JP5925571B2 - Liquid fragrance cleaning composition for flush toilet - Google Patents
Liquid fragrance cleaning composition for flush toilet Download PDFInfo
- Publication number
- JP5925571B2 JP5925571B2 JP2012094752A JP2012094752A JP5925571B2 JP 5925571 B2 JP5925571 B2 JP 5925571B2 JP 2012094752 A JP2012094752 A JP 2012094752A JP 2012094752 A JP2012094752 A JP 2012094752A JP 5925571 B2 JP5925571 B2 JP 5925571B2
- Authority
- JP
- Japan
- Prior art keywords
- cleaning composition
- flush toilets
- fragrance
- component
- flush
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003205 fragrance Substances 0.000 title claims description 114
- 238000004140 cleaning Methods 0.000 title claims description 82
- 239000000203 mixture Substances 0.000 title claims description 78
- 239000007788 liquid Substances 0.000 title description 77
- -1 oxypropylene group Chemical group 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 150000005215 alkyl ethers Chemical class 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000006353 oxyethylene group Chemical group 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 33
- 239000012459 cleaning agent Substances 0.000 description 23
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 239000000194 fatty acid Substances 0.000 description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 238000001879 gelation Methods 0.000 description 14
- 229910052708 sodium Inorganic materials 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 239000002304 perfume Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000003599 detergent Substances 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000796 flavoring agent Substances 0.000 description 7
- 235000019634 flavors Nutrition 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000011109 contamination Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 239000002280 amphoteric surfactant Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 229920001214 Polysorbate 60 Polymers 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 235000019568 aromas Nutrition 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229940075507 glyceryl monostearate Drugs 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
- 230000007928 solubilization Effects 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- ZCHHRLHTBGRGOT-SNAWJCMRSA-N (E)-hex-2-en-1-ol Chemical compound CCC\C=C\CO ZCHHRLHTBGRGOT-SNAWJCMRSA-N 0.000 description 2
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzylacetone Chemical compound CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- HCRBXQFHJMCTLF-ZCFIWIBFSA-N ethyl (2r)-2-methylbutanoate Chemical compound CCOC(=O)[C@H](C)CC HCRBXQFHJMCTLF-ZCFIWIBFSA-N 0.000 description 2
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
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- 239000001023 inorganic pigment Substances 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
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- NMRPBPVERJPACX-UHFFFAOYSA-N octan-3-ol Chemical compound CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
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- WODOUQLMOIMKAL-FJSYBICCSA-L disodium;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC([O-])=O WODOUQLMOIMKAL-FJSYBICCSA-L 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
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- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
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- 229940090910 ethyl 2-methylbutyrate Drugs 0.000 description 1
- 229940093503 ethyl maltol Drugs 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
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- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- HNZUNIKWNYHEJJ-FMIVXFBMSA-N geranyl acetone Chemical compound CC(C)=CCC\C(C)=C\CCC(C)=O HNZUNIKWNYHEJJ-FMIVXFBMSA-N 0.000 description 1
- HNZUNIKWNYHEJJ-UHFFFAOYSA-N geranyl acetone Natural products CC(C)=CCCC(C)=CCCC(C)=O HNZUNIKWNYHEJJ-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 229960004198 guanidine Drugs 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
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- MHUQWGIAOKFBJB-UHFFFAOYSA-N heptatriacontan-19-yl(dimethyl)azanium chloride Chemical compound [Cl-].C(CCCCCCCCCCCCCCCCC)C([NH+](C)C)CCCCCCCCCCCCCCCCCC MHUQWGIAOKFBJB-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 1
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- 238000009434 installation Methods 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 239000010656 jasmine oil Substances 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 229940071085 lauroyl glutamate Drugs 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- HRGPYCVTDOECMG-RHBQXOTJSA-N methyl cedryl ether Chemical compound C1[C@@]23[C@H](C)CC[C@H]2C(C)(C)[C@]1([H])[C@@](OC)(C)CC3 HRGPYCVTDOECMG-RHBQXOTJSA-N 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 229940074096 monoolein Drugs 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229940026235 propylene glycol monolaurate Drugs 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229930007790 rose oxide Natural products 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- LLELVHKMCSBMCX-UHFFFAOYSA-M sodium 1-[(4-chloro-5-methyl-2-sulfophenyl)diazenyl]naphthalen-2-olate Chemical compound [Na+].Cc1cc(N=Nc2c(O)ccc3ccccc23)c(cc1Cl)S([O-])(=O)=O LLELVHKMCSBMCX-UHFFFAOYSA-M 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- ZNYIJXQYUNSKDX-NTISSMGPSA-M sodium;hydron;(2s)-2-(tetradecanoylamino)pentanedioate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O ZNYIJXQYUNSKDX-NTISSMGPSA-M 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KYWIYKKSMDLRDC-UHFFFAOYSA-N undecan-2-one Chemical compound CCCCCCCCCC(C)=O KYWIYKKSMDLRDC-UHFFFAOYSA-N 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Description
本発明は、水洗トイレ用液体芳香洗浄剤組成物に関する。より詳細には、本発明は、様々な香料を可溶化でき、温度変化や水との接触によっても、ゲル化することなく、粘度変化が生じ難い水洗トイレ用液体芳香洗浄剤組成物に関する。 The present invention relates to a liquid fragrance cleaning composition for flush toilets. More specifically, the present invention relates to a liquid fragrance cleaning composition for flush toilets that can solubilize various fragrances and is less likely to change in viscosity without being gelled by temperature change or contact with water.
水洗トイレ用液体洗浄剤は、一般に、排出孔を有する容器に収容された状態で使用され、当該容器の排出孔から排出された水洗トイレ用液体洗浄剤がフラッシュ水と混合されて、フラッシュ時に、当該水洗トイレ用液体洗浄剤によって便器を洗浄することが可能になる。従来、水洗トイレ用液体洗浄剤は、水洗トイレの手洗い部上に設置して使用されるもの、水洗トイレの便器のリム部に取り付けて使用されるもの等がある。このような水洗トイレ用液体洗浄剤は、設置が容易である、便器の洗浄が簡便に行える、洗浄剤の残存量を容易に確認できる、等の使用上の利点があり、今日では広く流通している。 The flush toilet liquid cleaner is generally used in a state of being accommodated in a container having a discharge hole, and the flush toilet liquid detergent discharged from the discharge hole of the container is mixed with flush water. The toilet bowl can be washed by the flushing liquid cleaner. Conventionally, liquid cleaning agents for flush toilets include those that are used by being installed on a hand-washing part of a flush toilet, and those that are used by being attached to a rim part of a toilet of a flush toilet. Such liquid detergent for flush toilets has advantages in use such as easy installation, easy cleaning of toilet bowl, and easy confirmation of remaining amount of cleaning agent. ing.
このような水洗トイレ用液体洗浄剤は、毎使用時に安定した洗浄作用を発揮させるために、容器からの毎排出量が一定になるように設計することが重要である。特に、一般にトイレの室内空間は、一年を通じた寒暖による温度変化があり、このような温度変化によって、水洗トイレ用液体洗浄剤の粘度が大きく変動したり、ゲル化したりすると、容器からの毎排出量が変動し、所望の洗浄作用を発揮できなくなる。また、容器に収容された水洗トイレ用液体洗浄剤は、適量が容器外に排出されてフラッシュ水と混合されるように使用態様が設計されているが、容器中の水洗トイレ用液体洗浄剤の中に、フラッシュ水が不可避的に逆流することがある。水洗トイレ用液体洗浄剤は、洗浄成分が高濃度で含まれているため、このようにフラッシュ水が混入した場合、粘度変化を生じたり、ゲル化が生じて、容器からの毎排出量が不均一になることがある。そこで、従来、水洗トイレ用液体洗浄剤に温度変化や水の混入によっても、ゲル化を生じずに粘度を一定範囲に保持できる処方が検討されている。例えば、特許文献１には、２０℃で流動性を有する非イオン性界面活性剤と、２０℃で流動性を有しない非イオン性界面活性剤と、ポリオキシエチレンポリオキシプロピレンブロックポリマーと、水とを特定の比率で含有する液体洗浄組成物は、温度変化や水の混入によっても粘度変化を受け難く、容器からの排出量が不均一になるのを抑制できることが報告されている。また、特許文献２には、特定の構造のポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤４０〜９５重量％と、香料５〜６０重量％を含む液体芳香洗浄組成物は、高濃度の界面活性剤及び香料を含有していながら、広い温度領域で水と接触してもゲル化しないで優れた洗浄作用を発揮できることが報告されている。 It is important to design such a liquid detergent for flush toilets so that the amount discharged from the container is constant in order to exhibit a stable cleaning action at each use. In particular, the indoor space of a toilet generally changes in temperature due to cold and warm throughout the year, and if the viscosity of the liquid cleaning agent for flush toilets fluctuates or gels due to such temperature change, The discharge amount fluctuates and the desired cleaning action cannot be exhibited. In addition, the liquid cleaning agent for flush toilets contained in a container is designed so that an appropriate amount is discharged out of the container and mixed with flush water. In some cases, flush water inevitably flows backward. Since liquid cleaning agents for flush toilets contain cleaning components at high concentrations, when flush water is mixed in this way, viscosity changes or gelation occurs, resulting in an inefficient discharge from the container. May be uniform. Therefore, conventionally, a formulation that can maintain the viscosity in a certain range without causing gelation even when the liquid detergent for flush toilet is changed in temperature or mixed with water has been studied. For example, Patent Document 1 discloses a nonionic surfactant having fluidity at 20 ° C., a nonionic surfactant having no fluidity at 20 ° C., a polyoxyethylene polyoxypropylene block polymer, and water. It has been reported that a liquid cleaning composition containing the above in a specific ratio is less susceptible to a change in viscosity due to a change in temperature or mixing of water, and can suppress a non-uniform discharge amount from a container. Patent Document 2 discloses that a liquid fragrance cleaning composition containing 40 to 95% by weight of a polyoxyalkylene alkyl ether type nonionic surfactant having a specific structure and 5 to 60% by weight of a fragrance has a high concentration interface. It has been reported that even though it contains an activator and a fragrance, it can exhibit an excellent cleaning action without gelation even when it comes into contact with water in a wide temperature range.
