KR102663374B1 - 치환된 1,3,5-트리아진계 화합물, 조성물 및 이의 용도 - Google Patents
치환된 1,3,5-트리아진계 화합물, 조성물 및 이의 용도 Download PDFInfo
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- KR102663374B1 KR102663374B1 KR1020217035151A KR20217035151A KR102663374B1 KR 102663374 B1 KR102663374 B1 KR 102663374B1 KR 1020217035151 A KR1020217035151 A KR 1020217035151A KR 20217035151 A KR20217035151 A KR 20217035151A KR 102663374 B1 KR102663374 B1 KR 102663374B1
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- 239000000203 mixture Chemical class 0.000 title claims abstract description 57
- 125000003363 1,3,5-triazinyl group Chemical class N1=C(N=CN=C1)* 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 570
- 239000000463 material Substances 0.000 claims abstract description 246
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000010410 layer Substances 0.000 claims description 146
- 125000001072 heteroaryl group Chemical group 0.000 claims description 113
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 111
- 125000003118 aryl group Chemical group 0.000 claims description 99
- 229910052739 hydrogen Inorganic materials 0.000 claims description 74
- 239000001257 hydrogen Substances 0.000 claims description 74
- 229910052736 halogen Inorganic materials 0.000 claims description 61
- 150000002367 halogens Chemical group 0.000 claims description 61
- 125000005842 heteroatom Chemical group 0.000 claims description 46
- 150000002431 hydrogen Chemical group 0.000 claims description 44
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 34
- 230000005525 hole transport Effects 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 30
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 27
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical group [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 229910052805 deuterium Inorganic materials 0.000 claims description 23
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 18
- 238000002347 injection Methods 0.000 claims description 17
- 239000007924 injection Substances 0.000 claims description 17
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 16
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 13
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 13
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 13
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 13
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 13
- 125000001424 substituent group Chemical group 0.000 claims description 13
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 13
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 12
- 239000011737 fluorine Substances 0.000 claims description 12
- 125000004076 pyridyl group Chemical group 0.000 claims description 10
- 230000000903 blocking effect Effects 0.000 claims description 9
- -1 1,3,5-triazine compound Chemical class 0.000 claims description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052740 iodine Inorganic materials 0.000 claims description 7
- 239000011630 iodine Substances 0.000 claims description 7
- 125000001624 naphthyl group Chemical group 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000012776 electronic material Substances 0.000 claims description 5
- 239000002346 layers by function Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- 125000002950 monocyclic group Chemical group 0.000 claims description 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 12
- 230000008901 benefit Effects 0.000 abstract description 7
- 150000000182 1,3,5-triazines Chemical class 0.000 abstract description 2
- AWXGSYPUMWKTBR-UHFFFAOYSA-N 4-carbazol-9-yl-n,n-bis(4-carbazol-9-ylphenyl)aniline Chemical compound C12=CC=CC=C2C2=CC=CC=C2N1C1=CC=C(N(C=2C=CC(=CC=2)N2C3=CC=CC=C3C3=CC=CC=C32)C=2C=CC(=CC=2)N2C3=CC=CC=C3C3=CC=CC=C32)C=C1 AWXGSYPUMWKTBR-UHFFFAOYSA-N 0.000 description 928
