009-12-29 | ||
| PCT/US2010/061750 WO2011090672A1 (en) | 2009-12-29 | 2010-12-22 | Process to enhancing dry strength of paper by treatment with vinylamine-containing polymers and acrylamide containing polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120124398A true KR20120124398A (ko) | 2012-11-13 |
Family
ID=44063302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127016776A KR20120124398A (ko) | 2009-12-29 | 2010-12-22 | 비닐아민 포함 중합체 및 아크릴아미드 포함 중합체로 처리하여 종이의 건조 강도를 향상시키는 방법 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20110155339A1 (ja) |
| EP (2) | EP3124695A1 (ja) |
| JP (1) | JP6050122B2 (ja) |
| KR (1) | KR20120124398A (ja) |
| CN (2) | CN102713059B (ja) |
| AU (1) | AU2010343125B2 (ja) |
| BR (1) | BR112012015966B1 (ja) |
| CA (1) | CA2780597C (ja) |
| ES (1) | ES2625625T3 (ja) |
| MX (1) | MX2012006403A (ja) |
| PL (1) | PL2519692T3 (ja) |
| PT (1) | PT2519692T (ja) |
| TW (1) | TWI506182B (ja) |
| WO (1) | WO2011090672A1 (ja) |
| ZA (1) | ZA201205691B (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20150085762A (ko) * | 2014-01-16 | 2015-07-24 | 에코랍 유에스에이 인코퍼레이티드 | 건조 단부 강도용 습윤 단부 화학물질 |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| CN102459760A (zh) * | 2009-06-16 | 2012-05-16 | 巴斯夫欧洲公司 | 提高纸张、纸板和卡纸板干强度的方法 |
| US8636875B2 (en) | 2011-01-20 | 2014-01-28 | Hercules Incorporated | Enhanced dry strength and drainage performance by combining glyoxalated acrylamide-containing polymers with cationic aqueous dispersion polymers |
| CA2837149C (en) * | 2011-06-20 | 2017-01-24 | Basf Se | Process of making paper or paperboard with a dual polymeric retention system |
| CN103132383B (zh) * | 2011-11-25 | 2017-04-12 | 纳尔科公司 | 在造纸中用于改善纸强度助剂性能的浆料预处理 |
| US20130274369A1 (en) * | 2012-04-13 | 2013-10-17 | Basf Se | New cationic polymers |
| BR112015016533B1 (pt) | 2013-01-31 | 2022-06-07 | Championx Usa Inc | Método para recuperação de um fluido de hidrocarboneto de uma formação subterrânea, polímero hidrossolúvel e composição |
| WO2014159233A1 (en) | 2013-03-14 | 2014-10-02 | Ecolab Usa Inc. | Methods for increasing retention and drainage in papermaking processes |
| CN104452455B (zh) | 2013-09-12 | 2019-04-05 | 艺康美国股份有限公司 | 造纸助剂组合物以及增加成纸灰分保留的方法 |
| CN104452463B (zh) * | 2013-09-12 | 2017-01-04 | 艺康美国股份有限公司 | 造纸方法以及组合物 |
| CN108409905B (zh) * | 2013-10-31 | 2021-06-22 | 艺康美国股份有限公司 | 二醛改性的丙烯酰胺类聚合物及其制备方法 |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| US9885155B2 (en) | 2014-04-16 | 2018-02-06 | Solenis Technologies, L.P. | Modified vinylamine containing polymers and their use in papermaking |
| US10442980B2 (en) | 2014-07-29 | 2019-10-15 | Ecolab Usa Inc. | Polymer emulsions for use in crude oil recovery |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| EP3012282B1 (en) * | 2014-10-20 | 2020-10-07 | ABB Power Grids Switzerland AG | Pressboard |
| CN105696414B (zh) * | 2014-11-27 | 2022-08-16 | 艺康美国股份有限公司 | 造纸助剂组合物以及提高纸张抗张强度的方法 |
| FI126610B (en) * | 2015-01-27 | 2017-03-15 | Kemira Oyj | Particle polymer product and its use |
| US9783933B2 (en) * | 2015-04-10 | 2017-10-10 | Solenis Technologies, L.P. | Modified vinylamine-containing polymers and their use in papermaking |
