CN107880600A - Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room - Google Patents

Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room Download PDF

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Publication number
CN107880600A
CN107880600A CN201711211155.XA CN201711211155A CN107880600A CN 107880600 A CN107880600 A CN 107880600A CN 201711211155 A CN201711211155 A CN 201711211155A CN 107880600 A CN107880600 A CN 107880600A
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Prior art keywords
parts
powder
high osmosis
coating
preparation technology
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CN201711211155.XA
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Chinese (zh)
Inventor
杨常青
欧利萍
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Guangdong Yikang Grand Health Life Technology Co Ltd
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Guangdong Yikang Grand Health Life Technology Co Ltd
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Priority to CN201711211155.XA priority Critical patent/CN107880600A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room based on CRHD, the present invention relates to paint field, for caused secondary environmental pollution during interior decoration, the present invention provides inorganic environment-friendly coating in a kind of high osmosis room, including:Water, lithopone, nano-calcium carbonate, Nano silver solution, negative ion powder, vinylacetate, silica, talcum powder, titanium dioxide, acrylic emulsion, glycerine etc..The beneficial effects of the present invention are:1. its paint film formed is in tridimensional network, make paint adhesion big, water-fast washable, ageing-resistant, excellent performance.2. with preferably elasticity, wall crackle is can overcome the disadvantages that, decorative effect can be improved.3. antistatic, dust is not easy to adhere to, and coating bright color is lasting made of anti-corrosive antibacterial, and resistance tocrocking is strong.4. with indoor formaldehyde, benzene, release anion is removed, indoor secondary pollution is removed, the function such as improves, purify the air of a room, be environmentally friendly, choosing generation upgrading green coating.

Description

Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room
Technical field
The present invention relates to paint field, and in particular to inorganic environment-friendly coating in a kind of high osmosis room based on CRHD activity And its preparation technology and application method.
Background technology
Interior wall coating is exactly the emulsion paint of general finishing, is divided into polyvinyl acetate emulsion and propylene according to the difference of base material The major class of yogurt liquid two.Emulsion paint is a kind of convenient construction, safe, water-fastness, good permeability coating using water as diluent.Build Most of interior/exterior decoration material of material market supply is that organic material or organic-inorganic class composite, these materials contain The noxious materials such as a large amount of volatile organic matter formaldehyde, benzene, dimethylbenzene, cause indoor environmental pollution, have encroached on health.And Pollution during the production and use of inorganic coating base-material to environment is small, and product majority is no environment using water as decentralized medium With the harmful effect in terms of health, and the ageing-resistant and some physical property of inorganic coating, cost performance index are better than organic painting Material.
Anion be identified be with kill germ and purify air effective means, its mechanism essentially consist in change or Energy transfer causes bacterium to be destroyed, and negative ion powder not only has lasting negative ion generating function, good bactericidal anti-corrosion Effect, Strong oxdiative restoring function, pernicious gas, formaldehyde, benzene etc. can be degraded, be purified the air of a room.
" green " " green manufacturing " is to manufacture proposition to coating material production after people pay much attention to ecological environmental protection It is required that selecting natural organic coating and other activated materials, a kind of not only environmentally friendly but also reproducible " environmentally friendly " material is found, Existing inner wall decorative coating weak point can be made up, realizes that the iteration upgrading of traditional product is particularly important.
The content of the invention
It is an object of the present invention to for caused secondary environmental pollution during interior decoration, there is provided one kind is by hypertonic Permeability can nano composite material, natural stone-powder, metal powder, CRHD deionized waters and the nuisances such as indoor formaldehyde and benzene can be removed The biology enzyme of matter, the Antibacterial accessory ingredient such as negative ion powder and natural Flos Caryophylli extract, interior wall prepared by optimization component proportion technique apply Material, and by changing and optimizing molecular activity, the Antimicrobial preservative function of interior wall coating is improved, promotion realizes interior wall coating product Green iteration upgrading.