一方、水洗トイレ用液体洗浄剤は、便器の洗浄効果に止まらず、トイレの室内空間を快適な香気で満たすために、香料が配合されている。そして、近年、消費者の嗜好性の多様化に追従するために、様々な香気を呈する水洗トイレ用液体洗浄剤が開発されている。しかしながら、備えさせる香気の種類によって配合する香料成分の種類が異なり、それに応じて香料を可溶化させるために配合する成分の種類を選択することが必要とされている。そのため、従来報告されているトイレ用液体洗浄剤では、使用する香料成分の種類によって、個別に処方設計しなければならないという欠点がある。 On the other hand, the liquid cleaning agent for flush toilets contains not only the toilet cleaning effect but also a fragrance in order to fill the indoor space of the toilet with a comfortable aroma. In recent years, in order to follow the diversification of consumer preference, liquid cleaning agents for flush toilets having various aromas have been developed. However, the type of the fragrance component to be blended differs depending on the type of fragrance to be provided, and accordingly, it is necessary to select the type of the component to be blended in order to solubilize the fragrance. Therefore, the liquid detergent for toilets reported conventionally has the fault that it must be individually formulated and designed depending on the type of perfume ingredients used.
そこで、香料成分の種類に拘わらず、香料成分を可溶化でき、しかも温度変化や水の混入によっても、ゲル化せずに粘度変化が生じ難い水洗トイレ用液体洗浄剤の処方を開発できれば、１つの基本処方を採用することによって、備える香気が異なる複数タイプの水洗トイレ用液体洗浄剤の開発が可能になり、多様化する消費者の嗜好性に追従した製品の開発が容易になる。しかしながら、従来、香料成分の種類に拘わらず、あらゆる香料成分に対して普遍的に適用可能な処方は一切報告されていないのが現状である。 Therefore, if a prescription for a liquid detergent for flush toilets can be developed, which can solubilize the fragrance ingredient regardless of the kind of the fragrance ingredient, and is less likely to change in viscosity without gelation due to temperature change or water contamination, 1 By adopting one basic prescription, it becomes possible to develop a plurality of types of liquid cleaning agents for flush toilets with different aromas, and it becomes easy to develop products that follow the diversifying consumer preferences. However, the present situation is that no prescription universally applicable to any fragrance component has been reported, regardless of the type of fragrance component.
本発明は、香料成分の種類に拘わらず、香料成分を可溶化でき、しかも温度変化や水の混入によっても、ゲル化せずに粘度変化が生じ難い水洗トイレ用液体芳香洗浄剤組成物を提供することを目的とする。 The present invention provides a liquid fragrance cleaning composition for flush toilets that can solubilize the fragrance component regardless of the type of the fragrance component, and is less likely to change in viscosity without gelation due to temperature change or water contamination. The purpose is to do.
本発明者は、前記課題を解決すべく、鋭意検討を行ったところ、(A)炭素数８〜１１のアルキル基を有し、特定の物性を示すポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤と、(B)炭素数１２〜１４のアルキル基を有し、特定の物性を示すポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤と、(C)香料成分とを含み、且つ２５℃での粘度が６０〜８００ｍＰａ・ｓである水洗トイレ用液体芳香洗浄剤組成物は、香料成分の種類に拘わらず、香料成分を可溶化でき、しかも温度変化や水の混入によっても、ゲル化し難く、粘度変化が生じ難いことを見出した。本発明は、かかる知見に基づいて、更に検討を重ねることにより完成したものである。 The present inventor has conducted extensive studies to solve the above problems. As a result, (A) a polyoxyalkylene alkyl ether type nonionic surfactant having an alkyl group having 8 to 11 carbon atoms and exhibiting specific physical properties. And (B) a polyoxyalkylene alkyl ether type nonionic surfactant having an alkyl group having 12 to 14 carbon atoms and exhibiting specific physical properties, and (C) a perfume component, and at 25 ° C. The liquid fragrance cleaning composition for flush toilets having a viscosity of 60 to 800 mPa · s can solubilize the fragrance component regardless of the type of the fragrance component, and is hardly gelled even by temperature change or water contamination. It was found that the viscosity change hardly occurs. The present invention has been completed by further studies based on this finding.
即ち、本発明は、下記に掲げる態様の発明を提供する。
項１．(A)下記一般式(1)で表され、ＨＬＢ値が１４．３以下、及び１重量％水溶液での曇点が８０℃以下であるポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤
Ｒ1−Ｏ−［（ＥＯ）a／（ＰＯ）b］−Ｈ （１）
[一般式(1)中、Ｒ1は炭素数８〜１１の直鎖状又は分岐状のアルキル基、ＥＯはオキシエチレン基、ＰＯはオキシプロピレン基、ａはＥＯの平均付加モル数で５≦ａ、ｂはＰＯの平均付加モル数で０≦ｂ、［（ＥＯ）a／（ＰＯ）b］はＥＯとＰＯのランダム付加又はブロック付加を示す。]、
(B)下記一般式(2)で表され、１重量％水溶液での曇点が８０℃以上であるポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤
Ｒ2−Ｏ−［（ＥＯ）c／（ＰＯ）d］−Ｈ （２）
[一般式(2)中、Ｒ2は炭素数１２〜１４の直鎖状又は分岐状のアルキル基、ＥＯはオキシエチレン基、ＰＯはオキシプロピレン基、ｃはＥＯの平均付加モル数で１≦ｃ、ｄはＰＯの平均付加モル数で１≦ｄ、［（ＥＯ）c／（ＰＯ）d］はＥＯとＰＯのランダム付加又はブロック付加を示す。]、及び
(C)香料成分
を含有し、且つ
２５℃での粘度が６０〜８００ｍＰａ・ｓであることを特徴とする、水洗トイレ用芳香洗浄剤組成物。
項２． 前記一般式(1)におけるＲ1が炭素数１０の直鎖状又は分岐状のアルキル基である、項１に記載の水洗トイレ用芳香洗浄剤組成物。
項３． 前記一般式(2)におけるＲ2が炭素数１２〜１３の直鎖状又は分岐状のアルキル基である、項１又は２に記載の水洗トイレ用芳香洗浄剤組成物。
項４． 前記(A)成分の含有量が０．１〜５０重量％である、項１〜３のいずれかに記載の水洗トイレ用芳香洗浄剤組成物。
項５． 前記(B)成分の含有量が０．１〜５０重量％である、項１〜４のいずれかに記載の水洗トイレ用芳香洗浄剤組成物。
項６． 更に水を含む、項１〜５のいずれかに記載の水洗トイレ用芳香洗浄剤組成物。
項７． 水洗トイレのオンタンク用として使用される、項１〜６のいずれかに記載の水洗トイレ用芳香洗浄剤組成物。
項８． 水洗トイレのリム部用として使用される、項１〜６のいずれかに記載の水洗トイレ用芳香洗浄剤組成物。
That is, this invention provides the invention of the aspect hung up below.
Item 1. (A) A polyoxyalkylene alkyl ether type nonionic surfactant R 1 represented by the following general formula (1), having an HLB value of 14.3 or less and a cloud point in a 1 wt% aqueous solution of 80 ° C. or less. -O-[(EO) a / (PO) b ] -H (1)
[In the general formula (1), R 1 is a linear or branched alkyl group having 8 to 11 carbon atoms, EO is an oxyethylene group, PO is an oxypropylene group, and a is an average added mole number of EO of 5 ≦ a and b are average addition mole numbers of PO, 0 ≦ b, and [(EO) a / (PO) b ] represents random addition or block addition of EO and PO. ],
(B) Polyoxyalkylene alkyl ether type nonionic surfactant R 2 —O — [(EO) c / represented by the following general formula (2) and having a cloud point of 80 ° C. or more in a 1 wt% aqueous solution. (PO) d ] -H (2)
[In General Formula (2), R 2 is a linear or branched alkyl group having 12 to 14 carbon atoms, EO is an oxyethylene group, PO is an oxypropylene group, and c is an average added mole number of EO of 1 ≦ c and d are average addition mole numbers of PO, 1 ≦ d, and [(EO) c / (PO) d ] indicates random addition or block addition of EO and PO. ],as well as
(C) A fragrance cleaning composition for flush toilets containing a fragrance component and having a viscosity at 25 ° C. of 60 to 800 mPa · s.
Item 2. Item 2. The fragrance cleaning composition for flush toilets according to Item 1, wherein R 1 in the general formula (1) is a linear or branched alkyl group having 10 carbon atoms.
Item 3. Item 3. The fragrance cleaning composition for flush toilets according to Item 1 or 2, wherein R 2 in the general formula (2) is a linear or branched alkyl group having 12 to 13 carbon atoms.
Item 4. Item 4. The fragrance cleaning composition for flush toilets according to any one of Items 1 to 3, wherein the content of the component (A) is 0.1 to 50% by weight.
Item 5. Item 5. The fragrance cleaning composition for flush toilets according to any one of Items 1 to 4, wherein the content of the component (B) is 0.1 to 50% by weight.
Item 6. Item 6. The fragrance cleaning composition for flush toilets according to any one of Items 1 to 5, further comprising water.
Item 7. Item 7. The fragrance cleaning composition for flush toilets according to any one of Items 1 to 6, which is used as an on-tank for flush toilets.
Item 8. Item 7. The fragrance cleaning composition for flush toilets according to any one of Items 1 to 6, which is used as a rim part for flush toilets.
本発明の水洗トイレ用液体芳香洗浄剤組成物は、香料成分の構造や特性の別を問わず、あらゆるタイプの香料成分を可溶化させることができるので、１つの基本処方を採用することによって、備える香気が異なる複数タイプの水洗トイレ用液体洗浄剤を提供することが可能になる。そのため、本発明によれば、使用する香料成分の種類に応じた個別の処方設計が不要になり、様々な香気を呈する水洗トイレ用液体芳香洗浄剤組成物を簡便に提供でき、消費者の香気に対する嗜好性の多様化に追従することが容易になる。 The liquid fragrance cleaning composition for flush toilets of the present invention can solubilize any type of fragrance component regardless of the structure and characteristics of the fragrance component, so by adopting one basic formulation, It is possible to provide a plurality of types of liquid cleaning agents for flush toilets with different aromas. Therefore, according to the present invention, individual formulation design according to the type of fragrance component to be used is not required, and liquid fragrance cleaning compositions for flush toilets that exhibit various fragrances can be easily provided, and consumers' fragrances. It becomes easier to follow the diversification of palatability.
また、本発明の水洗トイレ用液体芳香洗浄剤組成物は、季節や地域等に起因する温度変化に晒されても、粘度変化が生じ難く、更に水が混入しても粘度変化が生じ難いため、容器からの排出量が不均一になるのを抑制して、容器からの毎排出量を一定に維持することができる。 In addition, the liquid fragrance cleaning composition for flush toilets of the present invention is less likely to change in viscosity even when exposed to temperature changes due to seasons, regions, etc., and is less likely to change in viscosity even when mixed with water. The amount of discharge from the container can be suppressed from becoming uneven, and the amount of discharge from the container can be kept constant.
