KR20040049035A - Method of producing polyester interlaced yarn with high-thermal- insulation and light-weight - Google Patents
Method of producing polyester interlaced yarn with high-thermal- insulation and light-weight Download PDFInfo
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- KR20040049035A KR20040049035A KR1020020076204A KR20020076204A KR20040049035A KR 20040049035 A KR20040049035 A KR 20040049035A KR 1020020076204 A KR1020020076204 A KR 1020020076204A KR 20020076204 A KR20020076204 A KR 20020076204A KR 20040049035 A KR20040049035 A KR 20040049035A
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/16—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/18—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by combining fibres, filaments, or yarns, having different shrinkage characteristics
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
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- General Chemical & Material Sciences (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
본 발명은 폴리에스테르 중공섬유와 고수축 폴리에스테르섬유를 인터레이스하여 보온성 및 경량감이 우수하고 벌키한 구조를 갖는 폴리에스테르복합공기교락사를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a polyester composite air entangled yarn having a bulky structure with excellent thermal insulation and lightness by interlacing a polyester hollow fiber and a high shrink polyester fiber.
중공사는 사내부의 중공으로 인해 보온성 및 경량성이 있고 가공후 반발탄력성 및 벌키성이 우수한 소재로써 경량감이 있고 부드러운 직물을 제조할 수 있는 소재로 추천되고 있는데 상기 중공사를 직물화하는 경우에는 원사상태의 중공율을 유지하는 것이 중요하다. 일반적으로 사가공, 제직준비, 제직, 염색가공을 진행하면서 중공사는 장력과 열을 받아 중공이 깨어지거나 수축하게 된다. 일반적인 교락방법에 의한 교락시에는 높은 열히터온도 등에 의해 중공사의 중공이 소멸되는 현상이 발생하였다. 한국특허 제1998-0000013호는 교락에 의해 벌키한 혼섬사를 제공하고 투톤발현이 가능하도록 하는 데 발명의 핵심을 두어 폴리에스터 중공사와 폴리에스터 반연신사를 공기교락처리에 의해 방모조의 이수축혼섬사를 제공하고 있으나 이 또한 중공사의 중공의 형태를 유지하는 것이 어렵고 경량감이나 부드러움을 제공하는데는 부적합한 단점이 있었다.Hollow yarn is recommended as a material that can be manufactured with light weight and soft fabric as a material having excellent heat insulation and lightness due to hollow inside and excellent resilience and bulkiness after processing. It is important to maintain the hollowness of the state. In general, hollow yarns are broken or shrunk under tension and heat while processing, weaving, weaving, and dyeing. In the entanglement by the common entanglement method, the hollow fiber disappears due to high heat heater temperature. Korean Patent No. 1998-0000013 has the core of the invention to provide bulky blended yarns by entanglement and to enable two-tone expression. However, this also has a disadvantage that is difficult to maintain the hollow form of the hollow yarns and inadequate in providing lightness or softness.
또한 중공사의 중공률을 최대로 유지하고, 타사와 복합하여 벌키한 구조의 직물을 제조하기 위해서는 인터레이스법을 이용한 복합화가 적절한 방법이다. 인터레이스는 2종이상의 실을 혼섬하는 방법으로 필라멘트사를 공기교락하여 일정 매듭을 부여시키는 것으로서 일반적으로 필라멘트사는 공정중 장력에 민감하고, 사의 집속력이 낮아서 제직공정시 불량이 발생하기 쉬우므로 이런 점을 개선하기 위해 가호(풀먹임) 또는 꼬임을 부여하는 방법을 사용하였다. 그러나 가호는 제직 후에 탈호를 해야 하므로 환경 및 비용 문제가 발생한다. 또한 연사를 하여 집속력을 강화하면 비용이 많이 소요되고, 원사의 특성이 변형되어 원하는 터치 발현이 어렵다. 또한 연사나 가호시에는 열 및 장력을 많이 받기 때문에 중공사의 중공율이 감소할 수 있는 확률이 크다.In addition, in order to maintain the hollow ratio of the hollow yarn to the maximum, and to manufacture a fabric having a bulky structure by combining with other companies, the complexation using the interlace method is an appropriate method. Interlacing is a method of interlacing two or more types of yarns to impart a certain knot by air-interlacing the filament yarns. In general, filament yarns are sensitive to the tension during the process, and the yarn's low focusing force tends to cause defects during the weaving process. In order to improve the method was used to give the protection (grass feed) or kink. However, since care needs to be removed after weaving, environmental and cost problems arise. In addition, it is costly to increase the focusing power by twisting the yarn, it is difficult to express the desired touch because the characteristics of the yarn is modified. In addition, when the yarn or protection is subjected to a lot of heat and tension, the hollow ratio of the hollow yarn is likely to decrease.
