KR20040066370A - Cosmetic composition of solid foundation without sweating phenomenon - Google Patents

Cosmetic composition of solid foundation without sweating phenomenon Download PDF

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Publication number
KR20040066370A
KR20040066370A KR1020030003408A KR20030003408A KR20040066370A KR 20040066370 A KR20040066370 A KR 20040066370A KR 1020030003408 A KR1020030003408 A KR 1020030003408A KR 20030003408 A KR20030003408 A KR 20030003408A KR 20040066370 A KR20040066370 A KR 20040066370A
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oil
cosmetic composition
solid foundation
sweating
wax
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KR1020030003408A
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Korean (ko)
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KR100537267B1 (en
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박병규
한종섭
이영근
윤명석
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주식회사 엘지생활건강
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE: A cosmetic composition of solid foundation without a sweating phenomenon is provided, thereby exhibiting no sweating phenomenon that oil is secreted to the surface of the skin by a change of the outer temperature, so that the skin surface of a user can be maintained at satisfactory condition. CONSTITUTION: The cosmetic composition of solid foundation comprising oil and wax without a sweating phenomenon comprises 1 to 15 wt.%, preferably 2 to 6 wt.% of sorbitan olivate which induces gelation of oil to inhibit expansion rate of oil by a change of the outer temperature, wherein the oil is selected from ester oil, volatile/non-volatile silicone oil, preferably 1 to 30 wt.% of volatile silicon oil to reduce greasy feeling; and the wax is animal, vegetable or synthetic wax.

Description

발한 현상이 없는 고형 파운데이션 화장료 조성물 {Cosmetic composition of solid foundation without sweating phenomenon}Solid foundation cosmetic composition without sweating {Cosmetic composition of solid foundation without sweating phenomenon}

본 발명은 발한 현상이 없는 고형 파운데이션 화장료 조성물에 관한 것으로서, 보다 상세하게는 외부환경의 온도 변화에도 오일이 표면으로 용출되어 나오는 발한 현상이 없으며 사용감도 양호한 고형 파운데이션 화장료 조성물에 관한 것이다.The present invention relates to a solid foundation cosmetic composition having no sweating effect, and more particularly, to a solid foundation cosmetic composition having no feeling of sweating when oil is eluted to the surface even with a temperature change of the external environment.

종래의 고형 파운데이션은 성형 후 일정시간이 경과되는 동안 외부 환경의 온도변화에 의해 내용물 중의 오일이 표면으로 용출되어 내용물 중의 색소가 같이 용출되거나 용출된 오일이 흘러내려 외관이 불량해질 뿐만 아니라 사용상에도 많은 불편을 주는 결점을 지니고 있다.In the conventional solid foundation, the oil in the contents elutes to the surface due to the temperature change of the external environment during a certain time after the molding, and the pigment in the contents elutes or the eluted oil flows out, resulting in poor appearance as well as many uses. It has some disadvantages that make it uncomfortable.

이러한 발한 현상을 해결하기 위하여 왁스의 함유량을 높이거나, 흡유력이 뛰어난 분체 또는 저융점 왁스를 화장료에 첨가하는 방법 등이 제안되었다.In order to solve this sweating, a method of increasing the content of the wax, or adding powder or low melting point wax having excellent oil absorption ability to the cosmetics has been proposed.

예를 들어, 미국 특허 제5,176,902호에는 색소를 다량 함유하는 스틱 제형에 새로운 왁스 시스템을 적용하여 경도를 높이므로써 발한 현상을 감소시키는 방법이 개시되어 있으나, 함유되는 왁스의 함량이 많으므로 사용감이 저하되는 단점이 있다. 또한, 미국 특허 제4,695,452호에는 저융점 왁스를 혼합하므로써 유분감, 부드럽고 매끄러운 발림성 등이 부여된 스틱 화장품이 개시되어 있으나, 융점이 낮은 왁스의 사용으로 인해 사용감은 개선될 수 있지만 경도가 저하되어 발한 현상이 완전히 해결되지는 못한다.For example, U. S. Patent No. 5,176, 902 discloses a method of reducing sweating by applying a new wax system to a stick formulation containing a large amount of pigment to increase hardness. There is a disadvantage. In addition, U.S. Patent No. 4,695,452 discloses stick cosmetics provided with oiliness, soft and smooth application by mixing low melting point wax. However, the use of wax having a low melting point can improve the feeling of use, but the hardness decreases, resulting in sweating. This is not completely solved.