CRHD(Based on human body " sense of taste conditioned reflex and health identification ")Structural system
“Conditional Reflex and Health Diagnostic based on taste”
Tested using the human body sense of taste to assess the structural system of human body health status, and obtained according to medical science and physiology promise prize Person has found:" only small-micelle water could pass through 2 nanometers(nm)Human body cell ion channel, into nucleus and DNA, excite Vitality, common pure water macromolecular mass can not be directly entered into the cell " discovery, prepared active water(Deionized water).
To realize above-mentioned purpose, the present invention is to realize above-mentioned purpose using following technical formula and technique.
The preparation technology of inorganic environment-friendly coating in a kind of high osmosis room, described preparation technology include the steps:
(1)Prepare the material of following parts by weight:
80 ~ 90 parts of water, preferably CRHD deionized waters;
20 ~ 30 parts of lithopone;
6 ~ 10 parts of nano-calcium carbonate;
0.02 ~ 0.05 part of Nano silver solution;
0.1 ~ 2.0 part of negative ion powder;
0.3 ~ 0.6 part of vinylacetate;
0.02 ~ 0.1 part of silica;
10 ~ 18 parts of talcum powder;
20 ~ 30 parts of titanium dioxide;
5 ~ 10 parts of acrylic emulsion;
1 ~ 2 part of glycerine;
2 ~ 4 parts of ethylene glycol;
Anti- anti-0.5 ~ 1.0 part of the drying prescription of enzyme;
0.1 ~ 0.4 part of thickener;
PH mediator agents are appropriate;
Nano-calcium carbonate, also known as super fine calcium carbonate, it is loading pigment, there is fine and smooth, uniform, whiteness height, good in optical property The advantages that, because nano-calcium carbonate has space steric effect, the larger lithopone of formula density can be made to suspend, play anti-settling and make With after painting, the increase of paint film whiteness, gloss is high, and covering power does not decline.
Nano silver solution primarily serves the effect of antibiotic and sterilizing, and its is nontoxic, safer without volatility.Dioxy SiClx is used for the weatherability for improving coating.PH mediator agents are also known as acidity regulator, are mainly used in the acidity adjustment of food, but originally In case, acidity regulator is additionally beneficial to and nano-silver ionic complex reaction, prevention in addition to it can help the pH value of adjusting coating Aoxidize or take off and become reaction, stable color, the effect for strengthening gelling characteristic.
Described acrylic emulsion dosage is few, for increasing the antiseepage of coating, anti-corrosion, anti-freezing property.Glycerine initial stage can be with Improve the dispersiveness of coating, the later stage can react with other acid, form esters, be beneficial to the film to form densification.Second Glycol contributes to plus improved the dissolving of organic matter and inorganic matter so that coating is more prone to well mixed.
Anion be identified be with kill germ and purify air effective means, its mechanism essentially consist in change or Energy transfer causes bacterium to be destroyed, and negative ion powder not only has lasting negative ion generating function, good bactericidal anti-corrosion Effect, Strong oxdiative restoring function, pernicious gas, formaldehyde, benzene etc. can be degraded, be purified the air of a room.
(2)Add water in agitator, start mixer, stirred with 1000 ~ 1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred until homogeneous;
(4)Continue addition vinylacetate, Nano silver solution, lithopone, negative ion powder, talcum powder mixing under stirring to stir Mix 30 ~ 40 minutes;
(5)Mixer mixing speed is reduced to 500 ~ 700r/min, adds ethylene glycol, the anti-drying prescription of anti-enzyme, glycerine, acrylic emulsion, Stirring 30 minutes;Stirring is advantageous to well mixed and appropriate radiating, but to reduce mixing speed, prevents from being layered or lumps, Possess suitable colloid size simultaneously.
(6)The pH value in agitator is adjusted, reaches 8 ~ 9;
(7)Thickener is added 7-14 minutes are stirred in agitator;
(8)Stop stirring, stand after bubble collapse, filtered with 90 ~ 120 mesh nylon leaching nets, obtain paint solution;
(9)By natural stone-powder, metal powder(Such as aluminium powder, copper powder)1 is pressed with paint solution:0.006:After 3 weight are than mixing, colloid is used Grinder is ground, filtered, and obtains wallpaper paint;The purpose of addition metal powder is the outward appearance for improving coating, with gold The color of category.
Described natural stone-powder is marble powder, red granite stone flour, yellow granite stone powder, black granite stone flour One or more of.
Further, described titanium dioxide is nanometer titanium dioxide, and dosage is the 10% of titanium dioxide weight.
Further, described silica is nano level silica.
Further, described thickener is ethyl acrylate or methacrylic acid copolymer.
Further, the described anti-drying prescription of anti-enzyme is Flos Caryophylli extract.Flos Caryophylli extract is used for the smell for improving coating.
The application method of inorganic environment-friendly coating in a kind of high osmosis room, described environmental protection coating material is dilute with 3 ~ 5% clear water After releasing.
The beneficial effects of the present invention are:1st, because the specific surface area of the high osmosis inorganic composite materials of the present invention is big, Active strong, its paint film formed is in tridimensional network, makes paint adhesion big, water-fast washable, ageing-resistant, excellent performance.
2nd, due to present invention employs high osmosis inorganic compounding raw material, after smearing surface drying time can≤2H(25 degree), because This, has preferably elasticity, can overcome the disadvantages that wall crackle, can improve decorative effect.
3rd, antistatic present invention employs high osmosis inorganic composite materials, dust is not easy to adhere to, made of anti-corrosive antibacterial Coating bright color is lasting, and resistance tocrocking is strong.
4th, due to present invention employs high osmosis inorganic composite materials, the exclusive recessive role of its biology enzyme, having clear Except indoor formaldehyde, benzene, release anion, indoor secondary pollution is removed, the function such as improves, purify the air of a room, being environment-friendly Type, choosing generation upgrading green coating.
Embodiment
Embodiment 1
(1)Prepare the material of following parts by weight:
85 parts of CRHD deionized waters;
25 parts of lithopone;
9 parts of nano-calcium carbonate;
0.04 part of Nano silver solution;
1 part of negative ion powder;
0.5 part of vinylacetate;
0.08 part of silica;
15 parts of talcum powder;
22 parts of titanium dioxide;
7 parts of acrylic emulsion;
1.5 parts of glycerine;
3 parts of ethylene glycol;
0.7 part of Flos Caryophylli extract;
0.3 part of ethyl acrylate;
PH mediator agents are appropriate;
(2)Add water in agitator, start mixer, stirred with 1000 ~ 1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred until homogeneous;
(4)Continue addition vinylacetate, Nano silver solution, lithopone, negative ion powder, talcum powder mixing under stirring to stir Mix 35 minutes;
(5)Mixer mixing speed is reduced to 500 ~ 700r/min, adds ethylene glycol, the anti-drying prescription of anti-enzyme, glycerine, acrylic emulsion, Stirring 30 minutes;
(6)The pH value in agitator is adjusted, reaches 8 ~ 9;
(7)Ethyl acrylate is added 7-14 minutes are stirred in agitator;
(8)Stop stirring, stand after bubble collapse, filtered with 120 mesh nylon leaching nets, obtain paint solution;
(9)Marble powder, aluminium powder and paint solution are pressed 1:0.006:After 3 weight are than mixing, it is ground using colloid mill, mistake Filter, obtains wallpaper paint.
Sprayed after wallpaper paint is diluted with 3 ~ 5% clear water.
