KR102444322B1 - 통합된 산소화물 전환 및 올레핀 올리고머화 - Google Patents

통합된 산소화물 전환 및 올레핀 올리고머화 Download PDF

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Publication number
KR102444322B1
KR102444322B1 KR1020197019635A KR20197019635A KR102444322B1 KR 102444322 B1 KR102444322 B1 KR 102444322B1 KR 1020197019635 A KR1020197019635 A KR 1020197019635A KR 20197019635 A KR20197019635 A KR 20197019635A KR 102444322 B1 KR102444322 B1 KR 102444322B1
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KR
South Korea
Prior art keywords
catalyst
conversion
weight
fraction
effluent
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KR1020197019635A
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English (en)
Korean (ko)
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KR20190094202A (ko
Inventor
스테픈 제이 맥카씨
브랜든 제이 오닐
Original Assignee
엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니
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Publication of KR20190094202A publication Critical patent/KR20190094202A/ko
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C10G57/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process with polymerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020197019635A 2016-12-07 2017-11-09 통합된 산소화물 전환 및 올레핀 올리고머화 KR102444322B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662431047P 2016-12-07 2016-12-07
US62/431,047 2016-12-07
PCT/US2017/060801 WO2018106396A1 (en) 2016-12-07 2017-11-09 Integrated oxygenate conversion and olefin oligomerization

Publications (2)

Publication Number Publication Date
KR20190094202A KR20190094202A (ko) 2019-08-12
KR102444322B1 true KR102444322B1 (ko) 2022-09-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020197019635A KR102444322B1 (ko) 2016-12-07 2017-11-09 통합된 산소화물 전환 및 올레핀 올리고머화

Country Status (6)

Country Link
US (1) US10590353B2 (de)
EP (1) EP3551729B1 (de)
JP (1) JP7128815B2 (de)
KR (1) KR102444322B1 (de)
CN (1) CN110036094B (de)
WO (1) WO2018106396A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11084983B2 (en) * 2019-01-24 2021-08-10 Exxonmobil Research And Engineering Company Fluidized bed conversion of oxygenates with increased aromatic selectivity
WO2022063995A1 (en) 2020-09-25 2022-03-31 Haldor Topsøe A/S Methanol to olefin (mto) process
CN116234890A (zh) 2020-09-25 2023-06-06 托普索公司 甲醇制烯烃(mto)方法
WO2023138876A1 (en) 2022-01-21 2023-07-27 Topsoe A/S Process and plant for conversion of oxygenates
US20230348341A1 (en) * 2022-03-29 2023-11-02 Uop Llc Process for converting olefins to distillate fuels
WO2024050427A1 (en) * 2022-08-30 2024-03-07 Uop Llc Process for converting olefins to distillate fuels with regeneration

Family Cites Families (28)

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US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
US4476338A (en) * 1983-06-02 1984-10-09 Mobil Oil Corporation Olefins from methanol and/or dimethyl ether
US4482772A (en) * 1983-11-03 1984-11-13 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4560537A (en) * 1983-11-03 1985-12-24 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4898717A (en) * 1984-01-04 1990-02-06 Mobil Oil Corp. Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
US4582815A (en) 1984-07-06 1986-04-15 Mobil Oil Corporation Extrusion of silica-rich solids
CA1235683A (en) * 1985-01-03 1988-04-26 Raymond Le Van Mao Zeolite catalysts
US4543435A (en) * 1985-01-17 1985-09-24 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle
US4935568A (en) * 1988-12-05 1990-06-19 Mobil Oil Corporation Multistage process for oxygenate conversion to hydrocarbons
EP0423288A1 (de) * 1989-04-24 1991-04-24 Mobil Oil Corporation Verwandlung von alkohol zum ätherreichen benzin
US7462207B2 (en) 1996-11-18 2008-12-09 Bp Oil International Limited Fuel composition
US6372949B1 (en) 1999-10-15 2002-04-16 Mobil Oil Corporation Single stage process for converting oxygenates to gasoline and distillate in the presence of undimensional ten member ring zeolite
MY146021A (en) 2003-06-18 2012-06-15 Shell Int Research Gasoline composition
US20070249884A1 (en) * 2006-04-20 2007-10-25 Innovenne Usa Polyolefin processes with constituent high conversion alkane dehydrogenation in membrane reactors
US9090525B2 (en) * 2009-12-11 2015-07-28 Exxonmobil Research And Engineering Company Process and system to convert methanol to light olefin, gasoline and distillate
WO2012161017A1 (ja) 2011-05-26 2012-11-29 Ｊｘ日鉱日石エネルギー株式会社 ガソリン組成物およびその製造方法
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CN107001943B (zh) * 2014-12-22 2019-06-14 埃克森美孚研究工程公司 有机含氧化合物至烃的转化

Also Published As

Publication number Publication date
JP2020513460A (ja) 2020-05-14
CN110036094A (zh) 2019-07-19
KR20190094202A (ko) 2019-08-12
JP7128815B2 (ja) 2022-08-31
EP3551729B1 (de) 2022-08-03
CN110036094B (zh) 2022-06-24
US10590353B2 (en) 2020-03-17
EP3551729A1 (de) 2019-10-16
US20180155637A1 (en) 2018-06-07
WO2018106396A1 (en) 2018-06-14

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