KR20030082943A - 광-유도된 친수성 제품 및 그의 제조방법 - Google Patents
광-유도된 친수성 제품 및 그의 제조방법 Download PDFInfo
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- KR20030082943A KR20030082943A KR10-2003-7011344A KR20037011344A KR20030082943A KR 20030082943 A KR20030082943 A KR 20030082943A KR 20037011344 A KR20037011344 A KR 20037011344A KR 20030082943 A KR20030082943 A KR 20030082943A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
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- C—CHEMISTRY; METALLURGY
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
- C03C17/256—Coating containing TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/54—Apparatus specially adapted for continuous coating
- C23C16/545—Apparatus specially adapted for continuous coating for coating elongated substrates
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/75—Hydrophilic and oleophilic coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
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- C—CHEMISTRY; METALLURGY
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
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- C03C2218/154—Deposition methods from the vapour phase by sputtering
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- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
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- Y10T428/00—Stock material or miscellaneous articles
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- Mechanical Engineering (AREA)
- Surface Treatment Of Glass (AREA)
- Catalysts (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
Description
시험 | 시험 조건 설명 | 필름 저하 | 접촉각 |
클리브랜드 응축 시험 | 70일; 100% RH; 60℃(140°F) | 없음 | 변화없음 |
황산 | 30분; 10 N 황산; 52℃(125°F) | 없음 | 변화없음 |
시트르산 | 15분; 10% 시트르산; 26℃(79°F) | 없음 | 변화없음 |
수산화암모늄 | 1분; 4% 수산화암모늄; 23℃(74°F) | 없음 | 변화없음 |
탄소-아크 내후성 시험기(weather-o-meter) | 1000시간; 7 주기(102분 광; 18분 광; 물 분무) | 없음 | 변화없음 |
가속화된 기상 주기 시험 | ASTM E-773(5주) | 없음 | 변화없음 |
Claims (53)
- 하나 이상의 표면을 갖는 기판; 및상기 하나 이상의 표면의 적어도 일부 상에 침착되어 있는 광-유도된 친수성 코팅층을 포함하는 제품으로서,상기 광-유도된 친수성 코팅층의 외부 표면이 2㎚ 이하의 평균 제곱근(root mean square, RMS) 조도를 갖고,상기 광-유도된 친수성 코팅층이 화학적 증착, 마그네트론 스퍼터링(sputtering)된 진공 침착 및 분무 열분해법에 의해 침착되는 제품.
- 제 1 항에 있어서,24 W/㎡에서 60분간 UVA340 방사선에 코팅층을 노출시킨 후 제품 위에서의 수적의 접촉각이 15° 미만인 제품.
- 제 1 항에 있어서,24 W/㎡에서 60분간 UVA340 방사선에 코팅층을 노출시킨 후 제품 위에서의 수적의 접촉각이 10° 미만인 제품.
- 제 1 항에 있어서,24 W/㎡에서 60분간 UVA340 방사선에 코팅층을 노출시킨 후 제품 위에서의 수적의접촉각이 5° 미만인 제품.
- 제 1 항에 있어서,제품 위에서의 수적의 접촉각이 1° 이하인 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 500Å 이하의 두께를 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 400Å 이하의 두께를 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 300Å 이하의 두께를 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 200Å 이하의 두께를 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 50 내지 500Å 범위의 두께를 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이, 산화티타늄, 산화규소, 산화알루미늄, 산화철, 산화은, 산화구리, 산화텅스텐, 아연/주석 합금 산화물, 아연 스타네이트, 산화몰리브덴, 산화아연, 스트론튬 티타네이트, 산화코발트, 산화크로뮴 및 그의 혼합물 또는 조합물로부터 선택된 금속 산화물 및/또는 금속 합금 산화물을 하나 이상 포함하는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 이산화티타늄을 포함하는 제품.
- 제 12 항에 있어서,이산화티타늄이 예추석, 금홍석, 판티탄석, 비결정성 및 그의 혼합물 또는 조합물로 이루어진 군으로부터 선택되는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층이 실질적으로 비다공성인 제품.
- 제 1 항에 있어서,코팅층의 외부 표면이 1㎚ 이하의 평균 제곱근 조도를 갖는 제품.
- 제 1 항에 있어서,코팅층의 외부 표면이 0.2 내지 0.7㎚ 범위의 평균 제곱근 조도를 갖는 제품.
- 제 1 항에 있어서,코팅층이 5×10-3㎝-1min-1이하의 광촉매적 활성을 갖는 제품.
- 제 1 항에 있어서,코팅층이 3×10-3㎝-1min-1이하의 광촉매적 활성을 갖는 제품.
- 제 1 항에 있어서,코팅층이 2×10-3㎝-1min-1± 2×10-3㎝-1min-1이하의 광촉매적 활성을 갖는 제품.
- 제 1 항에 있어서,15 내지 25% 범위의 가시광 반사율을 갖는 제품.
- 제 1 항에 있어서,광-유도된 친수성 코팅층과 기판 사이에 위치하는 추가의 코팅층을 하나 이상 포함하는 제품.
