KR102401324B1 - Manufacturing method of capsule-type laundry detergent - Google Patents
Manufacturing method of capsule-type laundry detergent Download PDFInfo
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- KR102401324B1 KR102401324B1 KR1020210164655A KR20210164655A KR102401324B1 KR 102401324 B1 KR102401324 B1 KR 102401324B1 KR 1020210164655 A KR1020210164655 A KR 1020210164655A KR 20210164655 A KR20210164655 A KR 20210164655A KR 102401324 B1 KR102401324 B1 KR 102401324B1
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- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 31
- 230000000813 microbial effect Effects 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 239000003085 diluting agent Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 238000004806 packaging method and process Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 8
- 239000012895 dilution Substances 0.000 claims description 8
- 239000002216 antistatic agent Substances 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 239000011550 stock solution Substances 0.000 claims description 6
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 150000005215 alkyl ethers Chemical class 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000001593 sorbitan monooleate Substances 0.000 claims description 4
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 4
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 2
- 239000002775 capsule Substances 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 7
- 239000000835 fiber Substances 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 4
- 239000000356 contaminant Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- 244000005700 microbiome Species 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000009447 edible packaging Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000005404 monopole Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009463 water soluble packaging Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C11D11/0017—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Microbiology (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 캡슐형 세탁세제의 제조방법으로서, 구체적으로는 계면활성제 조성물 및 미생물 희석액을 배합하여 제조한 세탁세제를 수용성 필름 안에 포장한 캡슐형 세탁세제를 제조하는 방법에 관한 것이다.The present invention relates to a method for manufacturing a capsule-type laundry detergent, and more particularly, to a method for manufacturing a capsule-type laundry detergent in which a laundry detergent prepared by mixing a surfactant composition and a microbial diluent is packaged in a water-soluble film.
캡슐형 세제는 물에 녹는 포장재(캡슐)에 1회분의 고농축 액체 세제를 채운 제품으로서, 가루형이나 액체형의 세탁세제보다 가벼우며, 쏟거나 흘릴 일이 없고 개별포장으로 사용하기 편리하다는 장점이 있다.Capsule-type detergent is a product in which a water-soluble packaging material (capsule) is filled with a high-concentrated liquid detergent.
종래에는 세탁시 편의를 높이기 위해 1회분으로 계량된 액체 세제를 수용성 필름 안에 포장하여 제조하였다. 캡슐을 구성하는 수용성 필름은 수용성으로 물 분자에 의해 쉽게 분해되는 성질이 있기 때문에, 필름이 물에 분해되지 않도록 액체세제는 물을 사용하지 않고 계면활성제만 조합하여 만들어졌으며, 이러한 방법으로 제조된 종래의 캡슐세제는 계면활성제의 성능에 높은 의존도를 가지게 되었다.Conventionally, in order to increase convenience during washing, a liquid detergent weighed in one batch was prepared by packaging in a water-soluble film. Since the water-soluble film constituting the capsule is water-soluble and has a property of being easily decomposed by water molecules, the liquid detergent is made by combining only a surfactant without using water so that the film is not decomposed in water. of capsule detergents have become highly dependent on the performance of surfactants.
또한, 종래에는 세탁세제의 부가적인 성능을 보조하기 위하여 분말형 원료를 배합하면 계면활성제의 포화도를 넘게 되어 원료의 완전 용해가 불가능하였다.In addition, in the prior art, when powdered raw materials were mixed in order to assist the additional performance of laundry detergent, the saturation of the surfactant was exceeded, so that it was impossible to completely dissolve the raw materials.
이로 인하여 세탁시 과량의 거품이 생성되고, 지방계 오염물이 발생하며, 섬유 속에 세제가 잔류하는 문제가 있었다.Due to this, there is a problem in that excessive foam is generated during washing, fatty contamination is generated, and detergent remains in the fibers.
이에 따라, 본 발명은 계면활성제에 추가적으로 배합되는 용액을 개발하여 종래의 고착화된 캡슐세제의 제조방법을 개선한 캡슐형 세탁세제의 제조방법을 제공하고 한다.Accordingly, the present invention provides a method for producing a capsule-type laundry detergent that is improved in the conventional method for producing a fixed capsule detergent by developing a solution additionally blended with a surfactant.
