CN107162498A - A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method - Google Patents

A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method Download PDF

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Publication number
CN107162498A
CN107162498A CN201710480965.9A CN201710480965A CN107162498A CN 107162498 A CN107162498 A CN 107162498A CN 201710480965 A CN201710480965 A CN 201710480965A CN 107162498 A CN107162498 A CN 107162498A
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parts
preparation
powder
paint
nano
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CN201710480965.9A
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Inventor
丘权华
张文俐
张粮菁
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Shenzhen green en Bei Intelligent Technology Co., Ltd.
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Shenzhen Xincheng Special Decoration Material Co Ltd
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Publication of CN107162498A publication Critical patent/CN107162498A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/203Oil-proof or grease-repellant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • C04B2111/2061Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • C04B2111/2069Self cleaning materials, e.g. using lotus effect
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2092Resistance against biological degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

Abstract

A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method, the invention belongs to colorful wall artistic paint field, to solve problems of the prior art, a kind of nano combined colorful liquid wallpaper paint that the present invention is provided, the paint includes:Water, lithopone, nano-calcium carbonate, Nano silver solution, alumina silicate, calgon, silica, hydroxyethyl cellulose, talcum powder, PH mediator agents, titanium dioxide, ethylene glycol, organosilicon modified crylic acid resin, glycerine, thickener;Antistatic present invention employs nano composite material, dust is difficult attachment, and persistently, resistance tocrocking is strong for the paint film bright color that it is formed.

Description

A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method
Technical field
The invention belongs to colorful wall artistic paint field, specifically, belong to one kind by natural pigment, circular nanometer structure Prepared and application method with the environmental-protection nano composite colorful liquid wallpaper paint that light is combined.
Background technology
Liquid wallpaper is emerging industry, and liquid wallpaper is also referred to as wall skill coating, be a kind of nontoxic, pollution-free, environmental protection characteristic it is strong, The high new decorative material of cost performance.By all kinds of specific purpose tools and skill and technique and coordinate different coloring process, produce metope A variety of texture textures and the artistic effect of light and shade shadow transition, wall covering from the artificial synthesized smooth type epoch, bring day into The new era of the right concavo-convex coating of environment-friendly type, is that the diversified quality requirements of consumer add more more options.Liquid wallpaper belongs to Without using 107 glue, polyethylene, alcohol etc. when water-soluble colorful coating, construction, so the heavy metal such as not leaded, mercury and aldehydes Material, so as to accomplish nontoxic pollution-free and with performances such as good protection against the tide, antibacterials, with environment-friendly feature, but one As without exterminating bacterium, it is anti-mildew, absorb ultraviolet, highlighted flash function.
Because surface texturisation is single, toughness is not strong, the composition of long acting antibiotic composition and anti-aging stripping is not contained in material, surely It is qualitative not good enough, also result in delamination during with wall, the degree of adhesion of cement bottom layer, adhesive force deficiency and peel off, have a strong impact on using effect.
The content of the invention
It is an object of the present invention to solve problems of the prior art, there is provided a kind of surface-coating and material are multiple Close, the environmental-protection nano composite colorful liquid wallpaper paint interacted by natural pigment circular nanometer structure and light and its preparation Technique.The liquid wallpaper paint, mixes ratio by nano composite material, natural stone-powder, metal powder and paint liquid and synthesizes.Make the present invention that there is color Rich real, the high intense flash of damp soft, texture, dual antibacterial bacteriostatic, environment-friendly, adhesive force are strong, the feature such as convenient of constructing, and significantly carry The synthesis physical and chemical index of liquid wallpaper paint is risen, the optimization and upgrading of product quality is promoted.
To realize above-mentioned purpose, the technical scheme that the present invention is provided is as follows:
A kind of preparation method of nano combined colorful liquid wallpaper paint, described preparation method comprises the following steps:
(1)Prepare the material of following parts by weight:
80-90 parts of water,
25 ~ 30 parts of lithopone,
8-10 parts of nano-calcium carbonate,
0.02-0.04 parts of Nano silver solution,
2-4 parts of alumina silicate,
0.3 ~ 0.8 part of calgon,
0.02 ~ 0.1 part of silica,
0.5 part of hydroxyethyl cellulose,
16-18 parts of talcum powder,
0.05 ~ 0.15 part of PH mediator agents,
20 ~ 35 parts of titanium dioxide,
2-4 parts of ethylene glycol,
5-7 parts of organosilicon modified crylic acid resin,
1-2 parts of glycerine,
0.1 ~ 0.4 part of thickener;
(2)Add water in agitator, start mixer and stirred with 1000-1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred;
(4)Continue under stirring add calgon, Nano silver solution, hydroxyethyl cellulose, lithopone, alumina silicate, Talcum powder, is stirred shearing 30 ~ 40 minutes, and mixing speed is 1000-1500r/min;
(5)Mixer mixing speed is reduced to 500-700r/min, adds ethylene glycol, glycerine, organosilicon-modified acrylic, stirring 30-40 minutes;
(6)The pH value in agitator is adjusted, 8 ~ 9 are reached;
(7)Thickener is added in agitator and stirred 7-14 minutes;
(8)Stop stirring, stand after bubble collapse, filtered with 90-120 mesh nylon leaching net, obtain painting liquid;
(9)Natural stone-powder, metal powder and paint liquid are pressed 1:0.006:After 3 weight are than mixing, be ground using colloid mill, Filtering, obtains wallpaper paint.
Further, described titanium dioxide is nano level titanium dioxide, and its consumption is the 10% of ordinary titanium powder.
Further, described silica is nano level silica.
Further, described thickener is ethyl acrylate or methacrylic acid copolymer.
Further, described natural stone-powder is marble powder, red granite stone flour, yellow granite stone powder, black One or more of granite stone powder.
Further, the particle diameter of the talcum powder is 1200 mesh.
