KR102440746B1 - 고함량-실리카 ssz-32x 제올라이트 - Google Patents

고함량-실리카 ssz-32x 제올라이트 Download PDF

Info

Publication number
KR102440746B1
KR102440746B1 KR1020197017230A KR20197017230A KR102440746B1 KR 102440746 B1 KR102440746 B1 KR 102440746B1 KR 1020197017230 A KR1020197017230 A KR 1020197017230A KR 20197017230 A KR20197017230 A KR 20197017230A KR 102440746 B1 KR102440746 B1 KR 102440746B1
Authority
KR
South Korea
Prior art keywords
zeolite
ssz
reaction mixture
feedstock
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020197017230A
Other languages
English (en)
Korean (ko)
Other versions
KR20190082919A (ko
Inventor
스테이시 이안 존스
공-얀 첸
아데올라 플로렌스 오조
Original Assignee
셰브런 유.에스.에이.인크.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 셰브런 유.에스.에이.인크. filed Critical 셰브런 유.에스.에이.인크.
Publication of KR20190082919A publication Critical patent/KR20190082919A/ko
Application granted granted Critical
Publication of KR102440746B1 publication Critical patent/KR102440746B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7492—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B01J35/0013—
    • B01J35/023—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Dispersion Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Glass Compositions (AREA)
KR1020197017230A 2016-11-17 2017-10-17 고함량-실리카 ssz-32x 제올라이트 Active KR102440746B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201662423259P 2016-11-17 2016-11-17
US62/423,259 2016-11-17
PCT/US2017/056936 WO2018093511A1 (en) 2016-11-17 2017-10-17 High-silica ssz-32x zeolite
US15/785,504 US10160657B2 (en) 2016-11-17 2017-10-17 High-silica SSZ-32x zeolite
US15/785,504 2017-10-17

Publications (2)

Publication Number Publication Date
KR20190082919A KR20190082919A (ko) 2019-07-10
KR102440746B1 true KR102440746B1 (ko) 2022-09-06

Family

ID=62106299

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020197017230A Active KR102440746B1 (ko) 2016-11-17 2017-10-17 고함량-실리카 ssz-32x 제올라이트

Country Status (6)

Country Link
US (1) US10160657B2 (enExample)
EP (1) EP3541750B1 (enExample)
JP (1) JP7138102B2 (enExample)
KR (1) KR102440746B1 (enExample)
CN (1) CN109890758B (enExample)
WO (1) WO2018093511A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4204519A1 (en) * 2020-08-31 2023-07-05 Chevron U.S.A. Inc. Process and system for base oil production
US20240165596A1 (en) 2021-03-26 2024-05-23 Chevron U.S.A. Inc. Molecular sieve ssz-93, catalyst, and methods of use thereof
US20230357030A1 (en) * 2022-05-09 2023-11-09 Chevron U.S.A. Inc. Synthesis of aluminum-containing cit-13 and cit-15 molecular sieves

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996029286A1 (en) 1995-03-17 1996-09-26 Chevron U.S.A. Inc. A process for preparing zeolites having mtt crystal structure using small, neutral amines
JP2724407B2 (ja) * 1988-06-15 1998-03-09 アンスティテュ・フランセ・デュ・ペトロール 新規ｍｔｔ構造型のゼオライトおよびその合成方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4490342A (en) * 1983-04-29 1984-12-25 Mobil Oil Corporation Synthesis of ZSM-23 zeolite
US5252527A (en) 1988-03-23 1993-10-12 Chevron Research And Technology Company Zeolite SSZ-32
US5053373A (en) 1988-03-23 1991-10-01 Chevron Research Company Zeolite SSZ-32
RU2140394C1 (ru) 1995-03-17 1999-10-27 Шеврон Ю.Эс.Эй.Инк. Получение цеолитов с использованием органического калибра и амина
FR2805255B1 (fr) 2000-02-21 2002-04-12 Inst Francais Du Petrole Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
US6509290B1 (en) * 2000-07-17 2003-01-21 Exxon Mobil Chemical Patents, Inc. Catalyst composition including attrition particles and method for making same
US6833127B2 (en) * 2000-12-22 2004-12-21 California Institute Of Technology Method of removing structure directing agents from molecular sieves
US7390763B2 (en) 2003-10-31 2008-06-24 Chevron U.S.A. Inc. Preparing small crystal SSZ-32 and its use in a hydrocarbon conversion process
US7157075B1 (en) * 2005-08-30 2007-01-02 Chevron U.S.A. Inc. Process for preparing MTT zeolites using nitrogen-containing organic compounds
US8263517B2 (en) 2007-12-28 2012-09-11 Exxonmobil Research And Engineering Company Hydroprocessing catalysts with low surface area binders
JP5468957B2 (ja) 2010-03-29 2014-04-09 Ｊｘ日鉱日石エネルギー株式会社 水素化異性化触媒、その製造方法、炭化水素油の脱蝋方法、炭化水素の製造方法及び潤滑油基油の製造方法
JP5687762B2 (ja) * 2010-06-25 2015-03-18 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ−８１
US8545805B2 (en) 2010-11-05 2013-10-01 Chevron U.S.A. Inc. Method for preparing small crystal SSZ-32
US9573124B2 (en) * 2014-05-21 2017-02-21 Chevron U.S.A. Inc. Method for making molecular sieve SSZ-95
CN105645428B (zh) 2016-02-29 2018-03-02 中国科学院山西煤炭化学研究所 具有介孔‑微孔分等级结构的ssz‑32分子筛的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2724407B2 (ja) * 1988-06-15 1998-03-09 アンスティテュ・フランセ・デュ・ペトロール 新規ｍｔｔ構造型のゼオライトおよびその合成方法
WO1996029286A1 (en) 1995-03-17 1996-09-26 Chevron U.S.A. Inc. A process for preparing zeolites having mtt crystal structure using small, neutral amines

Also Published As

Publication number Publication date
CN109890758B (zh) 2022-04-29
JP2020504698A (ja) 2020-02-13
CN109890758A (zh) 2019-06-14
US20180134572A1 (en) 2018-05-17
WO2018093511A1 (en) 2018-05-24
KR20190082919A (ko) 2019-07-10
US10160657B2 (en) 2018-12-25
JP7138102B2 (ja) 2022-09-15
EP3541750A1 (en) 2019-09-25
EP3541750B1 (en) 2020-09-09

Similar Documents

Publication Publication Date Title
JP5787765B2 (ja) 高活性のｍｔｔ骨格タイプモレキュラーシーブ
JP5586626B2 (ja) 脱ロウ触媒および方法
CN102958838B (zh) 分子筛ssz-81
AU2010321913B2 (en) Method for making aluminosilicate ZSM-12
JP2007511457A (ja) 小結晶ｓｓｚ‐３２の調製および炭化水素変換法におけるその使用
KR102691604B1 (ko) 알루미늄-풍부 *mre 골조형 분자체
CN103025659B (zh) 制备分子筛ssz-81的方法
KR102440746B1 (ko) 고함량-실리카 ssz-32x 제올라이트
EP2501664A2 (en) Process for isosomerizing a hydrocarbonaceos feedstock using aluminosilicate zsm-12
KR20230142537A (ko) Ton 프레임워크 유형 분자체의 합성

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

AMND Amendment
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E601 Decision to refuse application
PE0601 Decision on rejection of patent

St.27 status event code: N-2-6-B10-B15-exm-PE0601

AMND Amendment
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PX0901 Re-examination

St.27 status event code: A-2-3-E10-E12-rex-PX0901

PX0701 Decision of registration after re-examination

St.27 status event code: A-3-4-F10-F13-rex-PX0701

X701 Decision to grant (after re-examination)
GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000