KR20020088720A - Artificial stone manufacturing method - Google Patents

Artificial stone manufacturing method Download PDF

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Publication number
KR20020088720A
KR20020088720A KR1020010027583A KR20010027583A KR20020088720A KR 20020088720 A KR20020088720 A KR 20020088720A KR 1020010027583 A KR1020010027583 A KR 1020010027583A KR 20010027583 A KR20010027583 A KR 20010027583A KR 20020088720 A KR20020088720 A KR 20020088720A
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South Korea
Prior art keywords
hot air
artificial stone
hot
reflected
semi
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KR1020010027583A
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Korean (ko)
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유병욱
한동만
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주식회사 에버딜
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Priority to KR1020010027583A priority Critical patent/KR20020088720A/en
Publication of KR20020088720A publication Critical patent/KR20020088720A/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/54Pigments; Dyes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PURPOSE: Provided is a manufacturing method of artificial stones with light weight, easy coloration and strength equivalent to natural stones by using white cement, volcanic rocks as main materials. CONSTITUTION: The artificial stones used as exterior materials are manufactured by the following steps of: mixing 35-45wt.% of white cement, 45-55wt.% of volcanic rocks for light weight, and 5-10wt.% of waste construction materials(waste concrete, stone powder, etc.); adding 2-5wt.% of additives such as Co, Fe2O3, acryl, waterproof agent, water reducing agent and pigment; vibrational forming; curing and drying for 12hrs, with hot blast, repeating low temperature cycle(20deg.C) and high temperature cycle(45deg.C) every six hours in turns, wherein the hot blast is supplied to artificial stone compacts by repeating the process of spraying high-pressured hot blast over the compacts and re-spraying the reflected hot blast from the compacts; glazing and polishing for surface treatment.

Description

인조석 제조 방법{Artificial stone manufacturing method}Artificial stone manufacturing method

본 발명은 백시멘트, 화산석, 건축폐기물을 주원료로하여 경량화되고 착색이 용이한 인조석을 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a lightweight, easy to color artificial stone using white cement, volcanic stone, building waste as a main raw material.

건축물 외장용으로 석재가 사용되고 있다. 화강석이나 대리석 등의 자연석 외장재는 건물의 미감을 증대시키는 효과 때문에 최근에 많이 사용되고 있으나, 문제는 외장용 석재가 매우 무겁고 비싸다는 것이다. 무겁기 때문에 설치 시공이 곤란하고 중장비 사용비용이 추가되며 건물의 하중이 크게 커진다. 또한, 자연석은 고가이기 때문에 건축물 건조비용이 커지며 자연석 채취에 제한을 받게 된다.Stone is used for exterior of buildings. Natural stone exterior materials such as granite and marble have been used a lot recently because of the effect of increasing the aesthetics of the building, the problem is that the exterior stone is very heavy and expensive. The heavy construction makes installation difficult, adds heavy equipment cost and greatly increases the load on the building. In addition, since natural stone is expensive, building construction costs are increased and natural stone collection is restricted.

이러한 자연석의 단점을 극복하기 위해 시멘트 벽돌 등의 외부에 자연석과 유사한 칠을 하거나 표면 가공을 하는 방법이 시도되었으나, 이러한 외장재는 자연석과 비교할 때 그 미감이 매우 떨어지고 강도가 석재에 비해서 낮은 단점이 있다.In order to overcome the disadvantages of natural stone, a method of painting or surface processing similar to natural stone on the exterior of cement brick, etc. has been attempted. However, the exterior material has a weakness compared to natural stone and has a weak strength compared to natural stone. .

본 발명은 자연석과 동일한 질감을 가지면서도 사람이 쉽게 들 수 있을 정도로 경량화되고 석재와 유사한 강도를 가지며 착색이 용이하여 미감이 향상된 인조석을 제조하는 방법을 제공한다. 또한, 본 발명은 인조석 제조공정 중의 양생 및 건조 단계에 사용되는 열풍건조 장치를 제공한다.The present invention provides a method of manufacturing artificial stone having the same texture as natural stone, yet light enough to be easily lifted by humans, having a strength similar to that of stone, and easily coloring to improve aesthetics. The present invention also provides a hot air drying apparatus used in the curing and drying step of the artificial stone manufacturing process.

