KR20010100419A - Gel type detergent composition for a urinal - Google Patents

Abstract

The present invention discloses a gel-type urinal cleaner composition comprising 0.1 to 10 parts by weight of a natural water-soluble polymer, 1 to 30 parts by weight of a nonionic surfactant as a cleaning agent, and 0.1 to 10 parts by weight of a polybutadiene deodorant. The gel-type urinal cleaner composition of the present invention is a gel-type urinal cleaner comprising a nonionic surfactant having excellent cleaning power, a polybutadiene derivative having excellent odor resolution, and a gelling agent, and has a superior cleaning power and odor removal power as compared to a conventional detergent. The gel detergent of the present invention is a useful invention having superior effects as compared to conventional liquid cleaners or solid detergents.

Description

Gel-type urinal cleaner composition {GEL TYPE DETERGENT COMPOSITION FOR A URINAL}

The present invention relates to a gel urinal detergent composition containing a polybutadiene-based deodorant. More specifically, the present invention relates to a gel-type urinal cleaner composition comprising a polybutadiene derivative as a deodorant, a natural water-soluble polymer substance as a gelling agent, a nonionic surfactant as a cleaning agent, and other fragrances to remove the odor generated in the urinal barrel as well as cleaning the urinal barrel. will be.

Conventionally, as a detergent for urinals, as a solid detergent, naphthalene is solidified for hygiene and placed in the lower part of the urinal, and these solids melt | dissolve at the time of urine, and it has been used for the purpose of preventing the spread of bacteria etc. However, such sanitary treatment is rarely used due to the appearance of a flushing urinal, and a large amount of water is shed, and recently, such a washing alone is not satisfactory to remove odors, and various odors are constantly discharged during urine to remove odors. . However, releasing these scents only masks the odor, and since the odor itself cannot be disassembled, the masking agent must be continuously discharged at regular intervals. Hesitantly, moreover, these products themselves have no cleaning power, so if the toilet is not cleaned frequently, odors are generated and dirt has accumulated, requiring a new type of cleaner.

Detergents should have the ability to decompose pollutants themselves, but recently catalysts with photocatalytic functions have been known to decompose contaminants, but these materials are not yet widespread and expensive and are not suitable as cleaners. It has been attempted to be used directly in the composition of ceramics to manufacture a toilet, but has not been used as a cleaning agent yet. Therefore, it is still desirable to form a surfactant having a high cleaning power.

In addition, when the detergent is a liquid, there is a problem that requires a separate container and device that can be discharged constantly, which is expensive. Moreover, the odor flowing back through the urinal outlet cannot be removed, so it must always be discharged at regular intervals.

In the solid phase, the solubility in water should be adequate. If the dissolving power is excessive, it is used too quickly to be necessary and the product is not desirable because it is exhausting. If the dissolving power is not excessively dissolved, it is unsuitable in cleaning power, odor removing power and the like.

In order to solve such a problem, the present inventors have diligently researched and formulated a gelling agent with a detergent, a deodorant, a perfume, a dye, and the like, dissolved in water at 60 ° C. or higher, and then cooled to room temperature to prepare a gel detergent composition. As a result, the present inventors have found that they have cleaning power and odor resolution beyond the masking effect of maintaining only simple fragrance, which is a problem of conventional cleaning agents, and thus, the present invention has been completed.

Examples of the gelling agent used in the present invention include water-soluble natural polymers, and examples thereof include carrageenan, guar gum, sodium alginate and xanthan gum. Such polymers may be used, and the amount thereof is preferably 0.1 to 10 parts by weight based on the total composition. It may not gelate at 0.1 parts by weight or less, and at 10 parts by weight or more, the viscosity is too high, and it is not compatible with other ingredients, which may adversely affect the final product. In particular, it is suitable that the viscosity of this one solution is 10-500 cps.

The surfactant used for cleaning the toilet in the present invention is not particularly limited as long as it has excellent cleaning power, but alcohol phenyl, fatty alcohol, sorbitan fatty acid derivatives, etc. may be used, and especially those having 10 to 16 carbon atoms. Alcohol-based nonionic surfactants having 2 to 40 ethylene oxide added moles to the secondary alcohol are preferable. As for the compounding quantity of these nonionic surfactant, 1-30 weight part is preferable with respect to the whole composition. When the amount of the nonionic surfactant is used in an amount of 1 part by weight or less, it is difficult to expect a cleaning effect. At 30 parts by weight or more, a large amount of bubbles are generated after use, which may adversely affect the water environment.

In the present invention, the deodorant used for removing the odor in the urinary barrel before and after urine shows a very excellent odor removal effect to the ammonia source, ammonia, hydrogen sulfide, amines, and mercaptan compounds.

Preference is given to polybutadiene-based deodorants (Patent Publication No. 1999-0083707 of the present applicant) of the following general formula. The compounding quantity of this deodorant is suitable for 0.1-10 weight part with respect to rolling property. At 0.1 parts by weight or less, the odor removing effect is not sufficiently exhibited. At 10 parts by weight or more, the viscosity is too high, and it is difficult to produce the gelling agent of the present invention.

[Wherein n represents an integer of about 17 to 40,

R ₁ and R ₂ represent an alkyl group having 1 to 5 carbon atoms,

M represents sodium or potassium. ]

In addition to the above components, various flavors, such as lemon-based yellow dyes or blue dyes, may be blended to impart visual and olfactory cleanliness, and these kinds may be used in the art. As the fragrance, lemon-based fragrance (D-limonene), yellow no. 1, yellow no. 2, blue no. 1 and the like can be used. The usage-amount of these fragrances is 1-20 weight part. When it is used in an amount of 1 part by weight or less, the directional function can not be expected, and in the case of 20 parts by weight or more, the directionality is too large and may give an olfactory discomfort.