또한, 일본공개특허 평2-172902호에서는 흡유력이 우수한 다공성 실리카 분체를 혼합하여 퍼짐성, 발림성 등의 사용성을 개선함과 동시에 발한 현상을 감소시킨 화장료 조성물을 개시하고 있다. 그러나, 이러한 흡유력이 우수한 분체를 혼합하는 경우 그 함량이 증가함에 따라 겉보기 경도는 높아지지만, 왁스와 분체사이의 결합 매트릭스가 약화되므로 제품 사용시 용기와 접해지는 부분에 부러짐 현상이 발생하는 치명적인 결함을 내포하고 있다.In addition, Japanese Patent Laid-Open No. Hei 2-172902 discloses a cosmetic composition in which porous silica powder having excellent oil absorption ability is mixed to improve usability such as spreadability and spreadability, and at the same time reduce sweating. However, when the powder having excellent oil absorption power is mixed, the apparent hardness increases as the content increases, but since the binding matrix between the wax and the powder is weakened, a fatal defect that occurs when the product is in contact with the container is broken. It is implicated.

따라서, 본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여 온도변화에도 발한 현상이 나타나지 않을 뿐만 아니라 동시에 밀착감, 발림성, 화장 지속성, 내수성, 유분감 등과 같은 사용감도 매우 양호한 고형 파운데이션 화장료 조성물을 제공하는데 있다.Therefore, the technical problem to be achieved by the present invention is to solve the above problems to provide a solid foundation cosmetic composition with a very good feeling of use, such as adhesion, application, makeup persistence, water resistance, oily feeling as well as no sweating phenomenon in the temperature change. .

상기 기술적 과제를 달성하기 위하여 본 발명은 오일 및 왁스를 함유하여 이루어진 고형 파운데이션 화장료 조성물에 있어서, 조성물 총 중량을 기준으로 솔비탄올리베이트 1 내지 15중량%를 함유하는 고형 파운데이션 화장료 조성물을 제공한다.In order to achieve the above technical problem, the present invention provides a solid foundation cosmetic composition containing 1 to 15% by weight of sorbitan sulfate based on the total weight of the composition in the solid foundation cosmetic composition containing oil and wax.

본 발명에 따른 고형 파운데이션 화장료 조성물에 사용되는 오일에는 유분감을 줄이기 위하여 사이크로메치콘과 같은 휘발성 실리콘 오일 1 내지 30중량%를 함유할 수 있다.The oil used in the solid foundation cosmetic composition according to the present invention may contain 1 to 30% by weight of a volatile silicone oil such as cyclomethicone to reduce oiliness.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에 따른 고형 파운데이션 화장료 조성물의 특징은 솔비탄올리베이트를 함유하는데 있다.A feature of the solid foundation cosmetic composition according to the present invention is that it contains sorbitan oleate.

오일-왁스-안료로 구성된 분산형 커버 메이크업 화장료 조성물과 같은 계에서의 발한 현상은 온도변화시 오일 자체나 오일-왁스간의 체적 팽창율 변화에 주로 기인한다. 즉, 발한 현상이란 고형 구성물 중의 오일 성분이 온도상승에 따른 체적 팽창으로 고형물 내부에서 표면으로 흘러나오는 현상으로서, 이와 같은 발한 현상을 방지하기 위해서는 오일과 왁스간의 체적 팽창율의 차가 없는 원료를 사용하는 것이 바람직하나, 현재 사용되는 원료로는 오일-왁스간 체적 팽창율의 차를 감소시키는데 한계가 있다. 수상-유상-안료로 구성된 유화형 고형파운데이션 화장료 조성물과 같은 계에서의 발한현상은 분산형 커버 메이크업과 마찬가지로 오일과 왁스간의 체적 팽창율 차에 의해서 발생하는 것이다.The sweating phenomenon in a system such as a dispersible cover makeup cosmetic composition composed of an oil-wax-pigment is mainly attributable to the change in the volume of the oil itself or the volume expansion between the oil-wax at the temperature change. That is, sweating is a phenomenon in which the oil component in the solid composition flows out from the inside of the solid by the volume expansion due to the temperature rise. To prevent such sweating, it is recommended to use a raw material having no difference in the volume expansion ratio between the oil and the wax. Preferably, the presently used raw materials are limited in reducing the difference in volume expansion ratio between oil and wax. Perspiration, such as emulsion-based solid foundation cosmetic compositions consisting of water-oil-pigments, is caused by the difference in volume expansion between oil and wax, as is the case with dispersible cover makeup.