- 101000837344 Homo sapiens T-cell leukemia translocation-altered gene protein Proteins 0.000 description 928
- 102100028692 T-cell leukemia translocation-altered gene protein Human genes 0.000 description 928
- GEQBRULPNIVQPP-UHFFFAOYSA-N 2-[3,5-bis(1-phenylbenzimidazol-2-yl)phenyl]-1-phenylbenzimidazole Chemical compound C1=CC=CC=C1N1C2=CC=CC=C2N=C1C1=CC(C=2N(C3=CC=CC=C3N=2)C=2C=CC=CC=2)=CC(C=2N(C3=CC=CC=C3N=2)C=2C=CC=CC=2)=C1 GEQBRULPNIVQPP-UHFFFAOYSA-N 0.000 description 370
- 238000003786 synthesis reaction Methods 0.000 description 202
- 230000015572 biosynthetic process Effects 0.000 description 200
- 238000000034 method Methods 0.000 description 184
- 230000008569 process Effects 0.000 description 178
- 238000004458 analytical method Methods 0.000 description 173
- 239000000047 product Substances 0.000 description 173
- 238000004949 mass spectrometry Methods 0.000 description 172
- 239000013076 target substance Substances 0.000 description 171
- 150000001793 charged compounds Chemical class 0.000 description 168
- 230000000052 comparative effect Effects 0.000 description 41
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 40
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 38
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 32
- MLVNYXXTYFTPRK-UHFFFAOYSA-N 2-chloro-4,6-bis(4-fluorophenyl)-1,3,5-triazine Chemical compound C1=CC(F)=CC=C1C1=NC(Cl)=NC(C=2C=CC(F)=CC=2)=N1 MLVNYXXTYFTPRK-UHFFFAOYSA-N 0.000 description 28
- 230000000694 effects Effects 0.000 description 23
- OTJZMNIBLUCUJZ-UHFFFAOYSA-N 2,4-diphenyl-1,3,5-triazine Chemical compound C1=CC=CC=C1C1=NC=NC(C=2C=CC=CC=2)=N1 OTJZMNIBLUCUJZ-UHFFFAOYSA-N 0.000 description 20
- 150000004985 diamines Chemical class 0.000 description 17
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 13
- LPSLMIOUKRPZDC-UHFFFAOYSA-N 2-chloro-4,6-bis(4-methylphenyl)-1,3,5-triazine Chemical compound C1=CC(C)=CC=C1C1=NC(Cl)=NC(C=2C=CC(C)=CC=2)=N1 LPSLMIOUKRPZDC-UHFFFAOYSA-N 0.000 description 13
- QELBFKBJJRWUNG-UHFFFAOYSA-N 2-chloro-4,6-bis(4-propan-2-ylphenyl)-1,3,5-triazine Chemical compound C1=CC(C(C)C)=CC=C1C1=NC(Cl)=NC(C=2C=CC(=CC=2)C(C)C)=N1 QELBFKBJJRWUNG-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- PIKNVEVCWAAOMJ-UHFFFAOYSA-N 3-fluorobenzaldehyde Chemical compound FC1=CC=CC(C=O)=C1 PIKNVEVCWAAOMJ-UHFFFAOYSA-N 0.000 description 10
- 238000005401 electroluminescence Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- ZWDVQMVZZYIAHO-UHFFFAOYSA-N 2-fluorobenzaldehyde Chemical compound FC1=CC=CC=C1C=O ZWDVQMVZZYIAHO-UHFFFAOYSA-N 0.000 description 9
- UOQXIWFBQSVDPP-UHFFFAOYSA-N 4-fluorobenzaldehyde Chemical compound FC1=CC=C(C=O)C=C1 UOQXIWFBQSVDPP-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 229910001873 dinitrogen Inorganic materials 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 238000004440 column chromatography Methods 0.000 description 8
- 230000007246 mechanism Effects 0.000 description 8
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 8
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- LSZYULBSFXDTPV-UHFFFAOYSA-N 2,4-bis(4-fluorophenyl)-1,3,5-triazine Chemical compound Fc1ccc(cc1)-c1ncnc(n1)-c1ccc(F)cc1 LSZYULBSFXDTPV-UHFFFAOYSA-N 0.000 description 6
- SAHBFLYFJBLFIG-UHFFFAOYSA-N 2-chloro-4,6-bis[4-(trifluoromethyl)phenyl]-1,3,5-triazine Chemical compound ClC1=NC(=NC(=N1)C1=CC=C(C=C1)C(F)(F)F)C1=CC=C(C=C1)C(F)(F)F SAHBFLYFJBLFIG-UHFFFAOYSA-N 0.000 description 6
- 239000001431 2-methylbenzaldehyde Substances 0.000 description 6
- ASOFZHSTJHGQDT-UHFFFAOYSA-N 3,5-difluorobenzaldehyde Chemical compound FC1=CC(F)=CC(C=O)=C1 ASOFZHSTJHGQDT-UHFFFAOYSA-N 0.000 description 6
