KR20080039424A - 올레핀의 중합을 위한 테트라치환 플루오레닐 촉매의 제조및 용도 - Google Patents
올레핀의 중합을 위한 테트라치환 플루오레닐 촉매의 제조및 용도 Download PDFInfo
- Publication number
- KR20080039424A KR20080039424A KR1020087003830A KR20087003830A KR20080039424A KR 20080039424 A KR20080039424 A KR 20080039424A KR 1020087003830 A KR1020087003830 A KR 1020087003830A KR 20087003830 A KR20087003830 A KR 20087003830A KR 20080039424 A KR20080039424 A KR 20080039424A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- substituted
- alkyl
- fluorenyl
- metallocene component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
- B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/205,934 | 2005-08-17 | ||
| US11/205,934 US7335711B2 (en) | 2005-08-17 | 2005-08-17 | Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20080039424A true KR20080039424A (ko) | 2008-05-07 |
Family
ID=37758333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087003830A Ceased KR20080039424A (ko) | 2005-08-17 | 2006-08-16 | 올레핀의 중합을 위한 테트라치환 플루오레닐 촉매의 제조및 용도 |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US7335711B2 (https=) |
| EP (1) | EP1915401A4 (https=) |
| JP (1) | JP2009504888A (https=) |
| KR (1) | KR20080039424A (https=) |
| TW (1) | TW200720306A (https=) |
| WO (1) | WO2007022244A2 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101362991B1 (ko) * | 2010-05-28 | 2014-02-13 | 주식회사 엘지화학 | 메탈로센 촉매의 제조방법 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101044134B1 (ko) * | 2005-05-18 | 2011-06-28 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합용 촉매, 올레핀 중합체의 제조방법,프로필렌계 공중합체의 제조방법, 프로필렌 중합체,프로필렌계 중합체 조성물 및 이들의 용도 |
| US7514509B2 (en) * | 2005-12-16 | 2009-04-07 | Fina Technology, Inc. | Catalyst compositions and methods of forming isotactic polyproyplene |
| US7514510B2 (en) * | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
| US7538167B2 (en) * | 2006-10-23 | 2009-05-26 | Fina Technology, Inc. | Syndiotactic polypropylene and methods of preparing same |
| WO2008059974A1 (en) * | 2006-11-17 | 2008-05-22 | Mitsui Chemicals, Inc. | Method for producing syndiotactic propylene polymer |
| US8293856B2 (en) | 2008-08-19 | 2012-10-23 | Mitsui Chemicals, Inc. | Process for preparing olefin polymer using mixed catalyst |
| JP5178470B2 (ja) * | 2008-11-19 | 2013-04-10 | 三井化学株式会社 | フルオレン誘導体の製造方法 |
| EP2204375A1 (en) * | 2008-12-12 | 2010-07-07 | Total Petrochemicals Research Feluy | Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof |
| CA2863950C (en) | 2012-02-08 | 2022-06-07 | The Lubrizol Corporation | Method for preparing a sulfurized alkaline earth metal dodecylphenate |
| JP5972056B2 (ja) * | 2012-06-06 | 2016-08-17 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| KR101784463B1 (ko) * | 2014-10-06 | 2017-10-11 | 주식회사 엘지화학 | 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법 |
| US10968290B2 (en) | 2017-03-28 | 2021-04-06 | Exxonmobil Chemical Patents Inc. | Metallocene-catalyzed polyalpha-olefins |
| WO2018182984A1 (en) * | 2017-03-28 | 2018-10-04 | Exxonmobil Chemical Patents Inc. | Metallocene compounds |
| KR20210154818A (ko) * | 2019-04-12 | 2021-12-21 | 보레알리스 아게 | 촉매 시스템 |
| CN110922286B (zh) * | 2019-11-23 | 2022-08-16 | 上海化工研究院有限公司 | 一种非对称芳基取代富烯化合物及其制备方法与应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4767735A (en) * | 1987-02-02 | 1988-08-30 | Cosden Technology, Inc. | Catalyst pretreatment process |