본 발명은 종래의 고착화된 캡슐세제의 제조방법을 개선하기 위한 것으로서, 과량의 거품, 지방계 오염물 및 섬유 속 잔류 세제의 저감을 위한 캡슐형 세탁세제의 제조방법을 제공하는 것이다.An object of the present invention is to improve a conventional method for manufacturing a fixed-capsule detergent, and to provide a method for manufacturing a capsule-type laundry detergent for reducing excessive foam, fatty contaminants, and residual detergent in fibers.
본 발명은 캡슐형 세탁세제의 제조방법으로서, a) 대전방지제, 계면활성제, 에틸알코올 및 향료를 배합하여 계면활성제 조성물을 제조하는 단계; b) 수산화나트륨, 구연산, 미생물 원액, 설탕 및 물을 배합하여 미생물 희석액을 제조하는 단계; c) 상기 계면활성제 조성물 및 미생물 희석액을 배합하여 세탁세제를 제조하는 단계; 및 d) 상기 c) 단계에서 제조한 세탁세제를 수용성 필름 안에 포장하는 단계;를 포함하며, 상기 수용성 필름은 PVA film을 포함할 수 있다.The present invention provides a method for manufacturing a capsule-type laundry detergent, comprising the steps of: a) preparing a surfactant composition by mixing an antistatic agent, a surfactant, ethyl alcohol and a fragrance; b) preparing a microbial dilution solution by combining sodium hydroxide, citric acid, microbial stock solution, sugar and water; c) preparing a laundry detergent by combining the surfactant composition and a microbial diluent; And d) packaging the laundry detergent prepared in step c) in a water-soluble film; includes, wherein the water-soluble film may include a PVA film.
상기 계면활성제 조성물은 대전방지제 6~8중량%, 폴리옥시에틸렌알킬에테르 45~55중량%, 소르비탄모노올레산염 8~12중량%, 에틸알코올 30~35중량% 및 향료 0.5~1.5중량%를 포함하며, 상기 미생물 희석액은 수산화나트륨 8~10중량%, 구연산 10~15중량%, 미생물 원액 5~15중량%, 설탕 10~20중량% 및 물 45~55중량%를 포함하고, 상기 c) 단계에서 상기 계면활성제 조성물 및 미생물 희석액을 7~8 : 2~3의 중량비율로 배합하는 것을 특징으로 할 수 있다.The surfactant composition comprises 6 to 8% by weight of an antistatic agent, 45 to 55% by weight of polyoxyethylene alkyl ether, 8 to 12% by weight of sorbitan monooleate, 30 to 35% by weight of ethyl alcohol, and 0.5 to 1.5% by weight of fragrance Including, wherein the microbial diluent contains 8 to 10% by weight of sodium hydroxide, 10 to 15% by weight of citric acid, 5 to 15% by weight of the microbial stock solution, 10 to 20% by weight of sugar, and 45 to 55% by weight of water, wherein c) In the step, it may be characterized in that the surfactant composition and the microbial dilution solution are mixed in a weight ratio of 7-8: 2-3.
본 발명에 따라 제조된 캡슐형 세탁세제는 계면활성제 조성물 및 미생물 희석액을 배합하여 세탁세제를 제조하고 수용성 필름 안에 포장함으로써, 종래의 고착화된 캡슐세제의 제조방법을 개선하였으며, 계면활성제에 대한 의존도가 줄어들어 세탁 시 과량의 거품이 발생하지 않고, 지방계 오염물이 적으며, 섬유 속 잔류 세제의 양이 저감되는 효과가 있다.The capsule laundry detergent prepared according to the present invention improved the conventional manufacturing method of the fixed capsule detergent by mixing a surfactant composition and a microbial diluent to prepare the laundry detergent and packaging it in a water-soluble film, and the dependence on surfactant was reduced. It has the effect of not generating excessive foam during washing, reducing fat-based contaminants, and reducing the amount of detergent remaining in the fibers.
도 1은 본 발명의 캡슐형 세탁세제의 제조방법을 나타낸 공정도이다.
도 2는 본 발명에 따른 캡슐형 세탁세제의 모습을 나타낸 도면이다.
도 3은 본 발명의 일실시예에 따라 제조된 캡슐형 세탁세제의 모습을 나타낸 도면이다.1 is a process diagram showing a method for manufacturing a capsule-type laundry detergent of the present invention.
2 is a view showing the appearance of a capsule-type laundry detergent according to the present invention.
