KR20090026150A - High temperature polyethylene solution polymerization process - Google Patents
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Abstract
Description
<상호 참조 언급><Cross Reference Reference>
본원은 2006년 5월 17일자로 출원된 미국 가출원 제60/801,182호의 이익을 청구한다.This application claims the benefit of US Provisional Application No. 60 / 801,182, filed May 17, 2006.
올레핀 중합을 위한 보다 높은 온도의 용액 방법은 처리량 증가, 탈휘발화에 필요한 에너지 감소 및 보다 높은 이들 온도에 의한 부착물 감소로 인하여 매우 바람직하다. 지글러-나타 촉매계가 상업적으로 고온에서 수행될 수 있지만, 이들 촉매는 불량한 효율 및 승온에서의 불량한 공단량체 도입을 겪는다. 뿐만 아니라, 지글러-나타 촉매로부터 승온에서 제조된 중합체는 확대된 분자량 분포를 가지며, 이는 그의 많은 용도에서의 사용 적합성을 제한한다. 통상의 지글러-나타 촉매는 전형적으로 다수 유형의 촉매종으로 이루어지며, 이들 각각은 상이한 금속 산화 상태 및 리간드와의 상이한 배위 환경을 갖는다. 이러한 불균일 계의 예는 공지되어 있으며, 이는 유기알루미늄 및 유기알루미늄할라이드 보조촉매로 활성화된, 염화마그네슘 상에 지지된 염화티탄과 같은, 유기금속 보조촉매로 활성화된 금속 할라이드를 포함한다. 이들 계는 1종 초과의 촉매종을 함유하기 때문에, 상이한 활성을 갖는 중합 자리 및 중합체 사슬 내 공단량체를 도입하는 다양한 능력을 갖는다. 이러한 다중-자리 화학의 결과는 중합체 사슬 구조의 조절이 불량한 생성물이다. 또한, 개별 촉매 자리에서의 차이는 일부 자리에서 고분자량을, 또한 다른 자리에서 저분자량을 갖는 중합체를 생성하여, 넓은 분자량 분포 및 불균일한 조성을 갖는 중합체를 초래한다. 불균일성으로 인해, 중합체의 기계적 및 다른 특성이 요망되는 것보다 열등할 수 있다.Higher temperature solution processes for olefin polymerization are highly desirable due to increased throughput, reduced energy required for devolatilization and reduced deposits due to these higher temperatures. Although Ziegler-Natta catalyst systems can be carried out commercially at high temperatures, these catalysts suffer from poor efficiency and poor comonomer introduction at elevated temperatures. In addition, polymers prepared at elevated temperatures from Ziegler-Natta catalysts have an extended molecular weight distribution, which limits their suitability for use in many applications. Conventional Ziegler-Natta catalysts typically consist of a plurality of types of catalyst species, each of which has a different metal oxidation state and a different coordination environment with the ligand. Examples of such heterogeneous systems are known and include metal halides activated with organometallic cocatalysts, such as titanium chloride supported on magnesium chloride, activated with organoaluminum and organoaluminum halide cocatalysts. Because these systems contain more than one catalytic species, they have a variety of capacities for introducing comonomers in polymer chains and polymer chains with different activities. The result of this multi-site chemistry is a product with poor control of the polymer chain structure. In addition, differences in individual catalyst sites produce polymers having high molecular weight at some sites and low molecular weight at other sites, resulting in polymers having a broad molecular weight distribution and non-uniform composition. Due to the heterogeneity, the mechanical and other properties of the polymer may be inferior to what is desired.
보다 최근에는, 잘 정의된 금속 착물, 특히 구속 기하구조의 촉매 (CGC), 메탈로센 및 포스트-메탈로센 등의 전이 금속 착물을 기재로 하는 촉매 조성물이 높은 공단량체 도입률 및 좁은 분자량 분포를 갖는 생성물을 제공하는 것으로 나타났다. 그러나, 이들 촉매는 흔히 불량한 고온 안정성을 가지며, 또한 상승된 중합 온도에서 불량한 효율을 겪는다. 또한, 이들 촉매로부터 형성된 중합체의 분자량은 흔히 온도 증가에 따라, 특히 상당량의 공단량체 (저밀도)를 함유하는 중합체의 경우, 극적으로 감소한다. 즉, 대부분의 올레핀 중합 촉매가, 에틸렌/α-올레핀 공중합체 중에 보다 고도로 α-올레핀을 도입하는 능력은, 반응성 비, r1이 중합 온도에 따라 달라진다는 사실로 인하여, 중합 온도의 증가에 따라 감소한다.More recently, catalyst compositions based on well-defined metal complexes, especially transition metal complexes such as constrained geometry catalysts (CGCs), metallocenes and post-metallocenes, have shown high comonomer introduction rates and narrow molecular weight distributions. It was shown to provide a product having. However, these catalysts often have poor high temperature stability and also suffer poor efficiency at elevated polymerization temperatures. In addition, the molecular weight of polymers formed from these catalysts often decreases dramatically with increasing temperature, especially for polymers containing significant amounts of comonomers (low density). That is, the ability of most olefin polymerization catalysts to introduce higher α-olefins into the ethylene / α-olefin copolymer more highly depends on the increase in polymerization temperature due to the fact that the reactivity ratio, r 1 , depends on the polymerization temperature. Decreases.
촉매의 반응성 비는, 예를 들어 문헌 ["Linear Method for Determining Monomer Reactivity Ratios in Copolymerization", M. Fineman and S. D. Ross, J. Polymer Science, 5, 259 (1950)] 또는 ["Copolymerization", F. R. Mayo and C. Walling, Chem. Rev., 46, 191 (1950)]에 기재된 기술과 같은 공지된 방법에 의해 얻을 수 있다. 널리 사용되는 하나의 공중합 모델은 하기 반응식을 기초로 한다.Reactivity ratios of catalysts are described, for example, in "Linear Method for Determining Monomer Reactivity Ratios in Copolymerization", M. Fineman and SD Ross, J. Polymer Science, 5, 259 (1950) or in "Copolymerization", FR Mayo and C. Walling, Chem. Rev., 46, 191 (1950)]. One widely used copolymerization model is based on the following scheme.
상기 식에서, Mi는 "i"로서 임의로 명명한 단량체 분자를 나타내고, 여기서 i = 1, 2이며, M2 *는 단량체 i가 가장 최근에 결합된 성장하는 중합체 사슬을 나타낸다. Wherein, M i represents the named monomer molecule optionally as "i", and where i = 1, 2, M 2 * represents a polymer chain growing the i monomers are coupled to the last.
kij값은 기재된 반응에 대한 속도 상수이다. 예를 들어, 에틸렌/프로필렌 공중합에서, k11은 앞서 삽입된 단량체 단위 또한 에틸렌인 성장하는 중합체 사슬 내에 에틸렌 단위가 삽입되는 속도를 나타낸다. 반응성 비는, "r1 = k11/k12" 및 "r2 = k22/k21"을 따르며, 상기 식 에서 k11, k12, k22 및 k21은 마지막에 중합된 단량체가 에틸렌 (k1x) 또는 프로필렌 (k2x)인 촉매 자리에 대한 에틸렌 (1) 또는 프로필렌 (2) 부가에 대한 속도 상수이다.The k ij value is the rate constant for the reaction described. For example, in ethylene / propylene copolymerization, k 11 represents the rate at which ethylene units are inserted into the growing polymer chain, where the previously inserted monomeric units are also ethylene. Reactivity ratios follow "r 1 = k 11 / k 12 " and "r 2 = k 22 / k 21 ", where k 11 , k 12 , k 22 and k 21 indicate that the last polymerized monomer is ethylene Rate constant for the addition of ethylene (1) or propylene (2) to a catalyst site that is (k 1x ) or propylene (k 2x ).
올레핀 중합에 사용하기 위한, 3 내지 6족 또는 란탄족 금속 착물, 바람직하게는 2가 루이스(Lewis) 염기 킬레이트화 기를 함유하는 브릿징된 2가 방향족 리간드의 4족 금속 착물을 기재로 한 특정 포스트 메탈로센 촉매 조성물이 USP 6,827,976 및 US 2004/0010103에 개시되어 있다. 일반적으로, 이들 금속 착물은 승온에서의 용액 중합에 통용된다. 그러나, 에틸렌/α-올레핀 공중합체의 제조시 보다 높은 반응 온도에서의 이들의 사용은 흔히 높은 I10/I2를 갖는 중합체를 생성하는데, 이는 사용되는 중합 조건 하에 동일계에서 형성되는 장쇄 단량체의 높은 도입 수준 (장쇄 분지 형성)으로 인한 것으로 여겨진다. 많은 용도에서, 이러한 장쇄 분지형성의 존재는 좁은 분자량 분포를 유지하면서 증가된 가공능 및 생강도(green-strength)로 인해 유리한 특성을 갖는 중합체 생성물을 제공할 수 있다. 그러나, 필름, 섬유 및 접착제 등의 특정 다른 용도에서는, 높은 수준의 장쇄 분지형성이 바람직하지 않을 수 있다. 특히, 이러한 중합체로부터 제조된 필름의 보다 불량한 인열 특성, 불량한 섬유 형성 및 연신 특성, 및 감소된 고온 점착 강도는 증가된 I10/I2값에 상관될 수 있다. 따라서, 우수한 고온 작업 조건을 유지하면서 보다 낮은 I10/I2값을 갖는 에틸렌과 1종 이상의 C3-20 α-올레핀의 인터폴리머(interpolymer)를 제조하는 능력을 갖는 포스트 메탈로센 촉매를 제공하는 것이 바람직하다.Specific posts based on Group 4 metal complexes of bridged divalent aromatic ligands containing group 3 to 6 or lanthanide metal complexes, preferably divalent Lewis base chelating groups, for use in olefin polymerization Metallocene catalyst compositions are disclosed in USP 6,827,976 and US 2004/0010103. In general, these metal complexes are commonly used for solution polymerization at elevated temperatures. However, their use at higher reaction temperatures in the preparation of ethylene / α-olefin copolymers often results in polymers having high I 10 / I 2 , which is high in the in-situ of the long chain monomers formed in situ under the polymerization conditions used. It is believed to be due to the level of entry (long chain branching). In many applications, the presence of such long chain branching can provide polymer products with advantageous properties due to increased processability and green-strength while maintaining a narrow molecular weight distribution. However, for certain other applications, such as films, fibers and adhesives, high levels of long chain branching may be undesirable. In particular, the poorer tearing properties, poorer fiber formation and stretching properties, and reduced hot tack strength of films made from such polymers can be correlated to increased I 10 / I 2 values. Thus, there is provided a post metallocene catalyst having the ability to prepare interpolymers of ethylene with one or more C 3-20 α-olefins with lower I 10 / I 2 values while maintaining good high temperature operating conditions. It is desirable to.
또한, 이러한 부류의 포스트 메탈로센 금속 착물의 지방족 또는 환식지방족 탄화수소 용매 중에서의 용해도는 흔히 요망되는 것보다 낮다. 촉매 용해도는 촉매 효율을 최대화하고, 촉매 수송 부피를 감소시키기 위해 산업적 관점에서 매우 중요하다. 주어진 부피의 용매 중에 용해될 수 있는 금속 착물의 양이 많을수록 저장 및 수송 비용이 보다 크게 감소된다. 또한, 용매 중의 불순물의 자연 발생으로 인한 촉매 피독(catalyst poisoning)은 농도가 제한됨에 따라 현저하게 더 큰 문제가 된다. 많은 부분의 촉매가 피독으로 인해 희생되거나 손실된다.In addition, the solubility of aliphatic or cyclic aliphatic hydrocarbon solvents of this class of post metallocene metal complexes is often lower than desired. Catalyst solubility is very important from an industrial point of view to maximize catalyst efficiency and reduce catalyst transport volume. The greater the amount of metal complex that can be dissolved in a given volume of solvent, the greater the reduction in storage and transportation costs. In addition, catalyst poisoning due to the spontaneous generation of impurities in the solvent becomes a significantly greater problem as concentrations are limited. Many of the catalysts are sacrificed or lost due to poisoning.
따라서, 상승된 반응 온도에서 증가된 효율로 에틸렌/α-올레핀 공중합체를 형성하고 및 감소된 또는 낮은 I10/I2를 갖는 중합체를 형성할 수 있는 촉매 조성물의 선택이 매우 요망된다. 증가된 지방족 또는 환식지방족 탄화수소 중에서의 용해도를 갖는 촉매의 사용이 또한 매우 요망된다.Therefore, it is highly desirable to select catalyst compositions that can form ethylene / a-olefin copolymers with increased efficiency at elevated reaction temperatures and form polymers having reduced or low I 10 / I 2 . The use of catalysts with increased solubility in aliphatic or cyclic aliphatic hydrocarbons is also highly desired.
US 2005/0215737 A1에는, 높은 에틸렌 전환율로 에틸렌-부텐 및 에틸렌-프로필렌 인터폴리머를 제조하기 위한 올레핀의 연속적 용액 중합 방법이 개시되어 있다.US 2005/0215737 A1 discloses a process for the continuous solution polymerization of olefins for producing ethylene-butene and ethylene-propylene interpolymers at high ethylene conversion.
특히 연속적 용액 방법에서 고분자량 폴리올레핀을 산업적으로 제조하는 경우, 비교적 높은 반응기 온도의 조건 하에, 높은 고형분을 갖는 반응기에서 올레핀 단량체의 중합체로의 높은 전환율로, 모두 높은 촉매 효율로, 중합 반응을 수행하는 것이 특히 바람직하다. 상기 공정 요건의 조합은 적합하게 사용될 수 있는 금속 착물의 선택을 심히 제한한다. 보다 덜한 요구 조건 하에 사용하기에 적합한 금속 착물은 사실 상업적인 공정 조건 하에 사용하기 허용가능하지 않을 수 있다. 보다 장쇄의 공단량체를 도입하는 능력이 제한된 넓은 온도 범위에서 비교적 우수한 공단량체 도입자인 금속 착물이 특히 요망된다.Particularly for the industrial production of high molecular weight polyolefins in a continuous solution process, under the conditions of a relatively high reactor temperature, the polymerization reaction is carried out at a high conversion rate of the olefin monomer to the polymer in a reactor having a high solids content, all at a high catalytic efficiency. Is particularly preferred. The combination of these process requirements severely limits the choice of metal complexes that can be suitably used. Metal complexes suitable for use under lesser requirements may in fact not be acceptable for use under commercial process conditions. Particularly desirable are metal complexes which are relatively good comonomer introducers over a wide temperature range with limited ability to introduce longer chain comonomers.
WO 99/45041에는, 비배위 음이온성 보조촉매와 브릿징된 하프노센 착물을 사용하는 또다른 올레핀의 연속적 용액 중합 방법이 개시되어 있다. 생성된 중합체는 상당량의 공단량체를 함유하였지만, 촉매 효율은 비교적 낮았고, 사슬 전달제의 부재 하에서도 중합체 분자량이 바람직한 것보다 낮았다.WO 99/45041 discloses another process for the continuous solution polymerization of olefins using noncoordinated anionic cocatalysts and bridged hafnocene complexes. The resulting polymers contained significant amounts of comonomers, but the catalyst efficiency was relatively low and the polymer molecular weight was lower than desired even in the absence of a chain transfer agent.
WO 03/102042에는, 인데노인돌릴 전이 금속 착물을 사용하여 약 130℃를 초과하는 온도에서 폴리올레핀을 제조하는 올레핀의 고온 용액 중합 방법이 개시되어 있다. 하나의 실시예에서는, 에틸렌과 1-헥센의 공중합을 180℃에서 수행하여 비교적 낮은 촉매 효율로 불량한 공단량체 도입 (밀도 = 0.937 g/cm3)을 갖는 중합체의 형성을 초래하였다.WO 03/102042 discloses a high temperature solution polymerization process of olefins for producing polyolefins at temperatures in excess of about 130 ° C. using indenoindolyl transition metal complexes. In one example, copolymerization of ethylene and 1-hexene was performed at 180 ° C. resulting in the formation of a polymer with poor comonomer incorporation (density = 0.937 g / cm 3 ) with relatively low catalyst efficiency.
본 발명자들은 본 발명에서, 특정 금속 착물이, 비교적 낮은 I10/I2값 (감소된 장쇄 분지 형성의 지표임)을 유지하면서 비교적 다량의 도입된 C3-8 α-올레핀 공단량체를 함유하는 비교적 고분자량의 에틸렌 함유 인터폴리머를 제조하기 위한 용액 중합 방법에 사용될 수 있음을 발견하였다. 또한, 이러한 금속 착물의 지방족 또는 환식지방족 탄화수소 중에서의 용해도 (메틸시클로헥산, 헥산 또는 혼합 헥산 중의 20℃에서의 용해도로 측정됨)는 매우 예측불가능하게 높은 것으로 나타났다. 따라서, 본 발명에서는 이러한 올레핀 중합체 생성물, 특히 매우 높은 촉매 효율로 감소된 I10/I2값을 갖는 고분자량 폴리에틸렌 인터폴리머를 제조하는 방법이 제공된다.We believe that in the present invention, certain metal complexes contain relatively large amounts of introduced C 3-8 α-olefin comonomers while maintaining relatively low I 10 / I 2 values (which are indicative of reduced long chain branching formation). It has been found that it can be used in a solution polymerization process to produce relatively high molecular weight ethylene containing interpolymers. In addition, the solubility (measured as solubility at 20 ° C. in methylcyclohexane, hexane or mixed hexanes) in aliphatic or cyclic aliphatic hydrocarbons of these metal complexes was found to be very unpredictably high. Thus, the present invention provides a process for producing such olefin polymer products, in particular high molecular weight polyethylene interpolymers having reduced I 10 / I 2 values with very high catalytic efficiency.
발명의 요약Summary of the Invention
본 발명에 따라, 에틸렌/α-올레핀 인터폴리머, 특히 에틸렌과 1-부텐, 1-헥센 또는 1-옥텐의 공중합체 제조를 위한 매우 효율적인 용액 중합 방법에 사용될 수 있는 특정 금속 착물이 본 발명에서 제공된다. 또한, 증가된 지방족 또는 환식지방족 탄화수소 중에서의 용해도로 인한 높은 생산성 및 높은 중합 효율을 특징으로 하는 특정 금속 착물이 본 발명에서 제공된다. 본 발명의 최종 실시양태에서는, 바람직한 범위의 물리적 특성, 주로 감소된 I10/I2를 갖는 상기 에틸렌 인터폴리머의 제조를 위한 개선된 고온 연속적 용액 중합 방법이 본 발명에서 제공된다.According to the invention, certain metal complexes are provided in the present invention which can be used in highly efficient solution polymerization processes for the preparation of ethylene / a-olefin interpolymers, in particular copolymers of ethylene with 1-butene, 1-hexene or 1-octene. do. Also provided herein are certain metal complexes characterized by high productivity and high polymerization efficiency due to increased solubility in aliphatic or cyclic aliphatic hydrocarbons. In a final embodiment of the present invention, an improved high temperature continuous solution polymerization process for the preparation of said ethylene interpolymers having a preferred range of physical properties, mainly reduced I 10 / I 2 , is provided herein.
보다 구체적으로는, 본 발명에 따라, 비교적 낮은 I10/I2를 갖는, 비교적 고분자량 (상응하는 낮은 용융 지수와 함께) 및 높은 수준의 단량체 도입 (저밀도)을 갖는 인터폴리머를 제조할 수 있다. 중합체를 높은 촉매 효율로 고온, 고 전환율 조건 하에 제조할 수 있다.More specifically, according to the present invention, interpolymers with relatively low I 10 / I 2 , with relatively high molecular weight (with corresponding low melt index) and high levels of monomer introduction (low density) can be prepared. . The polymer can be prepared under high temperature, high conversion conditions with high catalytic efficiency.
