KR20050080055A - Environment friendship hydrogenous adhesives and the manufacturing method - Google Patents

Environment friendship hydrogenous adhesives and the manufacturing method Download PDF

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KR20050080055A
KR20050080055A KR1020050060570A KR20050060570A KR20050080055A KR 20050080055 A KR20050080055 A KR 20050080055A KR 1020050060570 A KR1020050060570 A KR 1020050060570A KR 20050060570 A KR20050060570 A KR 20050060570A KR 20050080055 A KR20050080055 A KR 20050080055A
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adhesive
environmentally friendly
inspection
liquid phase
physical property
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KR1020050060570A
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Korean (ko)
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이상준
진기창
이광환
한성욱
이인학
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신세계건설(주)
이상준
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

본 소재에 관계없이 초기 및 후기의 접착성을 향상시키고 음이온과 원적외선의 방출로 각종 기능성을 보장받을 수 있음은 물론, 새집증후군으로부터 탈피할 수 있는 환경 친화적 수성접착제 및 그 제조방법에 관한 것이다.Regardless of the material, the present invention relates to an environmentally friendly aqueous adhesive that can improve early and late adhesiveness and ensure various functionalities by releasing anions and far infrared rays, and to escape from sick house syndrome.

즉, 아크릴계에멀젼(55~65%), 석분(5~10%), 접착부여제(8~12%), 물(5~10%), 첨가제(2~5%), 기능성부여제(10~20%), 은나노(5%), 토르말린(8~15%)을 첨가하여 혼합하는 단계;That is, acrylic emulsion (55-65%), stone powder (5-10%), adhesion agent (8-12%), water (5-10%), additives (2-5%), functional emulsifiers (10 -20%), silver nano (5%), tourmaline (8-15%) by adding and mixing;

상기 혼합액을 100rpm의 속도로 1시간 동안 고속 분산하는 단계;Dispersing the mixed solution at a high speed of 100 rpm for 1 hour;

상기 고속분산 후 고형분(%), 점도, 비중, 외관 등의 액상검사를 하는 단계;Performing a liquid phase inspection of the solid content (%), viscosity, specific gravity, appearance after the high-speed dispersion;

상기 액상검사 후 오픈타임, 작업가능시간, 접착강도, 저장성 등의 물성검사를 하는 단계;Performing physical property inspection after the liquid phase inspection such as open time, working time, adhesive strength, and storage property;

상기 물성검사 후 중량단위로 밀봉 포장하는 단계를 포함하는 것을 특징으로 한다.After the physical property test characterized in that it comprises the step of sealing packaging by weight unit.

Description

환경 친화적 수성 접착제 및 그 제조방법 { Environment friendship hydrogenous adhesives and the manufacturing method }Environment-friendly water-based adhesive and its manufacturing method {Environment friendship hydrogenous adhesives and the manufacturing method}

본 발명은 환경 친화적 수성 접착제 및 그 제조방법에 관한 것으로서 더욱 상세히는 소재에 관계없이 초기 및 후기의 접착성을 향상시키고 손쉬운 작업이 될 수 있도록 크림상으로 되어 있을 뿐만 아니라, 음이온과 원적외선의 방출로 각종 기능성을 보장받을 수 있음은 물론, 새집증후군으로부터 탈피할 수 있는 환경 친화적 수성접착제 및 그 제조방법에 관한 것이다.The present invention relates to an environmentally friendly water-based adhesive and a method for manufacturing the same. More specifically, the present invention is not only made into a cream form to improve the initial and later adhesive properties and easy operation, regardless of the material, but also to release anions and far infrared rays. The present invention relates to an environmentally friendly aqueous adhesive which can be guaranteed from various functionalities and to escape from sick house syndrome, and a method of manufacturing the same.