Further, step(7)The color stuffing of 0.05-0.07 parts by weight is added afterwards, adds step(8)And step(9).
A kind of application method of nano combined colorful liquid wallpaper paint, by described wallpaper paint with after 3 ~ 5% clear water dilution .
The present invention also provides a kind of using nano combined colorful liquid wallpaper paint made from the above method.
The beneficial effects of the present invention are:
Because the specific surface area of the nano composite material of the present invention is big, its paint film formed is in three-dimensional netted destructing, strong covering power Adhesive force is big, water-fast washable, ageing-resistant, excellent performance.
Due to present invention employs nano combined raw material, after film surface drying time can≤2h(25 degree).Therefore, with preferable Elasticity, can overcome the disadvantages that wall crackle, decorative effect can be improved.
Antistatic present invention employs nano composite material, dust is difficult attachment, and its paint film bright color formed is held Long, resistance tocrocking is strong.
Because present invention employs nano combined raw material, the exclusive photocatalysis of its nano material can make nytron The material of species is oxidized to gas or changes into the material for being easy to be swabbed, therefore, any adhesion under the irradiation of light In the material of the hydrocarbon of surface of wall, bacterium, greasy dirt stain etc. are easily eliminated.
Embodiment
Embodiment 1
A kind of preparation method of nano combined colorful liquid wallpaper paint, it is characterised in that described preparation method includes following step Suddenly:
(1)Prepare the material of following parts by weight:
80-90 parts of water,
25 ~ 30 parts of lithopone,
8-10 parts of nano-calcium carbonate,
0.02-0.04 parts of Nano silver solution,
2-4 parts of alumina silicate,
0.3 ~ 0.8 part of calgon,
0.02 ~ 0.1 part of nanometer grade silica,
0.5 part of hydroxyethyl cellulose,
Particle diameter is 16-18 parts of 1200 mesh talcum powder,
0.05 ~ 0.15 part of PH mediator agents,
20 ~ 35 parts of nano grade titanium white powder,
2-4 parts of ethylene glycol,
5-7 parts of organosilicon modified crylic acid resin,
1-2 parts of glycerine,
0.1 ~ 0.4 part of ethyl acrylate;
(2)Add water in agitator, start mixer and stirred with 1000-1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred;
(4)Continue under stirring add calgon, Nano silver solution, hydroxyethyl cellulose, lithopone, alumina silicate, Talcum powder, is stirred shearing 30 ~ 40 minutes, and mixing speed is 1000-1500r/min;
(5)Mixer mixing speed is reduced to 500-700r/min, adds ethylene glycol, glycerine, organosilicon-modified acrylic, stirring 30-40 minutes;
(6)The pH value in agitator is adjusted, 8 ~ 9 are reached;
(7)Thickener is added in agitator and stirred 7-14 minutes;
(8)Stop stirring, stand after bubble collapse, filtered with 90-120 mesh nylon leaching net, obtain painting liquid;
(9)Marble powder, metal powder and paint liquid are pressed 1:0.006:After 3 weight are than mixing, be ground using colloid mill, Filtering, obtains wallpaper paint.
Embodiment 2
A kind of preparation method of nano combined colorful liquid wallpaper paint, described preparation method comprises the following steps:
(1)Prepare the material of following parts by weight:
80-90 parts of water,
25 ~ 30 parts of lithopone,
8-10 parts of nano-calcium carbonate,
0.02-0.04 parts of Nano silver solution,
2-4 parts of alumina silicate,
0.3 ~ 0.8 part of calgon,
0.02 ~ 0.1 part of silica,
0.5 part of hydroxyethyl cellulose,
16-18 parts of talcum powder,
0.05 ~ 0.15 part of PH mediator agents,
20 ~ 35 parts of titanium dioxide,
2-4 parts of ethylene glycol,
5-7 parts of organosilicon modified crylic acid resin,
1-2 parts of glycerine,
0.1 ~ 0.4 part of methacrylic acid copolymer;
(2)Add water in agitator, start mixer and stirred with 1000-1500r/min speed;
(3)Titanium dioxide and silica are added under stirring, is stirred;
(4)Continue under stirring add calgon, Nano silver solution, hydroxyethyl cellulose, lithopone, alumina silicate, Talcum powder, is stirred shearing 30 ~ 40 minutes, and mixing speed is 1000-1500r/min;
(5)Mixer mixing speed is reduced to 500-700r/min, adds ethylene glycol, glycerine, organosilicon-modified acrylic, stirring 30-40 minutes;
(6)The pH value in agitator is adjusted, 8 ~ 9 are reached;
(7)Thickener is added in agitator and stirred 7-14 minutes;
(8)Stirring, adds the color stuffing of 0.05-0.07 parts by weight;
(9)Stop stirring, stand after bubble collapse, filtered with 90-120 mesh nylon leaching net, obtain painting liquid;
(10)Yellow granite stone powder, metal powder and paint liquid are pressed 1:0.006:After 3 weight are than mixing, entered using colloid mill Row grinding, filtering, obtain wallpaper paint.
Embodiment 3
After after a kind of clear water dilution of the nano combined colorful liquid wallpaper paint 4% prepared in embodiment 1, using spraying, roller coating Or brush.

