KR20040044531A - 저분자량 불소화 계면활성제를 거의 함유하지 않는플루오로중합체 분산액 - Google Patents
저분자량 불소화 계면활성제를 거의 함유하지 않는플루오로중합체 분산액 Download PDFInfo
- Publication number
- KR20040044531A KR20040044531A KR10-2004-7003186A KR20047003186A KR20040044531A KR 20040044531 A KR20040044531 A KR 20040044531A KR 20047003186 A KR20047003186 A KR 20047003186A KR 20040044531 A KR20040044531 A KR 20040044531A
- Authority
- KR
- South Korea
- Prior art keywords
- dispersion
- fluoropolymer
- fluorinated
- surfactant
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 140
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 99
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 95
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 86
- 239000007787 solid Substances 0.000 claims abstract description 36
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 29
- 125000000129 anionic group Chemical group 0.000 claims abstract description 28
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 28
- 239000002245 particle Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 polytetrafluoroethylene Polymers 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 25
- 230000003827 upregulation Effects 0.000 claims description 19
- 239000000758 substrate Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 12
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000000108 ultra-filtration Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 2
- 239000003957 anion exchange resin Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920000307 polymer substrate Polymers 0.000 claims description 2
- 239000012875 nonionic emulsifier Substances 0.000 claims 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 9
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920003303 ion-exchange polymer Polymers 0.000 description 4
- 229920002312 polyamide-imide Polymers 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 3
- 239000010702 perfluoropolyether Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000004962 Polyamide-imide Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052731 fluorine Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 239000003930 superacid Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- HVXRCAWUNAOCTA-UHFFFAOYSA-N 4-(6-methylheptyl)phenol Chemical class CC(C)CCCCCC1=CC=C(O)C=C1 HVXRCAWUNAOCTA-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- FOKCKXCUQFKNLD-UHFFFAOYSA-N pent-1-enyl hypofluorite Chemical class C(CC)C=COF FOKCKXCUQFKNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 229920005548 perfluoropolymer Polymers 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920006294 polydialkylsiloxane Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920012287 polyphenylene sulfone Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 125000005497 tetraalkylphosphonium group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/16—Purification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/20—Concentration
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01203351.0 | 2001-09-05 | ||
| EP01203351 | 2001-09-05 | ||
| PCT/US2002/025114 WO2003020836A1 (en) | 2001-09-05 | 2002-08-06 | Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20040044531A true KR20040044531A (ko) | 2004-05-28 |
Family
ID=8180888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2004-7003186A Withdrawn KR20040044531A (ko) | 2001-09-05 | 2002-08-06 | 저분자량 불소화 계면활성제를 거의 함유하지 않는플루오로중합체 분산액 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1427788B1 (https=) |
| JP (1) | JP4295098B2 (https=) |
| KR (1) | KR20040044531A (https=) |
| CN (1) | CN100369988C (https=) |