따라서 본 발명은 상기한 바와 같은 선행기술의 제반 문제점을 해소하여 인터레이스방법을 이용하여 복합하면 중공율을 유지할 수 있고 제직중 필라멘트의 교락이 풀려져서 최종 직물상태에서는 본래 원사의 특성을 유지하게되어 보온성과 경량감이 우수한 폴리에스테르 복합공기교락사의 제조방법을 제공하는 것을 기술적 과제로 한다.Therefore, the present invention solves all the problems of the prior art as described above by using the interlacing method can maintain the hollowness and the filament is loosened during weaving to maintain the original yarn properties in the final fabric state It is a technical problem to provide a manufacturing method of polyester composite air entangled yarn which is excellent in lightness and lightness.
상기한 과제를 해결하기 위하여 본 발명자는 자발신장기능이 있는 반연신중공섬유와 고수축사의 수축력차이를 이용하고 기존의 공기교락을 개선하여 인터레이스시의 공기압을 조절하여 인터레이스하면 중공사의 중공의 변형율을 최대로 감소시키면서, 직물제조시 벌키한 구조를 가지며 경량감과 부드러움을 향상시킬 수 있다는 것을 알게 되어 본 발명을 완성하게 된 것이다.In order to solve the above problems, the present inventors use the contraction force difference of semi-stretched hollow fibers having high spontaneous extension and high shrinkage yarns, and improve the existing air entanglement to adjust the air pressure during interlacing to interlace the hollow strain of the hollow yarns. While reducing to the maximum, the present invention has been found to have a bulky structure in fabric manufacturing and improve the feeling of lightness and softness.
제1도는 본 발명인 공기압 3바로 인터레이스하여 제조된 폴리에스테르 복합공기교락사의 측면을 찍은 확대사진이다.Figure 1 is an enlarged photograph of the side of the polyester composite air interlock manufactured by interlacing with the bar pressure 3 bar of the present invention.
제2도는 본 발명인 공기압 3바로 인터레이스하여 제조된 폴리에스테르 복합공기교락사의 단면을 찍은 전자주사현미경 사진이다.2 is an electron scanning microscope photograph of a cross section of a polyester composite air interlock manufactured by interlacing with pneumatic pressure 3 bar of the present invention.
제3도는 본 발명인 공기압 4바로 인터레이스하여 제조된 폴리에스테르 복합공기교락사의 단면을 찍은 전자주사현미경 사진이다.3 is an electron scanning microscope photograph of a cross section of a polyester composite air interlock manufactured by interlacing with 4 bar air pressure according to the present invention.
제4도는 공기압 5바로 인터레이스하여 제조된 폴리에스테르 복합공기교락사의 단면을 찍은 전자주사현미경 사진이다.4 is an electron scanning microscope photograph of a cross section of a polyester composite air interlock manufactured by interlacing with 5 bar of air pressure.
제5도는 공기압 6바로 인터레이스하여 제조된 폴리에스테르 복합공기교락사의 단면을 찍은 전자주사현미경 사진이다.5 is an electron scanning microscope photograph of a cross section of a polyester composite air interlock manufactured by interlacing at 6 bar air pressure.
제6도는 인터레이스공정을 하지 않은 중공사의 단면을 찍은 전자주사현미경 사진이다.6 is an electron scanning microscope photograph of a cross section of a hollow yarn not subjected to an interlacing process.
그러므로 본 발명에 의하면 폴리에스테르 복합공기교락사를 제조하는 방법에 있어서, 3∼4 바의 공기압력 및 400∼450 m/분의 방출속도로 폴리에스테르 중공섬유와 고수축 폴리에스테르섬유를 인터레이스하는 것을 특징으로 하는 보온성과 경량감이 우수한 폴리에스테르 복합공기교락사의 제조방법이 제공된다.Therefore, according to the present invention, in the method for producing a polyester composite air entangled yarn, interlacing the polyester hollow fiber and the high shrink polyester fiber at an air pressure of 3-4 bar and a release rate of 400-450 m / min. Provided is a method for producing a polyester composite air entangled yarn having excellent heat retention and lightness.
