KR20030017722A - process for ceramic ware cooking ware - Google Patents
process for ceramic ware cooking ware Download PDFInfo
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- KR20030017722A KR20030017722A KR1020010050707A KR20010050707A KR20030017722A KR 20030017722 A KR20030017722 A KR 20030017722A KR 1020010050707 A KR1020010050707 A KR 1020010050707A KR 20010050707 A KR20010050707 A KR 20010050707A KR 20030017722 A KR20030017722 A KR 20030017722A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J27/00—Cooking-vessels
- A47J27/002—Construction of cooking-vessels; Methods or processes of manufacturing specially adapted for cooking-vessels
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
- A47J36/04—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay the materials being non-metallic
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00948—Uses not provided for elsewhere in C04B2111/00 for the fabrication of containers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00965—Uses not provided for elsewhere in C04B2111/00 for household applications, e.g. use of materials as cooking ware
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
Abstract
Description
본 발명은 점토,활석,백도사질로 구성된 도자기조리용기의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a ceramic cooking container composed of clay, talcum, white sand.
본 발명은 특히 백숙,전골찌게등 탕종류나,생선,육류등의 찜조리나 구이조리에 사용되는 조리용기의 제조방법에 관한 것으로 특히 열 보존도가 높아 조리시간이 단축되고 용기의 표면에 타서 엉겨붙지 않으며, 살균력이 높아 조리된 음식이 장시간 신선도를 유지 하는 도자기 조리용기의 제조방법에 관한 것이다.In particular, the present invention relates to a method of manufacturing a cooking vessel used for steaming or roasting such as steamed hot pot, hot pot, and other hot pots. Especially, the cooking time is shortened due to high heat preservation and burned on the surface of the container. The present invention relates to a method of manufacturing a porcelain cooker that does not become entangled and has high sterilizing power, so that the cooked food maintains freshness for a long time.
도자기,세라믹,유리등으로 된 조리용기는 일반화되어 있다.Cooking containers made of ceramics, ceramics and glass are common.
그러나 종래 도자기 조리용기는 일반적인 내열토를 조분쇄하여 조성하였기 때문에 기공이 커서 기름이 이 기공을 통해 침투되어 타는 냄새가 나며 음식이 쉽게 타는 결점이 있었다.그리고 탕 종류의 음식물의 조리시에도 수분의 탈루 현상이 심해 조리용기로는 부적합하였다. 그리고 고온에 장시간 대치하거나 약간의 충격에도 쉽게 파손되는 점과 특히 색상이 미려하지 못하는 결점이 있었다.(공개특허공보 1995.4. 17)However, since the conventional ceramic cooking container was formed by coarse grinding of general heat-resistant soil, the pores were large and oil penetrated through the pores, resulting in a burning smell and food easily burned. The fugitive phenomenon was severe and unsuitable for cooking vessels. In addition, there was a drawback of being easily damaged by a long time or a slight shock at a high temperature, and in particular, the color was not beautiful. (Patent Publication April 17, 1995)
세라믹조리용기는 비교적 제조가 간단하고 견고하나 장시간 고온에 방치하면쉽게 변색되고 특히 열전도성이 높아서 음식이 용기의 벽면에 침착되어 세척이 용이하지 않으며 비위생적이다.그러므로 생선이나 육식등의 구이조리에는 사용되지 못하였다.Ceramic cooking containers are relatively simple to manufacture and robust, but are easily discolored when left at high temperatures for a long time, and especially because of their high thermal conductivity, food is deposited on the walls of the containers, making them difficult to clean and unhygienic. Therefore, they are used for grilling food such as fish or meat. It didn't work.
유리재 조리용기는 파손율이 높고 저온과 고온의 온도차이에 민감하여 쉽게 파손되거나 특히 열전도성이 높아 음식이 쉽게 타거나 구이용으로는 적합하지 않고 주부들의 취급이 까다로워 극히 제한적이었다.Glass cooking containers were easily broken due to high breakage rate and sensitive to temperature difference between low temperature and high temperature, or especially because of high thermal conductivity, which was not suitable for easy burning or roasting and was difficult for housewives.
본 발명은 상기의 문제점을 해결하고, 백숙,전골찌게,등의 탕류의 조리는 물론 찜요리,구이등의 조리등을 겸 할 수 있는 도자기조리용기를 얻고자한 것으로 본 발명은 산화알루미늄과 규소가 다량 함유된 점토에다 활석,백토사질등이 함유된 혼합토를 이용한 도자기 조리용기의 제조방법을 제공하고자 한다.The present invention is to solve the above problems, and to obtain a porcelain cooking container that can serve as cooking, such as steamed dishes, grilled, such as steamed rice, hot pot, etc. The present invention is aluminum oxide and silicon To provide a method of manufacturing a ceramic cooking vessel using a mixed clay containing a large amount of clay and talc, clay and the like.