| BR (1) | BR0212308A (https=) |
| CA (1) | CA2458617A1 (https=) |
| PL (1) | PL207650B1 (https=) |
| RU (1) | RU2294940C2 (https=) |
| WO (1) | WO2003020836A1 (https=) |
| ZA (1) | ZA200402608B (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100982710B1 (ko) * | 2005-06-29 | 2010-09-17 | 듀폰-미쯔이 플루오로케미칼 가부시끼가이샤 | 진애 처리제 조성물 |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7045571B2 (en) | 2001-05-21 | 2006-05-16 | 3M Innovative Properties Company | Emulsion polymerization of fluorinated monomers |
| US7064170B2 (en) * | 2002-10-31 | 2006-06-20 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin |
| DE60301322T2 (de) | 2003-02-28 | 2006-06-08 | 3M Innovative Properties Co., St. Paul | Fluoropolymerdispersion enthaltend kein oder wenig fluorhaltiges Netzmittel mit niedrigem Molekulargewicht |
| BRPI0414785A (pt) * | 2003-09-25 | 2006-11-21 | Laurel Products Llc | dispersões de politetrafluoroetileno de alta estabilidade e método de obtenção das mesmas |
| ATE502062T1 (de) * | 2003-10-24 | 2011-04-15 | 3M Innovative Properties Co | Wässrige dispersionen von polytetrafluorethylenteilchen |
| EP1533325B1 (en) | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| ITMI20032377A1 (it) * | 2003-12-04 | 2005-06-05 | Solvay Solexis Spa | Copolimeri del tfe. |
| JPWO2005056614A1 (ja) * | 2003-12-09 | 2007-07-05 | ダイキン工業株式会社 | 含フッ素重合体水性分散体及びその製造方法 |
| US7304101B2 (en) | 2004-07-19 | 2007-12-04 | 3M Innovative Properties Company | Method of purifying a dispersion of ionic fluoropolymer |
| ITMI20042554A1 (it) * | 2004-12-30 | 2005-03-30 | Solvay Solexis Spa | Procedimento per la preparazione di dispersioni di fluoropolimeri |
| ITMI20042553A1 (it) * | 2004-12-30 | 2005-03-30 | Solvay Solexis Spa | Processo per la preparazione di dispersioni di fluoropolimeri |
| ITMI20050007A1 (it) * | 2005-01-05 | 2006-07-06 | Solvay Solexis Spa | Uso di dispersioni acquose di polimeri a base di vdf nella preparazione di vernici per rivestimenti di substrati architettonici |
| ITMI20050705A1 (it) * | 2005-04-20 | 2006-10-21 | Solvay Solexis Spa | Processo per la preparazione di dispersori di fluoropolimeri |
| US7514484B2 (en) * | 2005-06-06 | 2009-04-07 | Asahi Glass Company, Limited | Aqueous dispersion of polytetrafluoroethylene and process for its production |
| US8338518B2 (en) | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| DE602006018295D1 (de) * | 2005-06-10 | 2010-12-30 | Daikin Ind Ltd | Wässrige fluorpolymerdispersion und herstellungsverfahren dafür |
| RU2391375C2 (ru) * | 2005-06-29 | 2010-06-10 | Дюпон-Мицуи Флюорокемикалз Ко., Лтд. | Композиция для связывающей пыль обработки |
| EP2597124B1 (en) * | 2005-06-29 | 2015-09-16 | Nippo Corporation | Method for dust-preventive treatment of material having dusting property |
| JP4956925B2 (ja) | 2005-07-13 | 2012-06-20 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液およびその製造方法 |
| US20080015304A1 (en) | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
| WO2007026822A1 (ja) * | 2005-09-01 | 2007-03-08 | Daikin Industries, Ltd. | フルオロポリマー水性分散液 |
| JP2009057392A (ja) * | 2005-12-28 | 2009-03-19 | Daikin Ind Ltd | フルオロポリマー水性分散液 |
| WO2007074901A1 (ja) * | 2005-12-28 | 2007-07-05 | Daikin Industries, Ltd. | フルオロポリマー水性分散液 |
| US7754795B2 (en) * | 2006-05-25 | 2010-07-13 | 3M Innovative Properties Company | Coating composition |
| US20070282044A1 (en) * | 2006-05-31 | 2007-12-06 | Robert John Cavanaugh | Concentrated fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents |
| US7666928B2 (en) * | 2006-05-31 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Staged addition of non-fluorinated anionic surfactant to reduced fluorosurfactant fluoropolymer dispersion |
| US20090278092A1 (en) * | 2006-06-29 | 2009-11-12 | Daikin Industries, Ltd. | Aqueous fluororesin dispersion and method for producing the same |
| WO2008062653A1 (en) | 2006-11-24 | 2008-05-29 | Asahi Glass Company, Limited | Method for producing aqueous fluorine-containing polymer dispersion with reduced fluorine-containing emulsifier content |
| EP2145916B1 (en) * | 2008-07-17 | 2013-06-19 | W.L.Gore & Associates Gmbh | Substrate coating comprising a complex of an ionic fluoropolymer and surface charged nanoparticles |
| RU2401849C1 (ru) * | 2009-03-24 | 2010-10-20 | Открытое акционерное общество "Белкард" г. Гродно | Состав композиционного материала для триботехнических покрытий |
| RU2401855C1 (ru) * | 2009-03-27 | 2010-10-20 | Открытое акционерное общество "Белкард", г. Гродно | Композиционный триботехнический материал |
| RU2522749C2 (ru) | 2009-07-31 | 2014-07-20 | Зм Инновейтив Пропертиз Компани | Соединения фторполимера, содержащие многоатомные соединения, и способы из производства |
| RU2012120435A (ru) * | 2009-10-16 | 2013-11-27 | Асахи Гласс Компани, Лимитед | Способ получения водной политетрафторэтиленовой дисперсии для процесса коагуляции и водная политетрафторэтиленовая дисперсия для процесса коагуляции |
| EP2409998B1 (en) | 2010-07-23 | 2015-11-25 | 3M Innovative Properties Company | High melting PTFE polymers suitable for melt-processing into shaped articles |
| US9364859B2 (en) * | 2011-07-28 | 2016-06-14 | Kimberly-Clark Worldwide, Inc. | Superhydrophobic surfaces |
| JP5415496B2 (ja) * | 2011-08-16 | 2014-02-12 | 株式会社Ｎｉｐｐｏ | 塵埃抑制処理方法 |
| JP5421331B2 (ja) * | 2011-08-16 | 2014-02-19 | 株式会社Ｎｉｐｐｏ | 塵埃抑制処理方法 |
| JP2012077312A (ja) * | 2012-01-11 | 2012-04-19 | Du Pont Mitsui Fluorochem Co Ltd | 塵埃処理剤組成物 |
| EP2902424B1 (en) | 2014-01-31 | 2020-04-08 | 3M Innovative Properties Company | Tetrafluoroethene polymer dispersions stabilized with aliphatic non-ionic surfactants |
| EP3103836A1 (en) | 2015-06-12 | 2016-12-14 | 3M Innovative Properties Company | Fluoropolymer with improved transparency |
| EP3284762A1 (en) | 2016-08-17 | 2018-02-21 | 3M Innovative Properties Company | Fluoropolymers comprising tetrafluoroethene and one or more perfluorinated alkyl allyl ether comonomers |
| KR102719413B1 (ko) * | 2017-03-17 | 2024-10-21 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로중합체의 제조 방법 |
| WO2018229659A1 (en) | 2017-06-13 | 2018-12-20 | 3M Innovative Properties Company | Modified polytetrafluoroethylene and aqueous dispersion containing the same |
| DE202017003084U1 (de) | 2017-06-13 | 2017-09-19 | 3M Innovative Properties Company | Fluorpolymerdispersion |
| CN107353724A (zh) * | 2017-07-19 | 2017-11-17 | 日氟荣高分子材料(上海)有限公司 | 一种含氟超疏水涂料及其制备方法和用途 |
| US11634514B2 (en) | 2018-02-08 | 2023-04-25 | Daikin Industries. Ltd. | Method for manufacturing fluoropolymer, surfactant for polymerization, use for surfactant, and composition |
| EP3527634A1 (en) | 2018-02-15 | 2019-08-21 | 3M Innovative Properties Company | Fluoropolymers and fluoropolymer dispersions |
| JP6974784B2 (ja) | 2018-03-01 | 2021-12-01 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| US12583947B2 (en) | 2018-03-07 | 2026-03-24 | Daikin Industries, Ltd. | Method for producing fluoropolymer |
| CN113366034B (zh) | 2019-02-01 | 2022-11-11 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| EP3922435A4 (en) | 2019-02-07 | 2022-11-02 | Daikin Industries, Ltd. | Composition, stretched body and method of manufacturing thereof |
| WO2020213691A1 (ja) | 2019-04-16 | 2020-10-22 | ダイキン工業株式会社 | フルオロポリマー粉末の製造方法 |
| WO2020218618A1 (ja) * | 2019-04-26 | 2020-10-29 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法 |
| EP4006063A4 (en) | 2019-07-23 | 2023-10-25 | Daikin Industries, Ltd. | METHOD FOR PRODUCING A FLUROPOLYMER, POLYTETRAFLUORETHYLENE COMPOSITION AND POLYTETRAFLUORETHYLENE POWDER |
| CN114341209A (zh) | 2019-09-05 | 2022-04-12 | 大金工业株式会社 | 聚四氟乙烯水性分散液 |
| CN114269840A (zh) | 2019-09-05 | 2022-04-01 | 大金工业株式会社 | 组合物及其制造方法 |
| EP4039716A4 (en) | 2019-10-03 | 2023-10-25 | Daikin Industries, Ltd. | Polytetrafluoroethylene and method for producing same |
| JP7586090B2 (ja) * | 2019-10-29 | 2024-11-19 | Ａｇｃ株式会社 | ポリテトラフルオロエチレン水性分散液の製造方法 |
| EP4063405A4 (en) | 2019-11-19 | 2024-01-10 | Daikin Industries, Ltd. | PROCESS FOR PRODUCING POLYTETRAFLUOROETHYLENE |
| JP7311825B2 (ja) | 2020-09-07 | 2023-07-20 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレン水性分散液 |
| WO2022107894A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
| JP7810166B2 (ja) * | 2021-02-24 | 2026-02-03 | Ａｇｃ株式会社 | ポリテトラフルオロエチレン水性分散液の製造方法 |
| JP7644392B2 (ja) * | 2021-03-10 | 2025-03-12 | ダイキン工業株式会社 | フルオロポリマー水性分散液の製造方法 |
| CN114381013B (zh) * | 2022-01-30 | 2023-11-07 | 熵能创新材料(珠海)有限公司 | 一种含氟聚合物的浓缩水性分散体及其制备方法和应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2908001C2 (de) * | 1979-03-01 | 1981-02-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung konzentrierter Dispersionen von Fluorpolymeren |
| US4353950A (en) * | 1979-07-06 | 1982-10-12 | E. I. Du Pont De Nemours And Company | Stain-resistant cookware multi-layer coating system comprising pigments and a transluscent outer layer |
| US4425448A (en) * | 1982-05-20 | 1984-01-10 | E. I. Du Pont De Nemours & Co. | Polytetrafluoroethylene resin with degradation retarder |
| US5272186A (en) * | 1992-05-01 | 1993-12-21 | E. I. Du Pont De Nemours And Company | Concentration of fluoropolymer dispersions using acrylic polymers of high acid content |
| DE19857111A1 (de) * | 1998-12-11 | 2000-06-15 | Dyneon Gmbh | Wäßrige Dispersionen von Fluorpolymeren |
-
2002
- 2002-08-06 KR KR10-2004-7003186A patent/KR20040044531A/ko not_active Withdrawn
- 2002-08-06 CA CA002458617A patent/CA2458617A1/en not_active Abandoned
- 2002-08-06 WO PCT/US2002/025114 patent/WO2003020836A1/en not_active Ceased
- 2002-08-06 JP JP2003525098A patent/JP4295098B2/ja not_active Expired - Fee Related
- 2002-08-06 EP EP02753439.5A patent/EP1427788B1/en not_active Expired - Lifetime
- 2002-08-06 PL PL367296A patent/PL207650B1/pl unknown
- 2002-08-06 RU RU2004105259/04A patent/RU2294940C2/ru not_active IP Right Cessation
- 2002-08-06 BR BR0212308-8A patent/BR0212308A/pt not_active IP Right Cessation
- 2002-08-06 CN CNB028173287A patent/CN100369988C/zh not_active Expired - Lifetime
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2004
- 2004-04-01 ZA ZA200402608A patent/ZA200402608B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100982710B1 (ko) * | 2005-06-29 | 2010-09-17 | 듀폰-미쯔이 플루오로케미칼 가부시끼가이샤 | 진애 처리제 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0212308A (pt) | 2004-10-13 |
| PL207650B1 (pl) | 2011-01-31 |
| PL367296A1 (en) | 2005-02-21 |
| CA2458617A1 (en) | 2003-03-13 |
| CN100369988C (zh) | 2008-02-20 |
| JP2005501956A (ja) | 2005-01-20 |
| RU2294940C2 (ru) | 2007-03-10 |
| ZA200402608B (en) | 2005-05-13 |
| EP1427788A1 (en) | 2004-06-16 |
| CN1551909A (zh) | 2004-12-01 |
| RU2004105259A (ru) | 2005-06-27 |
| EP1427788B1 (en) | 2014-05-21 |
| WO2003020836A1 (en) | 2003-03-13 |
| JP4295098B2 (ja) | 2009-07-15 |
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