Claims (10)

1. a kind of preparation method of environmental-protection nano composite colorful liquid wallpaper paint, it is characterised in that described preparation method bag Include following steps:
Prepare the material of following parts by weight:
80-90 parts of water,
25 ~ 30 parts of lithopone,
8-10 parts of nano-calcium carbonate,
0.02-0.04 parts of Nano silver solution,
2-4 parts of alumina silicate,
0.3 ~ 0.8 part of calgon,
0.02 ~ 0.1 part of silica,
0.5 part of hydroxyethyl cellulose,
16-18 parts of talcum powder,
0.05 ~ 0.15 part of PH mediator agents,
20 ~ 35 parts of titanium dioxide,
2-4 parts of ethylene glycol,
5-7 parts of organosilicon modified crylic acid resin,
1-2 parts of glycerine,
0.1 ~ 0.4 part of thickener;
Add water in agitator, start mixer and stirred with 1000-1500r/min speed;
Titanium dioxide and silica are added under stirring, is stirred;
Continue to add calgon, Nano silver solution, hydroxyethyl cellulose, lithopone, alumina silicate, talcum under stirring Powder, is stirred shearing 30 ~ 40 minutes, and mixing speed is 1000-1500r/min;
Mixer mixing speed is reduced to 500-700r/min, adds ethylene glycol, glycerine, organosilicon-modified acrylic, stirs 30-40 Minute;
The pH value in agitator is adjusted, 8 ~ 9 are reached;
Thickener is added in agitator and stirred 7-14 minutes;
Stop stirring, stand after bubble collapse, filtered with 90-120 mesh nylon leaching net, obtain painting liquid;
Natural stone-powder, metal powder and paint liquid are pressed 1:0.006:After 3 weight are than mixing, it is ground using colloid mill, mistake Filter, obtains wallpaper paint.
2. preparation method as claimed in claim 1, it is characterised in that described titanium dioxide is nano level titanium dioxide, it is used Measure as the 10% of ordinary titanium powder.
3. preparation method as claimed in claim 1, it is characterised in that described silica is nano level silica.
4. preparation method as claimed in claim 1, it is characterised in that described thickener is ethyl acrylate or metering system Acid copolymer.
5. preparation method as claimed in claim 1, it is characterised in that described natural stone-powder is marble powder or granite Powder.
6. preparation method as claimed in claim 1, it is characterised in that described granite stone powder be red granite stone flour, Yellow granite stone powder or black granite stone flour.
7. preparation method as claimed in claim 1, it is characterised in that the particle diameter of the talcum powder is less than 1200 mesh.
8. preparation method as claimed in claim 1, it is characterised in that step(7)The face for adding 0.05-0.07 parts by weight afterwards is filled out Material, adds step(8)And step(9).
9. a kind of application method of environmental-protection nano composite colorful liquid wallpaper paint, it is characterised in that claim 1-8 is any Wallpaper paint described in claim is with after 3 ~ 5% clear water dilution.
10. a kind of environmental-protection nano composite colorful liquid wallpaper paint, it is characterised in that described wallpaper paint requires 1-8 using profit It is prepared by the preparation method described in any claim.
CN201710480965.9A 2017-06-22 2017-06-22 A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method Pending CN107162498A (en)

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CN201710480965.9A CN107162498A (en) 2017-06-22 2017-06-22 A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method

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Application Number Priority Date Filing Date Title
CN201710480965.9A CN107162498A (en) 2017-06-22 2017-06-22 A kind of preparation of environmental-protection nano composite colorful liquid wallpaper paint and application method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880600A (en) * 2017-11-28 2018-04-06 广东易康正道大健康生命科技有限公司 Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020444A (en) * 2009-09-21 2011-04-20 中科优富(北京)科技发展有限公司 Environmental-protection nano composite colorful liquid wallpaper paint
CN102532977A (en) * 2011-12-30 2012-07-04 黑龙江省玉琦装饰涂料有限公司 Composite multifunctional health paint mate and preparation method thereof
CN105860617A (en) * 2016-07-03 2016-08-17 佛山市南海万磊建筑涂料有限公司 Waterborne inorganic diatom ooze artistic coating and method for preparing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102020444A (en) * 2009-09-21 2011-04-20 中科优富(北京)科技发展有限公司 Environmental-protection nano composite colorful liquid wallpaper paint
CN102532977A (en) * 2011-12-30 2012-07-04 黑龙江省玉琦装饰涂料有限公司 Composite multifunctional health paint mate and preparation method thereof
CN105860617A (en) * 2016-07-03 2016-08-17 佛山市南海万磊建筑涂料有限公司 Waterborne inorganic diatom ooze artistic coating and method for preparing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880600A (en) * 2017-11-28 2018-04-06 广东易康正道大健康生命科技有限公司 Inorganic environment-friendly coating and its preparation technology and application method in a kind of high osmosis room

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