상기 목적을 이루기 위해 본 발명에 따른 인조석 제조방법은, 백시멘트, 화산석, 건축폐기물을 혼합하는 단계, 상기 혼합재료에 코발트, 산화철, 티탄, 액체 아크릴, 방수제, 감수제를 첨가하는 단계, 첨가제를 첨가한 혼합원료를 혼합한 후 금형에 투입하여 성형하는 단계, 열풍에 의해 양생 및 건조하는 단계, 시유기를 써서 표면처리를 하는 단계로 구성된다.In order to achieve the above object, the artificial stone manufacturing method according to the present invention includes mixing white cement, volcanic stone, and construction waste, adding cobalt, iron oxide, titanium, liquid acrylic, waterproofing agent, and water reducing agent to the mixed material, and adding an additive. After mixing a mixed raw material, it is composed of the steps of molding into a mold, curing and drying by hot air, and surface treatment by using a seasoning machine.

또한, 본 발명에 따른 열풍건조 장치는 성형된 인조석 반제품을 수용하는 건조실, 건조실의 일측 상부에 설치되어 인조석 반제품에 고압으로 열풍을 분사하는 제1 열풍분사구, 제1열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제2열풍분사구, 제2열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제n열풍분사구, 제n 열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 배출하는 열풍배출구로 구성된다.In addition, the hot air drying apparatus according to the present invention is a drying chamber accommodating the molded artificial stone semi-finished product is installed on one side of the drying chamber, the first hot air jet nozzle for spraying hot air at high pressure to the artificial stone semi-finished product, the hot air sprayed from the first hot air jet nozzle artificial stone A second hot air jet sphere that absorbs and re-injects the reflected hot air when reflected from the semi-finished product, the n hot air jet sphere which absorbs and re-injects the reflected hot air when the hot air jetted from the semi-finished semifinished product is reflected from the artificial stone product, n When the hot air injected from the hot air jet port is reflected from the artificial stone semi-finished product, the hot air discharge port is configured to absorb and discharge the reflected hot air.

도1은 본 발명의 공정 순서도.1 is a process flow chart of the present invention.

도2는 본 발명에 사용되는 열풍건조실의 개념도.2 is a conceptual diagram of a hot air drying room used in the present invention.

<도면부호의 설명><Description of Drawing>

건조실(11); 성형된 인조석 반제품(13); 제1열풍분사구(15); 제2열풍분사구(21); 제n열풍분사구(21'); 열풍배출구(19"); 흡입구(19, 19'); 덕트(17, 17', 17")Drying chamber 11; Molded artificial stone semi-finished product 13; A first hot air jet port 15; A second hot air jet port 21; N-th hot-air jet nozzle 21 '; Hot air outlet 19 "; Inlet 19, 19 '; Ducts 17, 17', 17"

이하, 본 발명에 따른 인조석 제조방법에 대해 도면을 참조하여 설명한다.Hereinafter, an artificial stone manufacturing method according to the present invention will be described with reference to the drawings.

도1은 본 발명의 제조방법의 흐름도이다. 그 순서는 다음과 같이 구성된다.1 is a flowchart of a manufacturing method of the present invention. The order is organized as follows.

(1) 백시멘트, 화산석, 건축폐기물(이하, "혼합원료")를 각각 35~45중량%, 45~55중량%, 5~10중량%의 비율로 혼합하는 단계[101]. 상기 혼합원료 중에서 화산석은 경량화를 위해서 투입하는 것으로서 화산석에 형성되어 있는 미세한 공극은 본 발명에 따른 인조석에 안료를 혼합할 때 착색력을 증강시킨다. 건축폐기물로는 콘크리트 폐자재, 석분 등을 사용할 수 있다.(1) mixing white cement, volcanic stone, and construction waste (hereinafter, "mixed raw materials") at a ratio of 35 to 45% by weight, 45 to 55% by weight, and 5 to 10% by weight, respectively [101]. As the volcanic stone is added to reduce the weight of the mixed raw material, the fine pores formed in the volcanic stone enhance the coloring power when mixing the pigment into the artificial stone according to the present invention. As construction waste, concrete waste materials, stone powder, etc. may be used.