본 발명은 특히, 금속 착물, 활성화 보조촉매, 임의로는 사슬 전달제, 및 1종 이상의 C2 -20 α-올레핀을 포함하는 반응 혼합물을 용액 중합 조건 하에 작동되는 반응기에 연속적으로 첨가하고, 중합체 생성물을 이로부터 연속적으로 또는 반-연속적으로 제거하는 연속적 용액 중합 조건 하에 사용하기에 특히 유리하다. 일 실시양태에서, 본 발명은 낮은 I10/I2 및 감소된 장쇄 분지를 갖는, 에틸렌과 1종 이 상의 C3-8 α-올레핀, 바람직하게는 에틸렌과 1-부텐, 에틸렌과 1-헥센, 또는 에틸렌과 1-옥텐의 공중합체를 제조하는 데 사용된다. 또한, 본 발명의 방법에서는 1종 초과의 금속 착물 또는 화합물을 포함하는 촉매 조성물 및/또는 다중 반응기를, 임의로는 사슬 이동제와 함께 사용할 수 있다.The present invention in particular, the metal complexes, activated co-catalyst, optionally a chain transfer agent, and at least one C 2 -20 and the reaction mixture containing α- olefin continuously added to a reactor operating under solution polymerization conditions, the polymer product Is particularly advantageous for use under continuous solution polymerization conditions in which it is removed continuously or semi-continuously therefrom. In one embodiment, the invention relates to ethylene and at least one C 3-8 α-olefin, preferably ethylene and 1-butene, ethylene and 1-hexene, having low I 10 / I 2 and reduced long chain branching. Or to prepare a copolymer of ethylene and 1-octene. In addition, in the process of the present invention, catalyst compositions and / or multiple reactors comprising more than one metal complex or compound can be used, optionally with chain transfer agents.
본 발명은 특히, 전선 및 케이블의 절연층에서, 특히 매체 및 고전압 용품에서, 필름 (다층 및 단일 성분 필름 포함)에서, 섬유 및 다른 압출 용품에서, 또한 접착제의 성분으로서 사용되는 수지의 제조에 적합하다.The invention is particularly suitable for the production of resins used in the insulation layers of wires and cables, in particular in media and high voltage articles, in films (including multi-layer and single component films), in fibers and other extruded articles, and also as components of adhesives. Do.
도 1은, 여러 금속 착물에 대한 반응기 온도의 함수로서의 에틸렌/옥텐 공중합체의 I10/I2값을 나타낸다.1 shows the I 10 / I 2 values of ethylene / octene copolymers as a function of reactor temperature for various metal complexes.
본원에서 원소 주기율표에 대한 모든 언급은 CRC 프레스 인코포레이티드(CRC Press, Inc.)에 의해 발행되고 저작권 소유된 원소 주기율표 (2003)를 지칭한다. 또한, 족(들)에 대한 임의의 언급은 족 번호부여에 IUPAC 시스템을 이용하는 상기 원소 주기율표에 반영된 족(들)의 언급이다. 달리 언급되지 않는 한, 당업계의 맥락 또는 관례로부터 암시되는 바, 모든 부 및 백분율은 중량 기준이며 모든 테스트 방법은 본원 출원일 당시에 통용되는 것이다. 미국 특허 실무를 위해, 본원에서 언급된 모든 특허, 특허 출원 또는 공보의 내용은 특히 합성 기술, 정의 (본원에서 제공된 임의의 정의와 상충되지 않는 범위까지) 및 당업계의 일반적 지식에 대하여, 그 전체가 본원에 참고로 도입된다 (또는 그 해당 US 버전이 이와 같이 참고로 도입됨).All references to the Periodic Table of Elements herein refer to the Periodic Table of Elements (2003) published and copyrighted by CRC Press, Inc. Also, any reference to the group (s) is that of the group (s) reflected in the Periodic Table of the Elements using the IUPAC system for group numbering. Unless otherwise stated, all parts and percentages are by weight and all test methods are current as of the filing date, as implied from the context or practice of the art. For the purposes of US patent practice, the content of all patents, patent applications or publications referred to herein is in its entirety, especially with regard to synthetic techniques, definitions (to the extent not in conflict with any definitions provided herein) and general knowledge in the art. Is incorporated herein by reference (or its corresponding US version is hereby incorporated by reference).
용어 "포함하는" 및 그의 파생어는, 그것이 본원에서 개시되었는지의 여부에 관계 없이, 임의의 추가 성분, 단계 또는 절차의 존재를 배제하도록 의도되지 않는다. 의심을 피하기 위해, 용어 "포함하는"을 사용하여 본원에서 청구된 모든 조성물은 달리 언급되지 않는 한, 중합체성이든 다른 것이든 관계 없이 임의의 추가 첨가제, 보조제, 또는 화합물을 포함할 수 있다. 반대로, 용어 "~를 주성분으로 하는"은 임의의 앞선 언급의 범위에서, 작업능에 필수적이지 않은 것들을 제외하고, 임의의 다른 성분, 단계 또는 절차를 배제한다. 용어 "~로 이루어진"은 구체적으로 서술되거나 나열되지 않은 임의의 성분, 단계 또는 절차를 배제한다. 용어 "또는"은, 달리 언급되지 않는 한, 개별적으로 나열된 요소 뿐만 아니라 임의의 조합을 지칭한다.The term “comprising” and derivatives thereof is not intended to exclude the presence of any additional component, step or procedure, whether or not it is disclosed herein. For the avoidance of doubt, all compositions claimed herein using the term "comprising" may include any additional additives, adjuvants, or compounds, whether polymeric or otherwise, unless stated otherwise. In contrast, the term "based on" excludes any other component, step, or procedure, except those not essential to workability, in the scope of any preceding statement. The term "consisting of" excludes any component, step or procedure not specifically described or listed. The term “or”, unless stated otherwise, refers to any combination as well as individually listed elements.
달리 구체적으로 명시되지 않는 한, 화학적 화합물에 대하여 본원에서 사용되는 단수형은 모든 이성질체 형태를 포함하고 그 반대도 마찬가지이다 (예를 들어, "헥산"은 헥산의 모든 이성질체를 개별적으로, 또는 총체적으로 포함함). 용어 "화합물" 및 "착물"은 유기-, 무기- 및 유기금속 화합물을 지칭하기 위해 본원에서 상호교환가능하게 사용된다. 용어 "원자"는 이온 상태와 무관하게, 즉 그것이 전하를 갖거나 부분 전하를 갖거나 또는 또다른 원자에 결합되었는지에 관계 없이 원소의 가장 작은 구성요소를 지칭한다. 용어 "헤테로원자"는 탄소 또는 수소 이외의 원자를 지칭한다. 바람직한 헤테로원자는 F, Cl, Br, N, O, P, B, S, Si, Sb, Al, Sn, As, Se 및 Ge를 포함한다. 용어 "무정형"은 시차 주사 열량측정법(DSC) 또는 동등한 기술에 의해 측정되는 결정성 융점을 갖지 않는 중합체를 지칭한다.Unless specifically stated otherwise, the singular forms used herein for the chemical compounds include all isomeric forms and vice versa (eg, "hexane" includes all isomers of hexane individually or in total). box). The terms "compound" and "complex" are used interchangeably herein to refer to organo-, inorganic- and organometallic compounds. The term "atom" refers to the smallest component of an element, regardless of its ionic state, ie whether it has a charge, a partial charge, or is bonded to another atom. The term "heteroatom" refers to an atom other than carbon or hydrogen. Preferred heteroatoms include F, Cl, Br, N, O, P, B, S, Si, Sb, Al, Sn, As, Se and Ge. The term "amorphous" refers to a polymer that does not have a crystalline melting point measured by differential scanning calorimetry (DSC) or equivalent technique.
용어 "히드로카르빌"은, 분지형 또는 비분지형, 포화 또는 불포화, 시클릭, 폴리시클릭 또는 비-시클릭 화학종을 포함하는, 수소 및 탄소 원자만을 함유하는 1가 치환체를 지칭한다. 그 예로는, 알킬-, 시클로알킬-, 알케닐-, 알카디에닐-, 시클로알케닐-, 시클로알카디에닐-, 아릴- 및 알키닐기가 포함된다. "치환된 히드로카르빌"은 1개 이상의 비-히드로카르빌 치환기로 치환된 히드로카르빌기를 지칭한다. 용어 "헤테로원자 함유 히드로카르빌" 또는 "헤테로히드로카르빌"은 수소 또는 탄소 이외의 1개 이상의 원자가 1개 이상의 탄소 원자 및 1개 이상의 수소 원자와 함께 존재하는 1가 기를 지칭한다. 용어 "헤테로카르빌"은 1개 이상의 탄소 원자 및 1개 이상의 헤테로원자를 함유하지만 수소 원자를 함유하지 않는 기를 지칭한다. 탄소 원자와 임의의 헤테로원자 사이의 결합, 뿐만 아니라 임의의 2개의 헤테로원자들 사이의 결합은 단일 또는 다중 공유 결합 또는 배위 또는 다른 공여성 결합일 수 있다. 따라서, 헤테로시클로알킬-, 아릴-치환된 헤테로시클로알킬-, 헤테로아릴-, 알킬-치환된 헤테로아릴-, 알콕시-, 아릴옥시-, 디히드로카르빌보릴-, 디히드로카르빌포스피노-, 디히드로카르빌아미노-, 트리히드로카르빌실릴-, 히드로카르빌티오-, 또는 히드로카르빌셀레노기로 치환된 알킬기는 용어 헤테로알킬의 범위 내에 있다. 구체적인 헤테로알킬기의 예로는, 시아노메틸-, 벤조일메틸-, (2-피리딜)메틸- 및 트리플루오로메틸기가 포함된다.The term "hydrocarbyl" refers to a monovalent substituent containing only hydrogen and carbon atoms, including branched or unbranched, saturated or unsaturated, cyclic, polycyclic or acyclic species. Examples include alkyl-, cycloalkyl-, alkenyl-, alkadienyl-, cycloalkenyl-, cycloalkadienyl-, aryl- and alkynyl groups. "Substituted hydrocarbyl" refers to a hydrocarbyl group substituted with one or more non-hydrocarbyl substituents. The term "heteroatom containing hydrocarbyl" or "heterohydrocarbyl" refers to a monovalent group wherein at least one atom other than hydrogen or carbon is present with at least one carbon atom and at least one hydrogen atom. The term “heterocarbyl” refers to a group containing at least one carbon atom and at least one heteroatom, but no hydrogen atoms. The bond between the carbon atom and any heteroatom, as well as the bond between any two heteroatoms, may be a single or multiple covalent bond or a coordination or other donor bond. Thus, heterocycloalkyl-, aryl-substituted heterocycloalkyl-, heteroaryl-, alkyl-substituted heteroaryl-, alkoxy-, aryloxy-, dihydrocarbylboryl-, dihydrocarbyl phosphino-, Alkyl groups substituted with dihydrocarbylamino-, trihydrocarbylsilyl-, hydrocarbylthio-, or hydrocarbylloseno groups are within the scope of the term heteroalkyl. Examples of specific heteroalkyl groups include cyanomethyl-, benzoylmethyl-, (2-pyridyl) methyl-, and trifluoromethyl groups.
본원에서 사용되는 용어 "방향족"은 (4δ+2) π-전자 (여기서, δ는 1 이상의 정수임)를 함유하는 다원자, 시클릭, 공액 고리계를 지칭한다. 2개 이상의 다원자, 시클릭 고리를 함유하는 고리계에 대하여 본원에서 사용되는 용어 "접합"은, 그의 2개 이상의 고리에 있어서, 적어도 한 쌍의 인접한 원자가 두 고리 모두에 포함되는 것을 의미한다. 용어 "아릴"은 함께 접합되거나, 공유 결합되거나, 메틸렌 또는 에틸렌 잔기와 같은 공통의 기에 결합된 다중 방향족 고리 또는 단일 방향족 고리일 수 있는 1가 방향족 치환체를 지칭한다. 방향족 고리(들)의 예로는, 특히 페닐, 나프틸, 안트라세닐 및 비페닐이 포함된다.As used herein, the term “aromatic” refers to a polyatomic, cyclic, conjugated ring system containing (4δ + 2) π-electrons, wherein δ is an integer of 1 or greater. The term "conjugation" as used herein for a ring system containing two or more multiatomic, cyclic rings means that, in its two or more rings, at least one pair of adjacent atoms is included in both rings. The term “aryl” refers to monovalent aromatic substituents that may be multiple aromatic rings or single aromatic rings bonded together, covalently bonded, or bonded to a common group such as methylene or ethylene moiety. Examples of aromatic ring (s) include especially phenyl, naphthyl, anthracenyl and biphenyl.
"치환된 아릴"은 임의의 탄소에 결합된 1개 이상의 수소 원자가 알킬, 치환된 알킬, 시클로알킬, 치환된 시클로알킬, 헤테로시클로알킬, 치환된 헤테로시클로알킬, 할로겐, 알킬할로 (예를 들어, CF3), 히드록시, 아미노, 포스피도, 알콕시, 아미노, 티오, 니트로, 및 방향족 고리(들)에 접합되거나, 공유 결합되거나, 메틸렌 또는 에틸렌 잔기와 같은 공통의 기에 결합된 포화 및 불포화 시클릭 탄화수소와 같은 1개 이상의 관능기로 치환된 아릴기를 지칭한다. 상기 공통의 결합기는 벤조페논에서와 같이 카르보닐이거나, 디페닐에테르에서와 같이 산소이거나, 또는 디페닐아민에서와 같이 질소일 수도 있다. “Substituted aryl” means that one or more hydrogen atoms bonded to any carbon is alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, heterocycloalkyl, substituted heterocycloalkyl, halogen, alkylhalo (eg , CF 3 ), hydroxy, amino, phosphido, alkoxy, amino, thio, nitro, and saturated and unsaturated upon conjugation to, covalently attached to, or common groups such as methylene or ethylene moieties An aryl group substituted with one or more functional groups, such as a click hydrocarbon. The common bonding group may be carbonyl as in benzophenone, oxygen as in diphenylether, or nitrogen as in diphenylamine.
용어 "입체적으로 벌키한"은, 결합된 아릴기 또는 아릴렌기의 평면 내에 있지 않은 (비-동일평면성의) 상당한 부피를 차지하는 치환체를 지칭한다. 본 발명의 목적상 입체적으로 벌키한 것으로 간주되는 기는 공지된 기술에 따라 이론적 계산에 기초하여 식별할 수 있다. QSAR 분석으로서 공지된 한가지 적합한 기술은 문헌 [C. Hansch and A. Leo: "Exploring QSAR Fundamentals and Applications in Chemistry and Biology" Chapter 3 (ACS Professional Reference Book, Washington, D.C. (1995)]에 개시되어 있다. 이 기술에 따라, 3차원적인 치환체의 입체적 벌키성의 지표가 되는 Es, 및 2차원적인 치환체의 입체적 벌키성의 지표가 되는 B1로서 식별되는 특정 입체 파라미터를 계산할 수 있다. 본 발명의 목적상, 3차원 벌키성은 효율성에 대한 가장 유의한 지표이고, 따라서 Es값은 입체적 벌키성을 나타내는 데 바람직하게 사용된다. 바람직한 입체적으로 벌키한 리간드기는 1.75 이상, 바람직하게는 1.90 이상, 가장 바람직하게는 2.50 이상의 B1값을 갖는다. 매우 바람직한 입체적으로 벌키한 리간드기는 -1.70 이하, 바람직하게는 -2.30 이하, 가장 바람직하게는 -2.50 이하의 Es값을 갖는다.The term "sterically bulky" refers to a substituent that occupies a significant volume (non-coplanar) that is not in the plane of the bound aryl group or arylene group. Groups considered to be three-dimensionally bulky for the purposes of the present invention may be identified based on theoretical calculations in accordance with known techniques. One suitable technique known as QSAR analysis is described in C. Hansch and A. Leo: "Exploring QSAR Fundamentals and Applications in Chemistry and Biology" Chapter 3 (ACS Professional Reference Book, Washington, DC (1995)), according to this technique, the three-dimensional bulk of the three-dimensional substituents It is possible to calculate specific stereoscopic parameters identified as Es as an indicator and B1 as an indicator of the stereoscopic bulkiness of the two-dimensional substituents For the purposes of the present invention, three-dimensional bulkiness is the most significant indicator of efficiency and thus Es Values are preferably used to exhibit steric bulkiness Preferred steric bulky ligand groups have a B1 value of at least 1.75, preferably at least 1.90 and most preferably at least 2.50 A highly preferred steric bulky ligand group is -1.70 Hereinafter, it has an Es value of preferably -2.30 or less, most preferably -2.50 or less.
본 발명의 실시양태는, 고온에서 높은 촉매 효율로 전이 금속 착물을 포함하는 촉매 조성물을 사용하여 올레핀 중합체를 제조하는 새로운 용액 방법을 제공하며, 여기서는 생성된 중합체가 가변적인 밀도 (중합체 내로 도입되는 공단량체의 양이 변하기 때문) 및 비교적 낮은 I10/I2값을 갖는다. 매우 높은 촉매 효율로 높은 전환율 조건 하에 130 내지 200℃의 반응 온도에서 고분자량 에틸렌/α-올레핀 인터폴리머를 생성하는 능력이 특히 중요하다. 이들 중합체는 바람직하게는 3.0 이하, 바람직하게는 2.7 이하, 가장 바람직하게는 2.4 이하의 좁은 분자량 분포 (Mw/Mn), 0.850 내지 0.950, 보다 바람직하게는 0.860 내지 0.930, 가장 바람직하게는 0.865 내지 0.920의 중합체 밀도를 제공하는 공단량체 함량, 및 10 이하, 보다 바람직하게는 6.0 내지 10.0의 I10/I2를 갖는다. 이러한 중합체는 특히 필름, 섬유 또는 전선 및 케이블 절연 용품에서 성형 및 압출 등급의 중합체에서와 같이 개선된 압출 성능이 요망되는 경우에 적합하게 사용된다.Embodiments of the present invention provide a novel solution process for preparing olefin polymers using catalyst compositions comprising transition metal complexes at high catalyst efficiency at high temperatures, wherein the resulting polymers are introduced at varying densities ( And the relatively low I 10 / I 2 values. Of particular importance is the ability to produce high molecular weight ethylene / α-olefin interpolymers at reaction temperatures of 130 to 200 ° C. under high conversion conditions with very high catalytic efficiency. These polymers preferably have a narrow molecular weight distribution (M w / M n ) of at most 3.0, preferably at most 2.7, most preferably at most 2.4, 0.850 to 0.950, more preferably 0.860 to 0.930, most preferably 0.865 Comonomer content giving a polymer density of from 0.9 to 0.920, and I 10 / I 2 of 10 or less, more preferably 6.0 to 10.0. Such polymers are suitably used when improved extrusion performance is desired, such as in polymers of molding and extrusion grades, especially in films, fibers or wire and cable insulation articles.
본원에서 사용되는 용어 "중합체"는 1종 이상의 단량체를 중합시켜 제조된 고분자 화합물을 지칭한다. 중합체는 단독중합체, 공중합체, 삼원공중합체, 인터폴리머 등을 지칭한다. 본원에서 용어 "인터폴리머"는 2종 이상의 공중합성 단량체를 중합된 형태로 포함하거나, 동일계에서 사슬 종결/올레핀 형성 반응의 결과로서 장쇄 분지를 도입하고, 동일계에서 형성된 올레핀을 재도입하는 중합체를 지칭하기 위해 용어 공중합체와 상호교환가능하게 사용된다. 따라서, 공중합체는 정확한 작업 조건 하에 단일 단량체의 중합으로부터 생성될 수 있다. 생성된 공중합체 또는 인터폴리머에서 가장 적은 비율의 단량체는 일반적으로 용어 "공단량체"로 지칭한다. 상기에서 언급된 장쇄 분지의 사슬 길이는 결과적으로, 임의의 정교하게 첨가된 공단량체의 중합으로부터 생성된 탄소 길이보다 길고, 특히 탄소수 6 초과이다. 장쇄 분지의 존재는 EP-A-608,369 등에 개시된 바와 같이, 중합체의 증가된 전단 민감성에 의해 검출될 수 있다. 본원에서 사용하기에 바람직하게는, 장쇄 분지가 매우 적다. 본 발명에 따른 바람직한 중합체는 상이한 하중 하에 측정된 중합체 용융 점도의 비인 용융 지수 비 (MIR), 특히 I21/I2가 30 미만이거나 또는 I10/I2값이 10 미만이다. 또한, 방법 및 그로부터 생성된 중합체는, 0.01 내지 50, 바람직하게는 0.1 내지 30, 가장 바람직하게는 0.3 내지 10 범위의 중합체 용융 지수 (MI)에 대해 MI가 수학식: "I10/I2 ≤ 10.32(MI)-0.0814"를 만족시키는 것을 특징으로 할 수 있다.The term "polymer," as used herein, refers to a polymeric compound prepared by polymerizing one or more monomers. Polymers refer to homopolymers, copolymers, terpolymers, interpolymers, and the like. The term “interpolymer” herein refers to a polymer comprising two or more copolymerizable monomers in polymerized form or introducing long chain branches as a result of chain termination / olefin formation reactions in situ and reintroducing olefins formed in situ. It is used interchangeably with the term copolymer for this purpose. Thus, copolymers can be produced from the polymerization of single monomers under precise operating conditions. The smallest proportion of monomer in the resulting copolymer or interpolymer is generally referred to by the term "comonomer". The chain length of the abovementioned long chain branch is consequently longer than the carbon length resulting from the polymerization of any finely added comonomer, in particular more than 6 carbon atoms. The presence of long chain branches can be detected by the increased shear sensitivity of the polymer, as disclosed in EP-A-608,369 and the like. Preferably for use herein, there are very few long chain branches. Preferred polymers according to the invention have a melt index ratio (MIR), in particular I 21 / I 2 of less than 30 or an I 10 / I 2 value of less than 10, which is the ratio of polymer melt viscosity measured under different loads. In addition, a method and a polymer produced therefrom is from 0.01 to 50, preferably 0.1 to 30, most preferably MI is equation for polymer melt index (MI) of 0.3 to 10 range: "I 10 / I 2 ≤ 10.32 (MI) -0.0814 ".
본원에 기재된 방법은 에틸렌과 C3-8 α-올레핀의 인터폴리머, 특히 에틸렌과 1-부텐, 1-헥센 또는 1-옥텐의 공중합체, 뿐만 아니라 에틸렌, 프로필렌 및 비공액 디엔의 공중합체, 예를 들어 EPDM 인터폴리머의 제조에 사용될 수 있다. 바람직한 인터폴리머는 2 내지 20, 바람직하게는 3 내지 12 몰%의 옥텐 공단량체를 함유하는 에틸렌/1-옥텐 공중합체이다.The processes described herein are interpolymers of ethylene and C 3-8 α-olefins, in particular copolymers of ethylene and 1-butene, 1-hexene or 1-octene, as well as copolymers of ethylene, propylene and nonconjugated dienes, eg For example, it can be used for the preparation of EPDM interpolymers. Preferred interpolymers are ethylene / 1-octene copolymers containing 2 to 20, preferably 3 to 12 mole percent octene comonomers.
중합 조건은 일반적으로 온도, 압력, 단량체 함량 (공단량체 농도 포함), 촉매 농도, 보조촉매 농도, 단량체 전환율, 또는 생성된 중합체의 특성에 영향을 주는 기타 조건을 지칭한다. 본 발명의 소정의 중합 조건에 따라 작업함으로써, 높은 촉매 활성, 낮은 보조촉매 사용도 및 높은 I10/I2 또는 MIR과 함께 비교적 높은 공단량체 도입률을 갖는 고분자량 중합체가 제조될 수 있다. 특히, 0.5 g/μg을 초과하는, 바람직하게는 0.55 g/μg을 초과하는, 심지어는 0.6 g/μg을 초과하는 활성 (전이 금속의 중량에 대한 중합체의 중량 기준)이 가능하다. 금속 착물의 용해도는 바람직하게는, 헥산, 메틸시클로헥산 또는 혼합 헥산 (엑손모빌 케미칼즈 인코포레이티드(ExxonMobil Chemicals Inc.)로부터 입수가능한 이소파르(Isopar) ETM으로서 시판되는 수소화된 프로필렌 이량체) 중에서 20℃에서 측정시 5 중량% 이상, 바람직하게는 6 중량% 이상이다.Polymerization conditions generally refer to temperature, pressure, monomer content (including comonomer concentration), catalyst concentration, cocatalyst concentration, monomer conversion, or other conditions that affect the properties of the resulting polymer. By working in accordance with the desired polymerization conditions of the present invention, high molecular weight polymers can be prepared having high catalytic activity, low cocatalyst utilization and a relatively high comonomer introduction rate with high I 10 / I 2 or MIR. In particular, activities exceeding 0.5 g / μg, preferably greater than 0.55 g / μg and even greater than 0.6 g / μg (based on the weight of the polymer relative to the weight of the transition metal) are possible. The solubility of the metal complex is preferably a hydrogenated propylene dimer commercially available as hexane, methylcyclohexane or mixed hexane (Isopar E ™ available from ExxonMobil Chemicals Inc.). ) Is at least 5% by weight and preferably at least 6% by weight at 20 ° C.
중합체 중량-평균 분자량(Mw)은 겔 투과 크로마토그래피에 의해 측정되며, 그 기술 중 하나가 USP 5,272,236에 기재되어 있다. 별법으로, 예를 들어 ASTM D-1238에 따라 측정된 용융 지수 I2, I10 또는 I21이 분자량의 지표로서 사용될 수 있다. 일반적으로, 용융 지수는 중합체의 분자량에 반비례한다. 분자량이 높을수록, 용융 지수가 낮지만, 그 관계가 반드시 선형적인 것은 아니다.Polymer weight-average molecular weight (M w ) is determined by gel permeation chromatography, one of which techniques is described in USP 5,272,236. Alternatively, melt indexes I 2 , I 10 or I 21 , measured according to ASTM D-1238, for example, can be used as an indicator of molecular weight. In general, the melt index is inversely proportional to the molecular weight of the polymer. The higher the molecular weight, the lower the melt index, but the relationship is not necessarily linear.
본 발명의 일 실시양태는, 연속적 용액 중합 방법에서 에틸렌과 1종 이상의 C3-8 α-올레핀, 또한 임의로는 공액 디엔을 접촉시키는 것을 포함하는 방법을 수반한다. 본 발명의 방법은, 금속 착물, 보조촉매, 에틸렌 및 1종 이상의 C3-8 α-올레핀 공단량체, 및 임의의 디올레핀을 포함하는 반응 혼합물 (또는 이들의 개별 성분)을, 임의로는 추가의 사슬 전달제의 존재 하에, 용액 중합 조건 하에 작동되는 반응기에 연속적으로 또는 간헐적으로 첨가하고, 중합 생성물을 이로부터 연속적으로 또는 반-연속적으로 제거하는 중합 조건 하에 사용하기에 특히 유리하다. 이 방법은 바람직하게는, 높은 에틸렌 전환율 조건 (> 85%, 바람직하게는 > 90%) 하에 100 내지 200℃, 바람직하게는 120 내지 190℃의 온도에서 연속적 용액 중합 조건 하에 지르코늄 착물 및 대략적 화학식 [(C14-18H27-35)2CH3N]+[B(C6F5)4]-의 보조촉매, 및 임의로는 알루목산 스캐빈저를 사용하여 에틸렌과 1종 이상의 C3-8 α-올레핀 및/또는 디올레핀을 중합하여, 0.850 내지 0.950 g/cm3, 바람직하게는 0.860 내지 0.930 g/cm3, 가장 바람직하게는 0.865 내지 0.920 g/cm3의 밀도, 0.01 내지 50.0, 바람직하게는 0.1 내지 30.0, 가장 바람직하게는 0.3 내지 10.0의 용융 지수 (I2), 좁은 분자량 분포 (Mw/Mn < 3.0, 바람직하게는 < 2.7, 특히 < 2.5)를 갖는 중합체를, 0.5 g중합체/μg금속 초과의 촉매 효율 및 0.0 내지 2.5 몰%, 바람직하게는 0.01 내지 2.0 몰%의 사슬 전달제 농도로 생성하는 것을 포함한다.One embodiment of the invention involves a process comprising contacting ethylene with at least one C 3-8 α-olefin, and optionally conjugated diene, in a continuous solution polymerization process. The process of the invention provides a reaction mixture (or individual component thereof), optionally comprising a metal complex, a cocatalyst, ethylene and at least one C 3-8 α-olefin comonomer, and any diolefin. It is particularly advantageous for use under polymerization conditions in which, in the presence of chain transfer agents, are continuously or intermittently added to a reactor operated under solution polymerization conditions and the polymerization product is removed therefrom continuously or semi-continuously. The process is preferably carried out with zirconium complexes and approximate chemical formulas under continuous solution polymerization conditions at temperatures of 100 to 200 ° C., preferably 120 to 190 ° C., under high ethylene conversion conditions (> 85%, preferably> 90%). (C 14-18 H 27-35) 2 CH 3 N] + [B (C 6 F 5) 4] - in the co-catalyst, and optionally an alumoxane scan using the scavenger at least one kinds of ethylene and C 3- 8 α-olefins and / or diolefins are polymerized to give a density of 0.850 to 0.950 g / cm 3 , preferably 0.860 to 0.930 g / cm 3 , most preferably 0.865 to 0.920 g / cm 3 , 0.01 to 50.0, Polymers having a melt index (I 2 ), narrow molecular weight distribution (M w / M n <3.0, preferably <2.7, in particular <2.5), preferably from 0.1 to 30.0, most preferably from 0.3 to 10.0, g polymer / μg catalyst efficiency and 0.0 to 2.5 mol% of metal in excess, preferably 0.01 to 2.0 mole% of chain transfer by the concentration It involves the castle.
사슬 전달제를 사용하는 경우에는, 사슬 전달제를 사용하지 않는 비교 중합에 비해 분자량의 상당한 감소 (> 10%)가 일어나도록 충분한 양을 사용한다. 매우 바람직하게는, 50,000 이상의 Mn을 갖는 중합체가 생성되도록 사슬 전달제의 사용량을 조정한다. 가장 바람직한 사슬 전달제는 수소이다.When using a chain transfer agent, an amount sufficient to cause a significant decrease in molecular weight (> 10%) as compared to comparative polymerization without a chain transfer agent is used. Very preferably, the amount of chain transfer agent used is adjusted to produce a polymer with 50,000 or more M n . Most preferred chain transfer agent is hydrogen.
놀랍게도, 본 발명의 금속 착물은 좁은 분자량 분포 (< 3.0) 및 0.5 g중합체/μg금속 초과의 촉매 효율을 유지하면서 다양한 중합 조건 하에 매우 높은 분자량의 중합체를 형성할 수 있고, 따라서 사슬 전달제를 사용하여 분자량을 조절할 수 있다. 특히, 밀도 (공단량체 함량)가 중합 온도에 의해 비교적 영향받지 않고 장쇄 분지형성이 상이한 치환체를 갖는 기존 유형의 다른 촉매에 비해 최소화된다는 사실이 놀랍다. 이는 다양한 수준의 공단량체로 비교적 낮은 I10/I2를 갖는 에틸렌/α-올레핀 인터폴리머의 효율적 제조를 가능하게 한다.Surprisingly, the metal complexes of the present invention can form very high molecular weight polymers under a variety of polymerization conditions while maintaining a narrow molecular weight distribution (<3.0) and catalytic efficiency of greater than 0.5 g polymer / μg metal , thus using chain transfer agents. To adjust the molecular weight. In particular, it is surprising that the density (comonomer content) is relatively unaffected by the polymerization temperature and the long chain branching is minimized compared to other catalysts of the existing type with different substituents. This allows for the efficient production of ethylene / a-olefin interpolymers having relatively low I 10 / I 2 with varying levels of comonomers.
금속 착물Metal complex
본 발명에 따라 사용하기에 적합한 금속 착물은 하기 화학식에 상응하는 화합물을 포함한다.Suitable metal complexes for use in accordance with the invention include compounds corresponding to the formula
상기 식에서, Where
M3은 Hf 또는 Zr, 바람직하게는 Zr이고;M 3 is Hf or Zr, preferably Zr;
Ar4는 각 경우에 독립적으로 치환된 C9-20 아릴기이며, 여기서 치환체는 각 경우에 독립적으로 알킬; 시클로알킬; 및 아릴기; 및 할로-, 트리히드로카르빌실릴- 및 할로히드로카르빌-치환된 이들의 유도체로 구성된 군으로부터 선택되되, 단 치환체는 그것이 결합된 아릴기와 동일평면성을 갖지 않아야 하며;Ar 4 is a C 9-20 aryl group independently substituted at each occurrence, wherein the substituents are independently alkyl at each occurrence; Cycloalkyl; And aryl groups; And halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, provided that the substituents do not have coplanarity with the aryl groups to which they are attached;
T4는 각 경우에 독립적으로 C2-20 알킬렌, 시클로알킬렌 또는 시클로알케닐렌기, 또는 불활성 치환된 이들의 유도체이고; T 4 in each occurrence is independently a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or inert substituted derivative thereof;
R21은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노기이며; R 21 independently in each occurrence is hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) having up to 50 atoms, excluding hydrogen ) An amino group;
R3은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 아미노이거나, 또는 동일한 아릴렌 고리 상의 2개의 R3기는 함께, 또는 동일하거나 상이한 아릴렌 고리 상의 R3 및 R21기는 함께 2개의 위치에서 아릴렌기에 결합된 2가 리간드기를 형성하거나, 또는 2개의 상이한 아릴렌 고리를 함께 연결시키고;R 3 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino having up to 50 atoms, excluding hydrogen, or the same Two R 3 groups on the arylene ring together or R 3 and R 21 groups on the same or different arylene ring together form a divalent ligand group bonded to an arylene group at two positions, or two different arylene rings Connect together;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 디엔 또는 폴리(히드로카르빌)실릴렌기이다. R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, Diene or poly (hydrocarbyl) silylene group.
본 발명자들은, 본 발명의 반응 조건 하에 요망되는 I10/I2 범위의 중합체를 달성하기 위해서는 각각의 Ar4기가 1개 이상의 입체적으로 벌키한 기로 치환, 바람직하게는 2개의 상기 기로 치환되어야 함을 발견하였다. 추가로 바람직하게는, 상이한 아릴렌 고리 상의 1개 이상의 R3기, 바람직하게는 2개의 상기 R3기가 또한 입체적으로 벌키하다. 아릴렌옥시기 상에 위치한 R3기가 선형 알킬기인 경우 약간 증가된 I10/I2의 희생으로 실질적으로 동등한 용해도의 금속 착물이 얻어질 수 있다. 매우 바람직하게는, 금속 착물 중의 아릴렌기의 4번 위치 둘 다에 위치한 R3 치환기가 입체적으로 벌키하다.The inventors have found that under the reaction conditions of the present invention each Ar 4 group must be substituted with at least one steric bulky group, preferably with two such groups, in order to achieve the polymer in the desired I 10 / I 2 range. Found. Further preferably, at least one R 3 group on a different arylene ring, preferably two said R 3 groups, is also stericly bulky. When the R 3 group located on the aryleneoxy group is a linear alkyl group, a metal complex of substantially equivalent solubility can be obtained at the expense of slightly increased I 10 / I 2 . Very preferably, the R 3 substituents located at both position 4 of the arylene group in the metal complex are stericly bulky.
추가로 바람직하게는, Ar4기는 하기 화학식에 상응한다.Further preferably, the Ar 4 group corresponds to the formula
상기 식에서, R11은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노이거나, 또는 2개의 R11기는 함께 2개의 위치에서 아릴기에 결합된 고리의 일부이되, 단 하나 이상의 경우의 R11 또는 2개의 상기 R11기의 2가 유도체는 입체적으로 벌키하고/거나, 그것이 결합된 아릴 고리와 동일평면성을 갖지 않는다.Wherein R 11 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di ( Hydrocarbyl) amino, or two R 11 groups together form part of a ring bonded to an aryl group at two positions, provided that at least one instance of R 11 or two divalent derivatives of said R 11 groups is sterically bulky and Or, it is not coplanar with the aryl ring to which it is attached.
바람직하게는 R11 및 R3 치환체는 이들이 결합된 페닐렌 고리와 동일평면성을 갖지 않는 입체적으로 벌키한 1가 리간드기, 특히 3개 내지 20개의 비-수소 원자를 갖는 3급 알킬-, sec-알킬, 시클로알킬-, 아릴-, 트리히드로카르빌실릴-, 트리(히드로카르빌)실릴히드로카르빌- 또는 (히드로카르빌)아릴기이다. 그 예로는, tert-부틸, sec-부틸, tert-옥틸 (2,4,4-트리메틸펜탄-2-일), 1-페닐에틸, 2,3-디메틸-부트-2-일, 트리틸 (트리페닐메틸), 쿠밀 (2-페닐프로프-2-일), tert-아밀 (1,1-디메틸프로필), 페닐, 시클로헥실, 트리메틸실릴, 트리메틸실릴메틸, 이소프로필, 2,4,6-트리메틸페닐, 2,6-디메틸페닐, 3,5-디(이소프로필)페닐 및 3,5-디(t-부틸)페닐이 포함된다.Preferably, the R 11 and R 3 substituents are sterically bulky monovalent ligand groups, in particular tertiary alkyl-, sec-, having 3 to 20 non-hydrogen atoms, which are not coplanar with the phenylene ring to which they are attached Alkyl, cycloalkyl-, aryl-, trihydrocarbylsilyl-, tri (hydrocarbyl) silylhydrocarbyl- or (hydrocarbyl) aryl group. Examples include tert-butyl, sec-butyl, tert-octyl (2,4,4-trimethylpentan-2-yl), 1-phenylethyl, 2,3-dimethyl-but-2-yl, trityl ( Triphenylmethyl), cumyl (2-phenylprop-2-yl), tert-amyl (1,1-dimethylpropyl), phenyl, cyclohexyl, trimethylsilyl, trimethylsilylmethyl, isopropyl, 2,4,6 -Trimethylphenyl, 2,6-dimethylphenyl, 3,5-di (isopropyl) phenyl and 3,5-di (t-butyl) phenyl.
적합한 금속 착물의 추가로 바람직한 예는 하기 화학식에 상응한다.Further preferred examples of suitable metal complexes correspond to the formula
상기 식에서,Where
M3은 Zr이고;M 3 is Zr;
Ar4는 3,5-디(tert-부틸)페닐, 3,5-디(이소프로필)페닐, 3,5-디(이소부틸)페닐, 3,5-디(tert-옥틸)페닐, 3,5-디(2,4,6-트리메틸페닐)페닐, 3,5-디(2,6-디메틸페닐)페닐, 3,5-디(2,4,6-트리-이소프로필페닐)페닐, 3,5-디(3,5-디-tert-부틸페닐)페닐, 1,2,3,4,6,7,8,9-옥타히드로안트라센-5-일, 3,6-디(tert-부틸)-9H-카르바졸-9-일, 3,6-디(tert-옥틸)-9H-카르바졸-9-일이며;Ar 4 is 3,5-di (tert-butyl) phenyl, 3,5-di (isopropyl) phenyl, 3,5-di (isobutyl) phenyl, 3,5-di (tert-octyl) phenyl, 3 , 5-di (2,4,6-trimethylphenyl) phenyl, 3,5-di (2,6-dimethylphenyl) phenyl, 3,5-di (2,4,6-tri-isopropylphenyl) phenyl , 3,5-di (3,5-di-tert-butylphenyl) phenyl, 1,2,3,4,6,7,8,9-octahydroanthracene-5-yl, 3,6-di ( tert-butyl) -9H-carbazol-9-yl, 3,6-di (tert-octyl) -9H-carbazol-9-yl;
R21은 각 경우에 독립적으로 메틸 또는 tert-부틸이고;R 21 in each occurrence is independently methyl or tert-butyl;
R3은 각 경우에 독립적으로 분지형 알킬, 시클로알킬, 치환된 아릴 또는 다른 입체적으로 벌키한 기이며;R 3 in each occurrence is independently branched alkyl, cycloalkyl, substituted aryl or other stericly bulky group;
T4는 프로판-1,3-디일, 부탄-1,4-디일, 시클로헥산-1,2-디일 또는 시클로헥산-1,2-디메틸렌이고;T 4 is propane-1,3-diyl, butane-1,4-diyl, cyclohexane-1,2-diyl or cyclohexane-1,2-dimethylene;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 1,4-디히드로카르빌-치환된 1,3-부타디엔 또는 폴리(히드로카르빌)실릴렌기이다.R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, 1,4-dihydrocarbyl-substituted 1,3-butadiene or poly (hydrocarbyl) silylene groups.