| US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| JP2927881B2 (ja) * | 1990-04-24 | 1999-07-28 | 三井化学株式会社 | シンジオタクチックポリα―オレフィンの製造方法 |
| JPH072935A (ja) * | 1993-06-15 | 1995-01-06 | Showa Denko Kk | ポリオレフィン製造用触媒成分およびポリオレフィンの製造方法 |
| US6313242B1 (en) * | 1996-05-20 | 2001-11-06 | Fina Technology, Inc. | Stereorigid bis-fluorenyl metallocenes |
| JP3320619B2 (ja) * | 1996-10-02 | 2002-09-03 | 三井化学株式会社 | 新規メタロセン化合物とそれを用いたオレフィンまたはジエンの重合方法 |
| DE19719103A1 (de) * | 1997-05-06 | 1998-11-12 | Targor Gmbh | Stereorigide Metallocenverbindung |
| US6469188B1 (en) * | 1999-01-20 | 2002-10-22 | California Institute Of Technology | Catalyst system for the polymerization of alkenes to polyolefins |
| DE60034308T2 (de) * | 1999-10-08 | 2007-12-20 | Mitsui Chemicals, Inc. | Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen |
| EP1241188B1 (en) * | 2000-09-13 | 2009-01-21 | Japan Polychem Corporation | Component of catalyst for olefin polymerization |
| EP2465879B1 (en) * | 2002-09-27 | 2019-04-24 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
| JP4367686B2 (ja) * | 2002-11-22 | 2009-11-18 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| JP2005200453A (ja) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | α−オレフィン(共)重合体の製造方法 |
| KR20070061567A (ko) * | 2004-03-31 | 2007-06-13 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조 방법 |
| US7214749B2 (en) * | 2004-07-09 | 2007-05-08 | The Texas A&M University Systems | Catalyst system for high activity and stereoselectivity in the homopolymerization and copolymerization of olefins |
| JP2006176760A (ja) * | 2004-11-26 | 2006-07-06 | Mitsui Chemicals Inc | 合成潤滑油および潤滑油組成物 |
| US7094938B1 (en) * | 2005-05-20 | 2006-08-22 | Fina Technology, Inc. | Process for the preparation of substituted fluorenes |
| JP5105772B2 (ja) * | 2005-07-25 | 2012-12-26 | 三井化学株式会社 | シンジオタクティックα−オレフィン重合体の製造方法 |
-
2005
- 2005-08-17 US US11/205,934 patent/US7335711B2/en not_active Expired - Fee Related
-
2006
- 2006-08-07 TW TW095128871A patent/TW200720306A/zh unknown
- 2006-08-16 JP JP2008527092A patent/JP2009504888A/ja active Pending
- 2006-08-16 EP EP06789797A patent/EP1915401A4/en not_active Withdrawn
- 2006-08-16 KR KR1020087003830A patent/KR20080039424A/ko not_active Ceased
- 2006-08-16 WO PCT/US2006/031950 patent/WO2007022244A2/en not_active Ceased
-
2007
- 2007-10-05 US US11/868,033 patent/US8093418B2/en not_active Expired - Fee Related
-
2011
- 2011-12-07 US US13/313,059 patent/US20120095175A1/en not_active Abandoned
-
2012
- 2012-09-05 US US13/604,081 patent/US20130237719A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101362991B1 (ko) * | 2010-05-28 | 2014-02-13 | 주식회사 엘지화학 | 메탈로센 촉매의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007022244A2 (en) | 2007-02-22 |
| US7335711B2 (en) | 2008-02-26 |
| TW200720306A (en) | 2007-06-01 |
| EP1915401A2 (en) | 2008-04-30 |
| US20070043183A1 (en) | 2007-02-22 |
| EP1915401A4 (en) | 2012-03-21 |
| JP2009504888A (ja) | 2009-02-05 |
| US8093418B2 (en) | 2012-01-10 |
| US20080026935A1 (en) | 2008-01-31 |
| US20130237719A1 (en) | 2013-09-12 |
| US20120095175A1 (en) | 2012-04-19 |
| WO2007022244A3 (en) | 2007-11-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
| A201 | Request for examination | ||
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
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