(2) 상기 혼합재료에 코발트, 산화철, 티탄, 액체 아크릴, 방수제, 감수제(이하, "첨가제")를 2~5중량% 첨가하는 단계[103]. 첨가제에는 착색용 안료가 포함될 수 있다. 안료를 혼합하면 안료가 화산석의 공극 내에 흡수되기 때문에 용이하고 영구적으로 착색할 수가 있어서, 최종 외장재로서의 본 발명에 따른 인조석의 가치를 극대화시킬 수 있다. 코발트, 산화철, 티탄은 석재에 함유되어 있는 물질들로서 본 발명에 따른 인조석의 강도 및 질감을 자연석과 유사하게 만들기 위한 첨가제이다. 방수제로는 레미타스(상표명임)를 사용할 수 있다.(2) adding 2 to 5% by weight of cobalt, iron oxide, titanium, liquid acrylic, waterproofing agent, water reducing agent (hereinafter, "additive") to the mixed material [103]. The additive may include coloring pigment. Mixing the pigment allows the pigment to be easily and permanently colored since the pigment is absorbed in the voids of the volcanic stone, thereby maximizing the value of the artificial stone according to the present invention as the final exterior material. Cobalt, iron oxide, and titanium are materials contained in the stone and are additives for making the strength and texture of the artificial stone according to the present invention similar to natural stone. As a waterproofing agent, Remitas (trade name) can be used.

(3) 첨가제를 첨가한 혼합원료를 고속믹서로 혼합한 후[105] 금형에 투입하여 성형하는 단계[107]. 성형은 PVC몰드에서 고속 진동 성형기에 의해 이루어질 수 있다.(3) mixing the mixed raw materials to which the additive is added with a high speed mixer [105], and then molding the mixed raw materials into a mold [107]. Molding can be done by a high speed vibration molding machine in the PVC mold.

(4) 열풍에 의해 양생 및 건조하는 단계[109]. 본 열풍건조 단계에서는, 열풍건조실에 성형된 인조석 반제품을 넣고 열풍을 공급하면서 20℃의 저온사이클과 45℃의 고온사이클을 6시간씩 교대로 반복하여 12시간 동안 양생 및 건조한다. 열풍공급은 성형된 인조석 반제품에 고압열풍을 분사하고 인조석 반제품에서 반사된 열풍을 받아서 재분사하는 것을 반복하여 이루어진다. 열풍공급에 대한 개념을 도2에 나타내었다. 도2는 본 양생 및 건조 단계가 이루어지는 열풍건조실의 개념도이다.(4) curing and drying by hot air [109]. In the hot-air drying step, the artificial stone semi-finished product is put into a hot-air drying chamber, and hot air is repeatedly cured and dried for 12 hours by alternately repeating the low temperature cycle of 20 ° C. and the high temperature cycle of 45 ° C. for 6 hours. Hot air supply is repeated by injecting high pressure hot air into the molded artificial semi-finished product and receiving and re-injecting the hot air reflected from the artificial artificial semi-finished product. The concept of hot air supply is shown in FIG. 2 is a conceptual diagram of a hot air drying chamber in which the present curing and drying steps are performed.

열풍건조실은, 성형된 인조석 반제품(13)을 수용하는 건조실(11); 건조실(11)의 일측 상부에 설치되어 인조석 반제품(13)에 고압으로 열풍을 분사하는 제1열풍분사구(15); 제1열풍분사구(15)에서 분사된 열풍이 인조석 반제품(13)에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제2열풍분사구(21); 제2열풍분사구(21)에서 분사된 열풍이 인조석 반제품(13)에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제n열풍분사구(21'); 제n열풍분사구(21')에서 분사된 열풍이 인조석 반제품(13)에서 반사되면, 반사된 열풍을 흡수하여 건조실 밖으로 배출하는 열풍배출구(19")로 구성된다. 제2 및 n열풍분사구(21, 21')는 인조석 반제품(13)에서 반사된 열풍을 흡입하는 흡입구(19, 19')와 흡입된 열풍이 유도되는 덕트(17, 17')를 포함한다.The hot air drying chamber includes a drying chamber 11 for receiving the molded artificial stone semi-finished product 13; A first hot air spraying port 15 installed at an upper portion of one side of the drying chamber 11 to spray hot air at a high pressure to the artificial stone semi-finished product 13; A second hot air jet port 21 which absorbs and re-injects the reflected hot air when the hot air jetted from the first hot air jet port 15 is reflected from the artificial stone semi-finished product 13; An n-th hot-air jet nozzle 21 'for absorbing and re-injecting the reflected hot air when the hot air jetted from the second hot-air jet nozzle 21 is reflected from the artificial stone semi-finished product 13; When the hot air jetted from the n-th hot-air jet nozzle 21 'is reflected from the artificial stone semi-finished product 13, the hot air discharge port 19 "absorbs the reflected hot air and discharges it out of the drying chamber. The second and n-hot air jet nozzles 21 , 21 'includes suction inlets 19, 19' for sucking hot air reflected from the artificial stone semifinished product 13 and ducts 17, 17 'for sucking hot air.