이하 도면을 참고하여 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings.
본 발명에서는 폴리에스테르 중공섬유와 고수축 폴리에스테르섬유를 동시에 공급하여 인터레이스 노즐에서 분산되는 공기에 의해 매듭을 형성하여 두 사가 집속이 되어 혼섬사를 제조하게 되는 것이다. 원료섬유인 폴리에스테르 중공섬유는 완전연신한 것이나 반연신한 것을 사용하여도 무방하나 고수축 폴리에스테르섬유와의 수축력차이를 크게 발현시켜 벌키구조를 부각시키기 위해서는 반연신한 것을 사용하는 것이 바람직하다. 상기 고수축 폴리에스테르섬유는 공기에 의해 폴리에스테르 중공섬유의 길이방향과 직각의 각도에 가깝게 둘러 싸여지게 되고 도 1과 같이 매듭형상을 발현시키게 된다. 이때 제조된 교락사를 히트셋팅구역(Heat setting zone)에서 형태의 안정화를 위해 열처리를 하는 경우도 있으나 이 경우에는 중공률이 감소하는 경향이 있으므로 본 발명의 공정에서는 중공률의 유지를 위해 열고정을 행하지 않는 것이 바람직하다.In the present invention, the polyester hollow fiber and the high shrink polyester fiber are supplied at the same time to form a knot by air dispersed in the interlace nozzle, so that the two yarns are focused to produce the blended yarn. The polyester hollow fiber, which is a raw material fiber, may be either fully stretched or semi-stretched, but it is preferable to use semi-stretched in order to highlight the bulky structure by expressing a difference in shrinkage force with the high shrink polyester fiber. The high shrink polyester fiber is enclosed by air close to the angle perpendicular to the longitudinal direction of the polyester hollow fiber and to express a knot shape as shown in FIG. In this case, the manufactured interlaced yarn may be heat treated to stabilize the shape in the heat setting zone, but in this case, the hollow ratio tends to decrease, so in the process of the present invention, the heat setting is performed to maintain the hollow ratio. It is preferable not to do this.
상기 인터레이스과정에서 공기압은 3 ∼ 4 바(bar)로 하는 것이 바람직한데 3바 미만의 공기압력에서는 공기압력이 약해 사의 매듭이 형성되지 못하며 6바 이상의 공기압력에서는 사의 매듭이 너무 강해 후에 직물로 제조되었을 때 매듭이 풀리지 않아서 원하는 터치가 발현되지 않는다. 그러나 공기압력이 5 바이상이 되면 중공율이 급격히 감소하는 경향을 보이므로 중공율 유지를 위해 5 바미만으로 하는 것이 좋다. 도 6에서와 같이 인터레이스를 하지 않은 중공사는 사내부의 중공의 형태가 그대로 유지되나 도 5와 같이 6바의 공기압력으로 인터레이스하는 경우에는 사내부의 중공의 변형이 나타났다. 본 발명에서 공기압이 3바인 경우에는 도 1에서 나타나는 바와 같이 인터레이스에 의한 중공율의 변화가 적다.In the interlacing process, the air pressure is preferably 3 to 4 bar. The air pressure is less than 3 bar, so the knot of yarn is not formed. When the knot does not loosen, the desired touch is not expressed. However, when the air pressure is 5 bi phase, the hollow ratio tends to decrease rapidly, so it is better to set it to less than 5 bar to maintain the hollow ratio. As shown in FIG. 6, the hollow yarns not interlaced remain intact in the interior of the company, but when interlaced at 6 bar air pressure as shown in FIG. In the present invention, when the air pressure is 3 bar, as shown in FIG. 1, the change of the hollow ratio due to the interlace is small.
상기 방법에 의해 제조된 복합교락사는 강도 및 신도가 우수하고 제직중 필라멘트의 교락이 풀려져서 최종 직물상태에서는 본래 원사의 특성을 잘 유지하게 된다.The composite entangled yarn produced by the above method is excellent in strength and elongation, and the entanglement of the filament is released during weaving, thereby maintaining the original yarn properties well in the final fabric state.