일반적으로 건축물의 내부 바닥재 및 벽지 도배시 유기 접착제를 사용하고 있는데 이 유기 접착제는 접착력은 우수하나 독성이 심하여 작업에 어려움이 있음은 물론, 작업 후에도 건축물의 바닥 및 벽면으로부터 미량의 휘발성 유해물질이 오랜 기간 동안 계속적으로 방출되어 인체에 해를 끼지는 것으로 밝혀지고 있는데, 이러한 휘발성 유해물질은 포름알데히드성분으로 새집에서 나는 메케한 냄새의 주범이며 증상으로는 눈과 코의 자극부터 어지럼증, 피부질환, 나아가 동물실험에서 코암(비암)까지 일으키는 시신경 손상이라든지 호흡 곤란, 후각 장애 등으로 집중력 결여 등의 중추신경 장애까지 일으킬 수 있는 치명적인 물질이다.In general, organic adhesives are used for the application of interior flooring and wallpaper in buildings. These organic adhesives have excellent adhesion but are toxic, which makes them difficult to work with. The volatile harmful substance is known to be harmful to the human body by releasing it continuously during the period. The volatile harmful substance is formaldehyde, which is the main culprit of the smell of smell in the new house. Symptoms include eye and nose irritation, dizziness, skin disease, and even It is a deadly substance that can cause central nerve disorders such as lack of concentration due to difficulty in breathing, olfactory disorders, etc. in animal experiments or even nose cancer (non-cancer).

또한 상기 휘발성 유기화합물(VOCs)은 톨루엔, 에틸벤젠, 자일렌 등을 말하며 바닥접착제, 칩보드, 페인트 등 건축마감재에서 주로 방출되며, 피부. 눈. 목을 자극하며 두통과 현기증, 피로를 일으킨다. In addition, the volatile organic compounds (VOCs) refer to toluene, ethylbenzene, xylene, etc., and are mainly released from building finishing materials such as floor adhesives, chipboards, and paints, and skin. Eye. It irritates the neck and causes headaches, dizziness and fatigue.

이와 같이 새집 증후군의 원인은 바닥재와 벽지, 접착제 등에 사용되는 건축자재에 들어 있는 화학물질에 있는 것으로 밝혀지고 있으며 이에 대하여 최근에는 숯과 옥, 맥반석, 황토 등의 음이온성 무기질이 인체에 유익한 원적외선과 음이온을 방사 하여 주위공기를 정화시켜 주는 공기정화기가 선풍적인 관심을 끌고 있다.The cause of the sick house syndrome is found in the chemicals contained in the building materials used for flooring, wallpaper, adhesives, etc. In recent years, anionic minerals such as charcoal, jade, elvan and loess are beneficial to the human body. Air purifiers that clean up the surrounding air by emitting negative ions are drawing attention.

상기와 같은 새집증후군을 예방하기 위해서는 시공 단계에서 수성의 접착제를 사용하여야 하나 수성의 접착제는 습한 곳에서 장시간 방치할 경우 곰팡이 및 각종 미생물의 번식이 발생하여 접착 강도의 약화 및 냄새가 발생하는 등의 문제가 발생 되고 있다.In order to prevent the sick house syndrome as described above, aqueous adhesive should be used in the construction stage. However, when the aqueous adhesive is left in a humid place for a long time, mold and various microorganisms may occur, resulting in weakened adhesive strength and odor. Problems are occurring.

이에 본 발명에서는 상기와 같은 문제점을 일소키 위해 안출한 것으로서 인체에 유해한 새집증후군의 발생을 미연에 억제시킴과 동시에 초기 및 후기 강력한 접착력을 보장받을 수 있는 수성 접착제를 제공함으로서 작업자의 작업환경을 개선시켜줌과 인체에 유익하고, 수월한 작업이 될 수 있게 하는 무공해 접착제를 제공함에 주안점을 두고 기술적 과제로서 완성한 것이다.Accordingly, the present invention has been made to solve the above problems, while preventing the occurrence of sick house syndrome harmful to the human body in advance, and at the same time providing an aqueous adhesive that can guarantee the early and late strong adhesive force to improve the working environment of the worker. It has been completed as a technical task with the focus on providing pollution-free adhesives that make them easy and beneficial to the human body.