本発明の水洗トイレ用液体芳香洗浄剤組成物は、(A)炭素数８〜１１のアルキル基を有し、ＨＬＢ値が１４．３以下、及び１重量％水溶液での曇点が８０℃以下である特定構造のポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤、(B)炭素数１２〜１４のアルキル基を有し、１重量％水溶液での曇点が８０℃以上である特定構造のポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤、及び(C)香料成分を含み、且つ２５℃での粘度が６０〜８００ｍＰａ・ｓであることを特徴とする。以下、本発明の水洗トイレ用液体芳香洗浄剤組成物について詳述する。 The liquid fragrance cleaning composition for flush toilets of the present invention has (A) an alkyl group having 8 to 11 carbon atoms, an HLB value of 14.3 or less, and a cloud point of 1% by weight aqueous solution of 80 ° C. or less. A polyoxyalkylene alkyl ether type nonionic surfactant having a specific structure of (B) having a specific structure having an alkyl group having 12 to 14 carbon atoms and a cloud point of 80 ° C. or more in a 1% by weight aqueous solution. A polyoxyalkylene alkyl ether type nonionic surfactant and (C) a fragrance component are included, and the viscosity at 25 ° C. is 60 to 800 mPa · s. Hereinafter, the liquid aromatic cleaning composition for flush toilets of the present invention will be described in detail.
(A)成分
本発明の水洗トイレ用液体芳香洗浄剤組成物は、ＨＬＢ値が１４．３以下、及び１重量％水溶液での曇点が８０℃以下であって、下記一般式(1)で表されるポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤（以下、単に、「(A)成分」と表記することもある）を含有する。
Ｒ1−Ｏ−［（ＥＯ）a／（ＰＯ）b］−Ｈ （１）
Component (A) The liquid fragrance cleaning composition for flush toilets of the present invention has an HLB value of 14.3 or less, and a cloud point of 1% by weight aqueous solution of 80 ° C. or less, represented by the following general formula (1): A polyoxyalkylene alkyl ether type nonionic surfactant represented (hereinafter, may be simply referred to as “component (A)”).
R 1 —O — [(EO) a / (PO) b ] —H (1)
一般式(1)中、Ｒ1は、炭素数８〜１１の直鎖状又は分岐状のアルキル基を示す。Ｒ1として、好ましくは炭素数９〜１０の直鎖状又は分岐状のアルキル基、更に好ましは炭素数１０の直鎖状又は分岐状のアルキル基、特に好ましくは炭素数１０の分岐状のアルキル基、特に好ましくはイソデシル基が挙げられる。 In general formula (1), R 1 represents a linear or branched alkyl group having 8 to 11 carbon atoms. R 1 is preferably a linear or branched alkyl group having 9 to 10 carbon atoms, more preferably a linear or branched alkyl group having 10 carbon atoms, particularly preferably a branched alkyl group having 10 carbon atoms. An alkyl group, particularly preferably an isodecyl group, can be mentioned.
また、一般式(1)中、ＥＯはオキシエチレン基を示す。また、ａはＥＯの平均付加モル数を示し、ａ≧５である。ＥＯの平均付加モル数ａは、好ましくは５≦ａ≦３０、更に好ましくは５≦ａ≦１５が挙げられる。 In the general formula (1), EO represents an oxyethylene group. Moreover, a shows the average addition mole number of EO, and is a> = 5. The average added mole number a of EO is preferably 5 ≦ a ≦ 30, more preferably 5 ≦ a ≦ 15.
また、一般式(1)中、ＰＯはオキシプロピレン基を示す。また、ｂはＰＯの平均付加モル数を示し、０≦ｂである。ＰＯの平均付加モル数ｂは、好ましくは０≦ｂ≦１５、更に好ましくは０≦ｂ≦１０が挙げられる。 In the general formula (1), PO represents an oxypropylene group. B represents the average added mole number of PO, and 0 ≦ b. The average added mole number b of PO is preferably 0 ≦ b ≦ 15, more preferably 0 ≦ b ≦ 10.
また、一般式(1)中、［（ＥＯ）a／（ＰＯ）b］は、ＥＯとＰＯのランダム付加又はブロック付加を示す。 In the general formula (1), [(EO) a / (PO) b ] indicates random addition or block addition of EO and PO.
本発明で使用される(A)成分は、上記一般式(1)で示す構造を備え、且つＨＬＢ値が１４．３以下である。(A)成分のＨＬＢ値として、好ましくは１２．０〜１４．３、更に好ましくは１２．８〜１３．９が挙げられる。なお、本明細書において、(A)成分のＨＬＢ値は、グリフィン法によって算出される値である。 The component (A) used in the present invention has a structure represented by the general formula (1) and has an HLB value of 14.3 or less. The HLB value of the component (A) is preferably 12.0 to 14.3, more preferably 12.8 to 13.9. In the present specification, the HLB value of the component (A) is a value calculated by the Griffin method.
また、本発明で使用される(A)成分は、更に１重量％水溶液にした場合の曇点が８０℃以下である。(A)成分の当該曇点として、好ましくは５０〜８０℃、更に好ましくは５０〜６０℃が挙げられる。ここで、当該曇点は、測定対象となる界面活性剤を精製水に１重量％となるように溶解し、ISO1065-1991に記載の測定法により決定される値である。 Further, the component (A) used in the present invention has a cloud point of 80 ° C. or lower when it is further made into a 1 wt% aqueous solution. The cloud point of the component (A) is preferably 50 to 80 ° C, more preferably 50 to 60 ° C. Here, the cloud point is a value determined by a measurement method described in ISO1065-1991 by dissolving a surfactant to be measured in purified water so as to be 1% by weight.
(A)成分に該当するポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤については、例えば、「FINESURF D-1305」、「FINESURF D-1307」、「FINESURF NDB-1000」、「FINESURF D-65」、「FINESURF D-85」、「ワンダサーフ ID-1033」、「セフティカット ID-1055」、「セフティカット ID-1061」、「ワンダサーフ ID-90」（以上、青木油脂工業株式会社製）、「ナロアクティー ID70」（三洋化成工業株式会社製）、「ノイゲン LF-60X」、「ノイゲン LF-80X」、「ノイゲン ＳＤ-70」、「ノイゲン ＳＤ-80」（以上、第一工業製薬株式会社製）等が市販されており、本発明では、これらの市販品を使用することもできる。 For the polyoxyalkylene alkyl ether type nonionic surfactant corresponding to the component (A), for example, “FINESURF D-1305”, “FINESURF D-1307”, “FINESURF NDB-1000”, “FINESURF D-65” "," FINESURF D-85 "," Wonder Surf ID-1033 "," Safety Cut ID-1055 "," Safety Cut ID-1061 "," Wonder Surf ID-90 "(Aoki Yushi Kogyo Co., Ltd.) , “Naroacty ID70” (manufactured by Sanyo Chemical Industries), “Neugen LF-60X”, “Neugen LF-80X”, “Neugen SD-70”, “Neugen SD-80” Etc.) are commercially available, and these commercially available products can also be used in the present invention.
本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(A)成分として、前記構造及び特性を満たすポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤を１種単独で使用してもよく、また２種以上を組み合わせて使用してもよい。 In the liquid fragrance cleaning composition for flush toilets of the present invention, as the component (A), a polyoxyalkylene alkyl ether type nonionic surfactant satisfying the structure and properties may be used alone, Two or more kinds may be used in combination.
本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(A)成分の含有量については、特に制限されないが、例えば０．１〜５０重量％、好ましくは０．５〜３０重量％、更に好ましくは２〜２５重量％が挙げられる。 In the liquid fragrance cleaning composition for flush toilets of the present invention, the content of the component (A) is not particularly limited, but is, for example, 0.1 to 50% by weight, preferably 0.5 to 30% by weight, Preferably 2 to 25 weight% is mentioned.
このように、(A)成分として、炭素数８〜１１のアルキル基を有し、前記HLB値及び曇点を満たすポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤を採用し、且つ後述する(B)成分と組み合わせて使用することにより、本発明の水洗トイレ用液体洗浄剤において、様々な種類の香料成分の可溶化が可能になり、しかも温度変化や水の混入によってもゲル化し難く、粘度変化が生じ難い特性を備えさせることが可能になる。 Thus, as the component (A), a polyoxyalkylene alkyl ether type nonionic surfactant having an alkyl group having 8 to 11 carbon atoms and satisfying the HLB value and cloud point is employed, and will be described later. By using it in combination with the component B), it becomes possible to solubilize various types of perfume ingredients in the liquid detergent for flush toilets of the present invention, and it is difficult to gel due to temperature changes and water contamination, and the viscosity It is possible to provide characteristics that hardly change.
(B)成分
本発明の水洗トイレ用液体芳香洗浄剤組成物は、上記(A)成分に加えて、１重量％水溶液での曇点が８０℃以上であって、下記一般式(2)で表されるポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤（以下、単に、「(B)成分」と表記することもある）を含有する。
Ｒ2−Ｏ−［（ＥＯ）c／（ＰＯ）d］−Ｈ （２）
(B) Component In addition to the component (A), the liquid fragrance cleaning composition for flush toilets of the present invention has a cloud point of 80 ° C. or higher in a 1 wt% aqueous solution, and is represented by the following general formula (2): A polyoxyalkylene alkyl ether type nonionic surfactant represented (hereinafter, may be simply referred to as “component (B)”).
R 2 -O - [(EO) c / (PO) d] -H (2)
一般式(2)中、Ｒ2は、炭素数１２〜１４の直鎖状又は分岐状のアルキル基を示す。Ｒ2として、好ましくは炭素数１２〜１３の直鎖状又は分岐状のアルキル基が挙げられる。 In the general formula (2), R 2 represents a linear or branched alkyl group having 12 to 14 carbon atoms. R 2 is preferably a linear or branched alkyl group having 12 to 13 carbon atoms.
また、一般式(2)中、ＥＯはオキシエチレン基を示す。また、ｃはＥＯの平均付加モル数を示し、１≦ｃである。ＥＯの平均付加モル数ｃは、好ましくは１≦ｃ≦３０、更に好ましくは５≦ｃ≦２５が挙げられる。 In the general formula (2), EO represents an oxyethylene group. C represents the average added mole number of EO, and 1 ≦ c. The average added mole number c of EO is preferably 1 ≦ c ≦ 30, more preferably 5 ≦ c ≦ 25.
また、一般式(2)中、ＰＯはオキシプロピレン基を示す。また、ｄはＰＯの平均付加モル数を示し、１≦ｄである。ＰＯの平均付加モル数ｄは、好ましくは１≦ｄ≦１５、更に好ましくは１≦ｄ≦１０が挙げられる。 In the general formula (2), PO represents an oxypropylene group. D represents the average number of moles of PO added and 1 ≦ d. The average added mole number d of PO is preferably 1 ≦ d ≦ 15, more preferably 1 ≦ d ≦ 10.