이하 다음의 실시예에서는 폴리에스테르 복합공기교락사를 제조하는 비한정적인 예시를 하고 있다.In the following examples, non-limiting examples of preparing a polyester composite air entangled yarn are given.
[실시예 1]Example 1
폴리에스테르 POY(반연신) 중공필라멘트 75d/24f와 비수수축율이 30%인 고수축 폴리에스테르 필라멘트 40d/24f를 인터레이스기(무라다사, 일본)에 속도 400m/분, 공기압력을 3바로 조정하여 인터레이스하여 115d/48f의 폴리에스테르 복합공기교락사를 제조하였다.The polyester POY (semi-stretched) hollow filament 75d / 24f and the high shrink polyester filament 40d / 24f with a non-shrinkage ratio of 30% were interlaced with an interlacer (Murada, Japan) at a speed of 400 m / min and an air pressure of 3 bars. To prepare a 115d / 48f polyester composite air entangled yarn.
제조한 폴리에스테르 복합공기교락사의 인터레이스부분을 절단시킨 후 전자주사현미경(SEM)을 이용하여 중공사와 고수축 폴리에스테르 필라멘트의 단면을 찍고 면적계를 이용하여 중공사의 면적과 중공부분의 면적을 측정하여 식(1)에 의해중공율을 계산하였다.Cut the interlaced portion of the manufactured polyester composite air entangled yarn, take a cross section of the hollow fiber and the high shrink polyester filament using an electron scanning microscope (SEM), and measure the area of the hollow yarn and the hollow part using an area meter. The hollow ratio was calculated by (1).
* 중공율 = (중공면적/사단면적) ×100* Hollow rate = (hollow area / section area) × 100
또한, 사인장강신도시험기(지글러우스터사, 스위스)를 이용하여 복합공기교락사의 강도와 신도를 측정하였고, 건조기와 항온수조를 이용하여 건열수축율과 비수수축율을 측정하였다. 또한 복합공기교락사의 교락수를 교락수측정기(러슨-헴필사, 미국)을 이용하여 측정하였다.In addition, the strength and elongation of the composite air entanglement were measured using a sinusoidal strength tester (Ziegler Oster, Switzerland), and the dry heat shrinkage and the non-shrinkage rate were measured using a dryer and a thermostatic bath. In addition, the number of entanglements of the composite air entanglement was measured using a entanglement measuring device (Lerson-Hempil, USA).
[실시예 2∼3 및 비교예 1∼4][Examples 2-3 and Comparative Examples 1-4]
인터레이스시 공기압 및 복합공기교락사의 방출속도를 표1과 같이 변경한 것을 제외하고는 실시예 1과 동일한 방법으로 복합공기교락사를 제조하고 중공율과 강도, 신도, 건조수축율 및 비수수축율를 측정하여 표2에 나타내었다.A composite air entangled yarn was prepared in the same manner as in Example 1 except that the air pressure and the release rate of the composite air entangled interlaced were changed as shown in Table 1, and the hollow ratio, strength, elongation, dry shrinkage ratio, and non-shrinkage ratio were measured. 2 is shown.
이상 설명한 바와 같이 본 발명에 의하면 인터레이스시 공기압을 조정하여 중공섬유의 중공율의 변화를 적게 하고 중공섬유사와 고수축사의 수축력차이에 의해 직물제조시 벌키한 구조를 갖게되며 강도 및 신도가 우수하고 제직중 고수축 폴리에스테르 필라멘트의 교락이 풀려져서 최종 직물상태에서는 본래 원사의 특성을 잘 유지하는 보온성 및 경량감이 우수한 복합공기교락사를 제조할 수 있다.As described above, according to the present invention, the air pressure at the time of interlacing is adjusted to reduce the change in the hollow ratio of the hollow fiber, and the bulky structure is produced during fabric manufacturing due to the difference in contraction force of the hollow fiber yarn and the high shrink yarn. Since the entanglement of the medium shrinkage polyester filament is released, it is possible to manufacture a composite air entangled yarn having excellent heat insulation and light weight which maintains the original yarn properties well in the final fabric state.
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