위의 기술적 과제를 달성하기 위한 환경 친화적 수성 접착제의 제조방법은,The environmentally friendly method for producing an aqueous adhesive for achieving the above technical problem,

아크릴계에멀젼(55~65%), 석분(5~10%), 접착부여제(8~12%), 물(5~10%), 첨가제(2~5%), 기능성부여제(10~20%), 은나노(5%), 토르말린(8~15%)을 첨가하여 혼합하는 단계;Acrylic emulsion (55 ~ 65%), stone powder (5 ~ 10%), adhesive agent (8 ~ 12%), water (5 ~ 10%), additive (2 ~ 5%), functional emulsifier (10 ~ 20 %), Silver nano (5%), tourmaline (8-15%) by adding and mixing;

상기 혼합액을 100rpm의 속도로 1시간 동안 고속 분산하는 단계;Dispersing the mixed solution at a high speed of 100 rpm for 1 hour;

상기 고속분산 후 고형분(%), 점도, 비중, 외관 등의 액상검사를 하는 단계;Performing a liquid phase inspection of the solid content (%), viscosity, specific gravity, appearance after the high-speed dispersion;

상기 액상검사 후 오픈타임, 작업가능시간, 접착강도, 저장성 등의 물성검사를 하는 단계;Performing physical property inspection after the liquid phase inspection such as open time, working time, adhesive strength, and storage property;

상기 물성검사 후 중량단위로 밀봉 포장하는 단계를 포함하는 것을 특징으로 한다.After the physical property test characterized in that it comprises the step of sealing packaging by weight unit.

이때 상기 접착부여제는 송진과 아크릴계점착제를 혼합한 것을 사용하며, 상기 첨가제는 분산제, 소포제, 증점제, 방부제, 유화제등을 혼합하여 사용함이 바람직하다.At this time, the adhesive agent is a mixture of rosin and acrylic adhesive is used, the additive is preferably used by mixing a dispersant, antifoaming agent, thickener, preservative, emulsifier and the like.

또한 상기 기능성부여제는 황토, 음이온, 게르마늄, 옥분말을 혼합하여 사용함으로서 인체에 유익한 원적외선을 방사 하여 각종 기능성을 보장받을 수 있을 뿐만 아니라, 상기 음이온은 인체 흡입시 신진대사를 촉진하고 활력을 증진시킴은 물론 피를 맑게 하고 신경안정과 피로회복, 식욕증진의 효과와 긴장을 완화시켜 준다.In addition, the functional imparting agent can not only ensure various functionalities by radiating far infrared rays beneficial to the human body by using a mixture of ocher, anion, germanium, jade powder, the anion promotes metabolism and enhances vitality when inhaling the human body Not only does it clear the blood, but it also relieves the effects and tension of nerve stability, fatigue, and appetite boosting.

그리고 상기 은나노는 곰팡이제거 및 살균 등 항균기능을 제공받을 수 있음과 동시에 습한 곳에서도 수성 접착제가 접착 강도를 유지할 수 있도록 해주며, 토르말린은 인체의 모세혈관을 크게 하여 혈액순환을 촉진, 세포의 활성화 신진대사 , 위장운동의 활성화, 온열효과, 피로회복, 신경통, 기미, 냉대하증에 효능이 있으며, 항산화 작용과 0.06A의 작은 전류가 흘러 발생하는 음이온과 원적외선 상승효과에 따라 다양한 효과를 인체에 결합하여 노화의 원인인 유해한 활성산소를 분해하고 알카리화 하여 두통과 얼굴축소, 다이어트에 큰 효과가 있다.In addition, the silver nano may be provided with antibacterial functions such as mold removal and sterilization, and at the same time, the aqueous adhesive maintains the adhesive strength even in wet places. Tourmaline promotes blood circulation by enlarging the capillaries of the human body and activates cells. It is effective in metabolism, activation of gastrointestinal motility, warming effect, fatigue, neuralgia, blemishes, and hypothermia, and combines various effects to the human body according to the anion and far-infrared synergistic effect generated by antioxidant action and small current of 0.06A By decomposing and alkalizing harmful free radicals that cause aging, it has a great effect on headache, face reduction, and diet.