| AU2016283021A1 (en) * | 2015-06-25 | 2017-11-09 | Kemira Oyj | A method for producing a material with a network of at least two polymers, a product thereof and use of the product |
| BR112018017107A2 (pt) | 2016-02-23 | 2019-01-15 | Ecolab Usa Inc | método para aumentar recuperação de óleo cru de uma formação subterrânea, uso de um agente de controle de mobilidade, composição, e, polímero reticulado. |
| WO2017147392A1 (en) | 2016-02-26 | 2017-08-31 | Ecolab Usa Inc. | Drainage management in multi-ply papermaking |
| FR3048436B1 (fr) | 2016-03-03 | 2018-03-23 | S.P.C.M. Sa | Procede de fabrication de papier et de carton |
| CN109072558A (zh) * | 2016-05-13 | 2018-12-21 | 艺康美国股份有限公司 | 薄纸粉尘减少 |
| WO2017214616A1 (en) | 2016-06-10 | 2017-12-14 | Ecolab Usa Inc. | Low molecular weight dry powder polymer for use as paper-making dry strength agent |
| AU2017322438B2 (en) | 2016-09-07 | 2021-01-28 | Kemira Oyj | Method for manufacture of paper, board or the like and use of the composition |
| RU2753445C2 (ru) | 2016-09-16 | 2021-08-16 | Соленис Текнолоджиз, Л.П. | Повышенная эффективность обезвоживания в бумагоделательных системах с использованием микрофибриллированной целлюлозы |
| WO2018055239A1 (en) * | 2016-09-26 | 2018-03-29 | Kemira Oyj | Dry strength composition, its use and method for making of paper, board or the like |
| FI127289B (en) * | 2016-11-22 | 2018-03-15 | Kemira Oyj | Use of a polymer product for controlling precipitation in the manufacture of paper or paperboard |
| JP2020529491A (ja) | 2017-07-31 | 2020-10-08 | エコラブ ユーエスエイ インク | 低分子量アクリラミド系ポリマーを含む粉末の高速溶解のためのプロセス |
| EP3662108A1 (en) | 2017-07-31 | 2020-06-10 | Ecolab Usa Inc. | Dry polymer application method |
| EP3724265A1 (en) | 2017-12-13 | 2020-10-21 | Ecolab USA Inc. | Solution comprising an associative polymer and a cyclodextrin polymer |
| KR20220157974A (ko) * | 2020-03-18 | 2022-11-29 | 케미라 오와이제이 | Gpam 조성물 및 방법 |
| WO2022119644A1 (en) | 2020-12-04 | 2022-06-09 | Agc Chemicals Americas, Inc. | Treated article, methods of making the treated article, and dispersion for use in making the treated article |
| US20240344271A1 (en) * | 2021-08-30 | 2024-10-17 | Ecolab Usa Inc. | Use of modified lignin as a wet end strength additive |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4894119A (en) * | 1985-04-10 | 1990-01-16 | Drew Chemical Corporation | Retention and/or drainage and/or dewatering aid |
| CA1283748C (en) * | 1986-06-25 | 1991-04-30 | Takaharu Itagaki | Vinylamine copolymer, flocculating agent and paper strength increasingagent using the same, as well as process for producing the same |
| JP2863275B2 (ja) * | 1990-06-25 | 1999-03-03 | 三井化学株式会社 | 製紙用添加剤及び紙の抄造方法 |
| DE4335567A1 (de) | 1993-10-19 | 1995-04-20 | Roehm Gmbh | Verfahren zur Herstellung von wasserlöslichen Polymerdispersionen mit hohem Polymeranteil |
| JP3394317B2 (ja) * | 1994-03-31 | 2003-04-07 | 三菱製紙株式会社 | 写真用支持体 |
| SE9502522D0 (sv) * | 1995-07-07 | 1995-07-07 | Eka Nobel Ab | A process for the production of paper |
| DE19627553A1 (de) | 1996-07-09 | 1998-01-15 | Basf Ag | Verfahren zur Herstellung von Papier und Karton |
| JP3807016B2 (ja) * | 1997-03-26 | 2006-08-09 | 栗田工業株式会社 | 製紙用添加剤 |
| US6426383B1 (en) | 1997-05-28 | 2002-07-30 | Nalco Chemical Company | Preparation of water soluble polymer dispersions from vinylamide monomers |