Embodiment 2
(1)Prepare the material of following parts by weight:
90 parts of water;
30 parts of lithopone;
6 parts of nano-calcium carbonate;
0.03 part of Nano silver solution;
0.9 part of negative ion powder;
0.4 part of vinylacetate;
0.06 part of silica;
13 parts of talcum powder;
2 parts of nanometer titanium dioxide;
7 parts of acrylic emulsion;
1.5 parts of glycerine;
2.5 parts of ethylene glycol;
Anti- anti-0.60 part of the drying prescription of enzyme;
0.2 part of thickener;
PH mediator agents are appropriate;
(2)Add water in agitator, start mixer, stirred with 1000 ~ 1500r/min speed;
(3)Nanometer titanium dioxide and silica are added under stirring, is stirred until homogeneous;
(4)Continue addition vinylacetate, Nano silver solution, lithopone, negative ion powder, talcum powder mixing under stirring to stir Mix 36 minutes;
(5)Mixer mixing speed is reduced to 500 ~ 700r/min, adds ethylene glycol, the anti-drying prescription of anti-enzyme, glycerine, acrylic emulsion, Stirring 30 minutes;
(6)The pH value in agitator is adjusted, reaches 8 ~ 9;
(7)Thickener is added 7-14 minutes are stirred in agitator;
(8)Stop stirring, stand after bubble collapse, filtered with 90 mesh nylon leaching nets, obtain paint solution;
(9)Red granite stone flour, copper powder and paint solution are pressed 1:0.006:After 3 weight are than mixing, carried out using colloid mill Grinding, filtering, obtain wallpaper paint.
Used after wallpaper paint is diluted with 5% clear water.
Embodiment 3
(1)Prepare the material of following parts by weight:
80 parts of water;
21 parts of lithopone;
9 parts of nano-calcium carbonate;
0.05 part of Nano silver solution;
2.0 parts of negative ion powder;
0.3 part of vinylacetate;
0.1 part of nano silicon;
18 parts of talcum powder;
20 parts of titanium dioxide;
9 parts of acrylic emulsion;
1 part of glycerine;
3 parts of ethylene glycol;
Anti- anti-1.0 parts of the drying prescription of enzyme;
0.3 part of methacrylic acid copolymer;
PH mediator agents are appropriate;
(2)Add water in agitator, start mixer, stirred with 1000 ~ 1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred until homogeneous;
(4)Continue addition vinylacetate, Nano silver solution, lithopone, negative ion powder, talcum powder mixing under stirring to stir Mix 30 ~ 40 minutes;
(5)Mixer mixing speed is reduced to 500 ~ 700r/min, adds ethylene glycol, the anti-drying prescription of anti-enzyme, glycerine, acrylic emulsion, Stirring 30 minutes;
(6)The pH value in agitator is adjusted, reaches 8 ~ 9;
(7)Methacrylic acid copolymer is added 7-14 minutes are stirred in agitator;
(8)Stop stirring, stand after bubble collapse, filtered with 90 ~ 120 mesh nylon leaching nets, obtain paint solution;
(9)Natural stone-powder, copper powder and paint solution are pressed 1:0.006:After 3 weight are than mixing, it is ground using colloid mill, mistake Filter, obtains wallpaper paint.Described natural stone-powder is yellow granite stone powder and black granite stone flour according to 1:1 ratio mixing Form.
Used after wallpaper paint is diluted with 3% clear water.
The embodiment 1-3 coating prepared is detected, benzene, toluene, ethylbenzene or dimethylbenzene is not detected, does not also detect Free formaldehyde, lead, cadmium, cadmium and mercury also do not detect.
Embodiment 1-3 sterilizing rates(Escherichia coli and black-koji mould)Reach 99%.