한편 100rpm의 속도로 고속분산 시켜서 얻어진 점성의 수성 접착제는 고형분(%)과 점도(10000~20000cps), 비중(1.1~1.25) 그리고 외관 등의 액상검사를 한 후 오픈타임, 작업가능시간, 접착강도, 저장성 등의 물성검사를 함으로서 검사단계가 이루어진다.On the other hand, the viscous water-based adhesive obtained by high-speed dispersion at the speed of 100rpm is tested for liquid content such as solid content (%), viscosity (10000 ~ 20000cps), specific gravity (1.1 ~ 1.25) and appearance, and then open time, working time, and adhesive strength. The inspection step is carried out by examining the physical properties such as storage and storage.

이때 상기 오픈타임은 타일의 변형을 없애고 부착 후 타일 이음매의 들뜸 현상을 방지하는 도포 후의 대기시간으로 접착제 속의 수분 증발시간을 말하는 것으로 건조가 됨과 동시에 약간 진한 색상으로 변색이 이루어지고 손으로 살짝 대면 껌처럼 달라붙기 시작한다. 이는 온도와 환경에 밀접한 관련이 있어 20℃조건이면 약 15분, 5℃ 조건이면 약 20분 정도가 바람직하다.At this time, the open time refers to the evaporation time of the moisture in the adhesive as the waiting time after application to remove the deformation of the tile and to prevent the lifting of the tile seam after attachment. It starts to cling like This is closely related to temperature and environment, so about 15 minutes at 20 ° C and about 20 minutes at 5 ° C are preferred.

그리고 상기 작업가능시간은 도포 후 약 60분 이내이면 무방하며 저장은 0~35℃의 직사광선을 피하여 실내에서 6개월간 보관 가능하다.In addition, the workable time may be within 60 minutes after application, and the storage may be stored for 6 months indoors away from direct sunlight at 0 ° C to 35 ° C.

상기와 같은 제조방법에 의해 얻어지는 수성 접착제는 데코타일, 골드타일, 우드타일, 각종 디럭스 및 합성수지 시트 등의 접착제로 사용함으로서 강력한 접착력을 제공받음은 물론 환경 친화적이어서 인체에도 유익함을 제공해 줄 수 있는 것이다.The water-based adhesive obtained by the above manufacturing method is used as an adhesive such as decotiles, gold tiles, wood tiles, various deluxe and synthetic resin sheets, so that strong adhesive strength is provided as well as environmentally friendly, which can provide benefits to the human body. will be.

이상에서 상세히 설명한 바와 같이, 본 발명에 따른 환경 친화적 수성 접착제 및 그 제조방법은 미생물에 대한 항균성이 우수하여 습한 곳에서도 강한 접착력을 유지할 수 있으며, 인체에 유익한 원적외선과 음이온을 방사하여 각종 기능성을 제공받을 수 있음은 물론, 그 조성물을 수성을 사용하기 때문에 새집증후군의 발생을 미연에 방지함과 아울러 환경 친화적인 고품질의 접착제를 제공하여 부가가치 증대에도 일익을 담당할 수 있는 등 그 기대되는 바가 매우 크다.As described in detail above, the environmentally friendly water-based adhesive according to the present invention and its manufacturing method are excellent in antimicrobial resistance to microorganisms can maintain a strong adhesion even in wet places, radiate far infrared rays and anions beneficial to the human body to provide a variety of functionality In addition, the composition is used in water, which prevents the occurrence of sick house syndrome in advance, and provides high-quality adhesives that are environmentally friendly, which can play a role in increasing added value. .