| US6103065A (en) * | 1999-03-30 | 2000-08-15 | Basf Corporation | Method for reducing the polymer and bentonite requirement in papermaking |
| KR100637091B1 (ko) | 1999-04-01 | 2006-10-23 | 바스프 악티엔게젤샤프트 | 양이온성 중합체에 의한 전분의 변성 및 변성된 전분의건조 강화제로서의 용도 |
| JP2001020198A (ja) * | 1999-07-09 | 2001-01-23 | Seiko Kagaku Kogyo Co Ltd | 製紙用添加剤 |
| DE10061483A1 (de) * | 2000-12-08 | 2002-06-13 | Stockhausen Chem Fab Gmbh | Verfahren zur Herstellung von Wasser-in-Wasser-Polymerdispersionen |
| US6824650B2 (en) | 2001-12-18 | 2004-11-30 | Kimberly-Clark Worldwide, Inc. | Fibrous materials treated with a polyvinylamine polymer |
| US6939443B2 (en) | 2002-06-19 | 2005-09-06 | Lanxess Corporation | Anionic functional promoter and charge control agent |
| DE20220979U1 (de) * | 2002-08-07 | 2004-10-14 | Basf Ag | Papierprodukt |
| US20040118540A1 (en) | 2002-12-20 | 2004-06-24 | Kimberly-Clark Worlwide, Inc. | Bicomponent strengtheninig system for paper |
| JP4465646B2 (ja) * | 2003-06-30 | 2010-05-19 | 荒川化学工業株式会社 | 製紙用添加剤および当該製紙用添加剤を用いた紙 |
| DE102004044379B4 (de) | 2004-09-10 | 2008-01-10 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton und Verwendung einer Retentionsmittelkombination |
| DE102004063793A1 (de) | 2004-12-30 | 2006-07-13 | Stockhausen Gmbh | Hoch kationische Polymerdispersionen, Verfahren zu deren Herstellung und deren Verwendung |
| FR2880901B1 (fr) * | 2005-01-17 | 2008-06-20 | Snf Sas Soc Par Actions Simpli | Procede de fabrication de papier et carton de grande resistance a sec et papiers et cartons ainsi obtenus |
| FR2882373B1 (fr) * | 2005-02-24 | 2007-04-27 | Snf Sas Soc Par Actions Simpli | Procede de fabrication de papier et carton de grande resistance a sec et papiers et cartons ainsi obtenus |
| DE102005043800A1 (de) * | 2005-09-13 | 2007-03-22 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton |
| JP4784857B2 (ja) * | 2005-11-02 | 2011-10-05 | 荒川化学工業株式会社 | 紙の製造方法 |
| ES2382574T3 (es) * | 2006-05-18 | 2012-06-11 | Hercules Incorporated | Aductos de adición de Michael como aditivos para papel y fabricación de papel |
| EP1918455A1 (en) | 2006-10-31 | 2008-05-07 | M-real Oyj | Method of producing paper and board |
| BRPI0814754B1 (pt) | 2007-08-02 | 2019-02-05 | Hercules Inc | polímeros contendo vinilamina modificada como aditivos na fabricação de papel |
| AR071441A1 (es) * | 2007-11-05 | 2010-06-23 | Ciba Holding Inc | N- vinilamida glioxilada |
| BRPI0909930A2 (pt) * | 2008-06-19 | 2015-10-20 | Buckman Labor Inc | polímero de poli (n-vinilformamida-co-vinilamina), processo para prover um polímero de vinilamina tendo baixos teores de amidina, composição para colagem de papel, processo para fazer papel e processo para a produção de papel ou papelão |
-
2010
- 2010-12-22 CN CN201080059943.1A patent/CN102713059B/zh active Active
- 2010-12-22 MX MX2012006403A patent/MX2012006403A/es active IP Right Grant
- 2010-12-22 KR KR1020127016776A patent/KR20120124398A/ko not_active Application Discontinuation
- 2010-12-22 EP EP16189885.3A patent/EP3124695A1/en not_active Withdrawn
- 2010-12-22 PL PL10799243T patent/PL2519692T3/pl unknown
- 2010-12-22 CA CA2780597A patent/CA2780597C/en active Active
- 2010-12-22 JP JP2012547151A patent/JP6050122B2/ja not_active Expired - Fee Related