본 발명의 도자기조리용기의 제조방법은 점토,활석,백토사질을 물과 혼합하여 여과기에서 압축하여 수분 20 - 25%정도를 탈수 시키고 진공 토련기(압축기)에 넣어 수분 함량 20 - 30% 정도의 내열 혼합토를 얻는 단계와The method for producing a ceramic cooking container of the present invention is to mix the clay, talcum, white clay with water and compress it in a filter to dehydrate 20-25% of water and put it in a vacuum grinder (compressor) of 20-30% of water. Obtaining heat resistant mixed soil
냄비모양의 조리용기 형태로 가공하여 적당한 시기에 탈형하여 자연건조 한 다음 수분함량 10 - 15%정도 되는 성형품을 900 - 950°C 에서 5 내지 6시간정도 가열하여 1차소성하는 단계와Process into a pot-shaped cooking container, demold at a suitable time, dry it naturally, and then heat the molded product having a moisture content of 10-15% at 900-950 ° C for 5 to 6 hours, and then primary firing.
초벌구이 제품에 유약을 도포하는 단계Applying glaze to roasting products
유약을 도포한 1차 소성한 초벌제품을 2차 소성하는 단계등으로 이루어진다.It consists of a step of second firing the primary fired primary product coated with glaze.
본 발명에서 사용되는 점토는 산화알루미늄,산화규소가 대량 함유되어 있으며,산화칼륨,티타늄등광물질이 소량 함유되어 있다.The clay used in the present invention contains a large amount of aluminum oxide and silicon oxide, and contains a small amount of potassium oxide, titanium and the like.
본 발명의 1단계에서의 혼합토는 상기 점토40중량 %와, 활석(2 - 10㎜)30 중량 %, 백토사질 30 중량 %를 물과 혼합하여 고루 분쇄한 다음 직물지등에 부어 180분 정도 압축상태로 유지하여 20 - 25 % 정도의 수분을 탈수 시킨다음 진공 토련기로써 그릇 성형이 가능한 점성의 혼합토를 만든다. 이때 소량의 경명주사(0.0005중량 %)를 혼합한다.In the first stage of the present invention, the mixed soil is 40% by weight of clay, 30% by weight of talc (2-10 mm), 30% by weight of clay sand, mixed with water and then pulverized and then poured into fabric paper and compressed for about 180 minutes. After dehydration, water is dehydrated by 20-25%, and a viscous mixed soil is prepared by using a vacuum drill. At this time, a small amount of light injection (0.0005% by weight) is mixed.
상기의 혼합토는 산화알루미늄과 산화규소가 대량 함유되어 있으므로 소성시 활석과 백토사질과 용융산화알루미늄,산화티타늄등이 용융 결합되어 있어 소성제품에는 미세한 기공이 발생된다. 또한 산화규소와 활석, 백토사질등에 의해 용기전체는 단시간내에 가온됨과 동시에 열 보존성이 높아서 하부의 계속되는 열원 공급에도 일정한 온도이상 상승하지 않아 용기내의 생선구이 육류구이 또는 찜조리시에도 타지 않으며, 탕 종류의 음식의 조리시간이 단축되는 효과가 있다.Since the mixed soil contains a large amount of aluminum oxide and silicon oxide, fine pores are generated in the fired product because talc, white clay, molten aluminum oxide, titanium oxide, etc. are melt-bonded during firing. In addition, the entire container is warmed within a short time due to silicon oxide, talc, and clay sand, and the heat preservation is high. Therefore, it does not rise above a certain temperature even if the supply of heat source in the lower part does not rise. The cooking time of the food is shortened.
한편 소량의 경명주사는 붉은 흙으로 된 것이므로 탈취 효과와 살균력이 우수한 것으로 판명되어 용기내의 살균력을 향상시켜준다.On the other hand, a small amount of light injection is made of red soil, so the deodorizing effect and bactericidal power are proved to be excellent, thereby improving the sterilizing power in the container.
또한 색상이 밝고 음식조리시 또는 조리된 음식을 보관할 때에도 신선한 음식을 보존하는 작용효과가 있다.It is also bright in color and has the effect of preserving fresh food even when cooking or storing cooked food.