도 1은 본 발명에 따른 수성 접착제의 제조방법에 대한 제조공정도1 is a manufacturing process diagram for the method of producing an aqueous adhesive according to the present invention

Claims (5)

아크릴계에멀젼(55~65%), 석분(5~10%), 접착부여제(8~12%), 물(5~10%), 첨가제(2~5%), 기능성부여제(10~20%), 은나노(5%), 토르말린(8~15%)을 첨가하여 혼합하는 단계;Acrylic emulsion (55 ~ 65%), stone powder (5 ~ 10%), adhesive agent (8 ~ 12%), water (5 ~ 10%), additive (2 ~ 5%), functional emulsifier (10 ~ 20 %), Silver nano (5%), tourmaline (8-15%) by adding and mixing; 상기 혼합액을 100rpm의 속도로 1시간 동안 고속 분산하는 단계;Dispersing the mixed solution at a high speed of 100 rpm for 1 hour; 상기 고속분산 후 고형분(%), 점도, 비중, 외관 등의 액상검사를 하는 단계;Performing a liquid phase inspection of the solid content (%), viscosity, specific gravity, appearance after the high-speed dispersion; 상기 액상검사 후 오픈타임, 작업가능시간, 접착강도, 저장성 등의 물성검사를 하는 단계;Performing physical property inspection after the liquid phase inspection such as open time, working time, adhesive strength, and storage property; 상기 물성검사 후 중량단위로 밀봉 포장하는 단계를 포함하는 것을 특징으로 하는 환경 친화적 수성 접착제.Environmentally friendly aqueous adhesive comprising the step of sealing packaging by weight unit after the physical property test. 제 1항에 있어서,The method of claim 1, 상기 접착부여제는 송진, 아크릴계점착제를 혼합한 것을 특징으로 하는 환경 친화적 수성 접착제.The adhesive agent is environmentally friendly water-based adhesive, characterized in that the mixture of rosin, acrylic adhesive. 제 1항에 있어서,The method of claim 1, 상기 첨가제는 분산제, 소포제, 증점제, 방부제, 유화제등을 혼합한 것을 특징으로 하는 환경 친화적 수성 접착제.The additive is an environmentally friendly water-based adhesive, characterized in that the dispersant, antifoaming agent, thickener, preservative, emulsifier is mixed. 제 1항에 있어서,The method of claim 1, 상기 기능성부여제는 황토, 음이온, 게르마늄, 옥분말을 혼합한 것을 특징으로 하는 환경 친화적 수성 접착제.The functional imparting agent is an environmentally friendly aqueous adhesive, characterized in that the mixture of ocher, anion, germanium, jade powder. 제 1 항의 방법으로 제조되는 것을 특징으로 하는 환경 친화적 수성 접착제.An environmentally friendly aqueous adhesive prepared by the method of claim 1.
KR1020050060570A 2005-07-06 2005-07-06 Environment friendship hydrogenous adhesives and the manufacturing method KR20050080055A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100738359B1 (en) * 2007-03-14 2007-07-12 엄점동 Mortar adhesion reinforcing agent and the finishing materials thereof
KR100973230B1 (en) * 2007-11-05 2010-07-30 서울대학교기술지주 주식회사 Orthodontic adhesive
KR101110235B1 (en) * 2009-06-01 2012-03-14 임채영 Cement nothing addition concrete water soluble bonding agent and manufacturing method of concrete
CN111748265A (en) * 2020-07-15 2020-10-09 美国维芙科技控股集团有限公司 Active antibacterial water-based epoxy seam beautifying agent capable of releasing negative ions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100738359B1 (en) * 2007-03-14 2007-07-12 엄점동 Mortar adhesion reinforcing agent and the finishing materials thereof
KR100973230B1 (en) * 2007-11-05 2010-07-30 서울대학교기술지주 주식회사 Orthodontic adhesive
KR101110235B1 (en) * 2009-06-01 2012-03-14 임채영 Cement nothing addition concrete water soluble bonding agent and manufacturing method of concrete
CN111748265A (en) * 2020-07-15 2020-10-09 美国维芙科技控股集团有限公司 Active antibacterial water-based epoxy seam beautifying agent capable of releasing negative ions

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