(5) 시유기를 써서 표면처리를 하여[111], 포장.출하하는 단계[113]. 시유기로는 표면처리, 광택 등의 마무리 작업을 한다.(5) Surface treatment using a seeder [111], packaging and shipping step [113]. As a seasoning machine, it finishes the surface treatment and gloss.

본 발명에 따르면 경량화된 인조석재를 생산할 수 있는데, 본 발명에 의해 제조된 인조석은 질감, 강도가 자연석과 거의 동일하면서 구성원료 중 하나인 화산석의 공극에 착색안료가 들어가면서 영구적으로 착색되어 외장재로서의 가치를 증대시키는 역할을 한다.According to the present invention, it is possible to produce a lightweight artificial stone, the artificial stone produced by the present invention is almost the same texture and strength as the natural stone, the coloring pigment enters the pores of volcanic stone which is one of the ingredients, permanently colored and value as an exterior material Serves to increase.

Claims (6)

백시멘트, 화산석, 건축폐기물(이하, "혼합원료")을 각각 35~45중량%, 45~55중량%, 5~10중량%의 비율로 혼합하는 단계,Mixing white cement, volcanic stone and construction waste (hereinafter referred to as "mixed raw materials") at a ratio of 35 to 45% by weight, 45 to 55% by weight and 5 to 10% by weight, respectively, 상기 혼합재료에 코발트, 산화철, 티탄, 액체 아크릴, 방수제, 감수제(이하, "첨가제"를 2~5중량% 첨가하는 단계,Adding 2 to 5% by weight of cobalt, iron oxide, titanium, liquid acrylic, waterproofing agent, water reducing agent (hereinafter, "additive") to the mixed material, 첨가제를 첨가한 혼합원료를 혼합한 후 금형에 투입하여 성형하는 단계,Mixing the raw materials with the additives added thereto and then molding them into a mold, 열풍에 의해 양생 및 건조하는 단계,Curing and drying by hot air, 시유기를 써서 표면처리를 하는 단계로 구성되는 인조석 제조방법.Artificial stone manufacturing method comprising the step of surface treatment using a seeder. 청구항 1에서, 첨가제에는 착색용 안료가 포함되는 것을 특징으로 하는 인조석 제조방법.The artificial stone manufacturing method of claim 1, wherein the additive includes a coloring pigment. 청구항 1에서, 열풍건조 단계에서는 20℃의 저온사이클과 45℃의 고온사이클을 6시간씩 교대로 반복하여 12시간 동안 양생 및 건조하는 단계가 포함되는 인조석 제조방법.The artificial stone manufacturing method of claim 1, wherein the hot air drying step includes curing and drying for 12 hours by alternately repeating a low temperature cycle of 20 ° C. and a high temperature cycle of 45 ° C. for 6 hours. 청구항 3에서, 열풍건조 단계에서는 성형된 인조석 반제품에 고압열풍을 분사하고 인조석 반제품에서 반사된 열풍을 받아서 재분사하는 것을 반복하는 단계가 추가로 포함되는 인조석 제조방법.The method of claim 3, wherein the hot-air drying step further includes spraying high-pressure hot air on the molded artificial semi-finished product and receiving and re-injecting hot air reflected from the artificial semi-finished product. 청구항 3의 인조석 제조방법에 사용되는 열풍건조 장치로서,A hot air drying apparatus used in the artificial stone manufacturing method of claim 3, 성형된 인조석 반제품을 수용하는 건조실,Drying chamber to house molded artificial stone semi-finished products, 건조실의 일측 상부에 설치되어 인조석 반제품에 고압으로 열풍을 분사하는 제1 열풍분사구,A first hot air jet nozzle installed at an upper part of the drying chamber to spray hot air at a high pressure to the artificial stone semi-finished product; 제1열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제2열풍분사구,A second hot air jet sphere for absorbing and re-injecting the reflected hot air when the hot air jetted from the first hot air jet nozzle is reflected from the artificial stone semi-finished