- 제 21 항에 있어서,추가의 코팅층이 나트륨 이온 확산 차단층, 솔라 콘트롤(solar control) 코팅층 및 무반사성 코팅층으로 이루어진 군으로부터 선택된 작용성 코팅층인 제품.
- 제 1 항 있어서,기판이 제 1 표면 및 제 2 표면을 포함하며, 상기 제 1 표면의 적어도 일부 상에 코팅층이 침착되어 있고 상기 제 2 표면이 내부에 확산된 주석을 갖는 제품.
- 제 1 항에 있어서,기판이 플로트 글래스 리본(float glass ribbon)이고 침착방법이 화학적 증착 및 분무 열분해법으로부터 선택되는 제품.
- 제 24 항에 있어서,플로트 글래스 리본이 용융 금속욕에 위치하고 침착방법이 화학적 증착인 제품.
- 제 1 항에 있어서,내부 표면 및 외부 표면을 가지며, 침착된 광-유도된 친수성 코팅층이 상기 외부 표면 상에 침착되어 있는 일체식 또는 적층식 창문 유닛인 제품.
- 제 1 항에 있어서,표면(1), 표면(2), 표면(3) 및 표면(4)를 갖는 단열 유리 유닛이고, 광-유도된 친수성 코팅층이 표면(1) 또는 표면(4) 중 하나 이상에 위치하는 제품.
- 제 27 항에 있어서,표면(2), 표면(3) 또는 표면(4) 중 하나 이상에 위치하는 작용성 코팅층을 포함하는 제품.
- 제 1 항에 있어서,자동차용 투명재인 제품.
- 제 1 항에 있어서,건축용 창유리인 제품.
- 제 1 항에 있어서,내부 표면을 갖는 자동차용 투명재이고, 코팅층이 상기 내부 표면에 침착되는 제품.
- 제 1 항에 있어서,코팅층이 200 내지 300Å 범위의 두께, 1㎚ 이하의 제곱 평균 평탄도, 및3×10-3㎝-1min-1이하의 광촉매적 활성을 갖는 이산화티타늄을 포함하는 제품.
- 제 1 항에 있어서,기판이 그의 적어도 일부 상에 침착되어 있는 작용성 코팅층을 포함하는 제품.
- 제 33 항에 있어서,작용성 코팅층이 솔라 콘트롤 코팅층인 제품.
- 제 1 항에 있어서,기판이 제 1 표면 및 제 2 표면을 포함하며, 상기 제 1 면의 적어도 일부 상에 광-유도된 친수성 코팅층이 침착되어 있고, 상기 제 2 표면의 적어도 일부 상에 작용성 코팅층이 침착되는 제품.
- 하나 이상의 표면을 갖는 플로트 글래스 리본; 및상기 하나 이상의 표면의 적어도 일부에 직접 침착되어 있는 광-유도된 친수성 코팅층을 포함하는 제품으로서,상기 광-유도된 친수성 코팅층이 용융 금속욕에서 플로트 글래스 리본에 직접 침착되는 제품.
- 하나 이상의 표면을 갖는 기판; 및상기 하나 이상의 표면의 적어도 일부 상에 직접 침착되어 있는 광-유도된 친수성 코팅층을 포함하는 제품으로서,상기 광-유도된 친수성 코팅층이 3×10-3㎝-1min-1이하의 광촉매적 활성을 갖는 제품.
- 하나 이상의 표면을 갖는 기판; 및상기 하나 이상의 표면의 적어도 일부 상에 직접 침착되어 있는 광-유도된 친수성 코팅층을 포함하는 제품으로서,상기 기판이 용융 금속욕에 위치한 플로트 글래스 리본이고,상기 광-유도된 친수성 코팅층이 500Å 이하의 두께를 갖고,상기 광-유도된 친수성 코팅층이 용융 금속욕에서 화학적 증착에 의해 하나 이상의 표면 상에 침착되는 제품.
- 하나 이상의 표면을 갖는 기판; 및상기 하나 이상의 표면의 적어도 일부 상에 직접 침착되어 있는 광-유도된 친수성 코팅층을 포함하는 제품으로서,상기 광-유도된 친수성 코팅층이 500 내지 1200℃ 범위의 온도에서 화학적 증착에 의해 침착되고,상기 광-유도된 친수성 코팅층이 500Å 이하의 두께를 갖는 제품.