그러나, 본 발명에 사용된 솔비탄올리베이트는 오일을 겔화시키므로써 외부환경의 온도변화에 따른 체적 팽창율을 억제시켜 발한현상을 방지하는데, 특히 물이 없는 포마드나 연고에서는 더 큰 효과를 발휘한다.However, sorbitan oleate used in the present invention prevents sweating by inhibiting the volume expansion rate due to the temperature change of the external environment by gelling oil, especially in pomade or ointment without water.

즉, 본 발명에 사용된 솔비탄올리베이트는 지방산과 올리브로 구성된 친유성 부분과 폴리 알콜릭 그룹을 지닌 친수성 부분으로 구성되어 있어 계면활성능력을갖으므로 기존 유화제의 사용을 대체할 수 있을 뿐만 아니라, 어떠한 종류의 오일내에서도 겔화 시키는 능력을 가지고 있으므로 수중유 타입의 고형 파운데이션에서 외상의 겔화를 촉진시켜 온도상승에 따른 오일의 체적상승율을 억제시키므로서 발한현상을 방지한다.That is, the sorbitan oleate used in the present invention is composed of a lipophilic portion composed of fatty acids and olives and a hydrophilic portion having a polyalcoholic group, and thus has a surface-active ability, thereby replacing the use of an existing emulsifier. Because it has the ability to gel in any kind of oil, it promotes the gelation of the trauma in the solid foundation of oil-in-water type to prevent sweating by suppressing the rate of rise of the oil according to the temperature rise.

또한, 유화형 고형파운데이션 분산형 커버 메이크업의 3본 밀의 공정상 사용할 수 없었던 휘발성 실리콘 오일을 유상에 다량으로 사용할 수 있게 함으로써 번들거리는 유분감이 사라져 화장에 대한 부담을 크게 줄일 수 있다.In addition, by using a large amount of volatile silicone oil that could not be used in the process of the three-mill mill of the emulsified solid foundation dispersed cover makeup, the greasy oiliness disappears and the burden on the makeup can be greatly reduced.

본 발명에 따른 고형 파운데이션 화장료 조성물에 있어서, 솔비탄올리베이트의 함량은 조성물 총 중량을 기준으로 1 내지 15중량%, 바람직하게는 2 내지 6중량%이다. 그 함량이 1중량% 미만이면 발한현상 방지효과가 미미할 수 있고, 15중량%를 초과하면 사용감이 나빠질 수 있다.In the solid foundation cosmetic composition according to the present invention, the content of sorbitan sulfate is 1 to 15% by weight, preferably 2 to 6% by weight based on the total weight of the composition. If the content is less than 1% by weight, the antiperspirant effect may be insignificant, and if the content exceeds 15% by weight, the feeling of use may deteriorate.

본 발명에 따른 고형 파운데이션 화장료 조성물에 사용될 수 있는 오일로는 에스테르계 오일, 휘발성/비휘발성 실리콘 오일 등을 들 수 있는데, 이러한 오일들은 단독으로 또는 서로 혼합하여 사용할 수 있다. 특히 화장료 조성물의 유분감을 줄이기 위하여 사이크로메치콘과 같은 휘발성 실리콘 오일을 1 내지 30중량% 사용하는 것이 바람직하다.Oils that can be used in the solid foundation cosmetic composition according to the present invention include ester-based oils, volatile / non-volatile silicone oils, etc., these oils may be used alone or mixed with each other. In particular, in order to reduce the oiliness of the cosmetic composition, it is preferable to use 1 to 30% by weight of a volatile silicone oil such as cyclomethicone.

또한, 본 발명에서는 앞서 서술한 필수 성분 이외에 화장품의 사용목적에 따라 이용되는 일반적인 성분을 사용할 수 있다. 예를 들면, 경도 형성을 위한 동물성, 식물성, 광물성 또는 합성 왁스와, 사용감 조절을 위한 극성 또는 비극성 오일, 유동도 및 분산 효율을 위한 계면활성제, 화장효과 및 사용성 조절을 위한 안료 등과 방부제, 자외선흡수제, 폴리머, 지방산 알코올 및 향료 등을 적당히 배합할 수 있다.In addition, in the present invention, in addition to the essential components described above, it is possible to use general ingredients used according to the purpose of use of cosmetics. For example, animal, vegetable, mineral or synthetic waxes for hardness formation, polar or nonpolar oils for controlling the feel, surfactants for fluidity and dispersion efficiency, pigments for controlling cosmetic effects and usability, and preservatives, UV absorbers , Polymers, fatty alcohols and fragrances can be blended as appropriate.