매우 바람직한 실시양태에서, 각각의 Ar4 고리 상의 1개 이상의 R11기, 가장 바람직하게는 Ar4 페닐 고리의 3번 및 5번 위치의 2개의 상기 R11기 및 상이한 아릴렌 고리 상의 2개 이상의 R3기는 3개 내지 20개의 탄소, 바람직하게는 4개 내지 12개의 탄소를 함유하는 분지형 알킬, 시클로알킬, 히드로카르빌-치환된 아릴 또는 폴리(히드로카르빌)-치환된 실릴기이다. 가장 매우 바람직한 입체적으로 벌키한 R11 및 R3기는 3급 부틸 및 3급 옥틸기이다. 가장 매우 바람직한 금속 착물은, Ar4기 둘 다가 3,5-디-t-부틸페닐 또는 3,5-디-t-옥틸페닐이고, 각각의 페닐렌옥시 리간드의 4번 또는 5번 위치의 1개의 R3기가 tert-부틸 또는 tert-옥틸이며, 각각의 R21기가 수소 또는 20개 이하의 탄소 원자를 갖는 히드로카르빌, 바람직하게는 tert-부틸인 상기 화학식의 지르코늄 착물이다.In highly preferred embodiments, each of Ar 1 or more on 4 rings R 11 group, and most preferably at least two on the two of the R 11 groups and different arylene rings of 3 and 5-position of the Ar 4 phenyl ring R 3 group is a branched alkyl, cycloalkyl, hydrocarbyl-substituted aryl or poly (hydrocarbyl) -substituted silyl group containing 3 to 20 carbons, preferably 4 to 12 carbons. Most highly preferred stericly bulky R 11 and R 3 groups are tertiary butyl and tertiary octyl groups. Most highly preferred metal complexes are those wherein both Ar 4 groups are 3,5-di-t-butylphenyl or 3,5-di-t-octylphenyl and are located at position 1 or 4 of each phenyleneoxy ligand. R 3 groups are tert-butyl or tert-octyl and each R 21 group is hydrogen or a hydrocarbyl having up to 20 carbon atoms, preferably a zirconium complex of the above formula.
본 발명에 따른 가장 매우 바람직한 금속 착물은 하기 화학식에 상응한다.Most highly preferred metal complexes according to the invention correspond to the formula
상기 식에서, RD는 각 경우에 독립적으로 클로라이드, 메틸 또는 벤질이다.Wherein R D is independently at each occurrence chloride, methyl or benzyl.
적합한 금속 착물의 구체적 예는 하기 화합물이다.Specific examples of suitable metal complexes are the following compounds.
A) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, A) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
B) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, B) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentane-2 -Yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
C) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, C) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) Propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
D) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, D) Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디 메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-],2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-], 2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
E) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, E) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
F) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, F) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4, 4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
G) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, G) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1, 3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
H) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, H) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, 및 Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride, and
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질.Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl.
상기 금속 착물은, 전이 금속의 공급원 및 중성 다관능성 리간드 공급원을 포함하는 표준 금속화 및 리간드 교환 절차에 의해 편리하게 제조할 수 있다. 사용되는 기술은 USP 6,827,976 및 US 2004/0010103 등에 개시된 것들과 동일하거나 유사하다.Such metal complexes can be conveniently prepared by standard metallization and ligand exchange procedures that include a source of transition metals and a neutral polyfunctional ligand source. The technology used is the same or similar to those disclosed in USP 6,827,976 and US 2004/0010103 and the like.
금속 착물은 활성화되어, 보조촉매와 조합됨으로써 활성 촉매 조성물을 형성한다. 활성화는 반응 혼합물의 다른 성분의 존재 또는 부재 하에 촉매 조성물을 반응기에 첨가하기 전에 일어나거나, 상기 금속 착물 및 활성화 보조촉매를 반응기에 개별 첨가하여 동일계에서 일어날 수 있다.The metal complex is activated and combined with the cocatalyst to form the active catalyst composition. Activation can occur prior to adding the catalyst composition to the reactor in the presence or absence of other components of the reaction mixture, or can occur in situ by separately adding the metal complex and the activating cocatalyst to the reactor.
활성화는 다양한 방식으로 일어나 부가 중합성 단량체, 특히 올레핀(들)을 배위하고, 삽입하고, 중합하는 비어있는 배위 자리를 갖는 촉매 화합물을 제공한다. 본원 명세서 및 첨부된 청구의 범위의 목적상, 용어 "활성화제" 또는 "보조촉매"는 상기 방식으로 금속 착물을 활성화시킬 수 있는 임의의 화합물 또는 성분 또는 방법으로 정의된다. 적합한 활성화제의 비제한적 예로는, 루이스산, 비배위 이온성 활성화제, 이온화 활성화제, 유기금속 화합물, 및 중성 금속 착물을 촉매적 활성종으로 전환시킬 수 있는 상기 물질의 조합이 포함된다. 본원에 사용되는 용어 "비배위"는 촉매 전구체 및 이로부터 유도된 활성 촉매종에 배위되지 않거나, 또는 이러한 착물 또는 화학종에 단지 약하게 배위됨으로써 올레핀과 같은 중성 루이스 염기에 의해 치환되기에 충분히 불안정성(labile)으로 남아 있는 물질 (용매, 음이온, 보조촉매 또는 보조촉매 잔류물)을 의미한다. Activation takes place in a variety of ways to provide a catalytic compound having an empty coordination site for coordinating, intercalating and polymerizing addition polymerizable monomers, in particular olefin (s). For the purposes of this specification and the appended claims, the term “activator” or “cocatalyst” is defined as any compound, component or method capable of activating a metal complex in this manner. Non-limiting examples of suitable activators include Lewis acids, noncoordinating ionic activators, ionization activators, organometallic compounds, and combinations of these materials capable of converting neutral metal complexes into catalytically active species. As used herein, the term "non-coordinating" is not coordinating to the catalyst precursor and the active catalytic species derived therefrom or is only unstable to be substituted by neutral Lewis bases such as olefins by weakly coordinating to such complexes or species ( labile) means a substance (solvent, anion, cocatalyst or cocatalyst residue).
이러한 고려에 의해 국한되길 바라지는 않지만, 본 발명의 일 실시양태에서, 촉매 활성화는 양성자 전달, 산화 또는 다른 적합한 활성화 과정에 의해 양이온성, 부분적 양이온성 또는 양쪽성 화학종의 형성을 포함할 수 있는 것으로 여겨진다. 본 발명은 이러한 식별가능한 양이온성, 부분적 양이온성 또는 양쪽성 화학종이 실제로 활성화 과정 (또한 본원에서 "이온화" 과정 또는 "이온 활성화 과정"으로서 상호교환가능하게 언급됨) 동안 형성되는지의 여부에 관계 없이 수행가능하고 완전히 가능함을 이해하여야 한다. While not wishing to be limited by these considerations, in one embodiment of the invention, catalytic activation may include the formation of cationic, partially cationic or amphoteric species by proton transfer, oxidation or other suitable activation process. It is considered to be. The present invention is independent of whether such identifiable cationic, partially cationic or amphoteric species are actually formed during the activation process (also referred to herein interchangeably as "ionization" process or "ion activation process"). It should be understood that it is feasible and fully possible.
이온화 보조촉매는, 활성 양성자, 또는 이온화 화합물의 음이온과 연합되지만 그에 배위되지 않은 또는 단지 약하게 배위된 일부 다른 양이온을 함유할 수 있다. 이러한 화합물은 유럽특허출원 공개 제EP-A-570982호, 동 제EP-A-520732호, 동 제EP-A-495375호, 동 제EP-A-500944호, 동 제EP-A-277003호 및 동 제EP-A-277004호 및 미국 특허 제5,153,157호, 동 제5,198,401호, 동 제5,066,741호, 동 제5,206,197호, 동 제5,241,025호, 동 제5,384,299호 및 동 제5,502,124호에 기재되어 있다. 상기 활성화제 중 암모늄 양이온 함유 염, 특히 1개 또는 2개의 C10-40 알킬기를 함유하는 트리히드로카르빌-치환된 암모늄 양이온, 특히 메틸비스(옥타데실)-암모늄- 및 메틸비스(테트라데실)-암모늄 양이온 및 비배위 음이온, 특히 테트라키스(퍼플루오로)아릴보레이트 음이온, 특히 테트라키스(펜타플루오로페닐)보레이트를 함유하는 것들이 바람직하다. 또한, 양이온은 상이한 길이의 히드로카르빌기의 혼합물을 포함할 수 있음을 이해한다. 예를 들어, 2개의 C14, C16 또는 C18 알킬기와 1개의 메틸기의 혼합물을 포함하는 상업적으로 입수가능한 장쇄 아민으로부터 유도된 양성자화된 암모늄 양이온이 있다. 이러한 아민은 켐투라 코포레이션(Chemtura Corp.)으로부터 상표명 켐아민(Kemamine)TM T9701으로, 또한 악조-노벨(Akzo-Nobel)로부터 상표명 아르민(Armeen)TM M2HT으로 입수가능하다. 가장 바람직한 암모늄염 활성화제는 메틸디(C14-20알킬)암모늄 테트라키스(펜타플루오로페닐)보레이트이다.The ionization cocatalyst may contain an active proton, or some other cation associated with, but only weakly coordinated with, the anion of the ionizing compound. Such compounds are disclosed in EP-A-570982, EP-A-520732, EP-A-495375, EP-A-500944, EP-A-277003 And EP-A-277004 and US Pat. Nos. 5,153,157, 5,198,401, 5,066,741, 5,206,197, 5,241,025, 5,384,299 and 5,502,124. Ammonium cation containing salts in the activator, in particular trihydrocarbyl -substituted ammonium cations containing one or two C 10-40 alkyl groups, in particular methylbis (octadecyl) -ammonium- and methylbis (tetradecyl) Preference is given to ammonium cations and uncoordinated anions, in particular tetrakis (perfluoro) arylborate anions, especially those containing tetrakis (pentafluorophenyl) borate. It is also understood that the cation may comprise a mixture of hydrocarbyl groups of different lengths. For example, there are protonated ammonium cations derived from commercially available long chain amines comprising a mixture of two C 14 , C 16 or C 18 alkyl groups and one methyl group. Such amines are available under the tradename Kemamine ™ T9701 from Chemtura Corp. and also under the tradename Armeen ™ M2HT from Akzo-Nobel. Most preferred ammonium salt activator is methyldi (C 14-20 alkyl) ammonium tetrakis (pentafluorophenyl) borate.
활성 양성자를 함유하지 않지만 활성 촉매 조성물을 형성할 수 있는 이온성 화합물, 예컨대 상기한 비배위 음이온의 페로세늄염을 이온화하는 것을 이용한 활성화 방법 또한 본원에서 사용하기 위해 고려되며, 이는 EP-A-426637, EP-A-573403 및 미국 특허 제5,387,568호에 기재되어 있다. 리간드기, 특히 히드로카르빌 리간드의 제거에 의해 금속 착물의 양이온성 유도체에 대한 비배위 상대 음이온을 형성할 수 있는 강한 루이스산, 특히 트리스(퍼플루오로)아릴 보란 화합물, 예컨대 트리스(펜타플루오로페닐)보란의 사용 또한 포함된다.Activation methods using ionizing ionic compounds that do not contain active protons but are capable of forming active catalyst compositions, such as the above-described coordinating salts of non-coordinating anions, are also contemplated for use herein, which is EP-A-426637. , EP-A-573403 and US Pat. No. 5,387,568. Strong Lewis acids, in particular tris (perfluoro) aryl borane compounds, such as tris (pentafluoro), which can form uncoordinated counter anions for cationic derivatives of metal complexes by removal of ligand groups, especially hydrocarbyl ligands The use of phenyl) borane is also included.
확장(expanded) 음이온으로서 일반적으로 지칭되며, 추가로 미국 특허 제6,395,671호에 개시되어 있는 비배위 음이온을 포함하는 보조촉매의 한 부류가 올레핀 중합을 위해 본 발명의 금속 착물을 활성화시키는 데 적합하게 사용될 수 있다. 일반적으로, 이들 보조촉매 (이미다졸리드, 치환된 이미다졸리드, 이미다졸리니드, 치환된 이미다졸리니드, 벤즈이미다졸리드 또는 치환된 벤즈이미다졸리드 음이온을 갖는 것들로 예시됨)는 하기와 같이 나타낼 수 있다.Generally referred to as expanded anions, a class of cocatalysts comprising uncoordinated anions, further disclosed in US Pat. No. 6,395,671, may be suitably used to activate the metal complexes of the present invention for olefin polymerization. Can be. In general, these cocatalysts are exemplified by those having imidazolides, substituted imidazolides, imidazolinides, substituted imidazolines, benzimidazolides or substituted benzimidazolides anions Can be expressed as follows.
상기 식에서,Where
A*+는 양이온, 특히 양성자 함유 양이온, 바람직하게는 1개 또는 2개의 C10-40 알킬기를 함유하는 트리히드로카르빌 암모늄 양이온, 특히 메틸디(C14-20알킬)암모늄-양이온이고,A * + is a cation, especially a proton-containing cation, preferably a trihydrocarbyl ammonium cation containing one or two C 10-40 alkyl groups, in particular methyldi (C 14-20 alkyl) ammonium-cation,
R4는 각 경우에 독립적으로 수소 또는 할로, 또는 수소를 제외하고 30개 이하의 원자를 갖는 히드로카르빌, 할로카르빌, 할로히드로카르빌, 실릴히드로카르빌 또는 실릴 (모노-, 디- 및 트리(히드로카르빌)실릴 포함)기, 바람직하게는 C1-20 알킬이며,R 4 independently in each occurrence is hydrogen or halo, or hydrocarbyl, halocarbyl, halohydrocarbyl, silylhydrocarbyl or silyl (mono-, di- and Tri (hydrocarbyl) silyl) group, preferably C 1-20 alkyl,
J*'는 트리스(펜타플루오로페닐)보란 또는 트리스(펜타플루오로페닐)알루만이다.J * 'is tris (pentafluorophenyl) borane or tris (pentafluorophenyl) alman.
이들 촉매 활성화제의 예로는, Examples of these catalyst activators include
비스(트리스(펜타플루오로페닐)보란)이미다졸리드, Bis (tris (pentafluorophenyl) borane) imidazolide,
비스(트리스(펜타플루오로페닐)보란)-2-운데실이미다졸리드, Bis (tris (pentafluorophenyl) borane) -2-undecylimidazolide,
비스(트리스(펜타플루오로페닐)보란)-2-헵타데실이미다졸리드, Bis (tris (pentafluorophenyl) borane) -2-heptadecylimidazolide,
비스(트리스(펜타플루오로페닐)보란)-4,5-비스(운데실)이미다졸리드,Bis (tris (pentafluorophenyl) borane) -4,5-bis (undecyl) imidazolide,
비스(트리스(펜타플루오로페닐)보란)-4,5-비스(헵타데실)이미다졸리드,Bis (tris (pentafluorophenyl) borane) -4,5-bis (heptadecyl) imidazolide,
비스(트리스(펜타플루오로페닐)보란)이미다졸리니드, Bis (tris (pentafluorophenyl) borane) imidazolinide,
비스(트리스(펜타플루오로페닐)보란)-2-운데실이미다졸리니드,Bis (tris (pentafluorophenyl) borane) -2-undecylimidazolinide,
비스(트리스(펜타플루오로페닐)보란)-2-헵타데실이미다졸리니드, Bis (tris (pentafluorophenyl) borane) -2-heptadecylimidazolinide,
비스(트리스(펜타플루오로페닐)보란)-4,5-비스(운데실)이미다졸리니드, Bis (tris (pentafluorophenyl) borane) -4,5-bis (undecyl) imidazolinide,
비스(트리스(펜타플루오로페닐)보란)-4,5-비스(헵타데실)이미다졸리니드, Bis (tris (pentafluorophenyl) borane) -4,5-bis (heptadecyl) imidazolinide,
비스(트리스(펜타플루오로페닐)보란)-5,6-디메틸벤즈이미다졸리드,Bis (tris (pentafluorophenyl) borane) -5,6-dimethylbenzimidazolide,
비스(트리스(펜타플루오로페닐)보란)-5,6-비스(운데실)벤즈이미다졸리드,Bis (tris (pentafluorophenyl) borane) -5,6-bis (undecyl) benzimidazolide,
비스(트리스(펜타플루오로페닐)알루만)이미다졸리드,Bis (tris (pentafluorophenyl) aluman) imidazolide,
비스(트리스(펜타플루오로페닐)알루만)-2-운데실이미다졸리드, Bis (tris (pentafluorophenyl) aluman) -2-undecylimidazolide,
비스(트리스(펜타플루오로페닐)알루만)-2-헵타데실이미다졸리드,Bis (tris (pentafluorophenyl) aluman) -2-heptadecylimidazolide,
비스(트리스(펜타플루오로페닐)알루만)-4,5-비스(운데실)이미다졸리드,Bis (tris (pentafluorophenyl) alman) -4,5-bis (undecyl) imidazolide,
비스(트리스(펜타플루오로페닐)알루만)-4,5-비스(헵타데실)이미다졸리드, Bis (tris (pentafluorophenyl) aluman) -4,5-bis (heptadecyl) imidazolide,
비스(트리스(펜타플루오로페닐)알루만)이미다졸리니드,Bis (tris (pentafluorophenyl) aluman) imidazolinide,
비스(트리스(펜타플루오로페닐)알루만)-2-운데실이미다졸리니드, Bis (tris (pentafluorophenyl) aluman) -2-undecylimidazolinide,
비스(트리스(펜타플루오로페닐)알루만)-2-헵타데실이미다졸리니드, Bis (tris (pentafluorophenyl) aluman) -2-heptadecylimidazolinide,
비스(트리스(펜타플루오로페닐)알루만)-4,5-비스(운데실)이미다졸리니드, Bis (tris (pentafluorophenyl) aluman) -4,5-bis (undecyl) imidazolinide,
비스(트리스(펜타플루오로페닐)알루만)-4,5-비스(헵타데실)이미다졸리니드,Bis (tris (pentafluorophenyl) alman) -4,5-bis (heptadecyl) imidazolinide,
비스(트리스(펜타플루오로페닐)알루만)-5,6-디메틸벤즈이미다졸리드, 및Bis (tris (pentafluorophenyl) aluman) -5,6-dimethylbenzimidazolide, and
비스(트리스(펜타플루오로페닐)알루만)-5,6-비스(운데실)벤즈이미다졸리드Bis (tris (pentafluorophenyl) alman) -5,6-bis (undecyl) benzimidazolide
의 트리히드로카르빌암모늄염, 특히 메틸디(C14-20알킬)암모늄염이 포함된다.Trihydrocarbyl ammonium salts, in particular methyldi (C 14-20 alkyl) ammonium salts.