product, 제2열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 재분사하는 제n열풍분사구,An n-th hot-air jet nozzle for absorbing and re-injecting the reflected hot air when hot air jetted from the second hot-air jet nozzle is reflected from the artificial stone semi-finished product, 제n 열풍분사구에서 분사된 열풍이 인조석 반제품에서 반사되면, 반사된 열풍을 흡수하여 배출하는 열풍배출구로 구성되는, 열풍건조 장치.And a hot air discharge port for absorbing and discharging the reflected hot air when the hot air jetted from the n-th hot-air jet nozzle is reflected from the artificial stone semi-finished product. 청구항 5에서, 제2 및 제n열풍분사구는 인조석 반제품에서 반사된 열풍을 흡입하는 흡입구와, 흡입된 열풍이 유도되는 덕트를 포함하는 것을 특징으로 하는, 열풍건조 장치.The hot-air drying apparatus of claim 5, wherein the second and n-th hot-air jet nozzles include a suction port for sucking hot air reflected from the artificial stone semifinished product, and a duct from which the hot air is sucked.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020094360A (en) * 2001-06-11 2002-12-18 박말용 Artificial marble posessed of an anchor
KR100913788B1 (en) * 2007-11-12 2009-08-26 한국세라믹기술원 Method for producing ALC panel using white portland cement and volcanic stone
RU2444486C1 (en) * 2010-10-13 2012-03-10 Юлия Алексеевна Щепочкина Artificial rock
RU2445284C1 (en) * 2010-11-09 2012-03-20 Юлия Алексеевна Щепочкина Artificial rock
CN103467032A (en) * 2013-07-30 2013-12-25 杭州茂华工贸有限公司 Preparation process for imitated natural Gaojia stone
ITUB20156270A1 (en) * 2015-12-03 2017-06-03 Gioacchino Pace MIXTURE FOR STONES AND RELATED PRODUCTION METHOD
CN107351236A (en) * 2017-08-21 2017-11-17 广西利升石业有限公司 A kind of square stock formula inorganic type process for producing artificial stone
IT201700019517A1 (en) * 2017-02-22 2018-08-22 Donatella Nicolardi Method for the production of small cement mortar blocks and the dowels thus obtained

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020094360A (en) * 2001-06-11 2002-12-18 박말용 Artificial marble posessed of an anchor
KR100913788B1 (en) * 2007-11-12 2009-08-26 한국세라믹기술원 Method for producing ALC panel using white portland cement and volcanic stone
RU2444486C1 (en) * 2010-10-13 2012-03-10 Юлия Алексеевна Щепочкина Artificial rock
RU2445284C1 (en) * 2010-11-09 2012-03-20 Юлия Алексеевна Щепочкина Artificial rock
CN103467032A (en) * 2013-07-30 2013-12-25 杭州茂华工贸有限公司 Preparation process for imitated natural Gaojia stone
ITUB20156270A1 (en) * 2015-12-03 2017-06-03 Gioacchino Pace MIXTURE FOR STONES AND RELATED PRODUCTION METHOD
WO2017093919A1 (en) * 2015-12-03 2017-06-08 Pace Gioacchino Mixture for manufacturing stone products and method for its production
IT201700019517A1 (en) * 2017-02-22 2018-08-22 Donatella Nicolardi Method for the production of small cement mortar blocks and the dowels thus obtained
CN107351236A (en) * 2017-08-21 2017-11-17 广西利升石业有限公司 A kind of square stock formula inorganic type process for producing artificial stone
CN107351236B (en) * 2017-08-21 2019-04-26 广西利升石业有限公司 A kind of square stock formula inorganic type process for producing artificial stone

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