또한, 화장기능성을 부과하기 위해 선스크린 스틱, 화이트닝 스틱 기능을 겸비하여 제조할 수 있다. 따라서, 본 발명에 따른 조성물 중에 자외선 차단제 또는 미백제 등이 추가될 수 있다.In addition, in order to impart cosmetic functionality, it can be manufactured by having a combination of a sunscreen stick and a whitening stick function. Therefore, a sunscreen or a whitening agent or the like may be added to the composition according to the present invention.

이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어져서는 안된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다.Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, the scope of the present invention should not be construed as limited to the embodiments described below. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.

실시예 1 내지 3Examples 1 to 3

하기 표 1에 기재된 바와 같은 성분과 함량으로 다음과 같이 제조하였다. 즉, 하기 표 1에 기재된 원료(유상 성분) 1 내지 11을 80 내지 85℃로 가열하여 용해시키고, 여기에 안료 12 내지 17을 투입하여 균일 분산시켰다. 이어서, 18 내지 20의 원료(수상성분)를 투입하여 유화시킨 다음, 이 혼합물을 탈포한 후 몰더에 충진하고 상온에서 냉각하여 W/S 유화형 고형 파운데이션을 제조하였다.It was prepared as follows with the ingredients and contents as described in Table 1. That is, the raw materials (oil phase component) 1-11 of Table 1 below were heated and melt | dissolved at 80-85 degreeC, and pigment 12-17 was thrown in here, and it was made to disperse | distribute uniformly. Subsequently, 18 to 20 raw materials (aqueous components) were added to emulsify, and then the mixture was degassed and filled in a molder and cooled at room temperature to prepare a W / S emulsion solid foundation.

비교예 1 내지 3Comparative Examples 1 to 3

하기 표 1에 기재된 성분과 함량을 참조하여, 상기 실시예 1 내지 3과 동일한 방식으로 제조하였다.It was prepared in the same manner as in Examples 1 to 3 with reference to the components and contents shown in Table 1 below.

실시예 1 내지 3 및 비교예 1 내지 3에서 얻은 고형 파운데이션에 대하여 발한 현상 및 전반적인 사용감에 대하여 평가하였다.The solid foundations obtained in Examples 1 to 3 and Comparative Examples 1 to 3 were evaluated for sweating and overall feeling of use.

<발한 현상 발생 평가><Perspiration occurrence evaluation>

상기 실시예 1 내지 3 및 비교예 1 내지 3의 파운데이션의 발한 현상 발생 정도를 알아보기 위하여, 하기 표 2에 제시한 온도 조건으로 상승시키면서 하기 기술된 평가기준에 따라 평가하였다.In order to determine the degree of sweating of the foundation of Examples 1 to 3 and Comparative Examples 1 to 3, it was evaluated according to the evaluation criteria described below while increasing to the temperature conditions shown in Table 2.

(평가기준)(Evaluation standard)

매우 나쁨 (매우 심한 발한) : 1Very bad (very severe sweating): 1

나 쁨 (심한 발한) : 2Bad (severe sweating): 2

좋 음 (미세한 발한) : 3Good (fine sweating): 3

매우 좋음 (발한 현상 전혀 없음) : 4Very good (no sweating at all): 4

온도(℃)Temperature (℃) 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 5050 33 44 44 1One 1One 1One 4545 44 44 44 1One 1One 22 3737 44 44 44 22 22 22 실온Room temperature 44 44 44 44 44 44

<사용감 평가><Evaluation of feeling>

30-45세 여성 50명을 대상으로 4개의 군으로 나누어 실시예 1 내지 3과 비교예 1 내지 3을 각 군에 적절히 조절하여 얼굴 양쪽 부위에 사용하게 한 후, 다음 평가 기준에 따라 발림성, 은폐력, 밀착감, 화장지속성, 내수성, 유분감 등의 사용감을 평가하여 그 결과를 표 3에 나타내었다.50 females aged 30-45 years were divided into four groups, and Examples 1 to 3 and Comparative Examples 1 to 3 were appropriately adjusted to each group to be used on both sides of the face. The feeling of adhesion, makeup persistence, water resistance, oiliness, and the like were evaluated, and the results are shown in Table 3.

<평가 기준><Evaluation Criteria>

매우나쁨 : 1, 나쁨 : 2, 보통 : 3, 좋음 : 4, 매우 좋음 : 5Very bad: 1, Bad: 2, Moderate: 3, Good: 4, Very good: 5

항목Item 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 발림성Application 4.44.4 4.24.2 3.83.8 3.93.9 3.33.3 2.82.8 은폐력Hiding power 4.14.1 4.24.2 4.14.1 4.14.1 3.53.5 3.73.7 밀착감Tightness 4.14.1 4.54.5 4.34.3 3.73.7 3.33.3 3.53.5 화장지속성Toilet paper 4.24.2 4.24.2 4.14.1 4.04.0 3.83.8 3.83.8 유분감Oiliness 4.54.5 4.34.3 4.04.0 4.14.1 3.23.2 3.53.5

상기 표 2에 나타난 바와 같이, 본 발명에 따른 솔비탄올리베이트를 함유한 실시예 1 내지 3은 비교예 1 내지 3과는 달리 37℃ 이상의 고온에서도 발한 현상이 발생하지 않았음을 알 수 있다. 또한, 상기 표 3에 나타난 바와 같이, 본 발명에따른 실시예 1 내지 3이 밀착감, 발림성, 화장지속성, 내수성, 유분감 등의 사용감 면에서도 비교예 1 내지 3보다 우수함을 알 수 있었다.As shown in Table 2, Examples 1 to 3 containing sorbitan olivate according to the present invention, unlike Comparative Examples 1 to 3 it can be seen that sweating did not occur at a high temperature of more than 37 ℃. In addition, as shown in Table 3, it can be seen that Examples 1 to 3 according to the present invention are superior to Comparative Examples 1 to 3 in terms of feeling of adhesion, spreadability, makeup persistence, water resistance, oiliness, and the like.

이상과 같이, 본 발명에 따라 솔비탄올리베이트를 함유하는 고형 파운데이션 화장료 조성물은 온도변화에 따른 발한 현상을 거의 완벽하게 개선할 수 있으며, 동시에 밀착감, 발림성, 화장 지속성, 내수성, 유분감 등과 같은 사용감도 우수하다. 또한, 휘발성 오일을 다량 함유할 수 있게 되어 사용감을 더욱 향상시킬 수 있으며,As described above, the solid foundation cosmetic composition containing sorbitan oleate in accordance with the present invention can almost completely improve the sweating phenomenon due to temperature changes, and at the same time excellent in the feeling of use such as adhesion, application, makeup persistence, water resistance, oily feeling, etc. Do. In addition, it can contain a large amount of volatile oil can further improve the feeling,

Claims (2)

오일 및 왁스를 함유하여 이루어진 고형 파운데이션 화장료 조성물에 있어서, 조성물 총 중량을 기준으로 솔비탄올리베이트 1 내지 15중량%를 함유하는 것을 특징으로 하는 고형 파운데이션 화장료 조성물.A solid foundation cosmetic composition comprising oil and wax, wherein the solid foundation cosmetic composition comprises 1 to 15% by weight of sorbitan sulfate based on the total weight of the composition. 제1항에 있어서, 상기 오일은 조성물 총 중량을 기준으로 휘발성 실리콘 오일 1 내지 30중량%를 함유하는 것을 특징으로 하는 고형 파운데이션 화장료 조성물.The solid foundation cosmetic composition of claim 1, wherein the oil contains 1 to 30 wt% of the volatile silicone oil based on the total weight of the composition.
KR10-2003-0003408A 2003-01-17 2003-01-17 Cosmetic composition of solid foundation without sweating phenomenon KR100537267B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100537266B1 (en) * 2004-03-12 2005-12-19 주식회사 엘지생활건강 Solid cosmetic composition in the form of water-in-oil emulsion
CN109381379A (en) * 2019-01-03 2019-02-26 张春华 A kind of stick lip balm and preparation method thereof
KR20200036054A (en) * 2015-05-29 2020-04-06 로레알 Solid water in silicone composition with water release effect

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101636386B1 (en) 2013-12-04 2016-07-07 한국콜마주식회사 Cosmetics having coating layer on solid cosmetic composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100537266B1 (en) * 2004-03-12 2005-12-19 주식회사 엘지생활건강 Solid cosmetic composition in the form of water-in-oil emulsion
KR20200036054A (en) * 2015-05-29 2020-04-06 로레알 Solid water in silicone composition with water release effect
CN109381379A (en) * 2019-01-03 2019-02-26 张春华 A kind of stick lip balm and preparation method thereof

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