다른 활성화제로는, PCT 특허출원 공개 제WO 98/07515호에 기재된 것들, 예컨대 트리스(2,2',2"-노나플루오로비페닐)플루오로알루미네이트가 포함된다. 활성화제의 조합, 예를 들어 조합된 알루목산 및 이온화 활성화제 또한 본 발명에서 고려된다 (예를 들어, EP-A-0 573120, PCT 특허출원 공개 제WO 94/07928호 및 동 제WO 95/14044호 및 미국 특허 제5,153,157호 및 동 제5,453,410호 참조). WO 98/09996에는 퍼클로레이트, 퍼요오데이트 및 요오데이트와 활성화 촉매 화합물 (이들의 수화물 포함)이 기재되어 있다. WO 99/18135에는 오르가노보로알루미늄 활성화제의 사용이 기재되어 있다. EP-A-781299에는 비배위 상용성 음이온과 조합된 실릴륨염의 사용이 기재되어 있다. 촉매 화합물의 활성화를 위한 다른 활성화제 또는 방법은, 예를 들어 미국 특허 제5,849,852호, 동 제5,859,653호, 동 제5,869,723호, EP-A-615981 및 PCT 특허출원 공개 제WO 98/32775호에 기재되어 있다.Other activators include those described in PCT Patent Application Publication No. WO 98/07515, such as tris (2,2 ', 2 "-nonafluorobiphenyl) fluoroaluminate. Combinations of activators, for example Combined alumoxanes and ionization activators are also contemplated in the present invention (eg, EP-A-0 573120, PCT Patent Application Publication Nos. WO 94/07928 and WO 95/14044 and US Pat. No. 5,153,157). And US Pat. No. 5,453,410. WO 98/09996 describes perchlorates, periodates and iodates and activating catalyst compounds, including their hydrates. WO 99/18135 uses organoboro aluminum activators EP-A-781299 describes the use of silyllium salts in combination with non-coordinating compatible anions Other activators or methods for the activation of catalytic compounds are described, for example, in US Pat. No. 5,849,852, 5,859,653 East, No. 5,869,723 claim is disclosed in EP-A-615981, and PCT Patent Application Publication No. WO 98/32775.
또다른 적합한 부류의 유기금속 활성화제 또는 보조촉매는, 알루목산 (또한 알킬알루미녹산으로서 지칭됨)이다. 알루목산은 부가 중합 촉매 제조를 위해 메탈로센형 촉매 화합물과 사용하는 것으로 공지된 활성화제이다. 알루목산 및 개질 알루목산의 다양한 제조 방법이 존재하며, 그의 비제한적 예는 미국 특허 제4,665,208호, 동 제4,952,540호, 동 제5,091,352호, 동 제5,206,199호, 동 제5,204,419호, 동 제4,874,734호, 동 제4,924,018호, 동 제4,908,463호, 동 제4,968,827호, 동 제5,308,815호, 동 제5,329,032호, 동 제5,248,801호, 동 제5,235,081호, 동 제5,157,137호, 동 제5,103,031호, 동 제5,391,793호, 동 제5,391,529호, 동 제5,693,838호, 동 제5,731,253호, 동 제5,731,451호, 동 제5,744,656호; 유럽특허출원 공개 제EP-A-561476호, 동 제EP-A-279586호 및 동 제EP-A-594218호; 및 PCT 특허출원 공개 제WO 94/10180호에 기재되어 있다. 바람직한 알루목산은 루이스산 개질된 알루목산, 특히 트리(C3-6)알킬알루미늄 개질된 메틸알루목산, 예컨대 트리(이소부틸)알루미늄 개질된 메탈루목산 (악조 노벨, 인코포레이티드(Akzo Nobel, Inc.)로부터 MMAO-3A로서 상업적으로 입수가능함) 또는 트리(n-옥틸)알루미늄 개질된 메탈루목산 (악조 노벨, 인코포레이티드로부터 MMAO-12로서 상업적으로 입수가능함)이다.Another suitable class of organometallic activator or cocatalyst is alumoxane (also referred to as alkylaluminoxane). Alumoxanes are activators known to be used with metallocene type catalyst compounds for the preparation of addition polymerization catalysts. There are various methods of making alumoxanes and modified alumoxanes, non-limiting examples of which are described in US Pat. Nos. 4,665,208, 4,952,540, 5,091,352, 5,206,199, 5,204,419, 4,874,734, 4,924,018, 4,908,463, 4,968,827, 5,308,815, 5,329,032, 5,248,801, 5,235,081, 5,157,137, 5,103,031, 5,391,793, 5,391,529, 5,693,838, 5,731,253, 5,731,451, 5,744,656; European Patent Application Publications EP-A-561476, EP-A-279586 and EP-A-594218; And PCT Patent Application Publication No. WO 94/10180. Preferred alumoxanes are Lewis acid modified alumoxanes, in particular tri (C 3-6 ) alkylaluminum modified methylalumoxanes such as tri (isobutyl) aluminum modified metallumoxanes (Azozo Nobel, Incorporated (Akzo Nobel) Commercially available as MMAO-3A from Co., Inc.) or tri (n-octyl) aluminum modified metallumoxane (Azo Nobel, commercially available as MMAO-12 from Incorporated).
본 발명의 방법에서 활성화제로서 또는 3차 성분으로서 알루목산(들) 또는 개질된 알루목산(들)을 사용하는 것은 본 발명의 범위 내에 있다. 즉, 화합물을 단독으로 또는 중성 또는 이온성인 다른 활성화제, 예컨대 트리(알킬)암모늄 테트라키스(펜타플루오로페닐)보레이트 화합물, 트리스퍼플루오로아릴 화합물, 폴리할로겐화 헤테로보란 음이온 (WO 98/43983에 개시된 바와 같음), 및 이들의 조합과 조합하여 사용할 수 있다. 3차 성분으로서 사용되는 경우, 알루목산의 사용량은 일반적으로 단독으로 사용되는 경우에 금속 착물을 효과적으로 활성화시키는 데 필요한 것보다 적은 양이다. 이러한 고려에 의해 국한되길 바라지는 않지만, 본 실시양태에서, 알루목산은 실제 촉매 활성화에 유의하게 기여하지 않는 것으로 여겨진다. 그럼에도 불구하고, 활성화 과정에서의 알루목산의 일부 참여가 반드시 배제되지는 않음을 이해하여야 한다.It is within the scope of the present invention to use alumoxane (s) or modified alumoxane (s) as activator or as tertiary component in the process of the present invention. That is, the compounds may be used alone or in neutral or ionic, such as tri (alkyl) ammonium tetrakis (pentafluorophenyl) borate compounds, trisperfluoroaryl compounds, polyhalogenated heteroborane anions (WO 98/43983). As disclosed), and combinations thereof. When used as tertiary components, the amount of alumoxane used is generally less than that required to effectively activate the metal complex when used alone. Although not wishing to be limited by this consideration, in the present embodiment, it is believed that alumoxane does not significantly contribute to the actual catalyst activation. Nevertheless, it should be understood that some involvement of alumoxane in the activation process is not necessarily excluded.
적합한 알루목산은 중합체 또는 올리고머 알루목산, 특히 메틸알루목산 (MAO) 뿐만 아니라 루이스 산 개질된 알루목산, 특히 각각의 히드로카르빌 또는 할로겐화된 히드로카르빌기 내에 1개 내지 10개의 탄소를 갖는 트리히드로카르빌알루미늄-, 할로겐화된 트리(히드로카르빌)알루미늄- 또는 할로겐화된 트리(히드로카르빌)붕소 개질된 알루목산을 포함한다. 이러한 활성화 보조촉매는 USP 6,214,760, 6,160,146, 6,140,521 및 6,696,379 등에서 이전에 개시되었다. 바람직한 루이스 산 개질된 알루목산 화합물은, 각각 10 내지 30, 바람직하게는 15 내지 25 몰%의 i-부틸 함량 및 10 내지 20, 바람직하게는 12 내지 18 몰%의 n-옥틸 함량을 갖는 (상기 몰%는 총 알킬 리간드 함량을 기준으로 한 것임) 트리(i-부틸)알루미늄 개질된 메탈루목산 및 트리(n-옥틸)알루미늄 개질된 메탈루목산이다. 알루목산 또는 루이스 산 개질된 알루목산 활성화제는 바람직하게는 20 내지 200, 보다 바람직하게는 20 내지 150, 가장 바람직하게는 20 내지 80의 보조촉매:촉매의 몰비로 사용된다.Suitable alumoxanes are polymer or oligomeric alumoxanes, in particular methylalumoxane (MAO) as well as Lewis acid modified alumoxanes, in particular trihydrocarbs having from 1 to 10 carbons in each hydrocarbyl or halogenated hydrocarbyl group Billuminum-, halogenated tri (hydrocarbyl) aluminum- or halogenated tri (hydrocarbyl) boron modified alumoxanes. Such activation cocatalysts have been previously disclosed in USP 6,214,760, 6,160,146, 6,140,521 and 6,696,379 and the like. Preferred Lewis acid modified alumoxane compounds each have an i-butyl content of 10-30, preferably 15-25 mol% and an n-octyl content of 10-20, preferably 12-18 mol% Mole% is based on total alkyl ligand content) tri (i-butyl) aluminum modified metallumoxane and tri (n-octyl) aluminum modified metallumoxane. The alumoxane or Lewis acid modified alumoxane activator is preferably used in a molar ratio of cocatalyst: catalyst of 20 to 200, more preferably 20 to 150, most preferably 20 to 80.
본 발명의 지르코늄 착물은, 높은 촉매 효율을 유지하면서 비교적 낮은 수준의 알루목산 또는 루이스 산 개질된 알루목산 보조촉매로 활성화되는 능력으로 인해, 생성된 중합체 중의 장쇄 분지 형성과 함께 생성된 중합체 중의 보조촉매 부산물 수준의 감소를 달성할 수 있다. 이러한 중합체는 특히 높은 투명성(clarity) 또는 낮은 유전 상수가 요구되는 것과 같은 용도 요구에 사용하기에 적합하다.The zirconium complexes of the present invention, due to their ability to be activated with relatively low levels of alumoxane or Lewis acid modified alumoxane cocatalysts while maintaining high catalytic efficiency, are cocatalysts in the resulting polymers with the formation of long chain branches in the resulting polymers. Reduction of by-product levels can be achieved. Such polymers are particularly suitable for use in application needs, such as where high clarity or low dielectric constant is required.
단량체Monomer
본원에서 사용하기에 적합한 올레핀 혼합물은, 에틸렌과 1종 이상의 C3-8 α-올레핀 공단량체, 및 임의로는 1종 이상의 공액 또는 비공액 디엔의 혼합물을 포함한다. 바람직한 공단량체로는, 프로필렌, 이소부틸렌, 1-부텐, 1-펜텐, 1-헥센, 4-메틸-1-펜텐, 3-메틸-1-부텐, 3-메틸-1-펜텐, 4-메틸-1-펜텐 및 1-옥텐이 포함되나, 이에 제한되지는 않는다. Suitable olefin mixtures for use herein include mixtures of ethylene and one or more C 3-8 α-olefin comonomers, and optionally one or more conjugated or nonconjugated dienes. Preferred comonomers are propylene, isobutylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 3-methyl-1-butene, 3-methyl-1-pentene, 4- Methyl-1-pentene and 1-octene include, but are not limited to.
적합한 공액 또는 비공액 디엔은, 4개 내지 15개의 탄소 원자를 갖는 직쇄, 분지쇄 또는 시클릭 탄화수소 디엔을 포함한다. 그 예로는, 1,3-부타디엔, 1,3-펜타디엔, 1,3-헥사디엔, 1,4-헥사디엔, 디시클로펜타디엔, 노르보르나디엔, 에틸리덴노르보르넨 및 이들의 혼합물이 포함되나, 이에 제한되지는 않는다. 가장 바람직한 디엔은 5-에틸리덴-2-노르보르넨 (ENB)이다.Suitable conjugated or nonconjugated dienes include straight chain, branched chain or cyclic hydrocarbon dienes having 4 to 15 carbon atoms. Examples include 1,3-butadiene, 1,3-pentadiene, 1,3-hexadiene, 1,4-hexadiene, dicyclopentadiene, norbornadiene, ethylidenenorbornene and mixtures thereof This includes, but is not limited to. Most preferred diene is 5-ethylidene-2-norbornene (ENB).
일반적으로, 중합은 올레핀 용액 중합 반응을 위해 종래 기술에서 공지된 조건에서 달성할 수 있다. 바람직한 중합 온도는 생성된 중합체의 공단량체 함량에 의존한다. 0.855 내지 0.885 g/cc 범위의 밀도를 갖는 중합체를 위해, 바람직한 온도 범위는 120 내지 250℃, 보다 바람직하게는 150 내지 220℃이다. 0.885 내지 0.955 g/cc 범위의 밀도를 갖는 중합체를 위해, 바람직한 온도 범위는 150 내지 250℃, 보다 바람직하게는 180 내지 250℃이다. 바람직한 중합 압력은 대기압 내지 3000 기압 (100 kPa 내지 300 MPa), 보다 바람직하게는 1 MPa 내지 10 MPa이다. 대부분의 중합 반응에서 사용되는 촉매:중합성 화합물의 몰비는 10-12:1 내지 10-1:1, 보다 바람직하게는 10-11:1 내지 10-5:1이다. 매우 바람직하게는, 반응은 연속적 용액 중합 조건 하에, 즉 단량체(들)를 용액 중합 조건 하에 작동하는 반응기에 연속적으로 첨가하고, 중합된 생성물을 연속적으로 또는 반-연속적으로 제거하여 회수하거나 제2 반응기로 보내는 조건 하에 수행된다.In general, the polymerization can be achieved at conditions known in the art for olefin solution polymerization. Preferred polymerization temperatures depend on the comonomer content of the resulting polymer. For polymers having a density in the range of 0.855 to 0.885 g / cc, the preferred temperature range is 120 to 250 ° C, more preferably 150 to 220 ° C. For polymers having a density in the range of 0.885 to 0.955 g / cc, the preferred temperature range is 150 to 250 ° C, more preferably 180 to 250 ° C. Preferred polymerization pressures are from atmospheric pressure to 3000 atmospheres (100 kPa to 300 MPa), more preferably 1 MPa to 10 MPa. Used in the majority of the polymerization catalyst the molar ratio of polymerizable compound is 10 -12: 1 to 10 -1: 1, more preferably from 10 -11: 1: 1 to 10 -5. Very preferably, the reaction is successively added to a reactor operating under continuous solution polymerization conditions, ie the monomer (s) are operated under solution polymerization conditions and the polymerized product is recovered by continuous or semi-continuous removal or recovered in a second reactor. Is carried out under conditions of sending.
바람직하게는, 상기 중합 혼합물은 지방족 또는 지환족 액체 희석제를 포함한다. 이러한 지방족 또는 지환족 액체 희석제의 예로는, 직쇄 및 분지쇄의 탄화수소, 예컨대 이소부탄, 부탄, 펜탄, 헥산, 헵탄, 옥탄 및 이들의 혼합물; 지환족 탄화수소, 예컨대 시클로헥산, 시클로헵탄, 메틸시클로헥산, 메틸시클로헵탄 및 이들의 혼합물; 및 퍼플루오르화 탄화수소, 예컨대 퍼플루오르화 C4 -10 알칸 등이 포함된다. 톨루엔, 에틸벤젠 또는 크실렌 등의 방향족 탄화수소가 소량 포함될 수도 있으나, 바람직하지는 않다. 상기한 것들의 혼합물이 또한 적합하다. 바람직한 액체 희석제는, 증류, ASTM D 86, IBP가 118℃, 증류, ASTM D 86, 건조 점이 137℃, 또한 비중, 15.6℃, ASTM D 1250이 0.72인, 엑손모빌 코포레이션(ExxonMobil Corporation)으로부터 입수가능한 상표명 이소파르™ E로 시판되는 수소화된 올리고머 지방족 탄화수소 혼합물이다. Preferably, the polymerization mixture comprises an aliphatic or cycloaliphatic liquid diluent. Examples of such aliphatic or cycloaliphatic liquid diluents include straight and branched chain hydrocarbons such as isobutane, butane, pentane, hexane, heptane, octane and mixtures thereof; Alicyclic hydrocarbons such as cyclohexane, cycloheptane, methylcyclohexane, methylcycloheptane and mixtures thereof; And is the buffer containing the fluorinated hydrocarbons such as perfluorinated C 4 -10 alkanes and the like. A small amount of aromatic hydrocarbons such as toluene, ethylbenzene or xylene may be included, but is not preferred. Mixtures of the foregoing are also suitable. Preferred liquid diluents are available from ExxonMobil Corporation, distillation, ASTM D 86, IBP of 118 ° C, distillation, ASTM D 86, dry point of 137 ° C, also specific gravity, 15.6 ° C, ASTM D 1250 of 0.72. Hydrogenated oligomeric aliphatic hydrocarbon mixtures sold under the tradename Isopar ™ E.
본 발명의 방법에서는 분자량 조절제 또는 사슬 전달제를 사용하는 것이 바람직하다. 이러한 분자량 조절제의 예로는, 수소, 트리알킬 알루미늄 화합물, 또는 기타 공지된 사슬 전달제가 포함된다. 수소가 가장 바람직한 분자량 조절제 또는 사슬 전달제다. 본 발명을 이용하는 것의 특별한 이점은 좁은 분자량 분포의 에틸렌/α-올레핀 인터폴리머를 제조할 수 있는 능력 (반응 조건에 따라)이다. 이러한 좁은 분자량 분포의 중합체 생성물은 감소된 수준의 추출가능 물질 및 금속 값 뿐만 아니라 향상된 인장 강도 특성으로 인하여 매우 바람직하다.Preference is given to using molecular weight regulators or chain transfer agents in the process of the invention. Examples of such molecular weight modifiers include hydrogen, trialkyl aluminum compounds, or other known chain transfer agents. Hydrogen is the most preferred molecular weight regulator or chain transfer agent. A particular advantage of using the present invention is its ability to produce narrow molecular weight distributions of ethylene / a-olefin interpolymers (depending on reaction conditions). Such narrow molecular weight distribution polymer products are highly desirable due to reduced levels of extractable material and metal values as well as improved tensile strength properties.
본 발명의 범위를 어떤 식으로든 제한하지 않고, 본 발명의 중합 방법을 수행하기 위한 하나의 수단은 하기와 같다. 교반-탱크 반응기에, 중합될 단량체를 임의의 용매 또는 희석제와 함께 연속적으로 도입한다. 반응기는 실질적으로 단량체와 함께 임의의 용매 또는 희석제 및 용해된 중합체로 구성된 액체 상을 함유한다. 보조촉매 및 임의로는 사슬 전달제와 함께 촉매를 상기 반응기의 액체 상 또는 그의 임의의 재순환된 부분에 연속적으로 또는 간헐적으로 도입한다. 반응기 온도는 용매/단량체 비, 촉매 첨가 속도를 조정함으로써, 뿐만 아니라 코일, 재킷 또는 이들 둘 다를 냉각 또는 가열하는 것을 이용하여 조절될 수 있다. 중합 속도는 촉매 첨가 속도에 의해 조절된다. 압력은 단량체 유량 및 휘발성 성분의 분압에 의해 조절된다. 중합체 생성물의 에틸렌 함량은 반응기 중 에틸렌 대 공단량체의 비에 의해 결정되며, 이는 이들 성분 각각의 반응기로의 공급 유량을 조절함으로써 조절된다. 중합체 생성물의 분자량은 온도, 단량체 농도 등의 여타 중합 변수를 조절함으로써, 또는 상기에 언급된 사슬 전달제의 유량에 의해 임의로 조절된다. 반응기를 빠져나오면, 유출물을 물, 수증기 또는 알코올 등의 촉매 소멸제와 접촉시킨다. 중합체 용액을 임의로 가열하고, 기체상 단량체 뿐만 아니라 잔류 용매 또는 희석제를 감압 하에 증발시킴으로써 중합체 생성물을 회수하고, 필요하다면 탈휘발화 압출기 등의 장비에서 추가의 탈휘발화를 수행한다. 연속적 공정에서, 촉매 및 중합체의 반응기 중 평균 체류 시간은 일반적으로 5분 내지 8시간, 바람직하게는 10분 내지 6시간이다.Without limiting in any way the scope of the present invention, one means for carrying out the polymerization process of the present invention is as follows. In a stirred-tank reactor, the monomers to be polymerized are introduced continuously with any solvent or diluent. The reactor contains substantially a liquid phase consisting of any solvent or diluent and dissolved polymer together with the monomers. The catalyst, together with the cocatalyst and optionally the chain transfer agent, is introduced continuously or intermittently into the liquid phase of the reactor or any recycled portion thereof. The reactor temperature can be adjusted by adjusting the solvent / monomer ratio, catalyst addition rate, as well as by cooling or heating the coil, jacket or both. The rate of polymerization is controlled by the rate of catalyst addition. The pressure is controlled by the monomer flow rate and the partial pressure of the volatile components. The ethylene content of the polymer product is determined by the ratio of ethylene to comonomers in the reactor, which is controlled by controlling the feed flow rate of each of these components to the reactor. The molecular weight of the polymer product is optionally adjusted by adjusting other polymerization parameters such as temperature, monomer concentration, or by the flow rates of the chain transfer agents mentioned above. Upon exiting the reactor, the effluent is contacted with a catalyst quenching agent such as water, steam or alcohol. The polymer solution is optionally heated and the polymer product is recovered by evaporation of the gaseous monomers as well as residual solvents or diluents under reduced pressure and, if necessary, further devolatilization is carried out in equipment such as a devolatilization extruder. In a continuous process, the average residence time of the catalyst and polymer in the reactor is generally 5 minutes to 8 hours, preferably 10 minutes to 6 hours.