3 is a view showing the appearance of a capsule-type laundry detergent manufactured according to an embodiment of the present invention.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다. 또한, 본 발명을 설명함에 있어, 관련된 공지 구성 또는 기능에 대한 구체적인 설명이 본 발명의 요지를 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명은 생략한다.Hereinafter, a preferred embodiment of the present invention and the physical properties of each component will be described in detail, which is intended to explain in detail enough that a person of ordinary skill in the art to which the present invention pertains can easily carry out the invention, This does not mean that the technical spirit and scope of the present invention is limited. In addition, in describing the present invention, if it is determined that a detailed description of a related known configuration or function may obscure the gist of the present invention, the detailed description thereof will be omitted.
계면활성제(surfactant, 界面活性劑)는 극성(친수성) 부분과 무극성(친유성/소수성) 부분을 동시에 가지고 있는 화합물로서, 물과 기름을 섞이게 해주는 물질이다. 생활 및 가정에서 가장 흔하게 볼 수 있는 계면활성제는 세제이다. 계면활성제의 소수성 꼬리 부분은 기름때와 상호 작용을 하고, 기름때를 둘러싼 계면활성제의 머리 부분은 이 기름때-계면활성제 덩어리들이 물에 녹을 수 있도록 상호 작용을 하여 기름이 물에 의해 씻겨 나가도록 한다.Surfactant (界面活性劑) is a compound that has a polar (hydrophilic) part and a non-polar (lipophilic/hydrophobic) part at the same time, and is a substance that allows water and oil to mix. The most commonly found surfactant in life and at home is detergent. The hydrophobic tail of the surfactant interacts with the grease, and the surfactant head surrounding the grease interacts to dissolve the grease-surfactant clumps in the water, causing the oil to be washed away by the water.
비이온 계면활성제(Nonionic surfactant)는 물에 녹여도 이온화되지 않는 계면활성제로서, 산이나 알칼리의 영향을 받지 않는다. 폴리옥시에틸렌알킬에테르와 다가 알코올을 친수기로 하는 고급 지방산 에스테르 등이 있다. 피부 자극이 적으며, 저농도로 높은 세정력을 얻을 수 있고, 거품 일어남이 적다. 유화제, 분산제, 세정제로서 널리 이용되고 있다.Nonionic surfactants are surfactants that do not ionize even when dissolved in water, and are not affected by acids or alkalis. and higher fatty acid esters using polyoxyethylene alkyl ethers and polyhydric alcohols as hydrophilic groups. There is little skin irritation, high cleaning power can be obtained with low concentration, and there is little foaming. It is widely used as an emulsifier, dispersant, and detergent.
본 발명에서 사용되는 계면활성제는 비이온 계면활성제인 폴리옥시에틸렌알킬에테르 및 소르비탄모노올레산염으로 한다.Surfactants used in the present invention include polyoxyethylene alkyl ether and sorbitan monooleate, which are nonionic surfactants.
대전방지제(anti-static agent, 帶電防止劑)는 합성 섬유 따위에 정전기가 발생하는 것을 막기 위해 사용하는 약제이다. 합성 섬유는 마찰에 의하여 대전(물체가 전기를 띠게 되는 현상)이 되기 쉽다. 합성 섬유 표면의 전기 저항을 작게 하여 정전기의 발생을 방지함으로써 먼지의 흡착을 막는다. 대전방지제로 표면 활성제를 주로 사용한다. 표면 활성제가 섬유의 표면에 흡착되어, 그 친수기가 표면에 배열해서 흡습성이 증대됨에 따라 전기 저항이 내려간다.An anti-static agent is a drug used to prevent static electricity from being generated in synthetic fibers, etc. Synthetic fibers are prone to electrification (a phenomenon in which an object becomes electrically charged) by friction. By reducing the electrical resistance of the synthetic fiber surface, the generation of static electricity is prevented, thereby preventing the adsorption of dust. Surface active agents are mainly used as antistatic agents. The surface active agent is adsorbed to the surface of the fiber, the hydrophilic groups are arranged on the surface, and the electrical resistance decreases as the hygroscopicity increases.
