KR20010002981A - A method of manufacturing an amorphous silicon hydride thin film transistor at a low temperature - Google Patents
A method of manufacturing an amorphous silicon hydride thin film transistor at a low temperature Download PDFInfo
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Abstract
Description
본 발명은 박막트랜지스터(Thin Film Transistor, 이하 TFT라함)의 제조방법에 관한 것으로, 특히 수소화 비정질실리콘(a-Si:H) TFT를 저온에서 제조하는 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a thin film transistor (hereinafter referred to as TFT), and more particularly to a method of manufacturing a hydrogenated amorphous silicon (a-Si: H) TFT at low temperature.
TFT는 대면적 전자기기의 많은 분야에서 정보를 나타내기 위한 스위칭 소자로써 널리 이용된다. 이러한 TFT는, 액티브매트릭스형 액정표시소자(Active Matrix Liquid Crystal Display; AMLCD)에 매우 효과적으로 이용되는 것으로서, 서로 교차하는 주사선과 신호선에 의해 정의되는 복수의 매트릭스 상에 형성되어 각각의 매트릭스를 별도로 스위칭한다. 전압이 인가되면 주사선 및 신호선의 제어에 의해 해당 TFT가 액정분자의 배열을 변화시켜 빛의 투과 여부를 결정하게 된다.TFTs are widely used as switching elements for displaying information in many fields of large area electronics. Such TFTs are very effectively used for an active matrix liquid crystal display (AMLCD), and are formed on a plurality of matrices defined by scan lines and signal lines that cross each other to switch each matrix separately. . When voltage is applied, the TFT changes the arrangement of liquid crystal molecules under the control of the scan line and the signal line to determine whether light is transmitted.
그러나, 상기한 TFT는 유리기판 상에서, 약 250∼400℃의 온도로 PECVD(Plasma Enhanced Chemical Vapor Depositon)법에 의해 처리되고, 250℃ 이상의 증착온도를 필요로 하기 때문에 고온에 의하여 기판의 휨이 발생하기 때문에 유리기판에 비해 열에 약한 플라스틱기판을 사용하는데 걸림돌이 되었다.However, the TFT is processed on a glass substrate by a Plasma Enhanced Chemical Vapor Depositon (PECVD) method at a temperature of about 250 to 400 ° C., and requires a deposition temperature of 250 ° C. or higher, so that warpage of the substrate occurs due to high temperature. As a result, it was an obstacle to using a plastic substrate that is weaker in heat than a glass substrate.
이러한 문제점을 해결하고자, 미국특허 5,796,121호 '플라스틱기판 상에 제조된 박막트랜지스터'에서는, 낮은 전이온도를 갖는 플라스틱기판 상에 TFT를 제조하는 방법 및 그러한 방법에 의해 제조된 TFT가 제시되어 있다.In order to solve this problem, US Pat. No. 5,796,121, 'Thin Film Transistor Fabricated on Plastic Substrate', discloses a method of manufacturing a TFT on a plastic substrate having a low transition temperature and a TFT manufactured by the method.