별법으로, 상기 중합은 반응기의 상이한 영역들 간에 구축된 단량체, 공단량체, 촉매 또는 보조촉매의 구배의 존재 또는 부재 하에 연속적 루프 반응기에서, 임의로는 촉매 및/또는 사슬 전달제의 별도 첨가와 함께, 및 단열 또는 비-단열 용액 중합 조건 하에, 또는 상기 반응기 조건의 조합 하에 작업하여 수행할 수 있다. 적합한 루프 반응기 및 그와 함께 사용하기에 적합한 다양한 작업 조건의 예는, USP 5,977,251, 6,319,989 및 6,683,149에서 찾아볼 수 있다.Alternatively, the polymerization may be carried out in a continuous loop reactor in the presence or absence of a gradient of monomers, comonomers, catalysts or cocatalysts built between different regions of the reactor, optionally with separate addition of catalyst and / or chain transfer agent, And under adiabatic or non-insulating solution polymerization conditions, or a combination of the above reactor conditions. Examples of suitable loop reactors and various working conditions suitable for use with them can be found in USP 5,977,251, 6,319,989 and 6,683,149.
다중 반응기 중합 방법이 본 발명에서 적합하게 사용된다. 그 예는, 특히 USP 3,914,342에 개시된 것과 같은 시스템을 포함한다. 다중 반응기는 하나 이상의 반응기에서 사용되는 1종 이상의 본 발명에 따른 촉매 조성물을 사용하여 연속하여 또는 동시에 작동될 수 있다. 하나의 반응기 또는 반응기 둘 다가 상이한 공단량체 도입능 및/또는 상이한 분자량 성능을 갖는 2종 이상의 촉매를 함유할 수도 있다. 일 실시양태에서는, 비교적 고분자량의 생성물 (Mw가 100,000 내지 1,000,000 초과, 보다 바람직하게는 200,000 내지 500,000)이 형성되며, 제2 반응기에서는 비교적 저분자량 (Mw가 2,000 내지 300,000)의 생성물이 형성된다. 이들 반응기 생성물 둘 다 유사하거나 상이한 밀도를 가질 수 있다. 최종 생성물은 두 반응기 유출물의 혼합물이며, 이는 두 중합체 생성물의 균일한 혼합을 제공하는 탈휘발화 전에 조합된다. 또다른 실시양태에서, 두 반응기로부터의 생성물의 분자량은 거의 동일하지만, 밀도는 반응기 중 하나가 0.865 내지 0.895 범위의 밀도를 갖는 중합체를 형성하면서, 다른 반응기는 0.885 내지 0.950 범위의 상이한 밀도를 갖는 중합체를 형성하는 정도로 달라진다. 이러한 이중 반응기/이중 촉매 방법은 맞춤화된(tailored) 특성을 갖는 생성물의 제조를 가능하게 한다. 일 실시양태에서는, 반응기를 직렬로 연결하고, 즉 제1 반응기로부터의 유출물을 제2 반응기로 향하게 하고, 새로운 단량체, 용매 및 수소를 임의로 제2 반응기에 첨가한다. 반응기 조건은 제1 반응기에서 생성된 중합체와 제2 반응기에서 생성된 중합체의 중량비가 이상적으로 20:80 내지 80:20 범위가 되도록 조정한다. 당업자는 상기 이중 반응기 방법으로부터 확장된 분자량 분포 또는 다분산 지수 (PDI)를 갖는 중합체를 생성할 수 있음을 인지한다. 상기 방식으로 제조된 바람직한 중합체는 2.8 내지 6.0, 보다 바람직하게는 3.0 내지 5.0의 PDI를 갖는다. 또한, 바람직한 실시양태에서, 고분자량 성분은 저분자량 성분에 비해 보다 많은 양의 공단량체 (보다 저밀도)를 함유한다.Multiple reactor polymerization processes are suitably used in the present invention. Examples include, in particular, systems such as those disclosed in USP 3,914,342. Multiple reactors can be operated continuously or simultaneously using one or more catalyst compositions according to the invention used in one or more reactors. One reactor or both reactors may contain two or more catalysts having different comonomer introduction and / or different molecular weight performance. In one embodiment, a relatively high molecular weight product (M w is greater than 100,000 to 1,000,000, more preferably 200,000 to 500,000) is formed, and a relatively low molecular weight (M w is 2,000 to 300,000) product is formed in the second reactor. do. Both of these reactor products may have similar or different densities. The final product is a mixture of two reactor effluents, which are combined prior to devolatilization which gives a uniform mixing of the two polymer products. In another embodiment, the molecular weights of the products from the two reactors are about the same, but the density is such that one of the reactors forms a polymer having a density in the range of 0.865 to 0.895, while the other reactor has a different density in the range of 0.885 to 0.950. Vary to form. This dual reactor / dual catalyst process allows the production of products with tailored properties. In one embodiment, the reactors are connected in series, that is, the effluent from the first reactor is directed to the second reactor and fresh monomer, solvent and hydrogen are optionally added to the second reactor. Reactor conditions are adjusted such that the weight ratio of the polymer produced in the first reactor to the polymer produced in the second reactor ideally ranges from 20:80 to 80:20. One skilled in the art recognizes that polymers having extended molecular weight distribution or polydispersity index (PDI) can be produced from the dual reactor process. Preferred polymers prepared in this way have a PDI of 2.8 to 6.0, more preferably 3.0 to 5.0. In a preferred embodiment, the high molecular weight component also contains a greater amount of comonomer (lower density) compared to the low molecular weight component.
또다른 실시양태에서, 중합 방법에서의 반응기 중 하나 (연속 작동되는 두 반응기 중 제1 반응기 포함)는 불균질 지글러-나타(Ziegler-Natta) 촉매 또는 크롬 함유 촉매, 예컨대 당업계에 공지된 많은 촉매 중 하나를 함유한다. 지글러-나타 촉매의 예로는, MgCl2 상에 지지된 티탄 기재의 촉매가 포함되나 이에 제한되지는 않고, 이는 추가로 1개 이상의 알루미늄-알킬 결합을 함유하는 알루미늄 화합물을 포함한다. 적합한 지글러-나타 촉매 및 이들의 제법은, USP 4,612,300, 4,330,646, 및 5,869,575에 개시된 것들을 포함하나, 이에 제한되지는 않는다. 적합한 크롬 기재의 촉매는 USP 4,981,927, 4,835,219, 4,564,660, 4,173,548, 3,953,413 등에 개시된 것들이다. In another embodiment, one of the reactors in the polymerization process (including the first reactor of two continuously operated reactors) is a heterogeneous Ziegler-Natta catalyst or a chromium containing catalyst such as many catalysts known in the art. Contains one. Examples of Ziegler-Natta catalysts include, but are not limited to, titanium based catalysts supported on MgCl 2 , which further include aluminum compounds containing at least one aluminum-alkyl bond. Suitable Ziegler-Natta catalysts and their preparation include, but are not limited to, those disclosed in USP 4,612,300, 4,330,646, and 5,869,575. Suitable chromium based catalysts are those disclosed in USP 4,981,927, 4,835,219, 4,564,660, 4,173,548, 3,953,413 and the like.
단일 반응기에서의 다중 촉매 방법 또한 본 발명에서 유용하다. 일 실시양태에서는, 2종 이상의 촉매를 본원에 개시된 반응 조건에서 단일 반응기 내에 도입하며, 여기서 각각의 촉매는 고유하게 상이한 폴리올레핀 공중합체를 생성한다. 일 실시양태에서는, 비교적 고분자량의 생성물 (Mw가 100,000 내지 1,000,000 초과, 보다 바람직하게는 200,000 내지 500,000)이 하나의 촉매로부터 형성되며, 비교적 저분자량 (Mw가 2,000 내지 300,000)의 생성물이 다른 촉매로부터 형성된다. 이들 촉매 조성물 둘 다 유사하거나 상이한 공단량체 도입능을 가질 수 있다. 생성된 중합체는 단일 반응기에서 사용된 두 촉매의 비율에 따라 달라지는 특성을 갖는다. 이동제가 사용되는 경우에는, 상이한 조성 및 물리적 특성을 갖는 중합체 세그먼트를 포함하는 멀티-블록 공중합체가 하나 이상의 반응기에서 제조될 수 있다. 중합체 분자량, 공단량체 도입능, 방법 및 이러한 생성물에 대한 촉매 비율의 적합한 조합이 USP 6,924,342, WO 2005/090425, WO 2005/090426 및 WO 2005/090427에 개시되어 있다. 본 발명의 촉매 조성물의 다른 올레핀 중합 촉매 (지글러/나타 촉매 포함)와의 독특한 상용성으로 인해, 제2 촉매 조성물은 본원에 개시된 바와 같은 금속 착물, 메탈로센 또는 다른 π-결합 리간드기를 함유하는 금속 착물 (구속된 기하구조의 금속 착물 포함), 또는 본 발명의 착물과 상이한 다가 헤테로원자 리간드기를 함유하는 금속 착물, 특히 다가 피리딜아민 또는 이미다졸릴아민 기재의 착물 및 4자리 산소-리게이트(oxygen-ligated) 비페닐페놀 기재의 4족 금속 착물을 포함할 수 있다.Multiple catalyst processes in a single reactor are also useful in the present invention. In one embodiment, two or more catalysts are introduced into a single reactor at the reaction conditions disclosed herein, wherein each catalyst produces a uniquely different polyolefin copolymer. In one embodiment, a relatively high molecular weight product (M w is greater than 100,000 to 1,000,000, more preferably 200,000 to 500,000) is formed from one catalyst and the relatively low molecular weight (M w is 2,000 to 300,000) product is different It is formed from a catalyst. Both of these catalyst compositions can have similar or different comonomer incorporation capacity. The resulting polymer has properties that depend on the ratio of the two catalysts used in a single reactor. If a transfer agent is used, multi-block copolymers comprising polymer segments having different compositions and physical properties can be prepared in one or more reactors. Suitable combinations of polymer molecular weight, comonomer incorporation capacity, methods and catalyst ratios for such products are disclosed in USP 6,924,342, WO 2005/090425, WO 2005/090426 and WO 2005/090427. Due to the unique compatibility of the catalyst composition of the present invention with other olefin polymerization catalysts (including Ziegler / Natta catalysts), the second catalyst composition is a metal containing a metal complex, metallocene or other π-linked ligand group as disclosed herein. Complexes (including metal complexes of constrained geometry), or metal complexes containing polyvalent heteroatomic ligand groups different from the complexes of the present invention, in particular complexes based on polyvalent pyridylamine or imidazolylamine and tetradentate oxygen-regate ( oxygen-ligated) biphenylphenol based Group 4 metal complexes.
<구체적 실시양태>Specific Embodiments
첨부된 청구의 범위에 대한 구체적 개시를 위해 하기 실시양태가 제공된다.The following embodiments are provided for specific disclosure of the appended claims.
1. 다가 아릴옥시에테르의 지르코늄 또는 하프늄 착물을 포함하는 촉매 조성물의 존재 하에 중합을 수행하는 것을 포함하며, 3.0 이하, 바람직하게는 2.7 이하, 가장 바람직하게는 2.4 이하의 분자량 분포 (Mw/Mn), 0.850 내지 0.950, 보다 바람직하게는 0.860 내지 0.930, 가장 바람직하게는 0.865 내지 0.920의 중합체 밀도를 제공하는 공단량체 함량, 및 10 이하의 I10/I2, 보다 바람직하게는 6.0 내지 10.0의 I10/I2를 갖는 것을 특징으로 하는 고분자량 중합체의 제조를 위한 연속적 용액 중합 조건 하에서의 에틸렌과 1종 이상의 C3-30 α-올레핀 또는 디올레핀의 중합 방법.1. Performing polymerization in the presence of a catalyst composition comprising a zirconium or hafnium complex of a polyvalent aryloxy ether, having a molecular weight distribution (M w / M of 3.0 or less, preferably 2.7 or less, most preferably 2.4 or less). n ), comonomer content providing a polymer density of 0.850 to 0.950, more preferably 0.860 to 0.930, most preferably 0.865 to 0.920, and I 10 / I 2 of 10 or less, more preferably 6.0 to 10.0 A process for the polymerization of ethylene and at least one C 3-30 α-olefin or diolefin under continuous solution polymerization conditions for the preparation of high molecular weight polymers characterized by having I 10 / I 2 .
2. 중합체가 0.01 내지 50 범위, 바람직하게는 0.1 내지 30, 가장 바람직하게는 0.3 내지 10의 I10/I2값에 대해 수학식 I10/I2 ≤ 10.32(MI)-0.0814를 만족시키는 I10 및 I2 특성을 갖는 것인, 실시양태 1에 따른 방법. 2. The polymer satisfies the formula I 10 / I 2 ≤ 10.32 (MI) -0.0814 for an I 10 / I 2 value in the range from 0.01 to 50, preferably from 0.1 to 30, most preferably from 0.3 to 10 The method according to embodiment 1, having 10 and I 2 properties.
3. 공중합된 에틸렌 및 1-옥텐을 주성분으로 하는 것인, 실시양태 1에 따른 방법.3. The process according to embodiment 1, consisting mainly of copolymerized ethylene and 1-octene.
4. 85% 이상의 에틸렌 전환율로 작업하는 것인, 실시양태 1에 따른 방법.4. The process according to embodiment 1, which works at an ethylene conversion of at least 85%.
5. 하기 화학식에 상응하는 다가 아릴옥시에테르의 지르코늄 착물을 포함하는 촉매 조성물의 존재 하에 중합을 수행하는 것을 포함하는, 고분자량 중합체의 제조를 위한 연속적 용액 중합 조건 하에서의 에틸렌과 1종 이상의 C3-30 α-올레핀 또는 디올레핀의 중합 방법. 5. Ethylene and at least one C 3- under continuous solution polymerization conditions for the preparation of high molecular weight polymers, comprising performing the polymerization in the presence of a catalyst composition comprising a zirconium complex of polyvalent aryloxyethers corresponding to the formula 30 Process for the polymerization of α-olefins or diolefins.
상기 식에서, Where
M3은 Hf 또는 Zr, 바람직하게는 Zr이고;M 3 is Hf or Zr, preferably Zr;
Ar4는 각 경우에 독립적으로 치환된 C9-20 아릴기이며, 여기서 치환체는 각 경우에 독립적으로 알킬; 시클로알킬; 및 아릴기; 및 할로-, 트리히드로카르빌실릴- 및 할로히드로카르빌-치환된 이들의 유도체로 구성된 군으로부터 선택되되, 단 1개 이상의 치환체는 그것이 결합된 아릴기와 동일평면성을 갖지 않아야 하며;Ar 4 is a C 9-20 aryl group independently substituted at each occurrence, wherein the substituents are independently alkyl at each occurrence; Cycloalkyl; And aryl groups; And halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, provided that at least one substituent does not have coplanarity with the aryl group to which it is attached;
T4는 각 경우에 독립적으로 C2-20 알킬렌, 시클로알킬렌 또는 시클로알케닐렌기, 또는 불활성 치환된 이들의 유도체이고; T 4 in each occurrence is independently a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or inert substituted derivative thereof;
R21은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노기이며; R 21 independently in each occurrence is hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) having up to 50 atoms, excluding hydrogen ) An amino group;
R3은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 아미노이거나, 또는 동일한 아릴렌 고리 상의 2개의 R3기는 함께, 또는 동일하거나 상이한 아릴렌 고리 상의 R3 및 R21기는 함께 2개의 위치에서 아릴렌기에 결합된 2가 리간드기를 형성하거나, 또는 2개의 상이한 아릴렌 고리를 함께 연결시키고;R 3 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino having up to 50 atoms, excluding hydrogen, or the same Two R 3 groups on the arylene ring together or R 3 and R 21 groups on the same or different arylene ring together form a divalent ligand group bonded to an arylene group at two positions, or two different arylene rings Connect together;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 디엔 또는 폴리(히드로카르빌)실릴렌기이다. R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, Diene or poly (hydrocarbyl) silylene group.
6. 금속 착물이 하기 화학식에 상응하는 것인, 실시양태 1에 따른 방법.6. The process according to embodiment 1, wherein the metal complex corresponds to the formula
상기 식에서, Where
M3은 Hf 또는 Zr, 바람직하게는 Zr이고;M 3 is Hf or Zr, preferably Zr;
Ar4는 각 경우에 독립적으로 치환된 C9-20 아릴기이며, 여기서 치환체는 각 경우에 독립적으로 알킬; 시클로알킬; 및 아릴기; 및 할로-, 트리히드로카르빌실릴- 및 할로히드로카르빌-치환된 이들의 유도체로 구성된 군으로부터 선택되되, 단 치환체는 그것이 결합된 아릴기와 동일평면성을 갖지 않아야 하며;Ar 4 is a C 9-20 aryl group independently substituted at each occurrence, wherein the substituents are independently alkyl at each occurrence; Cycloalkyl; And aryl groups; And halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, provided that the substituents do not have coplanarity with the aryl groups to which they are attached;
T4는 각 경우에 독립적으로 C2-20 알킬렌, 시클로알킬렌 또는 시클로알케닐렌기, 또는 불활성 치환된 이들의 유도체이고; T 4 in each occurrence is independently a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or inert substituted derivative thereof;
R21은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노기이며; R 21 independently in each occurrence is hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) having up to 50 atoms, excluding hydrogen ) An amino group;
R3은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 아미노이거나, 또는 동일한 아릴렌 고리 상의 2개의 R3기 또는 동일하거나 상이한 아릴렌 고리 상의 R3 및 R21기는 함께 2개의 위치에서 아릴렌기에 결합된 2가 리간드기를 형성하거나, 또는 2개의 상이한 아릴렌 고리를 함께 연결시키고;R 3 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino having up to 50 atoms, excluding hydrogen, or the same Two R 3 groups on the arylene ring or R 3 and R 21 groups on the same or different arylene ring together form a divalent ligand group bonded to an arylene group at two positions, or linking together two different arylene rings To;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 디엔 또는 폴리(히드로카르빌)실릴렌기이다. R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, Diene or poly (hydrocarbyl) silylene group.
7. 각각의 Ar4기가 1개 이상의 입체적으로 벌키한 기, 바람직하게는 2개의 입체적으로 벌키한 기로 치환되고, 상이한 아릴렌옥시기 상에 위치한 2개 이상의 R3기가 입체적으로 벌키한 것인, 실시양태 5 또는 6의 방법. 7. The practice wherein each Ar 4 group is substituted with at least one steric bulky group, preferably two steric bulky groups, and at least two R 3 groups located on different aryleneoxy groups are steric bulky The method of
8. 각각의 Ar4기가 하기 화학식에 상응하는 것인, 실시양태 7에 따른 방법.8. The process according to
상기 식에서, R11은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노이거나, 또는 2개의 R11기는 함께 2개의 위치에서 아릴기에 결합된 고리의 일부이되, 단 하나 이상의 경우의 R11 또는 2개의 상기 R11기의 2가 유도체는 입체적으로 벌키하다. Wherein R 11 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di ( Hydrocarbyl) amino, or two R 11 groups together form part of a ring bonded to an aryl group at two positions, with only one or more instances of R 11 or two divalent derivatives of said R 11 groups being steric bulky .