また、一般式(2)中、［（ＥＯ）c／（ＰＯ）d］は、ＥＯとＰＯのランダム付加又はブロック付加を示す。 In the general formula (2), [(EO) c / (PO) d ] indicates random addition or block addition of EO and PO.
本発明で使用される（B)成分は、上記一般式(2)で示す構造を備え、１重量％水溶液にした場合の曇点が８０℃以上である。(B)成分の当該曇点として、好ましくは８０〜９９℃、更に好ましくは８０〜９０℃が挙げられる。(B)成分の当該曇点の測定条件については、前記(A)成分の曇点の場合と同様である。 The component (B) used in the present invention has a structure represented by the above general formula (2) and has a cloud point of 80 ° C. or higher when a 1 wt% aqueous solution is formed. The cloud point of the component (B) is preferably 80 to 99 ° C, more preferably 80 to 90 ° C. The measurement conditions for the cloud point of the component (B) are the same as those for the cloud point of the component (A).
(B)成分に該当するポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤については、例えば、「サンノニック FN140」（三洋化成工業株式会社製）、「ワンダサーフ 140」、「ワンダサーフ S-1400」（以上、青木油脂工業株式会社製）、「ノイゲン TDX-120D」（第一工業製薬株式会社製）、等が市販されており、本発明では、これらの市販品を使用することもできる。 As for the polyoxyalkylene alkyl ether type nonionic surfactant corresponding to the component (B), for example, “Sannonic FN140” (manufactured by Sanyo Chemical Industries), “Wanda Surf 140”, “Wanda Surf S-1400” (As mentioned above, Aoki Yushi Kogyo Co., Ltd.), "Neugen TDX-120D" (Daiichi Kogyo Seiyaku Co., Ltd.), etc. are marketed. In the present invention, these commercial products can also be used.
本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(B)成分として、前記構造及び特性を満たすポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤を１種単独で使用してもよく、また２種以上を組み合わせて使用してもよい。 In the liquid fragrance cleaning composition for flush toilets of the present invention, as the component (B), a polyoxyalkylene alkyl ether type nonionic surfactant satisfying the structure and characteristics may be used alone, Two or more kinds may be used in combination.
本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(B)成分の含有量については、特に制限されないが、例えば０．１〜５０重量％、好ましくは２〜４５重量％、更に好ましくは５〜４０重量％が挙げられる。 In the liquid fragrance cleaning composition for flush toilets of the present invention, the content of the component (B) is not particularly limited, but for example 0.1 to 50% by weight, preferably 2 to 45% by weight, more preferably 5 to 40% by weight may be mentioned.
また、本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(A)成分と(B)成分の比率については、前述する各成分の含有量に基づいて定められるが、香料成分の可溶化作用や、粘度変化の抑制作用を一層効果的に発揮させるという観点から、上記(A)成分１００重量部に対して、上記(B)成分が、０．２〜５００００重量部、好ましくは６．６〜９０００重量部、更に好ましくは２０〜２０００重量部が挙げられる。 Further, in the liquid fragrance cleaning composition for flush toilets of the present invention, the ratio of the component (A) and the component (B) is determined based on the content of each component described above. From the viewpoint of more effectively exerting the action and the effect of suppressing the viscosity change, the component (B) is 0.2 to 50000 parts by weight, preferably 6. 5 parts by weight with respect to 100 parts by weight of the component (A). 6-9000 weight part, More preferably, 20-2000 weight part is mentioned.
このように、(B)成分として、炭素数１２〜１４のアルキル基を有し、前記曇点を満たすポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤を、前述する(A)成分と組み合わせることにより、様々な種類の香料成分の可溶化が可能になり、しかも温度変化や水の混入によってもゲル化し難く、粘度変化が生じ難い特性を備えさせることができる。 As described above, as the component (B), a polyoxyalkylene alkyl ether type nonionic surfactant having an alkyl group having 12 to 14 carbon atoms and satisfying the cloud point is combined with the component (A) described above. Thus, it is possible to solubilize various types of perfume ingredients, and it is possible to provide a characteristic that hardly changes into a viscosity and hardly changes in viscosity due to temperature change or water contamination.
(C)成分
本発明の水洗トイレ用液体芳香洗浄剤組成物は、上記(A)及び(B)成分に加えて、香料成分（以下、単に(C)成分と表記することもある）を含有する。このように香料成分を含有することにより、トイレ空間に所望の香気を付与することができる。
Component (C) The liquid fragrance cleaning composition for flush toilets of the present invention contains a fragrance component (hereinafter sometimes simply referred to as component (C)) in addition to the components (A) and (B). To do. Thus, by containing a fragrance | flavor component, a desired fragrance can be provided to toilet space.
本発明の水洗トイレ用液体芳香洗浄剤組成物では、香料成分の種類の別を問わず、あらゆる種類の香料成分を安定に可溶化できるので、配合される香料成分は、備えさせる香気に応じて適宜選択すればよい。本発明の水洗トイレ用液体芳香洗浄剤組成物に含有される香料成分としては、例えば、天然香料の他、炭化水素系香料、エーテル系香料、エステル系香料、アルコール系香料、アルデヒド系香料、ケトン系香料等の合成香料が挙げられる。 In the liquid fragrance cleaning composition for flush toilets of the present invention, any kind of fragrance component can be stably solubilized regardless of the type of the fragrance component, so that the blended fragrance component depends on the aroma to be provided. What is necessary is just to select suitably. Examples of the fragrance components contained in the liquid fragrance cleaning composition for flush toilets of the present invention include, in addition to natural fragrances, hydrocarbon fragrances, ether fragrances, ester fragrances, alcohol fragrances, aldehyde fragrances, and ketones. Synthetic fragrances such as system fragrances.
具体的には、天然香料としては、例えば、レモン油、オレンジ油、ベルガモット油、イランイラン油、パチュリ油、シトロネラ油、レモングラス油、ボアドローズ油、チョウジ油、ユーカリ油、セダー油、ラベンダー油、ビャクダン油、ベチバー油、ゼラニウム油、ラブダナム油、ミント油、ペパーミント油、ローズ油、ジャスミン油、リッツアキュベバ油等が挙げられる。また、炭化水素系香料としては、例えば、リモネン、α−ピネン、カンフェン、ｐ−サイメン、フェンチェン等が挙げられる。また、エーテル系香料としては、例えば、テトラヒドロ−２，４−ジメチル−４−フェニルフラン、１，８−シネオール、ローズオキサイド、セドロールメチルエーテル（セドランバー）、ｐ−クレジルメチルエーテル、イソアミルフエェニルエチルエーテル、４−フェニル−２，４，６−トリメチル−１，３−ジオキサン、アネトール等が挙げられる。また、エステル系香料としては、例えば、ゲラニルアセテート、エチルアセテート、エチルプロピオネート、メチルブチレート、エチルイソブチレート、エチルブチレート、ブチルアセテート、エチル２−メチルブチレート、イソアミルアセテート、エチル２−メチルペンタノエート（マンザネート）、ヘキシルアセテート、アリルヘキサノエート、トリシクロデセニルプロピオネート（ＶＥＲＴＯＰＲＯ；フロロシクレン）、アリルヘプタノエート、イソボルニルアセテート、リナリルアセテート、シトロネリルアセテート、２−ｔｅｒ−ブチルシクロヘキシルアセテート（ナルシドール）等が挙げられる。また、アルコール系香料としては、例えば、リナノール、３−オクタノール、２，６−ジメチル−ヘプタノール、１０−ウンデセノール、ゲラニオール、ネロール、シトロネロール、ロジノール、ミルセノール、テトラヒドロリナロール、ターピネオール、セドロール、２，４−ジメチル−３−シクロヘキサン−１−メタノール、４−イソプロピルシクロヘキサノール、ネロリドール、９−デセノール、シス−３−ヘキセノール、トランス−２−ヘキセノール、オイゲノール等が挙げられる。また、アルデヒド系香料としては、例えば、シトロネラール、オクタナール、パラアルデハイド、ベンズアルデヒド、アルデヒドＣ−６、アルデヒドＣ−７、 アルデヒドＣ−８、アルデヒドＣ−９、アルデヒドＣ−１０、トリプラール、ｐ−エチルジメチルヒドロシンナミックアルデヒド（フローラゾン）、２−トリデセナール、アルデヒドＣ１１等が挙げられる。また、ケトン系香料としては、例えば、１−（５，５−ジメチル−１−シクロヘキセン-１-イル）−４−ペンテン−１−オン、アセトイン、メチルアミルケトン、エチルアミルケトン、メチルヘキシルケトン、メチルノニルケトン、メチルヘプテノン、コアボン、カンファー、カルボン、メントン、ｄ−プレゴン、ピペリトン、フェンチョン、ゲラニルアセトン、マルトール、エチルマルトール、２，５−ジメチル−４−ヒドロキシフラノン、プリカトン、アセトフェノン、ｐ−メチルアセトフェノン、ベンジルアセトン、ベンジルケトン等が挙げられる。 Specifically, natural flavors include, for example, lemon oil, orange oil, bergamot oil, ylang ylang oil, patchouli oil, citronella oil, lemongrass oil, boad rose oil, clove oil, eucalyptus oil, cedar oil, lavender oil, Examples include sandalwood oil, vetiver oil, geranium oil, labdanum oil, mint oil, peppermint oil, rose oil, jasmine oil, and litz acbeba oil. Examples of the hydrocarbon-based fragrances include limonene, α-pinene, camphene, p-cymene, and fenchen. Examples of the ether perfume include tetrahydro-2,4-dimethyl-4-phenylfuran, 1,8-cineole, rose oxide, cedrol methyl ether (cedlum bar), p-cresyl methyl ether, and isoamyl phenylethyl. Examples include ether, 4-phenyl-2,4,6-trimethyl-1,3-dioxane, and anethole. Examples of ester flavors include geranyl acetate, ethyl acetate, ethyl propionate, methyl butyrate, ethyl isobutyrate, ethyl butyrate, butyl acetate, ethyl 2-methylbutyrate, isoamyl acetate, ethyl 2- Methylpentanoate (manzanate), hexyl acetate, allyl hexanoate, tricyclodecenyl propionate (VERTOPRO; fluorocyclene), allyl heptanoate, isobornyl acetate, linalyl acetate, citronellyl acetate, 2-ter -Butyl cyclohexyl acetate (narcidol) etc. are mentioned. Examples of alcohol-based fragrances include linanol, 3-octanol, 2,6-dimethyl-heptanol, 10-undecenol, geraniol, nerol, citronellol, rosinol, myrsenol, tetrahydrolinalol, terpineol, cedrol, 2,4-dimethyl. -3-cyclohexane-1-methanol, 4-isopropylcyclohexanol, nerolidol, 9-decenol, cis-3-hexenol, trans-2-hexenol, eugenol and the like. Examples of the aldehyde perfume include citronellal, octanal, para aldehyde, benzaldehyde, aldehyde C-6, aldehyde C-7, aldehyde C-8, aldehyde C-9, aldehyde C-10, tripral, and p-ethyldimethyl. Hydrocinnamic aldehyde (florazone), 2-tridecenal, aldehyde C11 and the like can be mentioned. Examples of the ketone flavor include 1- (5,5-dimethyl-1-cyclohexen-1-yl) -4-penten-1-one, acetoin, methyl amyl ketone, ethyl amyl ketone, methyl hexyl ketone, Methyl nonyl ketone, methyl heptenone, coabon, camphor, carvone, menthone, d-pulegone, piperiton, fenchon, geranylacetone, maltol, ethyl maltol, 2,5-dimethyl-4-hydroxyfuranone, plicatone, acetophenone, p-methylacetophenone , Benzylacetone, benzylketone and the like.