Claims (7)

1. the preparation technology of inorganic environment-friendly coating in a kind of high osmosis room, it is characterised in that described preparation technology is included such as Under step:
(1)Prepare the material of following parts by weight:
80 ~ 90 parts of water;
20 ~ 30 parts of lithopone;
6 ~ 10 parts of nano-calcium carbonate;
0.02 ~ 0.05 part of Nano silver solution;
0.1 ~ 2.0 part of negative ion powder;
0.3 ~ 0.6 part of vinylacetate;
0.02 ~ 0.1 part of silica;
10 ~ 18 parts of talcum powder;
20 ~ 30 parts of titanium dioxide;
5 ~ 10 parts of acrylic emulsion;
1 ~ 2 part of glycerine;
2 ~ 4 parts of ethylene glycol;
Anti- anti-0.5 ~ 1.0 part of the drying prescription of enzyme;
0.1 ~ 0.4 part of thickener;
PH mediator agents are appropriate;
(2)Add water in agitator, start mixer, stirred with 1000 ~ 1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred until homogeneous;
(4)Continue addition vinylacetate, Nano silver solution, lithopone, negative ion powder, talcum powder mixing under stirring to stir Mix 30 ~ 40 minutes;
(5)Mixer mixing speed is reduced to 500 ~ 700r/min, adds ethylene glycol, the anti-drying prescription of anti-enzyme, glycerine, acrylic emulsion, Stir;
(6)The pH value in agitator is adjusted, reaches 8 ~ 9;
(7)Thickener is added 7-14 minutes are stirred in agitator;
(8)Stop stirring, stand after bubble collapse, filtered with 90 ~ 120 mesh nylon leaching nets, obtain paint solution;
(9)Natural stone-powder, metal powder and paint solution are pressed 1:0.006:After 3 weight are than mixing, be ground using colloid mill, Filtering, obtains wallpaper paint;
Described natural stone-powder is in marble powder, red granite stone flour, yellow granite stone powder, black granite stone flour More than one.
2. the preparation technology of inorganic environment-friendly coating in a kind of high osmosis room as claimed in claim 1, it is characterised in that described Titanium dioxide be nanometer titanium dioxide, dosage is the 10% of titanium dioxide weight.
3. the preparation technology of inorganic environment-friendly coating in a kind of high osmosis room as claimed in claim 1, it is characterised in that described Silica be nano level silica.
4. the preparation technology of inorganic environment-friendly coating in a kind of high osmosis room as claimed in claim 1, it is characterised in that described Thickener be ethyl acrylate or methacrylic acid copolymer.
5. the preparation technology of inorganic environment-friendly coating in a kind of high osmosis room as claimed in claim 1, it is characterised in that described The anti-drying prescription of anti-enzyme be Flos Caryophylli extract.
A kind of 6. application method of inorganic environment-friendly coating in high osmosis room, it is characterised in that by described environmental protection coating material with 3 ~ After 5% clear water dilution.
7. inorganic environment-friendly coating in a kind of high osmosis room as described in claim 1-6 any claims.
CN201711211155.XA 2017-11-28 2017-11-28 Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room Pending CN107880600A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113477164A (en) * 2021-08-11 2021-10-08 姚焕芹 Water-based environment-friendly coating and processing method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592835A (en) * 2015-02-03 2015-05-06 泉州市新协志特种涂料有限公司 Environment-friendly finishing paint for ships
CN106395569A (en) * 2016-08-31 2017-02-15 住友富士电梯有限公司 Elevator having disinfection function
CN107162498A (en) * 2017-06-22 2017-09-15 深圳市特塍装饰材料有限公司 A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method
CN107254208A (en) * 2017-06-22 2017-10-17 深圳市特塍装饰材料有限公司 It is a kind of to purify green inner wall paint that benzene and formaldehyde be degerming and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104592835A (en) * 2015-02-03 2015-05-06 泉州市新协志特种涂料有限公司 Environment-friendly finishing paint for ships
CN106395569A (en) * 2016-08-31 2017-02-15 住友富士电梯有限公司 Elevator having disinfection function
CN107162498A (en) * 2017-06-22 2017-09-15 深圳市特塍装饰材料有限公司 A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method
CN107254208A (en) * 2017-06-22 2017-10-17 深圳市特塍装饰材料有限公司 It is a kind of to purify green inner wall paint that benzene and formaldehyde be degerming and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113477164A (en) * 2021-08-11 2021-10-08 姚焕芹 Water-based environment-friendly coating and processing method thereof

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Application publication date: 20180406