9. 입체적으로 벌키한 R11 및 R3 치환체가 3개 내지 20개의 비-수소 원자를 갖는 3급 알킬-, 시클로알킬-, 아릴-, 트리히드로카르빌실릴-, 트리(히드로카르빌)실릴히드로카르빌- 및 트리(히드로카르빌)페닐기로 구성된 군으로부터 독립적으로 선택되는 것인, 실시양태 8의 방법. 9. Ternally bulky R 11 and R 3 substituents are tertiary alkyl-, cycloalkyl-, aryl-, trihydrocarbylsilyl-, tri (hydrocarbyl) silyl having 3 to 20 non-hydrogen atoms The method of
10. 입체적으로 벌키한 R11 및 R3 치환체가 tert-부틸, sec-부틸, tert-옥틸 (2,4,4-트리메틸펜탄-2-일), 1-페닐에틸, 2,3-디메틸-부트-2-일, 트리틸 (트리페닐메틸), 쿠밀 (2-페닐프로프-2-일), tert-아밀 (1,1-디메틸프로필), 페닐, 시클로헥실, 트리메틸실릴, 트리메틸실릴메틸, 이소프로필, 2,4,6-트리메틸페닐, 2,6-디메틸페닐, 3,5-디(이소프로필)페닐 및 3,5-디(t-부틸)페닐로 구성된 군으로부터 독립적으로 선택되는 것인, 실시양태 9의 방법. 10. The stericly bulky R 11 and R 3 substituents are tert-butyl, sec-butyl, tert-octyl (2,4,4-trimethylpentan-2-yl), 1-phenylethyl, 2,3-dimethyl- But-2-yl, trityl (triphenylmethyl), cumyl (2-phenylprop-2-yl), tert-amyl (1,1-dimethylpropyl), phenyl, cyclohexyl, trimethylsilyl, trimethylsilylmethyl Independently selected from the group consisting of isopropyl, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 3,5-di (isopropyl) phenyl and 3,5-di (t-butyl) phenyl The method of embodiment 9,
11. 금속 착물이 하기 화학식에 상응하는 것인, 실시양태 6의 방법.11. The method of
상기 식에서,Where
M3은 Zr이고;M 3 is Zr;
Ar4는 3,5-디(tert-부틸)페닐, 3,5-디(이소프로필)페닐, 3,5-디(이소부틸)페닐, 3,5-디(tert-옥틸)페닐, 3,5-디(2,4,6-트리메틸페닐)페닐, 3,5-디(2,6-디메틸페닐)페닐, 3,5-디(2,4,6-트리-이소프로필페닐)페닐, 3,5-디(3,5-디-tert-부틸페닐)페닐, 1,2,3,4,6,7,8,9-옥타히드로안트라센-5-일, 3,6-디(tert-부틸)-9H-카르바졸-9-일 또는 3,6-디(tert-옥틸)-9H-카르바졸-9-일이며;Ar 4 is 3,5-di (tert-butyl) phenyl, 3,5-di (isopropyl) phenyl, 3,5-di (isobutyl) phenyl, 3,5-di (tert-octyl) phenyl, 3 , 5-di (2,4,6-trimethylphenyl) phenyl, 3,5-di (2,6-dimethylphenyl) phenyl, 3,5-di (2,4,6-tri-isopropylphenyl) phenyl , 3,5-di (3,5-di-tert-butylphenyl) phenyl, 1,2,3,4,6,7,8,9-octahydroanthracene-5-yl, 3,6-di ( tert-butyl) -9H-carbazol-9-yl or 3,6-di (tert-octyl) -9H-carbazol-9-yl;
R21은 각 경우에 독립적으로 메틸 또는 tert-부틸이고;R 21 in each occurrence is independently methyl or tert-butyl;
R3은 각 경우에 독립적으로 분지형 알킬, 시클로알킬, 치환된 아릴, 또는 다른 입체적으로 벌키한 기이며;R 3 in each occurrence is independently branched alkyl, cycloalkyl, substituted aryl, or other stericly bulky group;
T4는 프로판-1,3-디일, 부탄-1,4-디일, 시클로헥산-1,2-디일 또는 시클로헥산-1,2-디메틸렌이고;T 4 is propane-1,3-diyl, butane-1,4-diyl, cyclohexane-1,2-diyl or cyclohexane-1,2-dimethylene;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 1,4-디히드로카르빌-치환된 1,3-부타디엔 또는 폴리(히드로카르빌)실릴렌기이다.R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, 1,4-dihydrocarbyl-substituted 1,3-butadiene or poly (hydrocarbyl) silylene groups.
12. 각각의 Ar4 고리 상의 1개 이상의 R11기, 가장 바람직하게는 Ar4 페닐 고리의 3번 및 5번 위치의 2개의 상기 R11기, 및 상이한 아릴렌 고리 상의 2개 이상의 R3기가 3개 내지 20개의 탄소, 바람직하게는 4개 내지 12개의 탄소를 함유하는 분지형 알킬, 시클로알킬, 히드로카르빌-치환된 아릴 또는 폴리(히드로카르빌)-치환된 실릴기인, 실시양태 11의 방법.12. One or more R 11 groups on each Ar 4 ring, most preferably two said R 11 groups in positions 3 and 5 of the Ar 4 phenyl ring, and two or more R 3 groups on different arylene rings Of
13. 각각의 Ar4 고리 상의 2개의 R11기 및 상이한 아릴렌 고리 상의 2개의 R3기가 tert-부틸 또는 tert-옥틸인, 실시양태 12의 방법.13. The method of
14. 금속 착물이 14. metal complexes
(상기 식에서, RD는 각 경우에 독립적으로 클로라이드, 메틸 또는 벤질임)Wherein R D is independently at each occurrence chloride, methyl or benzyl
로 구성된 군으로부터 선택되는 것인, 실시양태 11의 방법.The method of
15. 금속 착물이 15. Metal Complexes
A) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,A) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
B) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, B) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentane-2 -Yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
C) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,C) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) Propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
D) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, D) Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
E) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, E) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
F) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, F) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4, 4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
G) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, G) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1, 3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
H) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, H) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, 및 Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride, and
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl
로 구성된 군으로부터 선택되는 것인, 실시양태 14의 방법.The method of embodiment 14, wherein the method is selected from the group consisting of:
16. 하기 화학식에 상응하는 다가 아릴옥시에테르의 금속 착물.16. A metal complex of a polyvalent aryloxyether corresponding to the formula
상기 식에서, Where
M3은 Hf 또는 Zr, 바람직하게는 Zr이고;M 3 is Hf or Zr, preferably Zr;
Ar4는 각 경우에 독립적으로 치환된 C9-20 아릴기이며, 여기서 치환체는 각 경우에 독립적으로 알킬; 시클로알킬; 및 아릴기; 및 할로-, 트리히드로카르빌실릴- 및 할로히드로카르빌-치환된 이들의 유도체로 구성된 군으로부터 선택되되, 단 1개 이상의 치환체는 그것이 결합된 아릴기와 동일평면성을 갖지 않으며;Ar 4 is a C 9-20 aryl group independently substituted at each occurrence, wherein the substituents are independently alkyl at each occurrence; Cycloalkyl; And aryl groups; And halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, provided that at least one substituent does not have coplanarity with the aryl group to which it is attached;
T4는 각 경우에 독립적으로 C2-20 알킬렌, 시클로알킬렌 또는 시클로알케닐렌기, 또는 불활성 치환된 이들의 유도체이고; T 4 in each occurrence is independently a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or inert substituted derivative thereof;
R21은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노기이며; R 21 independently in each occurrence is hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) having up to 50 atoms, excluding hydrogen ) An amino group;
R3은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 아미노이거나, 또는 동일한 아릴렌 고리 상의 2개의 R3기는 함께, 또는 동일하거나 상이한 아릴렌 고리 상의 R3 및 R21기는 함께 2개의 위치에서 아릴렌기에 결합된 2가 리간드기를 형성하거나, 또는 2개의 상이한 아릴렌 고리를 함께 연결시키고;R 3 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino having up to 50 atoms, excluding hydrogen, or the same Two R 3 groups on the arylene ring together or R 3 and R 21 groups on the same or different arylene ring together form a divalent ligand group bonded to an arylene group at two positions, or two different arylene rings Connect together;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 디엔 또는 폴리(히드로카르빌)실릴렌기이다. R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, Diene or poly (hydrocarbyl) silylene group.
17. 하기 화학식에 상응하는, 실시양태 16에 따른 금속 착물.17. A metal complex according to embodiment 16, corresponding to the formula
상기 식에서, Where
M3은 Hf 또는 Zr, 바람직하게는 Zr이고;M 3 is Hf or Zr, preferably Zr;
Ar4는 각 경우에 독립적으로 치환된 C9-20 아릴기이며, 여기서 치환체는 각 경우에 독립적으로 알킬; 시클로알킬; 및 아릴기; 및 할로-, 트리히드로카르빌실릴- 및 할로히드로카르빌-치환된 이들의 유도체로 구성된 군으로부터 선택되되, 단 1개 이상의 치환체는 그것이 결합된 아릴기와 동일평면성을 갖지 않으며;Ar 4 is a C 9-20 aryl group independently substituted at each occurrence, wherein the substituents are independently alkyl at each occurrence; Cycloalkyl; And aryl groups; And halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, provided that at least one substituent does not have coplanarity with the aryl group to which it is attached;
T4는 각 경우에 독립적으로 C2-20 알킬렌, 시클로알킬렌 또는 시클로알케닐렌기, 또는 불활성 치환된 이들의 유도체이고; T 4 in each occurrence is independently a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or inert substituted derivative thereof;
R21은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노기이며; R 21 independently in each occurrence is hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) having up to 50 atoms, excluding hydrogen ) An amino group;
R3은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 아미노이거나, 또는 동일한 아릴렌 고리 상의 2개의 R3기 또는 동일하거나 상이한 아릴렌 고리 상의 R3 및 R21기는 함께 2개의 위치에서 아릴렌기에 결합된 2가 리간드기를 형성하거나, 또는 2개의 상이한 아릴렌 고리를 함께 연결시키고;R 3 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino having up to 50 atoms, excluding hydrogen, or the same Two R 3 groups on the arylene ring or R 3 and R 21 groups on the same or different arylene ring together form a divalent ligand group bonded to an arylene group at two positions, or linking together two different arylene rings To;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 디엔 또는 폴리(히드로카르빌)실릴렌기이다. R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, Diene or poly (hydrocarbyl) silylene group.
18. 각각의 Ar4기가 1개 이상의 입체적으로 벌키한 기, 바람직하게는 2개의 입체적으로 벌키한 기로 치환되고, 상이한 아릴렌옥시기 상에 위치한 2개 이상의 R3기가 입체적으로 벌키한, 실시양태 16 또는 17에 따른 금속 착물. 18. Embodiment 16, wherein each Ar 4 group is substituted with one or more stericly bulky groups, preferably two stericly bulky groups, and two or more R 3 groups that are located on different aryleneoxy groups are stericly bulky Or a metal complex according to 17.
19. 각각의 Ar4기가 하기 화학식에 상응하는, 실시양태 18에 따른 금속 착물.19. Metal complex according to embodiment 18, wherein each Ar 4 group corresponds to the formula
상기 식에서, R11은 각 경우에 독립적으로 수소, 할로, 또는 수소를 제외하고 50개 이하의 원자를 갖는 히드로카르빌, 트리히드로카르빌실릴, 트리히드로카르빌실릴히드로카르빌, 알콕시 또는 디(히드로카르빌)아미노이거나, 또는 2개의 R11기는 함께 2개의 위치에서 아릴기에 결합된 고리의 일부이되, 단 하나 이상의 경우의 R11 또는 2개의 상기 R11기의 2가 유도체는 입체적으로 벌키하다. Wherein R 11 is independently at each occurrence hydrogen, halo, or hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di ( Hydrocarbyl) amino, or two R 11 groups together form part of a ring bonded to an aryl group at two positions, with only one or more instances of R 11 or two divalent derivatives of said R 11 groups being steric bulky .
20. 입체적으로 벌키한 R11 및 R3 치환체가 3개 내지 20개의 비-수소 원자를 갖는 3급 알킬-, 시클로알킬-, 트리히드로카르빌실릴-, 트리(히드로카르빌)실릴히드로카르빌- 및 트리(히드로카르빌)페닐기로 구성된 군으로부터 독립적으로 선택되는, 실시양태 19에 따른 금속 착물. 20. Three- dimensionally bulky R 11 and R 3 substituents are tertiary alkyl-, cycloalkyl-, trihydrocarbylsilyl-, tri (hydrocarbyl) silylhydrocarbyl having 3 to 20 non-hydrogen atoms And a metal complex according to embodiment 19, independently selected from the group consisting of tri (hydrocarbyl) phenyl groups.
21. 입체적으로 벌키한 R11 및 R3 치환체가 tert-부틸, sec-부틸, tert-옥틸 (2,4,4-트리메틸펜탄-2-일), 1-페닐에틸, 2,3-디메틸-부트-2-일, 트리틸 (트리페닐메틸), 쿠밀 (2-페닐프로프-2-일), tert-아밀 (1,1-디메틸프로필), 페닐, 시클로헥실, 트리메틸실릴, 트리메틸실릴메틸, 이소프로필, 2,4,6-트리메틸페닐, 2,6-디메틸페닐, 3,5-디(이소프로필)페닐 및 3,5-디(t-부틸)페닐로 구성된 군으로부터 독립적으로 선택되는, 실시양태 19에 따른 금속 착물. 21. The stericly bulky R 11 and R 3 substituents are tert-butyl, sec-butyl, tert-octyl (2,4,4-trimethylpentan-2-yl), 1-phenylethyl, 2,3-dimethyl- But-2-yl, trityl (triphenylmethyl), cumyl (2-phenylprop-2-yl), tert-amyl (1,1-dimethylpropyl), phenyl, cyclohexyl, trimethylsilyl, trimethylsilylmethyl Independently selected from the group consisting of isopropyl, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 3,5-di (isopropyl) phenyl and 3,5-di (t-butyl) phenyl , Metal complex according to embodiment 19.
22. 하기 화학식에 상응하는, 실시양태 16에 따른 금속 착물.22. A metal complex according to embodiment 16, corresponding to the formula
상기 식에서,Where
M3은 Zr이고;M 3 is Zr;
Ar4는 3,5-디(tert-부틸)페닐, 3,5-디(이소프로필)페닐, 3,5-디(이소부틸)페닐, 3,5-디(tert-옥틸)페닐, 3,5-디(2,4,6-트리메틸페닐)페닐, 3,5-디(2,6-디메틸페닐)페닐, 3,5-디(2,4,6-트리-이소프로필페닐)페닐, 3,5-디(3,5-디-tert-부틸페닐)페닐, 1,2,3,4,6,7,8,9-옥타히드로안트라센-5-일, 3,6-디(tert-부틸)-9H-카르바졸-9-일 또는 3,6-디(tert-옥틸)-9H-카르바졸-9-일이며;Ar 4 is 3,5-di (tert-butyl) phenyl, 3,5-di (isopropyl) phenyl, 3,5-di (isobutyl) phenyl, 3,5-di (tert-octyl) phenyl, 3 , 5-di (2,4,6-trimethylphenyl) phenyl, 3,5-di (2,6-dimethylphenyl) phenyl, 3,5-di (2,4,6-tri-isopropylphenyl) phenyl , 3,5-di (3,5-di-tert-butylphenyl) phenyl, 1,2,3,4,6,7,8,9-octahydroanthracene-5-yl, 3,6-di ( tert-butyl) -9H-carbazol-9-yl or 3,6-di (tert-octyl) -9H-carbazol-9-yl;
R21은 각 경우에 독립적으로 메틸 또는 tert-부틸이고;R 21 in each occurrence is independently methyl or tert-butyl;
R3은 각 경우에 독립적으로 분지형 알킬, 시클로알킬, 치환된 아릴 또는 다른 입체적으로 벌키한 기이며;R 3 in each occurrence is independently branched alkyl, cycloalkyl, substituted aryl or other stericly bulky group;
T4는 프로판-1,3-디일, 부탄-1,4-디일, 시클로헥산-1,2-디일 또는 시클로헥산-1,2-디메틸렌이고;T 4 is propane-1,3-diyl, butane-1,4-diyl, cyclohexane-1,2-diyl or cyclohexane-1,2-dimethylene;
RD는 각 경우에 독립적으로 할로, 또는 수소를 제외하고 20개 이하의 원자를 갖는 히드로카르빌 또는 트리히드로카르빌실릴기이거나, 또는 2개의 RD기는 함께 히드로카르빌렌, 히드로카르바디일, 1,4-디히드로카르빌-치환된 1,3-부타디엔 또는 폴리(히드로카르빌)실릴렌기이다.R D is independently at each occurrence a halo, or hydrocarbyl or trihydrocarbylsilyl group having up to 20 atoms, excluding hydrogen, or two R D groups together are hydrocarbylene, hydrocarbodiyl, 1,4-dihydrocarbyl-substituted 1,3-butadiene or poly (hydrocarbyl) silylene groups.
23. 각각의 Ar4 고리 상의 1개 이상의 R11기, 가장 바람직하게는 Ar4 페닐 고리의 3번 및 5번 위치의 2개의 상기 R11기, 및 상이한 아릴렌 고리 상의 2개 이상의 R3기가 3개 내지 20개의 탄소, 바람직하게는 4개 내지 12개의 탄소를 함유하는 분지형 알킬, 시클로알킬, 히드로카르빌-치환된 아릴 또는 폴리(히드로카르빌)-치환된 실릴기인, 실시양태 22에 따른 금속 착물.23. One or more R 11 groups on each Ar 4 ring, most preferably two such R 11 groups in positions 3 and 5 of the Ar 4 phenyl ring, and two or more R 3 groups on different arylene rings In embodiment 22, which is a branched alkyl, cycloalkyl, hydrocarbyl-substituted aryl or poly (hydrocarbyl) -substituted silyl group containing 3 to 20 carbons, preferably 4 to 12 carbons According to the metal complexes.
24. 각각의 Ar4 고리 상의 2개의 R11기 및 상이한 아릴렌 고리 상의 2개의 R3기가 tert-부틸인, 실시양태 23에 따른 금속 착물.24. The metal complex according to embodiment 23, wherein two R 11 groups on each Ar 4 ring and two R 3 groups on a different arylene ring are tert-butyl.
25. 25.
(상기 식에서, RD는 각 경우에 독립적으로 클로라이드, 메틸 또는 벤질임)Wherein R D is independently at each occurrence chloride, methyl or benzyl
로 구성된 군으로부터 선택되는 금속 착물.Metal complexes selected from the group consisting of.
26.26.
A) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,A) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
B) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, B) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentane-2 -Yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (2,4,4-trimethylpentan-2-yl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4 , 4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4 -Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
C) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,C) bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) Propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane- 1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) methyl) Cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl)- 2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
D) 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, D) Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2- Phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy Propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy ) Methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethyl Ethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
E) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, E) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
F) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, F) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4, 4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (2,4,4- Trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-메틸-4,4-디메틸펜-2-일-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-methyl-4,4-dimethylphen-2-yl-2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(2,4,4-트리메틸펜탄-2-일)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (2,4,4-trimethylpentan-2-yl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
G) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, G) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1, 3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -4- (1-butyl) -2 -Phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-4-(1-부틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -4- (1-butyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
H) 비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸, H) bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1- Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-메틸(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5-methyl (phenyl) -5- (1,1-dimethylethyl ) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(1,1-디메틸에틸)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (1,1-dimethylethyl) (phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디클로라이드, Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디클로라이드,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dichloride,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥산-1,2-디일 지르코늄 (IV) 디벤질,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohexane-1,2-diyl zirconium (IV) dibenzyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디메틸,Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dimethyl,
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디클로라이드, 및 Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dichloride, and
비스((2-옥소일-3-(3,5-비스-(2,4,4-트리메틸펜탄-2-일)페닐)-5-(2,4,4-트리메틸펜탄-2-일)(페닐)-5-(1,1-디메틸에틸)-2-페녹시)메틸)시클로헥스-4-엔-1,2-디일 지르코늄 (IV) 디벤질Bis ((2-oxoyl-3- (3,5-bis- (2,4,4-trimethylpentan-2-yl) phenyl) -5- (2,4,4-trimethylpentan-2-yl) (Phenyl) -5- (1,1-dimethylethyl) -2-phenoxy) methyl) cyclohex-4-ene-1,2-diyl zirconium (IV) dibenzyl
로 구성된 군으로부터 선택되는, 실시양태 25에 따른 금속 착물.A metal complex according to embodiment 25, selected from the group consisting of:
본 발명은 구체적으로 개시되지 않은 임의의 성분의 부재 하에 실시가능하며, 다단계 중합 시스템 디자인에서 임의의 다른 적합한 반응 또는 방법과 조합될 수 있음을 이해한다.It is understood that the present invention is feasible in the absence of any component not specifically disclosed and may be combined with any other suitable reaction or method in a multistage polymerization system design.
실시예 1 내지 3 및 비교예 A 내지 EExamples 1-3 and Comparative Examples A-E
본 발명의 추가의 예시로서 하기 실시예가 제공되며, 이는 제한적인 것으로 의도되어선 안된다. 용어 "밤새"가 사용된 경우, 이는 대략 16 내지 18시간의 시간을 지칭하고, 용어 "실온"은 20 내지 25℃의 온도를 지칭하며, 용어 "혼합 알칸"은, 상업적으로 구입한, 엑손모빌 케미칼즈 인코포레이티드로부터 상표명 이소파르 E®로 입수가능한 C6-9 지방족 탄화수소의 혼합물을 지칭한다. 본원에서 화합물의 명칭이 그의 구조식 표시에 합치되지 않는 경우, 구조식 표시가 우선적이 된다. 모든 금속 착물의 합성 및 모든 스크리닝 실험의 준비는 건조 박스 기술을 이용하여 건조 질소 분위기 중에서 수행하였다. 사용된 모든 용매는 HPLC 등급이었고, 이들은 건조시킨 후에 사용하였다.The following examples are provided as further examples of the invention, which should not be intended to be limiting. When the term “overnight” is used, it refers to a time of approximately 16 to 18 hours, the term “room temperature” refers to a temperature of 20 to 25 ° C., and the term “mixed alkanes” refers to a commercially available exonmobile Refers to a mixture of C 6-9 aliphatic hydrocarbons available under the tradename Isopar E ® from Chemicals Incorporated. If the name of a compound herein does not match its structural representation, the structural representation takes precedence. Synthesis of all metal complexes and preparation of all screening experiments were carried out in a dry nitrogen atmosphere using dry box technology. All solvents used were HPLC grade and they were used after drying.
분자량 측정에 적합한 한가지 기술은, 폴리머 래보래토리즈(Polymer Laboratories)로부터 입수가능한 모델 PL-210 또는 모델 PL-220 겔 투과 기기 또는 동등한 장비를 사용한 겔 투과 크로마토그래피이다. 컬럼 및 캐러셀(carousel) 구획은 140℃에서 작동되었다. 3개의 폴리머 래보래토리즈 10-㎛ 혼합-B 컬럼을 사 용하였다. 용매는 1,2,4-트리클로로벤젠이었다. 샘플은 부틸화된 히드록시톨루엔 (BHT) 200 ppm을 함유하는 용매 50 mL 중 중합체 0.1 g의 농도로 제조하였다. 샘플을 160℃에서 2시간 동안 약하게 교반하여 제조하였다. 사용된 주입 부피는 100 ㎕였고, 유속은 1.0 mL/분이었다.One technique suitable for molecular weight determination is gel permeation chromatography using Model PL-210 or Model PL-220 gel permeation instruments or equivalent equipment available from Polymer Laboratories. Column and carousel compartments were operated at 140 ° C. Three Polymer Laboratories 10-μm Mix-B columns were used. The solvent was 1,2,4-trichlorobenzene. Samples were prepared at a concentration of 0.1 g of polymer in 50 mL of solvent containing 200 ppm of butylated hydroxytoluene (BHT). Samples were prepared by light stirring at 160 ° C. for 2 hours. The injection volume used was 100 μl and the flow rate was 1.0 mL / min.
GPC 컬럼 세트의 보정은, 개개의 분자량 사이에 10개 이상의 분할을 갖는 6종의 "칵테일(cocktail)" 혼합물로 배열된, 580 내지 8,400,000 범위의 분자량을 갖는 21종의 좁은 분자량 분포의 폴리스티렌 표준물을 사용하여 수행하였다. 표준물은 폴리머 래보래토리즈 (영국 쉬롭샤이어 소재)로부터 구입하였다. 폴리스티렌 표준물은 1,000,000 이상의 분자량에 대해 용매 50 mL 중 0.025 g으로, 1,000,000 미만의 분자량에 대해 용매 50 mL 중 0.05 g으로 제조하였다. 폴리스티렌 표준물을 80℃에서 30분 동안 온화하게 교반하며 용해시켯다. 좁은 표준물 혼합물을 먼저, 또한 분해가 최소화되도록 최고 분자량 성분 감소 순서로 실행하였다. 폴리스티렌 표준물 피크 분자량을 수학식: M폴리에틸렌 = 0.431(M폴리스티렌)을 이용하여 폴리에틸렌 분자량으로 전환시켰다 (문헌 [Williams and Ward, J. Polvm. Sci.. Polym. Let.. 6, 621 (1968)]에 기재된 바와 같음). The calibration of the GPC column set consists of 21 narrow molecular weight distribution polystyrene standards with molecular weights ranging from 580 to 8,400,000, arranged in a mixture of six "cocktails" with at least 10 splits between the individual molecular weights. It was performed using. Standards were purchased from Polymer Laboratories, Shropshire, UK. Polystyrene standards were prepared at 0.025 g in 50 mL of solvent for molecular weights greater than 1,000,000 and 0.05 g in 50 mL of solvent for molecular weights less than 1,000,000. The polystyrene standards were dissolved with gentle stirring at 80 ° C. for 30 minutes. Narrow standard mixtures were run first, in order of highest molecular weight component reduction, to minimize degradation. Polystyrene standard peak molecular weights were converted to polyethylene molecular weight using Equation: M polyethylene = 0.431 (M polystyrene ) (Williams and Ward, J. Polvm. Sci .. Polym. Let .. 6, 621 (1968) As described].
비스코텍 코포레이션(Viscotek Corporation, 미국 텍사스주 휴스톤 소재)으로부터 입수가능한 비스코텍 트리섹(Viscotek TriSEC)TM 소프트 웨어 버젼 3.0을 이용하여 폴리에틸렌 등가 분자량 계산을 수행하였다.Polyethylene equivalent molecular weight calculations were performed using Viscotek TriSEC ™ software version 3.0, available from Viscotek Corporation, Houston, Texas.
금속 착물의 제조Manufacture of metal complexes
US-A-2004/0010103의 합성 절차를 실질적으로 반복하여 금속 착물 실시예 1 내지 3 및 비교예 A 내지 E를 제조하였다. The metal complexes Examples 1-3 and Comparative Examples A-E were prepared by substantially repeating the synthesis procedure of US-A-2004 / 0010103.
A: 비스((2-옥소일-3-(디벤조-1H-피롤-1-일)-5-(메틸)페닐)-2-페녹시)-트랜스-시클로헥산-1,2-디메틸레닐 지르코늄 (IV) 디메틸A: bis ((2-oxoyl-3- (dibenzo-1H-pyrrol-1-yl) -5- (methyl) phenyl) -2-phenoxy) -trans-cyclohexane-1,2-dimethylenyl Zirconium (IV) Dimethyl
B: 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸-에틸)펜-1-일)-5-(메틸)페닐)-2-페녹시)-프로판-1,3-디일 지르코늄 (IV) 디메틸B: bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethyl-ethyl) phen-1-yl) -5- (methyl) phenyl) -2-phenoxy) -propane -1,3-diyl zirconium (IV) dimethyl
C: 비스((2-옥소일-3-(디벤조-1H-피롤-1-일)-5-(메틸)페닐)-(4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸C: bis ((2-oxoyl-3- (dibenzo-1H-pyrrol-1-yl) -5- (methyl) phenyl)-(4- (1,1-dimethylethyl) -2-phenoxy) Propane-1,3-diyl zirconium (IV) dimethyl
D: 비스((2-옥소일-3-(디벤조-1H-피롤-1-일)-(5-((2-메틸)프로판-2-일)페닐)-(4-(1,1-디메틸)에틸)-2-페녹시)-트랜스-시클로헥산-1,2-디메틸레닐 지르코늄 (IV) 디메틸 D: bis ((2-oxoyl-3- (dibenzo-1H-pyrrol-1-yl)-(5-((2-methyl) propan-2-yl) phenyl)-(4- (1,1 -Dimethyl) ethyl) -2-phenoxy) -trans-cyclohexane-1,2-dimethylenyl zirconium (IV) dimethyl
E: 비스((2-옥소일-3-(디벤조-1H-피롤-1-일)-(5-((2-메틸)프로판-2-일)페닐)-(4-(1,1-디메틸에틸)-2-페녹시)프로판-1,3-디일 지르코늄 (IV) 디메틸E: bis ((2-oxoyl-3- (dibenzo-1H-pyrrol-1-yl)-(5-((2-methyl) propan-2-yl) phenyl)-(4- (1,1 -Dimethylethyl) -2-phenoxy) propane-1,3-diyl zirconium (IV) dimethyl
실시예 1: 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-(5-메틸)페닐)-(4-(1,1-디메틸에틸)-2-페녹시)-프로판-1,3-디일 지르코늄 (IV) 디메틸Example 1: bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl)-(5-methyl) phenyl)-(4- (1,1-dimethylethyl ) -2-phenoxy) -propane-1,3-diyl zirconium (IV) dimethyl
실시예 2: 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-(5-(1,1-디메틸에틸)페닐)-(4-(1,1-디메틸에틸)-2-페녹시)-프로판-1,3-디일 지르코늄 (IV) 디메틸Example 2: bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl)-(5- (1,1-dimethylethyl) phenyl)-(4- ( 1,1-dimethylethyl) -2-phenoxy) -propane-1,3-diyl zirconium (IV) dimethyl
실시예 3: 비스((2-옥소일-3-(3,5-비스-(1,1-디메틸에틸)페닐)-(5-(1-부틸)페닐)-4-(1-부틸)-2-페녹시)-프로판-1,3-디일 지르코늄 (IV) 디메틸Example 3: bis ((2-oxoyl-3- (3,5-bis- (1,1-dimethylethyl) phenyl)-(5- (1-butyl) phenyl) -4- (1-butyl) 2-phenoxy) -propane-1,3-diyl zirconium (IV) dimethyl
상기 금속 착물에 대해 20℃에서 메틸시클로헥산 중에서의 용해도를 측정하였다. 과량의 미분쇄 금속 착물을 1시간 동안 양을 알고 있는 용매 중에서 교반하였다. 용액을 여과하고, 용매를 감압 하에 제거하였다. 회수된 잔류물의 양을 칭량하여 용해도 (%)를 결정하였다. 결과를 하기 표 1에 나타내었다.The solubility in methylcyclohexane was measured at 20 ° C. for the metal complex. Excess pulverized metal complex was stirred for 1 hour in known solvent. The solution is filtered and the solvent is removed under reduced pressure. The amount of recovered residue was weighed to determine the solubility (%). The results are shown in Table 1 below.
표 1의 결과는, 본원에 개시된 바와 같은 적합하게 위치하는 입체적으로 벌키한 리간드기를 함유하는 본 발명에 따른 금속 착물이 상기와 같은 리간드기 및/또는 리간드 배치를 갖지 않는 금속 착물에 비해 보다 높은 지방족 또는 환식지방족 탄화수소 중에서의 용해도를 갖는다는 결론을 지지한다.The results in Table 1 show that metal complexes according to the invention containing suitably positioned stereoscopically bulky ligand groups as disclosed herein have higher aliphatics than metal complexes without such ligand groups and / or ligand configurations. Or the solubility in cyclic aliphatic hydrocarbons.
연속적 용액 중합Continuous Solution Polymerization
연속적 용액 중합은 내부 교반기가 장치된 컴퓨터 제어되는 오토클레이브 반응기에서 수행하였다. 정제된 혼합 알칸 용매 (엑손모빌 인코포레이티드로부터 입수가능한 이소파르™ E), 에틸렌, 1-옥텐, 및 수소를, 온도 조절을 위한 재킷 및 내부 열전쌍이 장치된 3.8 L의 반응기에 공급하였다. 반응기에 공급되는 용매는 질량-유동 조절기에 의해 측정된다. 가변 속도 격막 펌프가 용매 유량 및 반응기에 대한 압력을 조절하였다. 펌프의 배출구에서, 측부 스트림을 취하여 촉매 및 보조촉매 주입 라인 및 반응기 교반기를 위한 플러시(flush) 유동을 제공하였다. 상기 유동은 질량 유동계에 의해 측정되었고, 조절 밸브 또는 바늘 밸브의 수동 조절에 의해 조절되었다. 잔류 용매를 1-옥텐, 에틸렌 및 수소와 조합하여 상기 반응기에 공급하였다. 질량 유동 조절기를 이용하여 필요에 따라 수소를 상기 반응기에 공급하였다. 용매/단량체 용액의 온도는 반응기에 들어가기 전 열 교환기를 이용하여 조절하였다. 상기 스트림은 반응기의 바닥으로 들어갔다. 금속 착물 및 [(C14-18H27-35)2CH3N]+[B(C6F5)4]-의 대략적 화학식을 갖는 보조촉매 (이수소화 탈로우알킬)메틸암모늄 테트라키스(펜타-플루오로페닐)보레이트 1.2 당량은 트리이소부틸알루미늄 개질된 알루목산 (MMAO, 악조 케미칼즈, 인코포레이티드(Akzo Chemicals, Inc.)로부터 입수가능함) 5 당량과 함께 촉매 조성물을 형성하였다. 촉매 성분 용액은 펌프 및 질량 유동계를 이용하여 계량하였고 촉매 플러시 용매와 조합하여 반응기의 바닥으로 도입하였다. 상기 반응기를 격렬하게 교반하면서 500 psig (3.45 MPa)에서 액체-충만하게 가동시켰다. 반응기의 상단에 있는 출구 라인을 통해 생성물을 꺼내었다. 반응기로부터 모든 출구 라인을 스팀 트레이싱하고 절연시켰다. 상기 출구 라인에 소량의 물을 임의의 안정화제 또는 다른 첨가제와 함께 첨가하고 그 혼합물을 정적 혼합기로 통과시켜 중합을 중지시켰다. 이어서, 생성물 스트림을 탈휘발화에 앞서 열 교환기로 통과시켜 가열하였다. 상기 중합체 생성물은 탈휘발화 압출기 및 수-냉각되는 펠렛화기를 이용하여 압출에 의해 회수하였다. 방법 상세사항 및 결과를 하기 표 2에 나타내었다. 중합체 특성을 하기 표 3에 나타내었다.Continuous solution polymerization was carried out in a computer controlled autoclave reactor equipped with an internal stirrer. Purified mixed alkane solvent (Isopar ™ E available from ExxonMobil Incorporated), ethylene, 1-octene, and hydrogen were fed to a 3.8 L reactor equipped with a jacket for temperature control and an internal thermocouple. The solvent supplied to the reactor is measured by mass-flow controller. A variable speed diaphragm pump controlled the solvent flow rate and the pressure on the reactor. At the outlet of the pump, a side stream was taken to provide flush flow for catalyst and cocatalyst injection lines and reactor stirrers. The flow was measured by mass flow meter and controlled by manual adjustment of the control valve or the needle valve. The remaining solvent was fed to the reactor in combination with 1-octene, ethylene and hydrogen. Hydrogen was fed into the reactor as needed using a mass flow controller. The temperature of the solvent / monomer solution was controlled using a heat exchanger before entering the reactor. The stream entered the bottom of the reactor. Co- catalyst having approximate formula of a metal complex and [(C 14-18 H 27-35 ) 2 CH 3 N] + [B (C 6 F 5 ) 4 ] - (dihydrogenated tallowalkyl) methylammonium tetrakis ( 1.2 equivalents of penta-fluorophenyl) borate formed the catalyst composition with 5 equivalents of triisobutylaluminum modified alumoxane (available from MMAO, Akzo Chemicals, Inc.). The catalyst component solution was metered using a pump and a mass flow meter and introduced to the bottom of the reactor in combination with the catalyst flush solvent. The reactor was run liquid-full at 500 psig (3.45 MPa) with vigorous stirring. The product was taken out through the outlet line at the top of the reactor. All outlet lines were steam traced and insulated from the reactor. A small amount of water was added to the outlet line with any stabilizer or other additive and the mixture was passed through a static mixer to stop the polymerization. The product stream was then heated by passing through a heat exchanger prior to devolatilization. The polymer product was recovered by extrusion using a devolatilization extruder and a water-cooled pelletizer. The method details and results are shown in Table 2 below. Polymer properties are shown in Table 3 below.
표 3의 결과는, 본원에 기재된 바와 같은 금속 착물의 사용에 의해서만이 우수한 특성을 가지면서 감소된 I10/I2 (장쇄 분지 형성의 감소를 나타냄)를 갖는 중합체가 본 발명에 따라 제조될 수 있음을 나타낸다.The results in Table 3 show that polymers with reduced I 10 / I 2 (which indicates a reduction in long chain branching formation) can be prepared according to the invention, with excellent properties only by the use of metal complexes as described herein. It is present.
가변 온도 중합Variable temperature polymerization
상기에 언급된 중합 조건을 실질적으로 반복하여 일정 범위의 중합 온도에서 여러 중합체를 제조하였다. 중합체의 I10/I2값을 측정하고, 플롯팅(plotting)하였다. 데이타 포인트를 피팅한 라인을 도 1에 도시하였다. 도 1에서, PE는, (t-부틸아미도)디메틸(1,2,3,4,5-η)-1,5,6,7-테트라히드로-2-메틸-s-인다센-1-일)실란 티탄 (II) 1,3-펜타디엔 금속 착물 (USP 5,965,756에 따라 제조됨) 및 트리스펜타플루오로페닐보란 보조촉매와 MAO 스캐빈저를 1:3:1의 Ti:B:Al의 몰비로 사용하여 제조된 향상된 장쇄 분지를 함유하는 에틸렌/옥텐 공중합체이다. 비교예 중합체 AA (비교예 금속 착물 A를 사용함) 및 중합체 1A (금속 착물 실시예 1을 사용함)를 앞서 개시된 보조촉매/스캐빈저 조합을 사용하여 제조하였다. 테스트된 온도 범위에서, 본 발명에 따라 제조된 중합체 (1A)는 2개의 비교예 중합체의 I10/I2값보다 낮은 I10/I2값을 가졌다.Several polymers were prepared at a range of polymerization temperatures by substantially repeating the polymerization conditions mentioned above. The I 10 / I 2 values of the polymers were measured and plotted. The line fitting the data points is shown in FIG. 1. In FIG. 1, PE is (t-butylamido) dimethyl (1,2,3,4,5-η) -1,5,6,7-tetrahydro-2-methyl-s-indacene-1 -Yl) silane titanium (II) 1,3-pentadiene metal complex (prepared according to USP 5,965,756) and trispentafluorophenylborane cocatalyst and MAO scavenger with a 1: 3: 1 Ti: B: Al Ethylene / octene copolymers containing improved long chain branches made using a molar ratio of. Comparative Polymer AA (using Comparative Metal Complex A) and
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