これらの香料成分は、単品香料として１種単独で使用してもよく、また調合香料として２種以上を組み合わせて使用してもよい。 These fragrance | flavor components may be used individually by 1 type as a single item fragrance | flavor, and may be used in combination of 2 or more types as a mixing | blending fragrance | flavor.
本発明の水洗トイレ用液体芳香洗浄剤組成物において、上記(C)成分の含有量については、(C)成分の種類や備えさせる香気の強さ等に応じて適宜設定すればよいが、例えば０．１〜２０重量％、好ましくは１〜１５重量％、更に好ましくは２〜１５重量％が挙げられる。 In the liquid fragrance cleaning composition for flush toilets of the present invention, the content of the component (C) may be appropriately set according to the type of component (C), the intensity of the fragrance to be provided, etc. 0.1 to 20 weight%, Preferably it is 1 to 15 weight%, More preferably, 2 to 15 weight% is mentioned.
その他の成分
本発明の水洗トイレ用液体芳香洗浄剤組成物では、その基剤成分として水を含んでいてもよい。即ち、本発明の水洗トイレ用液体芳香洗浄剤組成物の一態様として、上記(A)〜（C）成分及び必要に応じて添加される他の配合成分以外の残部は水で構成されるものが挙げられる。
本発明の水洗トイレ用液体芳香洗浄剤組成物において、水を含有する場合、その含有量については、特に制限されないが、例えば０．１〜８０重量％、好ましくは１〜７０重量％、更に好ましくは２〜６０重量％が挙げられる。
Other components The liquid fragrance cleaning composition for flush toilets of the present invention may contain water as a base component. That is, as an aspect of the liquid fragrance cleaning composition for flush toilets of the present invention, the remainder other than the above-mentioned components (A) to (C) and other blending components added as necessary is composed of water. Is mentioned.
In the liquid fragrance cleaning composition for flush toilets of the present invention, when water is contained, the content thereof is not particularly limited, but is, for example, 0.1 to 80% by weight, preferably 1 to 70% by weight, and more preferably. 2 to 60% by weight.
本発明の水洗トイレ用液体芳香洗浄剤組成物は、洗浄効果を高めるために、上記(A)及び(B)成分以外の界面活性剤を更に含んでいてもよい。このような界面活性剤としては、具体的には、両性界面活性剤、上記(A)及び(B)成分以外の非イオン性界面活性剤、陽イオン性界面活性剤、陰イオン性界面活性剤等が挙げられる。 In order to enhance the cleaning effect, the liquid fragrance cleaning composition for flush toilets of the present invention may further contain a surfactant other than the above components (A) and (B). As such surfactants, specifically, amphoteric surfactants, nonionic surfactants other than the above components (A) and (B), cationic surfactants, anionic surfactants Etc.
より具体的には、両性界面活性剤として、ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン、ラウリルジメチルアミノ酢酸ベタイン、ラウリン酸アミドプロピルベタイン、2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾリニウムベタイン、ラウリルヒドロキシスルホベタイン等のベタイン型両性界面活性剤；β−ラウリルアミノプロピオン酸ナトリウム、ラウリルジアミノエチルグリシンナトリウム等のアミノ酸型両性界面活性剤；デシルジメチルアミンオキシド、ラウリルジメチルアミンオキシド等のアミンオキシド型両性界面活性剤等が挙げられる。 More specifically, as amphoteric surfactants, palm oil fatty acid amidopropyl dimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, lauric acid amidopropyl betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium Betaine-type amphoteric surfactants such as betaine and laurylhydroxysulfobetaine; amino acid-type amphoteric surfactants such as sodium β-laurylaminopropionate and sodium lauryldiaminoethylglycine; amine oxides such as decyldimethylamine oxide and lauryldimethylamine oxide Type amphoteric surfactants and the like.
また、上記(A)及び(B)成分以外の非イオン性界面活性剤としては、モノステアリン酸グリセリル、自己乳化型モノステアリン酸グリセリル、モノイソステアリン酸グリセリル等のグリセリン脂肪酸エステル；モノステアリン酸ＰＯＥグリセリル、モノオレイン酸ＰＯＥグリセリル等のポリオキシエチレングリセリン脂肪酸エステル；モノステアリン酸ジグリセリル、トリステアリン酸テトラグリセリル、ペンタステアリン酸デカグリセリル等のポリグリセリン脂肪酸エステル；モノラウリン酸ソルビタン、セスキステアリン酸ソルビタン、モノオレイン酸ソルビタン等のソルビタン脂肪酸エステル；モノヤシ脂肪酸ＰＯＥソルビタン、トリステアリン酸ＰＯＥソルビタン、トリオレイン酸ＰＯＥソルビタン等のポリオキシエチレンソルビタン脂肪酸エステル；モノラウリン酸ＰＯＥソルビット、テトラオレイン酸ＰＯＥソルビット等のポリオキシエチレンソルビット脂肪酸エステル；モノラウリン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、モノオレイン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール等のポリエチレングリコール脂肪酸エステル；プロピレングリコールモノラウリン酸エステル、プロピレングリコールモノミリスチン酸エステル等のアルキレングリコールモノ脂肪酸エステル類；グリセリンモノドデシルエーテル、グリセリンモノセチルエーテル、グリセリンモノステアリルエーテル、ペンタエリスリトールモノドデシルエーテル等のアルキル多価アルコールエーテル；ラウリルエーテル、ＰＯＥセチルエーテル、ＰＯＥステアリルエーテル等のポリオキシエチレンアルキルエーテル；ＰＯＥ・ＰＯＰセチルエーテル、ＰＯＥ・ＰＯＰデシルテトラデシルエーテル等のポリオキシエチレンポリオキシプロピレンアルキルエーテル；ＰＯＥノニルフェニルエーテル、ＰＯＥオクチルフェニルエーテル、ＰＯＥ分鎖オクチルフェニルエーテル等のポリオキシエチレンアルキルフェニルエーテル；ＰＯＥステアリルアミン、ＰＯＥオレイルアミン等のポリオキシエチレンアルキルアミン；ヤシ脂肪酸ジエタノールアミド、ラウリン酸ジエタノールアミド、パーム核油脂肪酸ジエタノールアミド等の脂肪酸アルカノールアミド；ラウリン酸メチルグルカミド、ヤシ脂肪酸メチルグルカミド等のアシルメチルグルカミド；その他アセチレングリコール、ＰＯＥアセチレングリコール、ＰＯＥラノリン、ＰＯＥラノリンアルコール、ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油、ＰＯＥフィトステロール、ＰＯＥコレスタノール、ＰＯＥノニルフェニルホルムアルデヒド縮合物、アルキルポリグルコシド等が挙げられる。 Examples of nonionic surfactants other than the above components (A) and (B) include glyceryl fatty acid esters such as glyceryl monostearate, glyceryl monostearate and glyceryl monoisostearate; POE glyceryl monostearate Polyoxyethylene glyceryl fatty acid esters such as POE glyceryl monooleate; polyglycerin fatty acid esters such as diglyceryl monostearate, tetraglyceryl tristearate, decaglyceryl pentastearate; sorbitan monolaurate, sorbitan sesquistearate, monoolein Sorbitan fatty acid esters such as acid sorbitan; polyoxyethylene sorbitan fats such as monococonut fatty acid POE sorbitan, tristearic acid POE sorbitan, trioleic acid POE sorbitan Acid esters; polyoxyethylene sorbite fatty acid esters such as monolauric acid POE sorbite and tetraoleic acid POE sorbite; polyethylene glycol fatty acid esters such as polyethylene glycol monolaurate, polyethylene glycol monostearate, polyethylene glycol monooleate, polyethylene glycol distearate; Alkylene glycol monofatty acid esters such as propylene glycol monolaurate and propylene glycol monomyristate; alkyl polyhydric alcohol ethers such as glycerol monododecyl ether, glycerol monocetyl ether, glycerol monostearyl ether, pentaerythritol monododecyl ether; lauryl Ether, POE cetyl ether, Polyoxyethylene alkyl ethers such as OE stearyl ether; Polyoxyethylene polyoxypropylene alkyl ethers such as POE · POP cetyl ether and POE · POP decyl tetradecyl ether; POE nonylphenyl ether, POE octylphenyl ether, POE branched octylphenyl Polyoxyethylene alkylphenyl ethers such as ethers; Polyoxyethylene alkylamines such as POE stearylamine and POE oleylamine; Fatty acid alkanolamides such as coconut fatty acid diethanolamide, lauric acid diethanolamide, and palm kernel oil fatty acid diethanolamide; Methyl gluca laurate Acyl methyl glucamide such as amide and palm fatty acid methyl glucamide; Other acetylene glycol, POE acetylene Glycol, POE lanolin, POE lanolin alcohol, POE castor oil, POE hydrogenated castor oil, POE phytosterol, POE cholestanol, POE nonylphenylformaldehyde condensate, alkylpolyglucoside and the like.
また、陰イオン性界面活性剤としては、セッケン用素地、ラウリン酸ナトリウム、パルミチン酸ナトリウム、ヤシカリセッケン等の脂肪酸塩；ＰＯＥラウリルエーテルカルボン酸塩、ＰＯＰ・ＰＯＥエーテルミリスチン酸塩；高級アルキル硫酸エステル塩（例えばラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ラウリル硫酸トリエタノールアミン等）等のアルキルエーテルカルボン酸塩；ＰＯＥラウリル硫酸トリエタノールアミン、ＰＯＥラウリル硫酸ナトリウム等のアルキルエーテル硫酸エステル塩；ラウロイルサルコシンナトリウム、ラウロイル−Ｎ−メチル−β−アラニンナトリウム、Ｎ−ラウロイルグルタミン酸モノナトリウム、Ｎ−ステアロイルグルタミン酸ジナトリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸モノナトリウム、Ｎ−パルミトイルアスパラギン酸ジエタノールアミン等のＮ−アシルアミン酸塩；Ｎ−ミリストイル−Ｎ−メチルタウリンナトリウム、ヤシ脂肪酸メチルタウリンナトリウム、ラウロイルメチルタウリンナトリウム、ＰＯＥラウリルアミドエーテルスルホン酸ナトリウム等の高級脂肪酸アミドスルホン酸塩；ＰＯＥオレイルエーテルリン酸ナトリウム、ＰＯＥステアリルエーテルリン酸、ＰＯＥラウリルアミドエーテルリン酸ナトリウム等のリン酸エステル塩；ジ−２−エチルヘキシルスルホコハク酸ナトリウム、モノラウロイルモノエタノールアミドポリオキシエチレンスルホコハク酸ナトリウム、ラウリルポリプロピレングリコールスルホコハク酸ナトリウム等のスルホコハク酸塩；リニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン、リニアドデシルベンゼンスルホン酸等のアルキルベンゼンスルホン酸塩；硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム、ロート油などの硫酸化油、α−オレフィンスルホン酸塩、高級脂肪酸エステルスルホン酸塩、二級アルコール硫酸エステル塩等の高級脂肪酸エステル硫酸エステル塩；ラウロイルモノエタノールアミドコハク酸ナトリウム、及びカゼインナトリウム等の高級脂肪酸アルキロールアミド硫酸エステル塩；アルキル硫酸エステル塩、ポリオキシエチレンアルキル硫酸エステル塩、脂肪酸アミドエーテル硫酸エステル塩、アシルイセチオン酸塩、スルホコハク酸塩等の硫酸エステル塩型またはスルホン酸塩型界面活性剤；エーテルカルボン酸塩、脂肪酸アミドエーテルカルボン酸塩、Ｎ−アシルイミノジ酢酸、Ｎ−アシルアミノ酸塩等のカルボン酸型界面活性剤等が挙げられる。 Examples of the anionic surfactant include soap bases, fatty acid salts such as sodium laurate, sodium palmitate, coconut soap, POE lauryl ether carboxylate, POP / POE ether myristate; higher alkyl sulfates Alkyl ether carboxylates such as salts (for example, sodium lauryl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate); alkyl ether sulfate esters such as POE lauryl sulfate triethanolamine, sodium POE lauryl sulfate; lauroyl sarcosine sodium, lauroyl -N-methyl-β-alanine sodium, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamate N-acylamine salts such as N-palmitoyl aspartate diethanolamine; higher fatty acid amide sulfonic acids such as N-myristoyl-N-methyl taurine sodium, palm fatty acid methyl taurine sodium, lauroyl methyl taurine sodium, POE sodium lauryl amide ether sulfonate Salts; phosphate ester salts such as sodium POE oleyl ether phosphate, POE stearyl ether phosphate, sodium POE laurylamide ether phosphate; sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, Sulfosuccinates such as sodium lauryl polypropylene glycol sulfosuccinate; sodium linear dodecyl benzene sulfonate; Alkylbenzene sulfonates such as triethanolamine and linear dodecyl benzene sulfonates; hydrogenated coconut oil fatty acid sodium glycerine sulfate, sulfated oil such as funnel oil, α-olefin sulfonate, higher fatty acid ester sulfonate Higher fatty acid ester sulfates such as secondary alcohol sulfates; higher fatty acid alkylolamide sulfates such as sodium lauroyl monoethanolamide succinate and sodium caseinate; alkyl sulfates, polyoxyethylene alkyl sulfates , Fatty acid amide ether sulfates, acyl isethionates, sulfosuccinates and other sulfate ester type or sulfonate type surfactants; ether carboxylates, fatty acid amide ether catalysts Bonn salt, N- Ashiruiminoji acid, a carboxylic acid type surface active agents such as N- acylamino acid salts.
また、陽イオン性界面活性剤としては、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ジステアリルトリメチルアンモニウム、塩化セチルピリジニウム、塩化アルキルジメチルベンジルアンモニウム、塩化ベンゼトニウム、塩化ベンザルコニウム等の第４級アンモニウム塩界面活性剤；ステアリン酸ジエチルアミノエチルアミドグルタミン酸塩、ラノリン脂肪酸ジエチルアミノエチルアミドグルタミン酸塩等のアミドアミン塩型カチオン性界面活性剤；ラウリン酸アミドグアニジン塩酸塩等が挙げられる。 As the cationic surfactant, quaternary ammonium such as cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyltrimethylammonium chloride, cetylpyridinium chloride, alkyldimethylbenzylammonium chloride, benzethonium chloride, benzalkonium chloride and the like. Salt surfactants; amidoamine salt type cationic surfactants such as stearic acid diethylaminoethylamide glutamate and lanolin fatty acid diethylaminoethylamide glutamate; lauric acid amidoguanidine hydrochloride and the like.
これらの(A)及び(B)成分以外の界面活性剤については、１種単独で使用してもよく、また２種以上を組み合わせて使用してもよい。 About surfactants other than these (A) and (B) components, you may use individually by 1 type and may be used in combination of 2 or more type.
本発明の水洗トイレ用液体芳香洗浄剤組成物において(A)及び(B)成分以外の界面活性剤を配合する場合、当該界面活性剤の含有量については、特に制限されないが、例えば０．１〜２０重量％、好ましくは０．２〜１５重量％、更に好ましくは０．５〜１０重量％が挙げられる。 In the case of blending a surfactant other than the components (A) and (B) in the liquid fragrance cleaning composition for flush toilets of the present invention, the content of the surfactant is not particularly limited. -20% by weight, preferably 0.2-15% by weight, more preferably 0.5-10% by weight.
更に、水洗トイレ用液体芳香洗浄剤組成物は、必要に応じて、可溶化剤を含んでいてもよい。可溶化剤を含むことによって、各種配合成分に良好な溶解性や分散性を付与することが可能になる。本発明に使用される可溶化剤としては、特に制限されないが、例えば、プロピレングリコール、エチレングリコール、エタノール、ジプロピレングリコール、グリセリン、２−メトキシエタノール、２−エトキシエタノール、３−メトキシ−３−メチルブタノール等が挙げられる。本発明の水洗トイレ用液体芳香洗浄剤組成物において可溶化剤を配合する場合、当該可溶化剤の含有量については、特に制限されないが、例えば０．１〜１０重量％、好ましくは０．２〜８重量％、更に好ましくは０．５〜６重量％が挙げられる。 Furthermore, the liquid fragrance cleaning composition for flush toilets may contain a solubilizer as necessary. By including a solubilizing agent, it is possible to impart good solubility and dispersibility to various blending components. The solubilizer used in the present invention is not particularly limited. For example, propylene glycol, ethylene glycol, ethanol, dipropylene glycol, glycerin, 2-methoxyethanol, 2-ethoxyethanol, 3-methoxy-3-methyl. Examples include butanol. When the solubilizer is blended in the liquid fragrance cleaning composition for flush toilets of the present invention, the content of the solubilizer is not particularly limited, but is, for example, 0.1 to 10% by weight, preferably 0.2. -8% by weight, more preferably 0.5-6% by weight.
また、水洗トイレ用液体芳香洗浄剤組成物には、更に必要に応じて、酵素、殺菌剤、キレート剤、着色剤、顔料、消臭剤、油性成分の乳化可溶化剤、増量剤、溶解性調整剤、漂白剤、撥水剤、親水剤、充填剤、ｐＨ調整剤、増粘剤、成形性向上剤、滑沢剤、緩衝剤、白濁化剤、消泡剤等の添加剤を適量含むことができる。 In addition, liquid fragrance cleaning compositions for flush toilets may further include enzymes, bactericides, chelating agents, colorants, pigments, deodorants, emulsifying and solubilizing agents for oily components, extenders, and solubility as necessary. Contains appropriate amounts of additives such as regulators, bleaches, water repellents, hydrophilic agents, fillers, pH adjusters, thickeners, moldability improvers, lubricants, buffers, clouding agents, antifoaming agents, etc. be able to.
本発明に使用される酵素としては、具体的には、プロテアーゼ、リパーゼ、アミラーゼ、セルラーゼ、キシラナーゼ、マンナーゼ等が例示される。 Specific examples of the enzyme used in the present invention include protease, lipase, amylase, cellulase, xylanase, and mannase.
本発明に使用される殺菌剤としては、具体的には、アルキルベンジルジメチルアンモニウム塩、ジデシルジメチルアンモニウム塩等の第４級アンモニウム塩；セチルピリジニウム塩、ベンゾイソチアゾリン等の複素環化合物；ポリヘキサメチレンビグアナイド塩酸塩、ポリヘキサメチレングアニジン塩酸塩、塩酸クロルヘキシジン等のグアニジン系化合物；酸化銀、銀含有の水溶性ガラス、銀を担持させたゼオライト等の銀化合物；その他金属化合物等が例示される。 Specific examples of the bactericidal agent used in the present invention include quaternary ammonium salts such as alkylbenzyldimethylammonium salt and didecyldimethylammonium salt; heterocyclic compounds such as cetylpyridinium salt and benzisothiazoline; polyhexamethylene Examples include guanidine-based compounds such as biguanide hydrochloride, polyhexamethylene guanidine hydrochloride, chlorhexidine hydrochloride; silver oxide, silver-containing water-soluble glass, silver compounds such as zeolite supporting silver; and other metal compounds.
本発明に使用されるキレート剤としては、具体的には、エチレンジアミン四酢酸（ＥＤＴＡ）、ニトリロ三酢酸、ヒドロキシエチルイミノ二酢酸、ジヒドロキシエチルグリシン、ヒドロキシエチレンジアミン三酢酸、ジエチレントリアミン五酢酸、トリエチレンテトラミン六酢酸、及びそれらの塩等が例示される。 Specific examples of the chelating agent used in the present invention include ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid, hydroxyethyliminodiacetic acid, dihydroxyethylglycine, hydroxyethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid, triethylenetetramine hexa Examples include acetic acid and salts thereof.