도 1은 종래 저온 제조된 a-Si:H TFT의 단면도로서, 도면에 나타내듯이, 플라스틱기판(도시하지 않음) 위에는 전기적 절연특성을 갖는 투명한 보호필름(10)이 스핀코팅 등에 의해 피복된다. 기판 위에는 Cr, Ta, Mo, W, Cu, 또는 그것의 화합물 등으로 이루어진 게이트전극(13)이 형성된다. 게이트전극(13) 위에는 SiNx 등으로 이루어진 게이트절연막(15)이 약 125℃에서 PECVD법에 의해 형성된다. 게이트절연막(15) 위에는 비정질실리콘(a-Si:H) 등으로 이루어진 반도체층(19)이 약 125℃에서 PECVD법에 의해 형성되고, 그 위에는 SiNx 등으로 이루어진 에칭스토퍼(21)가 PECVD방법에 의해 형성된다. 상기한 에칭스토퍼(21) 위에는 Mg 또는 Y 등과 같은 낮은 일함수(work function)의 금속으로 이루어진 오믹컨택층(23)이 PECVD법에 의해 형성되고, 그 위에는 Al 또는 Ta 등으로 이루어진 소스/드레인전극(25a, 25b)이 형성된다. 상기한 소스/드레인전극(25a, 25b) 위에는 기판의 전영역에 걸쳐 보호막(도시하지 않음)이 형성된다.1 is a cross-sectional view of a conventionally manufactured low-temperature a-Si: H TFT, and as shown in the drawing, a transparent protective film 10 having electrical insulation properties is coated on a plastic substrate (not shown) by spin coating or the like. On the substrate, a gate electrode 13 made of Cr, Ta, Mo, W, Cu, a compound thereof, or the like is formed. On the gate electrode 13, a gate insulating film 15 made of SiNx or the like is formed at about 125 DEG C by PECVD. A semiconductor layer 19 made of amorphous silicon (a-Si: H) or the like is formed on the gate insulating film 15 by PECVD at about 125 ° C, and an etching stopper 21 made of SiNx or the like is formed on the PECVD method. Is formed by. On the etching stopper 21, an ohmic contact layer 23 made of a low work function metal such as Mg or Y is formed by PECVD, and a source / drain electrode made of Al or Ta is formed thereon. 25a and 25b are formed. On the source / drain electrodes 25a and 25b, a protective film (not shown) is formed over the entire area of the substrate.
그러나, 상기한 TFT는 반도체층 위에 오믹컨택층으로서 불순물 비정질실리콘층을 사용하지 않으므로서, 높은 문턱전압(약 10 Volt)을 필요로 하는 등의 소자 특성이 나쁘고, SiNx증착시 SiH4/He/N2/NH3를 사용하므로써 H2의 에칭효과를 기대하기가 곤란하여, 요구되는 수준의 절연막특성을 얻기 힘들다.However, the above-mentioned TFTs do not use an impurity amorphous silicon layer as an ohmic contact layer on the semiconductor layer, and thus have poor device characteristics such as requiring a high threshold voltage (about 10 Volt), and SiH4 / He / N during deposition of SiNx. By using 2 / NH 3 , it is difficult to expect the etching effect of H 2 , and it is difficult to obtain the required level of insulating film characteristics.
본 발명은 상기한 종래 기술을 감안하여 이루어진 것으로서, 본 발명의 목적은 저온에서 a-Si:H TFT를 제조하고 플라스틱기판을 이용하므로써, 저가이고 경량인 액정표시소자를 제공하는 것이다.The present invention has been made in view of the above-described prior art, and an object of the present invention is to provide an inexpensive and lightweight liquid crystal display device by manufacturing a-Si: H TFT at low temperature and using a plastic substrate.
본 발명의 다른 목적은 상기한 TFT의 제조공정 중에 Nin+층을 연속하여 성막하고, 절연막 및 a-Si:H막의 성막 중에 H2를 첨가하므로써 H플라즈마에 의한 에칭 특성을 향상시켜 절연막의 특성을 향상시키고자 하는 것이다.Another object of the present invention is to continuously form a Nin + layer during the above-described TFT manufacturing process, and to improve the etching characteristics by H plasma by adding H 2 to the insulating film and the a-Si: H film. It is to improve.