성형단계에서는 본 발명의 조리용기는 좌우에 냄비형상과 같은 손잡이가 형성되어 있는데 이러한 형틀에 혼합토를 투입한 다음 형틀을 회전시키면서 용기 내부를 깍아내는 작업으로 용기를 성형한다.In the forming step, the cooking vessel of the present invention is formed with a handle such as a pot shape on the left and right sides, and then mixing the clay into the mold and then rotating the mold to mold the container.
1차 성형된 용기는 수공으로 외부티등을 깨끗이 제거한다음 1차 초벌소성한다.The first molded container is manually removed from the outer tee and then first fired.
1차 소성 제품은 유약을 고루 도포하여 2차 소성하여 완성품을 얻는다.The primary fired product is applied by glaze evenly and fired secondly to obtain a finished product.
본 발명에서 사용되는 유약은 게르마늄,성형파(파제품을 다시 분쇄한것),황토,모래,활석,장석,석회석,약토,참나무숯등을 적당량 혼합하여 장시간 분쇄하여 미세하게 갈아 물과 혼합 한 것이므로 용기표면에 도포하여 소성하면 미세한 기공이 있는 일정두께의 윤활면이 생성된다.Glaze used in the present invention is a mixture of germanium, shaping wave (re-crushed green onion product), ocher, sand, talcum, feldspar, limestone, weak soil, oak charcoal, etc. Since it is applied to the surface of the container and fired, a lubricating surface having a certain thickness with fine pores is produced.
특히 2차 소성시(재벌소성) 고온 약 1300°C 이상의 고온에서 장시간(약10시간)소성하므로써 유약의 표면 유착상태는 최상으로 유지된다.Particularly, the surface adhesion state of the glaze is maintained best by firing for a long time (about 10 hours) at a high temperature of about 1300 ° C or more during secondary firing (chaebol firing).
그러므로 상기 유약 도포층은 음식물 특히 구이음식조리시 타지 않으며, 음식이 달라 붙지 않는다.Therefore, the glaze coating layer does not burn food, especially grilled food, food does not stick.
이상 본 발명의 실시예를 들어 상세히 설명한다.The embodiment of the present invention will be described in detail above.
1단계Stage 1
점토40중량 %,활석 30 중량 %, 백토사질 30 중량 %를 물에 혼합하여 분쇄기로써 120분 정도 분쇄하는 1차 혼합토를 얻는 단계Mixing 40% by weight of clay, 30% by weight of talcum, and 30% by weight of clay sand in water to obtain a primary mixed soil which is ground for about 120 minutes with a grinder.
2단계Tier 2
1단계에서 얻은 1차 혼합토를 구멍이 있는 직물지로 감싸 180분정도 가압상태에서 방치하여 수분 20 - 25 %정도를 탈수 시키고 이것을 진공토련기(압축기)에서 수분 함량 20 - 30 % 되게 탈수시켜 2차 혼합토를 얻는 단계The primary mixed soil obtained in the first step was wrapped in fabric paper with holes and left for about 180 minutes under pressure to dehydrate 20-25% of water, which was then dehydrated to 20-30% of moisture in a vacuum drill (compressor). Step to get mixed soil
3단계Tier 3
2단계에서 얻은 2차 혼합토를 형틀에 투입하여 용기형태로 가공하는 1차 성형단계The first molding step in which the second mixed soil obtained in step 2 is put into the mold and processed into a container form
4단계4 steps
3단계에서 얻은 1차성형제품을 1시간 후 탈형하여 건조시킨후 티등을 제거하는 2차성형단계After 1 hour, the primary molding product obtained in step 3 is demolded and dried, and then the secondary molding step is used to remove the tee.
5단계5 steps
4단계에서 얻은 2차성형제품을 2 - 3일정도 자연건조하여 수분함량 10 -15 %되도록하여 900 - 950°C 온도에서 약 5 - 6시간 1차소성하는 1차소성단계The primary firing step of first firing at 900-950 ° C for 5-6 hours at 900-950 ° C temperature by drying the secondary molded product obtained in step 4 for 2-3 days in a natural way to make water content 10 -15%
6단계6 steps
5단계에서 얻은 1차소성제품은 티를 제거한 후 유약을 도포하는 단계The primary firing product obtained in step 5 is to apply a glaze after removing the tee
7단계7 steps
6단계에서 얻은 유약을 도포한 1차소성제품을 약 1200 - 1300°C 온도하에서 약 10시간 정도 소성하는 2차소성단계로 이루어 지는 것을 특징으로 한다.The primary firing product coated with the glaze obtained in step 6 is characterized in that it consists of a secondary firing step of firing for about 10 hours at a temperature of about 1200-1300 ° C.
