CN109890758B - 高硅ssz-32x沸石 - Google Patents

高硅ssz-32x沸石 Download PDF

Info

Publication number
CN109890758B
CN109890758B CN201780066492.6A CN201780066492A CN109890758B CN 109890758 B CN109890758 B CN 109890758B CN 201780066492 A CN201780066492 A CN 201780066492A CN 109890758 B CN109890758 B CN 109890758B
Authority
CN
China
Prior art keywords
zeolite
ssz
sio
reaction mixture
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780066492.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN109890758A (zh
Inventor
S·I·佐内斯
陈聪岩
A·F·奥乔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Publication of CN109890758A publication Critical patent/CN109890758A/zh
Application granted granted Critical
Publication of CN109890758B publication Critical patent/CN109890758B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7492—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Dispersion Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Glass Compositions (AREA)
CN201780066492.6A 2016-11-17 2017-10-17 高硅ssz-32x沸石 Active CN109890758B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662423259P 2016-11-17 2016-11-17
US62/423,259 2016-11-17
PCT/US2017/056936 WO2018093511A1 (en) 2016-11-17 2017-10-17 High-silica ssz-32x zeolite

Publications (2)

Publication Number Publication Date
CN109890758A CN109890758A (zh) 2019-06-14
CN109890758B true CN109890758B (zh) 2022-04-29

Family

ID=62106299

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780066492.6A Active CN109890758B (zh) 2016-11-17 2017-10-17 高硅ssz-32x沸石

Country Status (6)

Country Link
US (1) US10160657B2 (enExample)
EP (1) EP3541750B1 (enExample)
JP (1) JP7138102B2 (enExample)
KR (1) KR102440746B1 (enExample)
CN (1) CN109890758B (enExample)
WO (1) WO2018093511A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4204519A1 (en) * 2020-08-31 2023-07-05 Chevron U.S.A. Inc. Process and system for base oil production
US20240165596A1 (en) 2021-03-26 2024-05-23 Chevron U.S.A. Inc. Molecular sieve ssz-93, catalyst, and methods of use thereof
US20230357030A1 (en) * 2022-05-09 2023-11-09 Chevron U.S.A. Inc. Synthesis of aluminum-containing cit-13 and cit-15 molecular sieves

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185779A (zh) * 1995-03-17 1998-06-24 切夫里昂美国公司 一种用小的中性胺类制备有mtt晶体结构的沸石的方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4490342A (en) * 1983-04-29 1984-12-25 Mobil Oil Corporation Synthesis of ZSM-23 zeolite
US5252527A (en) 1988-03-23 1993-10-12 Chevron Research And Technology Company Zeolite SSZ-32
US5053373A (en) 1988-03-23 1991-10-01 Chevron Research Company Zeolite SSZ-32
FR2632943B1 (fr) * 1988-06-15 1990-09-28 Inst Francais Du Petrole Nouveau procede de synthese de zeolites de type structural mtt
RU2140394C1 (ru) 1995-03-17 1999-10-27 Шеврон Ю.Эс.Эй.Инк. Получение цеолитов с использованием органического калибра и амина
FR2805255B1 (fr) 2000-02-21 2002-04-12 Inst Francais Du Petrole Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
US6509290B1 (en) * 2000-07-17 2003-01-21 Exxon Mobil Chemical Patents, Inc. Catalyst composition including attrition particles and method for making same
US6833127B2 (en) * 2000-12-22 2004-12-21 California Institute Of Technology Method of removing structure directing agents from molecular sieves
US7390763B2 (en) 2003-10-31 2008-06-24 Chevron U.S.A. Inc. Preparing small crystal SSZ-32 and its use in a hydrocarbon conversion process
US7157075B1 (en) * 2005-08-30 2007-01-02 Chevron U.S.A. Inc. Process for preparing MTT zeolites using nitrogen-containing organic compounds
US8263517B2 (en) 2007-12-28 2012-09-11 Exxonmobil Research And Engineering Company Hydroprocessing catalysts with low surface area binders
JP5468957B2 (ja) 2010-03-29 2014-04-09 Ｊｘ日鉱日石エネルギー株式会社 水素化異性化触媒、その製造方法、炭化水素油の脱蝋方法、炭化水素の製造方法及び潤滑油基油の製造方法
JP5687762B2 (ja) * 2010-06-25 2015-03-18 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ−８１
US8545805B2 (en) 2010-11-05 2013-10-01 Chevron U.S.A. Inc. Method for preparing small crystal SSZ-32
US9573124B2 (en) * 2014-05-21 2017-02-21 Chevron U.S.A. Inc. Method for making molecular sieve SSZ-95
CN105645428B (zh) 2016-02-29 2018-03-02 中国科学院山西煤炭化学研究所 具有介孔‑微孔分等级结构的ssz‑32分子筛的制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185779A (zh) * 1995-03-17 1998-06-24 切夫里昂美国公司 一种用小的中性胺类制备有mtt晶体结构的沸石的方法

Also Published As

Publication number Publication date
JP2020504698A (ja) 2020-02-13
CN109890758A (zh) 2019-06-14
US20180134572A1 (en) 2018-05-17
WO2018093511A1 (en) 2018-05-24
KR20190082919A (ko) 2019-07-10
US10160657B2 (en) 2018-12-25
KR102440746B1 (ko) 2022-09-06
JP7138102B2 (ja) 2022-09-15
EP3541750A1 (en) 2019-09-25
EP3541750B1 (en) 2020-09-09

Similar Documents

Publication Publication Date Title
JP5586626B2 (ja) 脱ロウ触媒および方法
KR101646299B1 (ko) 고 활성 ｍｔｔ 골격구조 유형 분자체
KR100804732B1 (ko) 작은 결정체 제올라이트 ｓｓｚ-32 및 이의 제조방법과 이를 이용한 탈납방법
EP3215267B1 (en) Base stock production using a high activity catalyst
CN109890758B (zh) 高硅ssz-32x沸石
US11542446B2 (en) Dewaxing using a molecular sieve catalyst

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant