KR20010003057A - Method of forming resist pattern for semiconductor device - Google Patents

Method of forming resist pattern for semiconductor device Download PDF

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Publication number
KR20010003057A
KR20010003057A KR1019990023188A KR19990023188A KR20010003057A KR 20010003057 A KR20010003057 A KR 20010003057A KR 1019990023188 A KR1019990023188 A KR 1019990023188A KR 19990023188 A KR19990023188 A KR 19990023188A KR 20010003057 A KR20010003057 A KR 20010003057A
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South Korea
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pattern
resist
transmittance
resist pattern
interval
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KR1019990023188A
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Korean (ko)
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KR100376890B1 (en
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이철승
이희목
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김영환
현대전자산업 주식회사
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Priority to KR10-1999-0023188A priority Critical patent/KR100376890B1/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0273Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
    • H01L21/0274Photolithographic processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/26Phase shift masks [PSM]; PSM blanks; Preparation thereof
    • G03F1/32Attenuating PSM [att-PSM], e.g. halftone PSM or PSM having semi-transparent phase shift portion; Preparation thereof

Abstract

PURPOSE: A method for manufacturing a resist pattern of a semiconductor device is provided to uniformly control critical dimension of a contact hole in forming contact holes of different sizes, by performing an exposure regarding a resist layer using a reticle with patterns having different light transmissivities to make the resist patterns have the same volume, and by flowing the resist layer pattern. CONSTITUTION: A resist layer is applied on a semiconductor substrate. Exposure and developing processes are performed regarding the resist layer. The first resist pattern(32A1,32A2) which has the first height, the first width and the first volume and is separated by the first interval, is formed in the first region of the semiconductor substrate. The second resist pattern(32B1,32B2) which has the second height higher than the first height, the second width wider than the first width and the second volume which is almost the same as the first volume, is separated by the second interval broader than the first interval, is formed in the second region of the substrate. The first and second resist patterns are flowed.

Description

반도체 소자의 레지스트 패턴 형성방법{Method of forming resist pattern for semiconductor device}Method of forming resist pattern for semiconductor device

본 발명은 반도체 소자의 제조방법에 관한 것으로, 특히 고집적화에 따른 미세한 콘택홀을 구현할 수 있는 반도체 소자의 레지스트 패턴 형성방법에 관한 것이다.The present invention relates to a method of manufacturing a semiconductor device, and more particularly, to a method of forming a resist pattern of a semiconductor device capable of realizing a fine contact hole according to high integration.

최근 고집적화에 따른 미세한 콘택홀을 형성하기 위한 광파장의 한계를 극복하기 위하여 레지스트 플로우 기술이 제시되었다.In order to overcome the limitations of the optical wavelength for forming fine contact holes due to the recent high integration, a resist flow technique has been proposed.

도 1a 및 도 1b는 상기한 레지스트 플로우 기술을 이용한 레지스트 패턴 형성방법을 설명하기 위한 단면도이다.1A and 1B are cross-sectional views illustrating a method of forming a resist pattern using the resist flow technique described above.

도 1a를 참조하면, 상부에 절연막(11)이 형성된 반도체 기판(10) 상에 레지스트막을 도포하고 노광 및 현상하여, 제 1 간격(A1)으로 이격된 레지스트 패턴 (12)을 형성한다. 그런 다음, 레지스트 패턴(12)을 열공정으로 플로우시켜 그의 수직 프로파일을 완만하게 하여, 도 1b에 도시된 바와 같이, 레지스트 패턴(12) 사이의 간격을 제 1 간격(A1) 보다 작은 제 2 간격(A2)으로 감소시킨다. 그 후, 도시되지는 않았지만, 레지스트 패턴(12)을 식각 마스크로하여 기판(10)이 노출되도록 절연막(11)을 식각하여 제 2 간격(A2)의 크기를 갖는 콘택홀을 형성한다.Referring to FIG. 1A, a resist film is coated, exposed, and developed on a semiconductor substrate 10 having an insulating film 11 formed thereon to form a resist pattern 12 spaced at a first interval A1. Then, the resist pattern 12 is flowed in a thermal process to smooth its vertical profile, so that the gap between the resist patterns 12 is smaller than the first gap A1 as shown in FIG. 1B. Decrease to (A2). Thereafter, although not illustrated, the insulating layer 11 is etched to expose the substrate 10 by using the resist pattern 12 as an etching mask to form a contact hole having a size of the second gap A2.

레지스트 패턴의 플로우에 의해 그들 사이의 간격이 좁혀지기 때문에, 고집적화에 따른 콘택홀 형성이 가능하다.Since the gap between them is narrowed by the flow of the resist pattern, contact holes can be formed due to high integration.

한편, 레지스트량은 콘택홀의 크기 및 광파형의 듀티비(duty ratio)에 따라 다르다. 따라서, 상기한 바와 같이, 동일한 크기의 콘택홀을 형성하는 경우에는 광파형의 듀티비가 동일하고 레지스트량이 동일하기 때문에 콘택홀의 CD(Critical Dimension) 조절이 용이하다. 반면, 서로 다른 크기의 콘택홀을 형성하는 경우에는 광파형의 듀티비가 서로 다르기 때문에 레지스트 패턴의 폭 및 그들 사이의 간격이 서로 다르다. 이에 따라, 레지스트 패턴의 부피가 서로 다르고 플로우시 레지스트 패턴의 플로우량 차이로 인하여 콘택홀의 균일한 CD 조절이 용이하지 못하므로, 고집적화에 따른 콘택홀을 구현하는데 어려움이 있다.On the other hand, the resist amount depends on the size of the contact hole and the duty ratio of the light waveform. Therefore, as described above, in the case of forming contact holes having the same size, the duty ratio of the light waveform is the same and the amount of the resist is the same, so it is easy to adjust the CD (critical dimension) of the contact holes. On the other hand, in the case of forming contact holes of different sizes, since the duty ratios of the optical waveforms are different from each other, the widths of the resist patterns and the intervals therebetween are different. Accordingly, since the volume of the resist pattern is different from each other and the flow volume of the resist pattern is not easily adjusted, uniform CD adjustment of the contact hole is not easy, and thus, there is a difficulty in implementing the contact hole due to high integration.

따라서, 본 발명은 상기한 종래의 문제점을 해결하기 위한 것으로서, 서로 다른 크기의 미세한 콘택홀을 용이하게 구현할 수 있는 반도체 소자의 레지스트 패턴 형성방법을 제공함에 그 목적이 있다.Accordingly, an object of the present invention is to provide a method of forming a resist pattern of a semiconductor device capable of easily implementing fine contact holes having different sizes.

도 1a 및 도 1b는 종래의 반도체 소자의 레지스트 패턴 형성방법을 설명하기 위한 단면도.1A and 1B are cross-sectional views for explaining a resist pattern forming method of a conventional semiconductor device.

도 2a 및 도 2b는 본 발명의 실시예에 따른 반도체 소자의 레지스트 패턴 형성방법을 설명하기 위한 단면도.2A and 2B are cross-sectional views illustrating a method of forming a resist pattern in a semiconductor device according to an embodiment of the present invention.

(도면의 주요부분에 대한 부호의 설명)(Explanation of symbols for the main parts of the drawing)

30 : 반도체 기판30: semiconductor substrate

31 : 절연막31: insulating film

32A1, 32A2 : 제 1 레지스트 패턴32A1, 32A2: first resist pattern

32B1, 32B2 : 제 2 레지스트 패턴32B1, 32B2: second resist pattern

100 : 레티클100: reticle

100A1, 100A2 : 제 1 패턴100A1, 100A2: first pattern

100B1, 100B2 : 제 2 패턴100B1, 100B2: second pattern

W1, W2 : 레지스트 패턴의 폭W1, W2: width of resist pattern

H1, H2 : 레지스트 패턴의 높이H1, H2: height of resist pattern

C1, C2, C2, C4 : 레지스트 패턴 사이의 간격C1, C2, C2, C4: gap between resist patterns

Ⅰ, Ⅱ : 제 1 및 제 2 영역I, II: first and second regions

상기한 본 발명의 목적을 달성하기 위하여, 본 발명에 따라 반도체 기판 상에 레지스트막을 도포하고, 레지스트막을 노광 및 현상하여, 제 1 높이, 제 1 폭 및 제 1 부피를 갖고 제 1 간격으로 이격된 제 1 레지스트 패턴을 상기 기판의 제 1 영역에 형성하고, 상기 제 1 높이 보다 낮은 제 2 높이, 상기 제 1 폭보다 넓은 제 2 폭 및 상기 제 1 부피와 거의 동일한 제 2 부피를 갖고 상기 제 1 간격 보다 넓은 제 2 간격을 갖는 제 2 레지스트 패턴을 상기 기판의 제 2 영역에 형성한 후, 제 1 및 제 2 레지스트 패턴을 플로우시킨다.In order to achieve the object of the present invention described above, in accordance with the present invention, a resist film is applied onto a semiconductor substrate, and the resist film is exposed and developed to have a first height, a first width, and a first volume spaced at a first interval. A first resist pattern is formed in the first region of the substrate, the first resist pattern having a second height lower than the first height, a second width wider than the first width, and a second volume substantially equal to the first volume; After forming a second resist pattern having a second gap wider than the gap in the second region of the substrate, the first and second resist patterns are flowed.

본 실시예에서, 레지스트막의 노광은 제 1 영역의 대향부분에 제 1 간격으로 이격되어 배치되고 제 1 투과율을 갖는 제 1 패턴과, 제 2 영역의 대향 부분에 상기 제 2 간격으로 이격되어 배치되고 제 1 투과율보다 높은 제 2 투과율을 갖는 제 2 패턴을 구비한 레티클을 이용하여 진행한다.In the present embodiment, the exposure of the resist film is disposed spaced apart at first intervals on the opposite portions of the first region and is spaced apart at the second interval on the first pattern having a first transmittance and on the opposite portions of the second region. It proceeds using a reticle having a second pattern having a second transmittance higher than the first transmittance.

또한, 제 1 패턴은 0%의 투과율을 갖는 크롬패턴과 같은 광차단물질이고, 제 2 패턴은 5 내지 10%의 투과율을 갖는 광투과물질이다. 또한, 제 1 패턴은 5 내지 10%의 투과율을 갖는 광투과물질이고, 상기 제 2 패턴은 10 내지 20%의 투과율을 갖는 광투과물질이다.In addition, the first pattern is a light blocking material such as a chromium pattern having a transmittance of 0%, and the second pattern is a light transmitting material having a transmittance of 5 to 10%. In addition, the first pattern is a light transmitting material having a transmittance of 5 to 10%, and the second pattern is a light transmitting material having a transmittance of 10 to 20%.

이하, 첨부된 도면을 참조하여 본 발명의 실시예를 설명한다.Hereinafter, with reference to the accompanying drawings will be described an embodiment of the present invention.

도 2a 및 도 2b는 본 발명의 실시예에 따른 반도체 소자의 레지스트 패턴 형성방법을 설명하기 위한 단면도이다.2A and 2B are cross-sectional views illustrating a method of forming a resist pattern in a semiconductor device according to an embodiment of the present invention.

도 2a를 참조하면, 서로 다른 크기의 콘택홀이 형성될 제 1 및 제 2 영역(Ⅰ, Ⅱ)이 정의된 반도체 기판(20) 상에 절연막(21)을 형성하고, 절연막(21) 상에 레지스트막을 도포한다. 그런 다음, 레티클(100)을 이용하여 포토레지스트막을 노광한 후 현상하여, 도 2a에 도시된 바와 같이, 제 1 높이(H1), 제 1 폭(W1) 및 제 1 부피를 갖고 제 1 간격(C1)으로 이격된 제 1 레지스트 패턴(32A1, 32A2)을 제 1 영역(Ⅰ)에 형성하고, 제 1 높이(H1) 보다 낮은 제 2 높이(H2), 제 1 폭(W1)보다 넓은 제 2 폭(W2) 및 제 1 부피와 거의 동일한 제 2 부피를 갖고 제 1 간격(C1) 보다 넓은 제 2 간격(C2)을 갖는 제 2 레지스트 패턴(32B1, 32B2)을 형성한다.Referring to FIG. 2A, an insulating film 21 is formed on a semiconductor substrate 20 on which first and second regions I and II in which contact holes of different sizes are to be formed are formed, and on the insulating film 21. A resist film is applied. Then, the photoresist film is exposed and developed by using the reticle 100, and as shown in FIG. 2A, the first space H1 has the first height H1, the first width W1, and the first volume. The first resist patterns 32A1 and 32A2 spaced apart from C1) are formed in the first region I, the second height H2 lower than the first height H1, and the second wider than the first width W1. Second resist patterns 32B1 and 32B2 are formed having a width W2 and a second volume approximately equal to the first volume and having a second interval C2 wider than the first interval C1.