本発明に使用される着色剤としては、具体的には、青色１号、青色２号、青色３号、青色２０５号、黄色３号、黄色４号、黄色２０２号の（１）、黄色２０３号、赤色１０５号、赤色１０６号、赤色２号及び赤色３号等が例示される。 Specific examples of the colorant used in the present invention include blue No. 1, blue No. 2, blue No. 3, blue No. 205, yellow No. 3, yellow No. 4, yellow No. 202 (1), yellow 203. No., Red No. 105, Red No. 106, Red No. 2 and Red No. 3 and the like.
本発明に使用される顔料は、有機顔料又は無機顔料のいずれであってもよい。また、白色顔料又は有色顔料の別も問うものではなく、水洗トイレ用液体芳香洗浄剤組成物に付与する色調に応じて適宜選択すればよい。無機顔料の具体例としては、酸化チタン、タルク、炭酸カルシウム、酸化亜鉛、硫化亜鉛、硫酸バリウム、硫酸カルシウム及びその水和物、酸化鉄、硫化カドミウム、クロム酸鉛、クロム酸亜鉛、カーボンブラック等が例示される。有機顔料としては赤色２０１号、赤色２０２号、赤色２０３号、赤色２０４号、赤色２０５号、赤色２０６号、赤色２０７号、赤色２０８号、赤色２２０号、赤色２２１号、橙色２０３号、橙色２０４号、黄色２０５号、赤色４０４号、赤色４０５号、黄色４０１号、青色４０４号等が例示される。 The pigment used in the present invention may be either an organic pigment or an inorganic pigment. Moreover, it does not ask | require the distinction of a white pigment or a colored pigment, What is necessary is just to select suitably according to the color tone provided to the liquid fragrance cleaning composition for flush toilets. Specific examples of inorganic pigments include titanium oxide, talc, calcium carbonate, zinc oxide, zinc sulfide, barium sulfate, calcium sulfate and its hydrate, iron oxide, cadmium sulfide, lead chromate, zinc chromate, carbon black, etc. Is exemplified. As organic pigments, red 201, red 202, red 203, red 204, red 205, red 206, red 207, red 208, red 220, red 221, orange 203, orange 204 No., yellow 205, red 404, red 405, yellow 401, blue 404, and the like.
物性
本発明の水洗トイレ用液体芳香洗浄剤組成物は、２５℃での粘度が６０〜８００ｍＰａ・ｓを充足する。このような粘度範囲を充足することにより、温度変化や水の混入を受けても、粘度変化を容器からの毎排出量を均一にできる範囲に保持でき、トイレ用液体洗浄剤として適した特性を備えさせることができる。
Physical Properties The liquid fragrance cleaning composition for flush toilets of the present invention satisfies a viscosity at 25 ° C. of 60 to 800 mPa · s. By satisfying such a viscosity range, even if it receives temperature change or water mixing, it can keep the viscosity change in a range where the discharge amount from the container can be made uniform, and has characteristics suitable as a liquid cleaning agent for toilets. Can be provided.
本発明の水洗トイレ用液体芳香洗浄剤組成物の２５℃での粘度として、好ましくは６０〜８００ｍＰａ・ｓ、更に好ましくは７０〜６００ｍＰａ・ｓ、最も好ましくは８０〜３００ｍＰａ・ｓが挙げられる。ここで、当該粘度は、１００ｍＰａ・ｓ未満の範囲は、Ｂ型粘度計（ＴＶ−１０型、東機産業株式会社製）でSPINDLE No-M1のローターを用いて、２５℃にて３０ｒｐｍの回転速度で測定され、１００ｍＰａ・ｓ以上の範囲は、Ｂ型粘度計（ＴＶ−１０型、東機産業株式会社製）でSPINDLE No-M2のローターを用いて、２５℃にて３０ｒｐｍの回転速度で測定される。 The viscosity at 25 ° C. of the liquid aromatic cleaning composition for flush toilets of the present invention is preferably 60 to 800 mPa · s, more preferably 70 to 600 mPa · s, and most preferably 80 to 300 mPa · s. Here, in the range of less than 100 mPa · s, the viscosity is 30 rpm at 25 ° C. using a SPINDLE No-M1 rotor with a B-type viscometer (TV-10 type, manufactured by Toki Sangyo Co., Ltd.). The range of 100 mPa · s or higher is measured at a speed of 30 rpm at 25 ° C. using a SPINDLE No-M2 rotor with a B-type viscometer (TV-10 type, manufactured by Toki Sangyo Co., Ltd.). Measured.
使用態様
本発明の水洗トイレ用液体芳香洗浄剤組成物は、洗浄対象となる便器にそのまま塗布して洗浄に使用してもよいが、フラッシュ水で希釈して、水洗トイレのフラッシュ時にフラッシュ水を用いた便器の洗浄に使用することが好ましい。本発明の水洗トイレ用液体芳香洗浄剤組成物をフラッシュ水に希釈して使用する場合、その希釈倍率については、特に制限されないが、例えば１万〜１００万倍程度、好ましくは２万〜５０万倍程度が挙げられる。
Use Mode The liquid fragrance cleaning composition for flush toilets of the present invention may be applied to the toilet bowl to be washed as it is and used for washing, but it is diluted with flush water, and flush water is used when flushing toilet flushes. It is preferable to use it for washing the toilet bowl used. When the liquid fragrance cleaning composition for flush toilets of the present invention is used after being diluted in flush water, the dilution ratio is not particularly limited, but is, for example, about 10,000 to 1,000,000 times, preferably 20,000 to 500,000. About double.
発明の水洗トイレ用液体芳香洗浄剤組成物をフラッシュ水に希釈して使用する場合、本発明の水洗トイレ用液体芳香洗浄剤組成物は、水洗トイレのオンタンク用の洗浄剤として使用してもよく、またリム部用の洗浄剤として使用してもよい。ここで、オンタンク用の洗浄剤とは、水洗トイレの手洗い部の上に設置して使用されるものであって、液体芳香洗浄剤組成物が収容された容器に、手洗い部に供給された洗浄用のフラッシュ水と接触することにより、当該液体芳香洗浄剤組成物が容器から流出され、液体芳香洗浄剤組成物が溶け込んだフラッシュ水が便器内に放出されることによって便器を洗浄する洗浄剤である。また、リム部用の洗浄剤とは、水洗トイレのリム部に取り付けて使用されるものであって、液体芳香洗浄剤組成物が収容された容器に、便器に放出されるフラッシュ水が接触することにより、当該液体芳香洗浄剤組成物が容器から流出され、液体芳香洗浄剤組成物が溶け込んだフラッシュ水が便器内に放出されることによって便器を洗浄する洗浄剤である。 When the liquid fragrance cleaning composition for flush toilets of the invention is used after being diluted in flush water, the liquid fragrance cleaning composition for flush toilets of the present invention may be used as a cleaning agent for on-tanks of flush toilets. Moreover, you may use as a washing | cleaning agent for rim parts. Here, the cleaning agent for on-tank is used by being installed on the hand-washing part of the flush toilet, and the washing supplied to the hand-washing part in the container containing the liquid aromatic detergent composition A cleaning agent that cleans the toilet bowl by contacting the flush water for use with the liquid fragrance cleaning composition and then flushing the liquid fragrance cleaning composition into the toilet bowl. is there. The rim cleaning agent is used by being attached to the rim of a flush toilet, and the flush water discharged to the toilet comes into contact with the container containing the liquid fragrance cleaning composition. Thus, the liquid fragrance cleaning composition flows out of the container, and flush water in which the liquid fragrance cleaning composition is dissolved is discharged into the toilet bowl, thereby cleaning the toilet bowl.
本発明の液体芳香洗浄剤組成物によれば、温度変化等による排出量の不均一性が改善されているので、水洗トイレのオンタンク用の洗浄剤やリム部用の洗浄剤として使用される場合であっても、共に流されるフラッシュ水の温度は通常の範囲であれば限定されず、冷水や温水も使用できる。 According to the liquid fragrance cleaning composition of the present invention, since the non-uniformity of the discharge amount due to a temperature change or the like is improved, the liquid fragrance cleaning composition is used as a cleaning agent for an on-tank of a flush toilet or a cleaning agent for a rim portion. However, the temperature of the flush water that flows together is not limited as long as it is in a normal range, and cold water or hot water can also be used.
本発明の液体芳香洗浄剤組成物を水洗トイレのオンタンク用の洗浄剤又はリム部用の洗浄剤として使用する場合、当該液体芳香洗浄剤組成物を収容する容器については、当該液体芳香洗浄剤組成物を収容する収容部と、当該液体芳香洗浄剤組成物を容器外に排出するための排出孔を備え、当該容器が水と接触すると、収容部内の当該液体芳香洗浄剤組成物が当該排出孔を介して容器外に排出可能であることを限度として、その構造については、特に制限されず、水洗トイレのオンタンク用の洗浄剤用の容器又はリム部用の洗浄剤用の容器として、従来使用されているものを用いることができる。例えば、オンタンク用の洗浄剤用の容器の構造については、特開２００４−３００８６１号、特開２００６−２８３５３９号公報、特開２００６−２８３５４０号公報等に開示されている。また、リム部用の洗浄剤用の容器の構造については、特表２００３−５１７１２４号、特開２００９−５７７６９号、特開２０１０−２４２４８０号公報等に開示されている。但し、本発明の液体芳香洗浄剤組成物を収容する容器の構造については、オンタンク用又はリム部用として使用し得る限り、これらの容器に限定されるものではない。 When the liquid fragrance cleaning composition of the present invention is used as a cleaning agent for an on-tank of a flush toilet or a cleaning agent for a rim part, the liquid fragrance cleaning composition is used for a container containing the liquid fragrance cleaning composition. A container for storing the product, and a discharge hole for discharging the liquid fragrance cleaning composition to the outside of the container. When the container comes into contact with water, the liquid fragrance cleaning composition in the storage section is discharged into the discharge hole. The structure is not particularly limited as long as it can be discharged out of the container through the wall, and is conventionally used as a container for a cleaning agent for an on-tank of a flush toilet or a container for a cleaning agent for a rim part. Can be used. For example, the structure of an on-tank cleaning agent container is disclosed in JP-A-2004-300861, JP-A-2006-283539, JP-A-2006-283540, and the like. Further, the structure of the cleaning agent container for the rim portion is disclosed in JP-T-2003-517124, JP-A-2009-57769, JP-A-2010-242480, and the like. However, the structure of the container containing the liquid fragrance cleaning composition of the present invention is not limited to these containers as long as it can be used for an on-tank or rim part.
以下、実施例を挙げて、本発明を説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated, this invention is not limited to these Examples.