- 제 1 표면 및 제 2 표면을 가지며 상기 표면 중 하나 이상에 주석이 확산되어 있는 기판을 제공하는 단계;코팅 장치로부터의 금속 산화물 전구체를 화학적 증착, 분무 열분해법, 및 마그네트론 스퍼터링된 진공 침착법으로부터 선택된 방법에 의해 하나 이상의 표면 상으로 침착시키는 단계; 및기판을 금속 산화물 전구체가 분해하기에 충분한 온도로 가열하여 2㎚ 이하의 평균 제곱근 조도를 갖는 광-유도된 친수성 코팅층을 형성하는 단계를 포함하는,기판의 적어도 일부 상에서의 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,코팅 장치가 화학적 증착 코팅기이고, 금속 산화물 전구체가 티타늄 테트라클로라이드, 티타늄 테트라이소프로폭사이드, 티타늄 테트라에톡사이드, 티타늄 테트라부톡사이드 및 그의 혼합물로부터 선택되는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,광-유도된 친수성 코팅층이 이산화티타늄을 포함하는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,광-유도된 친수성 코팅층이, 코팅층을 24 W/㎡에서 60분간 UVA340 방사선에 노출시킨 후 코팅된 기판 위에서의 수적의 접촉각이 15° 미만이 되는 두께는 갖는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,광-유도된 친수성 코팅층이 300Å 이하의 두께를 갖는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,광-유도된 친수성 코팅층이 50 내지 250Å의 두께를 갖는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,코팅 장치가 열분해 코팅기이고, 방법이 상기 열분해 코팅기로부터의 금속 산화물 전구체 현탁액을 제 1 표면으로 급송시키는 것을 포함하는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,금속 산화물 전구체가 기판의 표면으로 직접 침착되는, 광-유도된 친수성 코팅층의형성 방법.
- 제 40 항에 있어서,코팅층이 3×10-3㎝-1min-1이하의 광촉매적 활성을 갖는, 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항에 있어서,코팅층이 200 내지 300Å 범위의 두께, 0.2 내지 1.5㎚의 평균 제곱근 조도 및 3×10-3㎝-1min-1이하의 광촉매적 활성을 갖는, 광-유도된 친수성 코팅층의 형성 방법.
- 플로트 글래스 리본을 용융 금속욕에 제공하는 단계;코팅 장치로부터의 금속 산화물 전구체를 화학적 증착에 의해 상기 글래스 리본의 상부 표면으로 직접 침착시키는 단계; 및상기 글래스 리본을 금속 산화물 전구체가 분해하기에 충분한 온도로 가열하여 광-유도된 친수성 코팅층을 형성하는 단계를 포함하는,기판의 적어도 일부 상에서의 광-유도된 친수성 코팅층의 형성 방법.
- 제 50 항에 있어서,금속 산화물 전구체 물질을 침착시켜 500Å 이하의 두께를 갖는 광-유도된 친수성 코팅층을 제공하는, 광-유도된 친수성 코팅층의 형성 방법.
- 하나 이상의 표면을 갖는 기판을 제공하는 단계;CVD 코팅 장치로부터의 금속 산화물 전구체를 상기 하나 이상의 표면의 적어도 일부 상에 침착시키는 단계;상기 기판을 400 내지 1200℃ 범위의 온도로 가열하여 금속 산화물 전구체를 분해하여 광-유도된 친수성 코팅층을 형성하는 단계; 및상기 광-유도된 친수성 코팅층이 500Å 이하의 두께를 갖도록 충분한 전구체 물질을 제공하는 단계를 포함하는,기판의 적어도 일부 상에서의 광-유도된 친수성 코팅층의 형성 방법.
- 제 40 항의 방법에 의해 형성된 생성물.
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-
2002
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- 2002-02-22 EP EP02746298A patent/EP1366000A2/en not_active Withdrawn
- 2002-02-22 CN CNB028053141A patent/CN100480204C/zh not_active Expired - Fee Related
- 2002-02-22 WO PCT/US2002/005260 patent/WO2002085809A2/en active IP Right Grant
- 2002-02-22 KR KR1020037011344A patent/KR100939392B1/ko not_active IP Right Cessation
- 2002-02-22 JP JP2002583346A patent/JP2005500230A/ja active Pending
- 2002-02-22 MX MXPA03007287A patent/MXPA03007287A/es active IP Right Grant
- 2002-02-22 AU AU2002316028A patent/AU2002316028B2/en not_active Ceased
- 2002-02-22 CA CA002434560A patent/CA2434560C/en not_active Expired - Fee Related
- 2002-02-26 AR ARP020100655A patent/AR032859A1/es active IP Right Grant
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2007
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Also Published As
Publication number | Publication date |
---|---|
US7960043B2 (en) | 2011-06-14 |
KR100939392B1 (ko) | 2010-01-28 |
AU2002316028B2 (en) | 2005-04-21 |
EP1366000A2 (en) | 2003-12-03 |
AR032859A1 (es) | 2003-11-26 |
JP6247141B2 (ja) | 2017-12-13 |
WO2002085809A8 (en) | 2003-04-10 |
CA2434560A1 (en) | 2002-10-31 |
US20020155299A1 (en) | 2002-10-24 |
JP2014133700A (ja) | 2014-07-24 |
US20070218265A1 (en) | 2007-09-20 |
WO2002085809A3 (en) | 2002-12-27 |
CN100480204C (zh) | 2009-04-22 |
CN1501895A (zh) | 2004-06-02 |
WO2002085809A2 (en) | 2002-10-31 |
JP2005500230A (ja) | 2005-01-06 |
MXPA03007287A (es) | 2003-12-04 |
CA2434560C (en) | 2008-05-20 |
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