여기서, 레티클(100)은 제 1 영역(Ⅰ)의 대향부분에 제 1 간격(C1)으로 이격되어 배치되고 제 1 투과율을 갖는 제 1 패턴(100A1, 100A2)과, 제 2 영역(Ⅱ)의 대향 부분에 제 2 간격(C2)으로 이격되어 배치되고 제 1 투과율보다 높은 제 2 투과율을 갖는 제 2 패턴(100B1, 100B2)을 구비한다. 예컨대, 제 1 패턴(100A1, 100A2)이 0%의 투과율을 갖는 크롬패턴과 같은 광차단물질인 경우, 제 2 패턴(100B1, 100B2)은 5 내지 10%의 투과율을 갖는 광투과물질이고, 제 1 패턴 (100A1, 100A2)이 5 내지 10%, 바람직하게 6% 정도의 투과율을 갖는 광투과물질인 경우, 제 2 패턴(100B1, 100B2)은 10 내지 20%, 바람직하게 18%정도의 투과율을 갖는 광투과물질이다.Here, the reticle 100 is disposed at opposite portions of the first region I at a first interval C1 and is spaced apart from the first patterns 100A1 and 100A2 having the first transmittance and the second region II. The second portions 100B1 and 100B2 are disposed in the opposite portions to be spaced apart at the second interval C2 and have a second transmittance higher than the first transmittance. For example, when the first patterns 100A1 and 100A2 are light blocking materials such as chromium patterns having a transmittance of 0%, the second patterns 100B1 and 100B2 are light transmitting materials having a transmittance of 5 to 10%. When the first patterns 100A1 and 100A2 are light transmitting materials having a transmittance of about 5 to 10%, preferably about 6%, the second patterns 100B1 and 100B2 have a transmittance of about 10 to 20%, preferably about 18%. It is a light transmitting material having.

이에 따라, 노광시 제 2 영역(Ⅱ)의 레지스트막 상부가 얕게 노광되어 제거됨으로써, 제 1 레지스트 패턴(32A1, 32A2)보다 높이가 낮아지게 된다.As a result, the upper portion of the resist film in the second region (II) is shallowly exposed and removed during exposure, so that the height is lower than that of the first resist patterns 32A1 and 32A2.

그리고 나서, 제 1 및 제 2 레지스트 패턴(32A1, 32A2, 32B1, 32B2)을 열공정으로 플로우시켜 그의 수직 프로파일을 완만하게 하여, 도 2b에 도시된 바와 같이, 제 1 레지스트 패턴(32A1, 32A2) 사이의 간격을 제 1 간격(C1) 보다 작은 제 3 간격(C3)으로 감소시키고, 제 2 레지스트 패턴(32B1, 32B2) 사이의 간격을 제 2 간격(C2)보다 작은 제 4 간격(C4)으로 감소시킨다. 그 후, 도시되지는 않았지만, 제 1 및 제 2 레지스트 패턴(32A1, 32A2, 32B1, 32B2)을 식각 마스크로하여 기판(20)이 노출되도록 절연막(21)을 식각하여 제 3 및 제 4 간격(C3, C4)의 크기를 갖는 콘택홀을 각각 형성한다.Then, the first and second resist patterns 32A1, 32A2, 32B1, and 32B2 are flowed in a thermal process to smooth their vertical profiles, as shown in FIG. 2B, to form the first resist patterns 32A1 and 32A2. Reduce the space between the third space (C3) smaller than the first space (C1), and the space between the second resist pattern (32B1, 32B2) to the fourth space (C4) less than the second space (C2) Decrease. Subsequently, although not shown, the insulating film 21 is etched to expose the substrate 20 using the first and second resist patterns 32A1, 32A2, 32B1, and 32B2 as an etching mask to form third and fourth gaps ( Contact holes having the sizes C3 and C4) are formed, respectively.

상기한 본 발명에 의하면, 광투과율이 다른 패턴을 갖는 레티클을 이용하여 레지스트막의 노광을 진행하여 레지스트 패턴들의 부피를 동일하게 조절한 후, 레지스트막 패턴의 플로우를 진행함으로써, 서로 다른 크기의 콘택홀의 형성시 콘택홀의 균일한 CD 조절이 가능해지므로, 고집적화에 따른 콘택홀 형성이 용이해진다.According to the present invention described above, by using a reticle having a pattern having a different light transmittance, the resist film is exposed to adjust the volume of the resist patterns in the same manner, and then the resist film pattern is flowed to provide contact holes of different sizes. Since the CD can be uniformly adjusted during the formation of the contact hole, the contact hole can be easily formed due to high integration.

또한, 본 발명은 상기 실시예에 한정되지 않고, 본 발명의 기술적 요지를 벗어나지 않는 범위내에서 다양하게 변형시켜 실시할 수 있다.In addition, this invention is not limited to the said Example, It can variously deform and implement within the range which does not deviate from the technical summary of this invention.