- WTWBUQJHJGUZCY-UHFFFAOYSA-N 4-Isopropyl benzaldehyde Natural products CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000012043 crude product Substances 0.000 description 6
- 239000012044 organic layer Substances 0.000 description 6
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- 239000000126 substance Substances 0.000 description 6
- MTDFZPKKVXCFLS-UHFFFAOYSA-N 1-(3-propan-2-ylphenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound C(C)(C)C=1C=C(C=CC1)C1(C(C=CC=C1)N)N MTDFZPKKVXCFLS-UHFFFAOYSA-N 0.000 description 5
- VBUCTUDUHYMXKV-UHFFFAOYSA-N 1-(4-propan-2-ylphenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound C(C)(C)C1=CC=C(C=C1)C1(C(C=CC=C1)N)N VBUCTUDUHYMXKV-UHFFFAOYSA-N 0.000 description 5
- HCGZTGWBSHYUBR-UHFFFAOYSA-N 2-n-(2-propan-2-ylphenyl)benzene-1,2-diamine Chemical compound CC(C)C1=CC=CC=C1NC1=CC=CC=C1N HCGZTGWBSHYUBR-UHFFFAOYSA-N 0.000 description 5
- 239000004305 biphenyl Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
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- 239000010408 film Substances 0.000 description 5
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 4
- VNAHZHWURTWPAL-UHFFFAOYSA-N 1-(3-fluorophenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound FC=1C=C(C=CC1)C1(C(C=CC=C1)N)N VNAHZHWURTWPAL-UHFFFAOYSA-N 0.000 description 4
- DDGPPAMADXTGTN-UHFFFAOYSA-N 2-chloro-4,6-diphenyl-1,3,5-triazine Chemical compound N=1C(Cl)=NC(C=2C=CC=CC=2)=NC=1C1=CC=CC=C1 DDGPPAMADXTGTN-UHFFFAOYSA-N 0.000 description 4
- VFEOWFKLGIXFND-UHFFFAOYSA-N 2-n-pyridin-3-ylbenzene-1,2-diamine Chemical compound NC1=CC=CC=C1NC1=CC=CN=C1 VFEOWFKLGIXFND-UHFFFAOYSA-N 0.000 description 4
- WDRQNOGGIOMQNA-UHFFFAOYSA-N 2-n-pyridin-4-ylbenzene-1,2-diamine Chemical compound NC1=CC=CC=C1NC1=CC=NC=C1 WDRQNOGGIOMQNA-UHFFFAOYSA-N 0.000 description 4
- NMTUHPSKJJYGML-UHFFFAOYSA-N 3-(trifluoromethyl)benzaldehyde Chemical compound FC(F)(F)C1=CC=CC(C=O)=C1 NMTUHPSKJJYGML-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 230000003111 delayed effect Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 235000011056 potassium acetate Nutrition 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 238000001771 vacuum deposition Methods 0.000 description 4
- JLXHGJHEUWPEKD-UHFFFAOYSA-N 1-(2-fluorophenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound FC1=C(C=CC=C1)C1(C(C=CC=C1)N)N JLXHGJHEUWPEKD-UHFFFAOYSA-N 0.000 description 3
- OAOKAISXSFKHME-UHFFFAOYSA-N 1-(2-phenylphenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound C1(=C(C=CC=C1)C1(C(C=CC=C1)N)N)C1=CC=CC=C1 OAOKAISXSFKHME-UHFFFAOYSA-N 0.000 description 3
- NXQFHIDPABMEQB-UHFFFAOYSA-N 1-(3,5-difluorophenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound FC=1C=C(C=C(C1)F)C1(C(C=CC=C1)N)N NXQFHIDPABMEQB-UHFFFAOYSA-N 0.000 description 3
- NLRJDDXKPOKRMM-UHFFFAOYSA-N 1-(3-phenylphenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound C1=CC=C(C=C1)C2=CC(=CC=C2)C3(C=CC=CC3N)N NLRJDDXKPOKRMM-UHFFFAOYSA-N 0.000 description 3
- PZWCYOMAPAAIKM-UHFFFAOYSA-N 1-(4-fluorophenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound FC1=CC=C(C=C1)C1(C(C=CC=C1)N)N PZWCYOMAPAAIKM-UHFFFAOYSA-N 0.000 description 3
- NXGISHNBTXEMBP-UHFFFAOYSA-N 1-(4-phenylphenyl)cyclohexa-3,5-diene-1,2-diamine Chemical compound C1=CC=C(C=C1)C2=CC=C(C=C2)C3(C=CC=CC3N)N NXGISHNBTXEMBP-UHFFFAOYSA-N 0.000 description 3
- JQEUBSXRRWBZLZ-UHFFFAOYSA-N 1-[3,5-di(propan-2-yl)phenyl]cyclohexa-3,5-diene-1,2-diamine Chemical compound C(C)(C)C=1C=C(C=C(C1)C(C)C)C1(C(C=CC=C1)N)N JQEUBSXRRWBZLZ-UHFFFAOYSA-N 0.000 description 3
- UNKHZTKLZVMGCA-UHFFFAOYSA-N 1-[3-(trifluoromethyl)phenyl]cyclohexa-3,5-diene-1,2-diamine Chemical compound C1=CC(C(C=C1)(C2=CC(=CC=C2)C(F)(F)F)N)N UNKHZTKLZVMGCA-UHFFFAOYSA-N 0.000 description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical class C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 3