- 2010-12-22 ES ES10799243.0T patent/ES2625625T3/es active Active
- 2010-12-22 PT PT107992430T patent/PT2519692T/pt unknown
- 2010-12-22 WO PCT/US2010/061750 patent/WO2011090672A1/en active Application Filing
- 2010-12-22 CN CN201510471542.1A patent/CN105040517A/zh active Pending
- 2010-12-22 EP EP10799243.0A patent/EP2519692B1/en active Active
- 2010-12-22 US US12/975,441 patent/US20110155339A1/en not_active Abandoned
- 2010-12-22 AU AU2010343125A patent/AU2010343125B2/en active Active
- 2010-12-22 BR BR112012015966-6A patent/BR112012015966B1/pt active IP Right Grant
- 2010-12-28 TW TW099146428A patent/TWI506182B/zh active
-
2012
- 2012-07-27 ZA ZA2012/05691A patent/ZA201205691B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20150085762A (ko) * | 2014-01-16 | 2015-07-24 | 에코랍 유에스에이 인코퍼레이티드 | 건조 단부 강도용 습윤 단부 화학물질 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201137201A (en) | 2011-11-01 |
| TWI506182B (zh) | 2015-11-01 |
| JP6050122B2 (ja) | 2016-12-27 |
| BR112012015966A2 (pt) | 2016-04-19 |
| EP3124695A1 (en) | 2017-02-01 |
| MX2012006403A (es) | 2012-07-10 |
| BR112012015966B1 (pt) | 2020-05-12 |
| CN102713059A (zh) | 2012-10-03 |
| CA2780597C (en) | 2017-04-04 |
| CA2780597A1 (en) | 2011-07-28 |
| ZA201205691B (en) | 2014-01-29 |
| JP2013515877A (ja) | 2013-05-09 |
| CN102713059B (zh) | 2015-09-02 |
| ES2625625T3 (es) | 2017-07-20 |
| US20110155339A1 (en) | 2011-06-30 |
| CN105040517A (zh) | 2015-11-11 |
| EP2519692B1 (en) | 2017-03-15 |
| WO2011090672A1 (en) | 2011-07-28 |
| AU2010343125B2 (en) | 2014-10-16 |
| PL2519692T3 (pl) | 2017-08-31 |
| PT2519692T (pt) | 2017-04-24 |
| AU2010343125A1 (en) | 2012-06-21 |
| EP2519692A1 (en) | 2012-11-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR20120124398A (ko) | 비닐아민 포함 중합체 및 아크릴아미드 포함 중합체로 처리하여 종이의 건조 강도를 향상시키는 방법 | |
| US8636875B2 (en) | Enhanced dry strength and drainage performance by combining glyoxalated acrylamide-containing polymers with cationic aqueous dispersion polymers | |
| CN113529479B (zh) | 通过在含有淀粉的施胶压榨制剂中使用二烯丙基胺丙烯酰胺共聚物来提高纸块体强度的方法 | |
| CN109072557B (zh) | 用于制造纸、纸板或类似物的系统和方法 | |
| CN107109796B (zh) | 提高纸强度的方法 | |
| CN106930142B (zh) | 干强剂组合物以及提高纸张干强度的方法 | |
| CN107849815B (zh) | 制造纸和纸板的方法 | |
| WO2009136024A2 (fr) | Procédé de fabrication de papier et carton | |
| CN115516030B (zh) | 用于增加湿强度和干强度的组合物和方法 | |
| CN102226324B (zh) | 生产纸张的方法 | |
| KR20180072706A (ko) | 폴리아크릴아미드계 제지용 첨가제 및 그의 제조 방법, 및 종이의 제조 방법 | |
| US10822462B2 (en) | Paper product and method for increasing the strength thereof | |
| CA3037000A1 (en) | Increased drainage performance in papermaking systems using microfibrillated cellulose | |
| CA3099514A1 (en) | Paper strength improving composition, manufacture thereof and use in paper making | |
| WO2018063273A1 (en) | Drainage system and process for manufacturing paper product or the like |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| N231 | Notification of change of applicant | ||
| A201 | Request for examination | ||
| AMND | Amendment | ||
| E902 | Notification of reason for refusal | ||
| AMND | Amendment | ||
| E601 | Decision to refuse application | ||
| E601 | Decision to refuse application | ||
| E801 | Decision on dismissal of amendment |