Yellow or blue dyes may be used for clean images of the compositions of the present invention. The amount of use thereof is appropriately 0.1 to 10 parts by weight. At 0.1 parts by weight or less, a clean image of the product may fall, and at 10 parts by weight or more, it may show a rejection due to too dark color.

Conventionally, urinal cleaner is a product that has only aroma function without cleaning power and deodorizing power. It is difficult to remove odor caused by backflow from urinal when used for a long time, and aroma function that has aroma function is not uniform when used for a long time. Compared with the disadvantages, the gel urine cleaner composition of the present invention has superior cleaning power than the conventional urinal cleaner, and directly reacts with the malodorous component flowing back from the urinal and the polybutadiene deodorant to decompose the malodorous component and also serves as a perfume. By using it in combination, the gel-type urinal cleaner composition according to the present invention exhibits an olfactory clean image while having excellent cleaning power and deodorization and aroma function.

Hereinafter, the present invention will be described in more detail with reference to Examples.

Examples 1 to 3

Next, the gelling agent (carrageenan) was added to the water according to the composition of Table 1 to raise the temperature to 70-80 ° C, and alcohol-based nonionic surfactant, lemon flavor, deodorant, and yellow dye were added to the mixture, followed by homogeneous mixing. Manufactured by lowering below ℃.

Furtherance Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 water 82 61 30 37 87 82 86 Carrageenan One 5 10 One One One One Polyoxyethylene octylphenyl ether (10) 5 15 30 50 5 - 5 Polyoxyethylene glycol (400) - - - - - 5 - Lemon scent ²⁾ 4 8 16 4 4 4 - Deodorant ¹⁾ (polybutadiene) 5 5 5 5 - 5 5 Yellow No. 1 Dye 3 6 9 3 3 3 3

Note: 1)

(Wherein n represents an integer of about 40,

R ₁ and R ₂ each represent a methyl group,

M represents a sodium atom.

2): Midas 400 (contains Zico Co., Ltd., 50 parts by weight or less of D-limonene)

Assessment Methods

Using the composition, a bubble measurement test method (KSM-2709), a biodegradability measurement method (KSM-2714), a deodorization, a fragrance test, and a detergency test were performed.

◆ bubble test

○; Less than 200ml by Ross-Miles Foam

×; More than 200ml by Ross-Miles Foam Measurement

◆ biodegradation test

○; 90 or more (average of physical properties on day 7, 8 after experiment in accordance with KSM-2714)

×; 90 or less (average of physical properties on day 7, 8 after experiment in accordance with KSM-2714)

◆ Deodorization, direction test (self test)

1. Pour 10 g of urine into a 500 ml round barrel.

2. 1 g of the present invention is placed in a 500 ml round cylinder.

3. After closing, seal and leave for 30 minutes.

4. The average value after the test by the sensory method after 10 people

Odor Determination Table <Odor Odor Determination Table of Q-Mark Test Method> Odor Judgment 0 degrees Odorless (no smell at all) 1 degree Detection odor (we detect slight odor) 2 degrees Normal odor (we detect normal odor) 3 degree Strong odor (we sense strong odor) 4 degree Extreme odor (detects very strong odor) 5 degrees Unbearable odor (unbearable odor)

◆ cleaning power test

Observed before and after urine using 10 people for 30 days in three illuminances of 60W incandescent bulbs in a closed space of 1.3 pyeong.

2. Observe the scale of dirt and mildew in the urinals before and after urine.

○; Bites and foreign objects (fungus) do not get stuck in urinal

×; Moss and foreign matter (fungus) form in urinal

The evaluation results are shown in Table 3 below.

division Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Bubble Test ○ ○ ○ × ○ ○ ○ Biodegradation Test ○ ○ ○ × ○ × ○ Deodorization test 0 degrees 0 degrees 0 degrees ○ degree 5 degrees 0 degrees 1 degree Detergency Test ○ ○ ○ ○ ○ × ×

The gel-type urinal cleaner composition of the present invention is a gel-type urinal cleaner comprising a nonionic surfactant having excellent cleaning power, a polybutadiene derivative having excellent odor decomposition ability, and a gelling agent, and has a superior cleaning power and odor removal power as compared to a conventional detergent. The gel detergent of the present invention is a useful invention having superior effects as compared to conventional liquid cleaners or solid detergents.

Claims (5)

A gel-type urinal cleaner composition comprising 0.1 to 10 parts by weight of a natural water-soluble polymer, 1 to 30 parts by weight of a nonionic surfactant as a gelling agent, and 0.1 to 10 parts by weight of a polybutadiene deodorant. The gel-type urinal cleaner composition according to claim 1, wherein the gelling agent is carrageenan, and the one-solution viscosity is a natural water-soluble polymer having 10 to 500 cps. The gel-type urinal cleaner composition according to claim 1, wherein the nonionic surfactant is an alcoholic nonionic surfactant having 2 to 40 ethylene oxides of a secondary alcohol having 10 to 16 carbon atoms. The gel urinal cleaning composition according to claim 1, which contains 1 to 20 parts by weight of lemon flavor (containing 50 or less D-limonene). The gel-type urinal cleaner composition according to claim 1, wherein the polybutadiene derivative has a molecular weight of 1000 to 5000, has an alkylamino group at one end of the formula, and contains a sulfonate group at the other end thereof. [Wherein n represents an integer of about 17 to 45, R ₁ and R ₂ represent an alkyl group having 1 to 5 carbon atoms, M represents sodium or potassium. ]