- 125000004198 2-fluorophenyl group Chemical group [H]C1=C([H])C(F)=C(*)C([H])=C1[H] 0.000 description 3
- LCRCBXLHWTVPEQ-UHFFFAOYSA-N 2-phenylbenzaldehyde Chemical compound O=CC1=CC=CC=C1C1=CC=CC=C1 LCRCBXLHWTVPEQ-UHFFFAOYSA-N 0.000 description 3
- KFKSIUOALVIACE-UHFFFAOYSA-N 3-phenylbenzaldehyde Chemical compound O=CC1=CC=CC(C=2C=CC=CC=2)=C1 KFKSIUOALVIACE-UHFFFAOYSA-N 0.000 description 3
- ISDBWOPVZKNQDW-UHFFFAOYSA-N 4-phenylbenzaldehyde Chemical compound C1=CC(C=O)=CC=C1C1=CC=CC=C1 ISDBWOPVZKNQDW-UHFFFAOYSA-N 0.000 description 3
- 150000001556 benzimidazoles Chemical class 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000005281 excited state Effects 0.000 description 3
- 238000004770 highest occupied molecular orbital Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000004768 lowest unoccupied molecular orbital Methods 0.000 description 3
- 238000004020 luminiscence type Methods 0.000 description 3
- BTFQKIATRPGRBS-UHFFFAOYSA-N o-methyl-benzaldehyde Natural products CC1=CC=CC=C1C=O BTFQKIATRPGRBS-UHFFFAOYSA-N 0.000 description 3
- FXLOVSHXALFLKQ-UHFFFAOYSA-N para-methylbenzaldehyde Natural products CC1=CC=C(C=O)C=C1 FXLOVSHXALFLKQ-UHFFFAOYSA-N 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 150000003918 triazines Chemical class 0.000 description 3
- PBPKTJQXZHKCJC-UHFFFAOYSA-N 1-[3,5-bis(trifluoromethyl)phenyl]cyclohexa-3,5-diene-1,2-diamine Chemical compound C1=CC(C(C=C1)(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)N)N PBPKTJQXZHKCJC-UHFFFAOYSA-N 0.000 description 2
- CYKLTULAUWZNIU-UHFFFAOYSA-N 2-n-(2-methylphenyl)benzene-1,2-diamine Chemical compound CC1=CC=CC=C1NC1=CC=CC=C1N CYKLTULAUWZNIU-UHFFFAOYSA-N 0.000 description 2
- MKWLGVQXOJRYGU-UHFFFAOYSA-N 2-n-(3-methylphenyl)benzene-1,2-diamine Chemical compound CC1=CC=CC(NC=2C(=CC=CC=2)N)=C1 MKWLGVQXOJRYGU-UHFFFAOYSA-N 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 240000001624 Espostoa lanata Species 0.000 description 2
- UUFIHEBXYDLWTO-UHFFFAOYSA-N N2-(4-methylphenyl)benzene-1,2-diamine Chemical compound C1=CC(C)=CC=C1NC1=CC=CC=C1N UUFIHEBXYDLWTO-UHFFFAOYSA-N 0.000 description 2
- 229940058303 antinematodal benzimidazole derivative Drugs 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003636 chemical group Chemical group 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- NXQGGXCHGDYOHB-UHFFFAOYSA-L cyclopenta-1,4-dien-1-yl(diphenyl)phosphane;dichloropalladium;iron(2+) Chemical compound [Fe+2].Cl[Pd]Cl.[CH-]1C=CC(P(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1.[CH-]1C=CC(P(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 NXQGGXCHGDYOHB-UHFFFAOYSA-L 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
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- INAAIJLSXJJHOZ-UHFFFAOYSA-N pibenzimol Chemical group C1CN(C)CCN1C1=CC=C(N=C(N2)C=3C=C4NC(=NC4=CC=3)C=3C=CC(O)=CC=3)C2=C1 INAAIJLSXJJHOZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/56—Ring systems containing three or more rings
- C07D209/80—[b, c]- or [b, d]-condensed
- C07D209/82—Carbazoles; Hydrogenated carbazoles
- C07D209/86—Carbazoles; Hydrogenated carbazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
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| CN113024477A (zh) * | 2021-03-12 | 2021-06-25 | 陕西维世诺新材料有限公司 | 一种三嗪类化合物及其制备方法 |
| EP4124619A1 (en) | 2021-07-29 | 2023-02-01 | Idemitsu Kosan Co., Ltd. | Compound, material for an organic electroluminescence device and an organic electroluminescence device comprising the compound |
| CN114518350A (zh) * | 2022-02-24 | 2022-05-20 | 吉林大学 | 一种荧光传感器及其检测气相有机胺类化合物的应用 |
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| CN106946853A (zh) * | 2017-05-11 | 2017-07-14 | 江苏三月光电科技有限公司 | 一种基于三嗪和苯并咪唑的有机化合物及其在有机电致发光器件上的应用 |
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