Claims (4)

반도체 기판 상에 레지스트막을 도포하는 단계;Applying a resist film on the semiconductor substrate; 상기 레지스트막을 노광 및 현상하여,Exposing and developing the resist film; 제 1 높이, 제 1 폭 및 제 1 부피를 갖고 제 1 간격으로 이격된 제 1 레지스트 패턴을 상기 기판의 제 1 영역에 형성하고, 상기 제 1 높이 보다 낮은 제 2 높이, 상기 제 1 폭보다 넓은 제 2 폭 및 상기 제 1 부피와 거의 동일한 제 2 부피를 갖고 상기 제 1 간격 보다 넓은 제 2 간격을 갖는 제 2 레지스트 패턴을 상기 기판의 제 2 영역에 형성하는 단계;A first resist pattern having a first height, a first width, and a first volume, spaced at a first interval, is formed in the first region of the substrate, and has a second height lower than the first height and wider than the first width. Forming a second resist pattern in a second region of the substrate, the second resist pattern having a second width and a second volume substantially equal to the first volume and having a second interval wider than the first interval; 상기 제 1 및 제 2 레지스트 패턴을 플로우시키는 단계를 포함하는 것을 특징으로 하는 반도체 소자의 레지스트 패턴 형성방법.And flowing the first and second resist patterns. 제 1 항에 있어서, 상기 레지스트막의 노광은 상기 제 1 영역의 대향부분에 상기 제 1 간격으로 이격되어 배치되고 제 1 투과율을 갖는 제 1 패턴과,The method of claim 1, wherein the exposure of the resist film comprises: a first pattern spaced apart from each other at the first interval on an opposite portion of the first region and having a first transmittance; 상기 제 2 영역의 대향 부분에 상기 제 2 간격으로 이격되어 배치되고 상기 제 1 투과율보다 높은 제 2 투과율을 갖는 제 2 패턴을 구비한 레티클을 이용하여 진행하는 것을 특징으로 하는 반도체 소자의 레지스트 패턴 형성방법.Forming a resist pattern of the semiconductor device by using a reticle having a second pattern disposed at opposite portions of the second region at the second interval and having a second transmittance higher than the first transmittance Way. 제 2 항에 있어서, 상기 제 1 패턴은 0%의 투과율을 갖는 크롬패턴과 같은 광차단물질이고, 상기 제 2 패턴은 5 내지 10%의 투과율을 갖는 광투과물질인 것을 특징으로 하는 반도체 소자의 레지스트 패턴 형성방법.The semiconductor device of claim 2, wherein the first pattern is a light blocking material such as a chromium pattern having a transmittance of 0%, and the second pattern is a light transmitting material having a transmittance of 5 to 10%. Resist Pattern Formation Method. 제 2 항에 있어서, 상기 제 1 패턴은 5 내지 10%의 투과율을 갖는 광투과물질이고, 상기 제 2 패턴은 10 내지 20%의 투과율을 갖는 광투과물질인 것을 특징으로 하는 반도체 소자의 레지스트 패턴 형성방법.The resist pattern of claim 2, wherein the first pattern is a light transmissive material having a transmittance of 5 to 10%, and the second pattern is a light transmissive material having a transmittance of 10 to 20%. Formation method.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100393230B1 (en) * 2001-08-16 2003-07-31 삼성전자주식회사 Formation method of photoresist pattern for controlling the remaining rate
KR100489521B1 (en) * 2002-09-09 2005-05-16 동부아남반도체 주식회사 Reticle for fabricating multi-level pattern

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JPH01109717A (en) * 1987-10-22 1989-04-26 Oki Electric Ind Co Ltd Resist pattern inspecting method
JPH02297557A (en) * 1989-05-12 1990-12-10 Mitsubishi Electric Corp Formation of resist pattern
JPH04318852A (en) * 1991-04-18 1992-11-10 Fujitsu Ltd Resist pattern forming method
JPH0697065A (en) * 1992-09-17 1994-04-08 Mitsubishi Electric Corp Fine resist pattern forming method
KR960035776A (en) * 1995-03-22 1996-10-28 김주용 Fine pattern formation method
KR19980048210A (en) * 1996-12-17 1998-09-15 김영환 Method of forming fine pattern of semiconductor device
JPH11283920A (en) * 1997-06-18 1999-10-15 Toshiba Corp Resist pattern formation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100393230B1 (en) * 2001-08-16 2003-07-31 삼성전자주식회사 Formation method of photoresist pattern for controlling the remaining rate
KR100489521B1 (en) * 2002-09-09 2005-05-16 동부아남반도체 주식회사 Reticle for fabricating multi-level pattern

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