상기한 목적을 달성하기 위하여, 본 발명에 따른 a-Si:H TFT 제조방법은, 투명한 플라스틱기판 위에 스퍼터링방법으로 금속을 적층한 후, 마스크를 이용하여 포토에칭하여 게이트전극을 형성하는 단계와, 상기한 게이트전극 위에 SiNx 또는 SiOx, 비정질실리콘(a-Si) 및 불순물 비정질실리콘(n+ a-Si)을 PECVD법으로 연속 적층(Nin+연속증착)한 후, 에칭하여 게이트절연막, 반도체층 및 오믹컨택층을 형성하는 단계와, 상기한 오믹컨택층 위에 스퍼터링방법으로 Cr, Mo, 또는 Ti와 같은 금속을 적층하고 포토에칭하여 소스/드레인전극을 형성한 후, 상기한 소스/드레인전극을 마스크로하여 채널영역(channel region)의 오믹컨택층을 에칭하는 단계와, 상기한 기판 전체에 걸쳐서 보호막을 PECVD방법으로 적층한 후, 플라즈마 에칭방법으로 상기한 보호막을 패터닝하여 상기한 소스/드레인전극 콘택홀을 형성하는 단계를 포함하여 이루어진다.In order to achieve the above object, a-Si: H TFT manufacturing method according to the present invention comprises the steps of forming a gate electrode by laminating a metal on a transparent plastic substrate by a sputtering method, and then photoetched using a mask, SiNx or SiOx, amorphous silicon (a-Si), and impurity amorphous silicon (n + a-Si) are sequentially deposited (Nin + continuous deposition) on the gate electrode by PECVD, and then etched to form a gate insulating film, a semiconductor layer, and an ohmic. Forming a contact layer, and forming a source / drain electrode by photo-etching a metal such as Cr, Mo, or Ti on the ohmic contact layer by sputtering, and then using the source / drain electrode as a mask. Etching the ohmic contact layer in the channel region, laminating a protective film over the entire substrate by PECVD, and then patterning the protective film by plasma etching. Forming a source / drain electrode contact hole.
상기한 PECVD법은 120℃와 150℃ 사이의 등온에서 수행되는데, 이러한 온도는 공정 중에 일정하게 유지된다.The above PECVD method is carried out at an isothermal temperature between 120 ° C. and 150 ° C., which temperature is kept constant during the process.
또한, SiNx 또는 SiOx, 비정질실리콘(a-Si) 및 불순물 비정질실리콘(n+ a-Si)의 증착시에 H2를 첨가/증가시켜 수소플라즈마에 의한 에칭효과를 증가시켜 막의 특성을 향상시킨다.In addition, H 2 is added / increased during deposition of SiNx or SiOx, amorphous silicon (a-Si), and impurity amorphous silicon (n + a-Si) to increase the etching effect by hydrogen plasma, thereby improving film properties.
도 1은 종래 저온에서 제조된 수소화 비정질실리콘 박막트랜지스터의 단면도.1 is a cross-sectional view of a hydrogenated amorphous silicon thin film transistor prepared at a low temperature in the prior art.
도 2(a), (b), (c) 및 (d)는 본 발명에 따라 수소화 비정질실리콘 박막트랜지스터를 저온에서 제조하는 방법을 나타내는 도면.2 (a), (b), (c) and (d) show a method for producing a hydrogenated amorphous silicon thin film transistor at low temperature according to the present invention;
이하, 첨부한 도면을 참조하여 본 발명에 따른 a-Si:H TFT 저온 제조방법을 상세히 설명한다.Hereinafter, a low-temperature manufacturing method of a-Si: H TFT according to the present invention will be described in detail with reference to the accompanying drawings.
우선, 도 2(a)에 나타낸 바와 같이, 투명한 플라스틱기판(110) 위에 스퍼터링방법으로 금속을 적층한 후, 마스크(mask)를 이용하여 포토에칭(photo etching)하여 게이트전극(113)을 형성한다. 이때, 상기한 플라스틱기판(110) 상에는 보호필름(도시하지 않음)이 형성되어 외부의 불리한 환경으로부터 기판을 보호한다. 또한, 상기한 게이트전극(113)은 Cr, Mo, Mo/Al, Ti 등과 같이 힐록(hillock)이 발생하지 않으며 양극산화가 일어나지 않는 금속으로 이루어져 있으며, 절연성의 향상을 위해 양극산화막을 형성하기도 한다.First, as shown in FIG. 2A, metal is deposited on a transparent plastic substrate 110 by sputtering, and then photoetched using a mask to form a gate electrode 113. . At this time, a protective film (not shown) is formed on the plastic substrate 110 to protect the substrate from adverse environmental conditions. In addition, the gate electrode 113 is made of a metal that does not generate hillocks such as Cr, Mo, Mo / Al, Ti, and the like, and does not cause anodization, and may form an anodization film to improve insulation. .
그후, 도 2(b)에 나타낸 바와 같이, 상기한 플라스틱기판(110) 위에 SiNx 또는 SiOx, 비정질실리콘(a-Si) 및 불순물 비정질실리콘(n+ a-Si)을 PECVD법으로 연속 적층(Nin+연속증착)한 후, 에칭하여 게이트절연막(115), 반도체층(119) 및 오믹컨택층(123)을 형성한다.Subsequently, as shown in FIG. 2 (b), SiNx or SiOx, amorphous silicon (a-Si), and impurity amorphous silicon (n + a-Si) are successively stacked on the plastic substrate 110 by PECVD (Nin +). Continuous deposition), and then etched to form the gate insulating film 115, the semiconductor layer 119, and the ohmic contact layer 123.
이때, 상기한 PECVD법은 120℃와 150℃ 사이의 등온에서 수행되는데, 이러한 온도는 공정 중에 일정하게 유지된다. 또한, SiNx 또는 SiOx, 비정질실리콘(a-Si) 및 불순물 비정질실리콘(n+ a-Si)의 증착시에 H2를 첨가/증가시켜 수소플라즈마에 의한 에칭효과를 증가시켜 막의 특성을 향상시킨다.At this time, the above-described PECVD method is performed at an isothermal temperature between 120 ° C. and 150 ° C., and this temperature is kept constant during the process. In addition, H 2 is added / increased during deposition of SiNx or SiOx, amorphous silicon (a-Si), and impurity amorphous silicon (n + a-Si) to increase the etching effect by hydrogen plasma, thereby improving film properties.
이어서, 도 2(c)에 나타낸 바와 같이, 상기한 오믹컨택층(123) 위에 스퍼터링방법으로 Cr, Mo, 또는 Ti와 같은 금속을 적층하고 포토에칭하여 소스/드레인전극(125a, 125b)을 형성한 후, 상기한 소스/드레인전극(125a, 125b)을 마스크로하여 채널영역(channel region)의 오믹컨택층(123)을 에칭한다.Subsequently, as shown in FIG. 2 (c), a metal such as Cr, Mo, or Ti is laminated on the ohmic contact layer 123 by sputtering and photoetched to form source / drain electrodes 125a and 125b. After that, the ohmic contact layer 123 of the channel region is etched using the source / drain electrodes 125a and 125b as a mask.
그후, 도 2(d)에 나타낸 바와 같이, 상기한 TFT 및 상기한 기판(110) 전체에 걸쳐서 보호막(127)을 PECVD방법으로 적층한 후, 플라즈마 에칭방법으로 상기한 보호막(127)을 패터닝하여 TFT부의 소스/드레인전극(125a, 125b) 콘택홀을 형성한다. 이때, 상기한 PECVD법은 120℃와 150℃ 사이의 등온에서 수행되는데, 이러한 온도는 상기한 Nin+연속증착과 마찬가지로 공정 중에 일정하게 유지된다. 이때, 상기한 소스/드레인전극(1125a, 125b)이 Cr, Mo, Ti 등으로 이루어져 있기 때문에, TFT부에서는 에칭이 상기한 소스/드레인전극(1125a, 125b)에 의해 저지된다.Thereafter, as shown in FIG. 2 (d), the protective film 127 is laminated over the TFT and the entire substrate 110 by PECVD, and then the protective film 127 is patterned by a plasma etching method. Source / drain electrodes 125a and 125b contact holes are formed in the TFT portion. At this time, the above-described PECVD method is performed at an isothermal temperature between 120 ° C. and 150 ° C., and this temperature is kept constant during the process as in the above-described Nin + continuous deposition. At this time, since the source / drain electrodes 1125a and 125b are made of Cr, Mo, Ti, or the like, etching is prevented by the source / drain electrodes 1125a and 125b in the TFT section.
그후, 비록 도면으로 나타내지는 않았지만, 상기한 보호막(127) 위에 스퍼터링방법으로 ITO(indium tin oxide)와 같은 투명금속을 적층하고 에칭하여 화소전극(도시하지 않음)을 형성한다. 상기한 화소전극은 보호막(127)의 컨택홀을 통해 TFT의 소스/드레인전극(125a, 125b)에 연결된다.Thereafter, although not shown in the drawings, a transparent metal such as indium tin oxide (ITO) is laminated and etched on the passivation layer 127 by sputtering to form a pixel electrode (not shown). The pixel electrode is connected to the source / drain electrodes 125a and 125b of the TFT through the contact hole of the passivation layer 127.
본 발명의 TFT제조방법에 따르면, 저온PECVD법에 의해 TFT소자들을 형성하므로써, 제조공정 중에 기판이 고온에서 휘거나 수축되는 것을 방지하는 것이 가능하고, 비교적 열에 약한 저가, 경량의 플라스틱기판을 제공하므로써 대면적의 액정표시소자를 가능하게 한다.According to the TFT manufacturing method of the present invention, by forming TFT elements by low-temperature PECVD, it is possible to prevent the substrate from bending or shrinking at high temperatures during the manufacturing process, and by providing a low-cost, lightweight plastic substrate that is relatively heat resistant. It allows a large area liquid crystal display device.
또한, 본 발명에서는 Nin+연속증착시에 H2를 첨가/증가 시키므로써 에칭효과를 높일 수 있다.In the present invention, the etching effect can be enhanced by adding / increasing H 2 during Nin + continuous deposition.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20030009824A (en) * | 2001-07-24 | 2003-02-05 | (주)신종 | A method of producing a thin film device |
KR100398590B1 (en) * | 2001-05-17 | 2003-09-19 | 비오이 하이디스 테크놀로지 주식회사 | Method for manufacturing thin film transistor liquid crystal display device |
KR100488955B1 (en) * | 2002-01-15 | 2005-05-11 | 비오이 하이디스 테크놀로지 주식회사 | Thin film transistor array and fabricating method thereof |
KR100641627B1 (en) * | 2000-07-19 | 2006-11-02 | 엘지.필립스 엘시디 주식회사 | Amorphous-Silicon Thin Film Transistor and method for fabricating the same |
US7532267B2 (en) | 2002-12-31 | 2009-05-12 | Lg Display Co., Ltd. | Liquid crystal display device and method of fabricating the same |
KR20140033847A (en) * | 2012-09-11 | 2014-03-19 | 엘지디스플레이 주식회사 | Method of forming low resistance wire and method of manufacturing thin film transistor using the same |
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1999
- 1999-06-19 KR KR1019990023080A patent/KR20010002981A/en active Search and Examination
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100641627B1 (en) * | 2000-07-19 | 2006-11-02 | 엘지.필립스 엘시디 주식회사 | Amorphous-Silicon Thin Film Transistor and method for fabricating the same |
KR100398590B1 (en) * | 2001-05-17 | 2003-09-19 | 비오이 하이디스 테크놀로지 주식회사 | Method for manufacturing thin film transistor liquid crystal display device |
KR20030009824A (en) * | 2001-07-24 | 2003-02-05 | (주)신종 | A method of producing a thin film device |
KR100488955B1 (en) * | 2002-01-15 | 2005-05-11 | 비오이 하이디스 테크놀로지 주식회사 | Thin film transistor array and fabricating method thereof |
US7532267B2 (en) | 2002-12-31 | 2009-05-12 | Lg Display Co., Ltd. | Liquid crystal display device and method of fabricating the same |
US7824940B2 (en) | 2002-12-31 | 2010-11-02 | Lg Display Co., Ltd. | Liquid crystal display device and method of fabricating the same |
US8053295B2 (en) | 2002-12-31 | 2011-11-08 | Lg Display Co., Ltd. | Liquid crystal display device and method of fabricating the same |
US8232214B2 (en) | 2002-12-31 | 2012-07-31 | Lg Display Co., Ltd | Liquid crystal display device and method of fabricating the same |
KR20140033847A (en) * | 2012-09-11 | 2014-03-19 | 엘지디스플레이 주식회사 | Method of forming low resistance wire and method of manufacturing thin film transistor using the same |
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