試験例１
表１に示す各種非イオン性界面活性剤を使用して、表２〜６に示す各成分を所定量混合し、トイレ用液体芳香洗浄剤組成物を調製した。各トイレ用液体芳香洗浄剤組成物について、２５℃での香料成分の可溶化の状態、２５℃での粘度、５℃での粘度、及び水を混入させた後の５℃でのゲル化の有無について、以下の条件で測定を行った。
Test example 1
Using various nonionic surfactants shown in Table 1, predetermined amounts of the components shown in Tables 2 to 6 were mixed to prepare a toilet liquid fragrance cleaning composition. For each liquid fragrance cleaning composition for toilets, the state of solubilization of perfume ingredients at 25 ° C., the viscosity at 25 ° C., the viscosity at 5 ° C., and the gelation at 5 ° C. after mixing water The presence or absence was measured under the following conditions.
＜２５℃での香料成分の可溶化の状態＞
２５℃における各トイレ用液体芳香洗浄剤組成物の外観を評価するために、５００ｍL容量でφ９２ｍｍの透明ガラスビーカーを、黒文字（縦２０ｍｍ、横２０ｍｍ）を表示した白色紙状に設置し、このガラスビーカーに２５℃の各トイレ用液体芳香洗浄剤組成物５００ｇを入れて、ガラスビーカーの上面から黒文字を目視にて観察し、下記の判定基準に従って、各トイレ用液体芳香洗浄剤組成物における香料成分の可溶化の状態を評価した。
判定基準
○：黒文字がクリアに読める完全に透明な状態
△：黒文字がややぼやけているやや不透明な状態
×：黒文字が全く読めない不透明な状態
<State of solubilization of perfume ingredients at 25 ° C.>
In order to evaluate the appearance of each liquid fragrance cleaning composition for toilets at 25 ° C., a transparent glass beaker with a capacity of 500 mL and a diameter of 92 mm is placed on a white paper that displays black characters (vertical 20 mm, horizontal 20 mm). 500 g of liquid fragrance cleaning composition for each toilet at 25 ° C. is put into a beaker, black characters are visually observed from the upper surface of the glass beaker, and the fragrance components in the liquid fragrance cleaning composition for each toilet according to the following criteria The solubilization state of was evaluated.
Judgment criteria ○: Fully transparent state where black characters can be read clearly △: Black character is slightly blurred and slightly opaque ×: Opaque state where black characters cannot be read at all
＜２５℃での粘度＞
Ｂ型粘度計（ＴＶ−１０型、東機産業株式会社製）を用いて、２５℃にて３０ｒｐｍの回転速度で、各トイレ用液体芳香洗浄剤組成物の粘度を測定した。１００ｍＰａ・ｓ未満の範囲はSPINDLE No-M1のローターを用い、１００ｍＰａ・ｓ以上の範囲は、SPINDLE No-M2のローターを用いて行った。
<Viscosity at 25 ° C>
Using a B-type viscometer (TV-10 type, manufactured by Toki Sangyo Co., Ltd.), the viscosity of each liquid fragrance cleaning composition for toilets was measured at 25 ° C. and a rotation speed of 30 rpm. A range of less than 100 mPa · s was performed using a SPINDLE No-M1 rotor, and a range of 100 mPa · s or more was performed using a SPINDLE No-M2 rotor.
＜５℃での粘度＞
温度条件を５℃に変えたこと以外は、上記２５℃での粘度の測定と同条件で測定を行った。
<Viscosity at 5 ° C>
The measurement was performed under the same conditions as the measurement of the viscosity at 25 ° C., except that the temperature condition was changed to 5 ° C.
＜水を混入させた後の５℃でのゲル化の有無＞
各トイレ用液体芳香洗浄剤組成物８０ｇと水２０ｇを混合した後に、５℃の温度条件にして静置した。その後、ゲル化の有無を目視にて確認し、ゲル化していないものについては、５℃での粘度の測定を行った。当該度の測定条件は、温度条件を５℃に変えたこと以外は、上記２５℃での粘度の測定の場合と同様である。得られた結果を下記の判定基準に従って分類した。
判定基準
○：ゲル化が認められず、且つ５℃での粘度が１０００ｍＰａ・Ｓ未満である。
△：ゲル化が認められず、且つ５℃での粘度が１０００ｍＰａ・Ｓ以上５０００ｍＰａ・Ｓ未満である。
×：ゲル化が認められた、又は５℃での粘度が５０００ｍＰａ・Ｓ以上である。
<Presence / absence of gelation at 5 ° C. after mixing water>
After mixing 80 g of each liquid fragrance cleaning composition for toilet and 20 g of water, it was allowed to stand at a temperature of 5 ° C. Then, the presence or absence of gelation was confirmed visually, and the viscosity at 5 ° C. was measured for those that were not gelled. The measurement conditions for this degree are the same as those in the measurement of the viscosity at 25 ° C., except that the temperature conditions are changed to 5 ° C. The obtained results were classified according to the following criteria.
Judgment standard ( circle): Gelation is not recognized and the viscosity in 5 degreeC is less than 1000 mPa * S.
(Triangle | delta): Gelation is not recognized and the viscosity in 5 degreeC is 1000 mPa * S or more and less than 5000 mPa * S.
X: Gelation was recognized or the viscosity at 5 ° C. is 5000 mPa · S or more.
得られた結果を表２〜６に併せて示す。この結果から、本発明で規定する(A)及び(B)成分を併用した処方では、あらゆる種類の香料の可溶化が可能であり、且つ低温（５℃）での粘度も３００〜１０００ｍＰａ・ｓの範囲内になり、温度変化に晒されても、ゲル化せずに粘度変化を抑制できていた。これに対して、(A)又は(B)成分に該当しない２種のポリオシキアルキレンアルキルエーテルを使用した場合には、使用する香料成分の種類によっては、低温（５℃）でのゲル化が生じたり（比較例１参照）、香料成分を十分に可溶化できなかった（比較例６参照）。また、炭素数12又は13のアルキル基を有するが(B)成分には該当しないポリオキシアルキレンアルキルエーテルと、(A)成分との組み合わせの場合、及び炭素数10のアルキル基を有するが(A)成分には該当しないポリオキシアルキレンアルキルエーテルと、(B)成分との組み合わせの場合には、２５℃での粘性が著しく低くなったり、低温や水の混入によってゲル化して、トイレ用液体洗浄剤として要求される特性を満足できていなかった（比較例３〜５参照）。 The obtained result is combined with Tables 2-6, and is shown. From this result, in the prescription combined with the components (A) and (B) defined in the present invention, all kinds of perfume can be solubilized, and the viscosity at low temperature (5 ° C.) is also 300 to 1000 mPa · s. Even when exposed to a temperature change, the viscosity change could be suppressed without gelation. On the other hand, when two types of polyoxyalkylene alkyl ethers that do not fall under component (A) or (B) are used, depending on the type of fragrance component used, gelation at a low temperature (5 ° C) may occur. Produced (see Comparative Example 1), or the perfume component could not be sufficiently solubilized (see Comparative Example 6). Further, in the case of a combination of a polyoxyalkylene alkyl ether having an alkyl group having 12 or 13 carbon atoms but not corresponding to the component (B) and the component (A), and having an alkyl group having 10 carbon atoms (A ) In the case of a combination of polyoxyalkylene alkyl ether that does not fall under component and component (B), the viscosity at 25 ° C becomes extremely low, or gelation occurs due to low temperature or water contamination. The properties required as an agent were not satisfied (see Comparative Examples 3 to 5).
Claims (8)
Ｒ1−Ｏ−［（ＥＯ）a／（ＰＯ）b］−Ｈ （１）
[一般式(1)中、Ｒ1は炭素数８〜１１の直鎖状又は分岐状のアルキル基、ＥＯはオキシエチレン基、ＰＯはオキシプロピレン基、ａはＥＯの平均付加モル数で５≦ａ、ｂはＰＯの平均付加モル数で０≦ｂ、［（ＥＯ）a／（ＰＯ）b］はＥＯとＰＯのランダム付加又はブロック付加を示す。]、
(B)下記一般式(2)で表され、１重量％水溶液での曇点が８０℃以上であるポリオキシアルキレンアルキルエーテル型非イオン性界面活性剤
Ｒ2−Ｏ−［（ＥＯ）c／（ＰＯ）d］−Ｈ （２）
[一般式(2)中、Ｒ2は炭素数１２〜１４の直鎖状又は分岐状のアルキル基、ＥＯはオキシエチレン基、ＰＯはオキシプロピレン基、ｃはＥＯの平均付加モル数で１≦ｃ、ｄはＰＯの平均付加モル数で１≦ｄ、［（ＥＯ）c／（ＰＯ）d］はＥＯとＰＯのランダム付加又はブロック付加を示す。]、及び
(C)香料成分
を含有し、且つ
２５℃での粘度が６０〜８００ｍＰａ・ｓであることを特徴とする、水洗トイレ用芳香洗浄剤組成物。 (A) A polyoxyalkylene alkyl ether type nonionic surfactant R 1 represented by the following general formula (1), having an HLB value of 14.3 or less and a cloud point in a 1 wt% aqueous solution of 80 ° C. or less. -O-[(EO) a / (PO) b ] -H (1)
[In the general formula (1), R 1 is a linear or branched alkyl group having 8 to 11 carbon atoms, EO is an oxyethylene group, PO is an oxypropylene group, and a is an average added mole number of EO of 5 ≦ a and b are average addition mole numbers of PO, 0 ≦ b, and [(EO) a / (PO) b ] represents random addition or block addition of EO and PO. ],
(B) Polyoxyalkylene alkyl ether type nonionic surfactant R 2 —O — [(EO) c / represented by the following general formula (2) and having a cloud point of 80 ° C. or more in a 1 wt% aqueous solution. (PO) d ] -H (2)
[In General Formula (2), R 2 is a linear or branched alkyl group having 12 to 14 carbon atoms, EO is an oxyethylene group, PO is an oxypropylene group, and c is an average added mole number of EO of 1 ≦ c and d are average addition mole numbers of PO, 1 ≦ d, and [(EO) c / (PO) d ] indicates random addition or block addition of EO and PO. ],as well as
(C) A fragrance cleaning composition for flush toilets containing a fragrance component and having a viscosity at 25 ° C. of 60 to 800 mPa · s.
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| JP2012094752A JP5925571B2 (en) | 2012-04-18 | 2012-04-18 | Liquid fragrance cleaning composition for flush toilet |
| PCT/JP2013/061347 WO2013157561A1 (en) | 2012-04-18 | 2013-04-17 | Liquid aromatic cleaner composition for flushing toilets |
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| JP7308010B2 (en) * | 2016-12-28 | 2023-07-13 | 小林製薬株式会社 | surface smoothing agent |
| JP7178217B2 (en) * | 2018-09-06 | 2022-11-25 | 小林製薬株式会社 | detergent composition |
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