상기 점토는 물을 제외한 산화알루미늄27중량 %,산화규소 58중량 %,산화칼륨 과 산화제2철이 각각 4중량 %이 함유되고 그외 산화구리,산화아연,등이 약간 함유되어 있다. 그러므로 활석과 백토사질등과 혼합되어 미세한 분쇄단계를 거치므로 소성되었을 때에는 용기의 내부에는 미세한 기공이 발생되며 이 기공은 점토에 포함된 산화 알루미늄과 기타 금속성분(비철금속포함)과 활석,그리고 백토사질(유리성분과 광물질이 포함)의 성질과 잘 혼합되어 있으므로 상호 균일하게 혼합 용융되어 미세한 기공이 균일하게 분포생성된다.The clay contains 27% by weight of aluminum oxide, 58% by weight of silicon oxide, 4% by weight of potassium oxide and ferric oxide, and a little other amount of copper oxide, zinc oxide, and the like. Therefore, micropore is generated inside the container when it is fired because it is mixed with talc and clay sand, and the pores are made of aluminum oxide and other metal components (including non-ferrous metal), talc, and clay sand. It is well mixed with the properties of (including glass components and minerals), so it is mixed and melted uniformly with each other to produce evenly distributed fine pores.
또한 유약은 게르마늄(Ge - 32)20중량 %,성형파 10중량 %, 황토 10중량 %, 모래 10 중량 %, 활석 15중량 %,장석 5 중량 %,석회석 5중량 %,약토 20중량 %,참나무숯 5중량 %로 비율로 구성되어 있으므로 1차소성 (900 - 950°C)과 2차소성(1200 - 1300°C)단계를 거치는 과정에서 용기의 표면에 고루 도포됨과 동시에 기공을 통해 약 2㎜정도 침투되어 소결되므로 용기의 표면은 윤활면작용을 하게된다.Also glaze is 20% germanium (Ge-32), 10% by weight shaping wave, 10% by weight ocher, 10% by weight sand, 15% by weight talc, 5% by weight feldspar, 5% by weight limestone, 20% by weight clay, oak Since it is composed of 5% by weight of charcoal, it is applied evenly to the surface of the container during the first step (900-950 ° C) and the second step (1200-1300 ° C) and at the same time, about 2mm through pores. As it penetrates and sinters to a degree, the surface of the container acts as a lubricating surface.
이상의 단계로 이루어진 본 발명인 도자기 조리용기의 제조방법에서 얻은 조리용기는 하부에서 일정한 열을 계속하여 가열하여도 조리용기전체는 기공을 통한 방열효과에 의해 일정온도 이상 가온되지 않으므로 탕이나 찜조리 구이조리에도 타지 않고 엉겨 붙지 않으며,가열된 용기는 그 온도가 오래 유지되므로 탕음식인 경우 쉽게 식지 않으며, 특히 경명주사가 함유되어 있으므로 외관이 미려하고 신선도가 높아 음식이 잘 상하지 않는 잇점이 있다.The cooking vessel obtained by the method of manufacturing the porcelain cooking vessel of the present invention consisting of the above steps is heated evenly at a lower portion of the cooking vessel, so that the whole cooking vessel is not heated above a certain temperature by the heat dissipation effect through the pores. Edo is not burnt or tangled, and heated containers do not cool easily in hot foods because their temperature is maintained for a long time. Especially, because they contain light injections, they are beautiful in appearance and have high freshness.
이상의 단계로 이루어진 본 발명의 도자기용기의 제조방법에서 얻은 본발명의 도자기조리용기는 탕이나 찜등 국물이 있는 조리시에는 용기가 단시간내로 가온되고 또 그 온도가 장시간 보존되므로 조리시간이 단축되고 국물등이 쉽게 식지 않으며,생선이나 육류의 구이조리시에는 용기의 표면온도가 일정온도 이상 상승하지 않으므로 타서 붙거나 용기에 엉겨붙지 않으며,생선이나 육류의 내부까지 고루 익는 효과가 있다.Pottery cooking vessel of the present invention obtained in the manufacturing method of the porcelain container of the present invention consisting of the above steps, when cooking with soup, such as hot water or steaming, the container is warmed in a short time and the temperature is stored for a long time, so the cooking time is shortened and the soup, etc. This does not cool easily, and when grilling fish or meat, the surface temperature of the container does not rise above a certain temperature, so it does not burn or stick to the container, and it evenly cooks the inside of the fish or meat.
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