수용성필름(water-soluble film)은 물에 쉽게 녹는 필름으로, 녹말 따위로 만든 먹을 수 있는 포장 필름과 세제나 생리용품 따위에 쓰는 플라스틱 필름이 있다. PVA film은 PVA(polyvinyl alcohol)로 만들어진 수용성 필름으로, PVA는 용제에는 녹지 않으나 물에 녹는 독특한 플라스틱 수지이다. 탁월한 접착성능, 필름형성능력, 무독성 및 화학안정성이 우수하여 접착, 코팅, 제지, 섬유, 도료 등 다양한 분야에 활용되고 있다. PVA로 만든 PVA film은 수용성으로 물에 잘 녹고, 무독성이며 포장 안정성이 높아 식품, 세제, 의약품, 농약 등 다양한 포장재의 냉온수용 필름으로 널리 사용된다.A water-soluble film is a film that dissolves easily in water, and there are edible packaging films made of starch and plastic films used for detergents and sanitary products. PVA film is a water-soluble film made of PVA (polyvinyl alcohol). PVA is a unique plastic resin that does not dissolve in solvents but dissolves in water. It has excellent adhesive performance, film forming ability, non-toxicity and chemical stability, so it is used in various fields such as adhesion, coating, paper, textile, and paint. PVA film made of PVA is water-soluble, soluble in water, non-toxic, and has high packaging stability, so it is widely used as a film for cold and hot water in various packaging materials such as food, detergent, medicine, and pesticide.
미생물 원액은 EM(effective micro-organisms) 원액으로서, 자연계에 존재하는 많은 미생물 중에서 효모균, 유산균, 광합성 세균 등 유익한 미생물 수십 종을 조합, 배양한 것이다. 이러한 미생물들은 항산화 작용 혹은 생리 활성물질을 생성하며 부패를 억제하는 역할을 한다. 미생물이 생성한 효소와 유기산이 가정의 싱크대, 화장실, 하수구 등의 청소에 도움을 준다. 살균, 악취 제거 등에 뛰어난 친환경 용액이며, 주방 세제 및 세탁 세제로도 활용 가능하여 합성 세제의 사용을 줄일 수 있어 환경 개선에 도움이 된다.The microbial stock solution is an EM (effective micro-organisms) stock solution, and is a combination and culture of dozens of beneficial microorganisms, such as yeast, lactic acid bacteria, and photosynthetic bacteria, among many microorganisms in nature. These microorganisms act as antioxidants or produce physiologically active substances and inhibit spoilage. Enzymes and organic acids produced by microorganisms help clean household sinks, toilets, and sewers. It is an eco-friendly solution that is excellent for sterilization and odor removal, and it can be used as a kitchen detergent and laundry detergent, thereby reducing the use of synthetic detergents, which helps to improve the environment.
본 발명은 캡슐형 세탁세제의 제조방법에 관한 것으로서, 첨부된 도면들을 참조하여, 본 발명의 실시예에 따른 캡슐형 세탁세제의 제조방법에 대하여 설명하도록 한다. The present invention relates to a method for manufacturing a capsule-type laundry detergent, and with reference to the accompanying drawings, a method for manufacturing a capsule-type laundry detergent according to an embodiment of the present invention will be described.
도 1은 본 발명의 캡슐형 세탁세제의 제조방법을 나타낸 공정도이다.1 is a process diagram showing a method for manufacturing a capsule-type laundry detergent of the present invention.
도 1을 참조하면 캡슐형 세탁세제의 제조방법(S100)은 계면활성제 조성물 제조 단계(S110), 미생물 희석액 제조 단계(S120), 원료 배합 단계(S130), 수용성 필름 포장 단계(S140)를 포함한다.Referring to FIG. 1 , the manufacturing method (S100) of the capsule-type laundry detergent includes a surfactant composition preparation step (S110), a microbial diluent preparation step (S120), a raw material mixing step (S130), and a water-soluble film packaging step (S140). .
a) 계면활성제 조성물 제조 단계a) preparing the surfactant composition
대전방지제 6~8%, 폴리옥시에틸렌알킬에테르 45~55%, 소르비탄모노올레산염 8~12%, 에틸알코올 30~35% 및 향료 0.5~1.5%를 상온에서 배합한 후, 10분간 교반하여 계면활성제 조성물을 제조한다.After mixing 6-8% of antistatic agent, 45-55% of polyoxyethylene alkyl ether, 8-12% of sorbitan monooleate, 30-35% of ethyl alcohol and 0.5-1.5% of fragrance at room temperature, stir for 10 minutes. A surfactant composition is prepared.
상기 대전방지제로는 monopol RPE 72를 사용할 수 있으며, 상기 소르비탄모노올레산염으로는 span 80을 사용할 수 있다.Monopol RPE 72 may be used as the antistatic agent, and span 80 may be used as the sorbitan monooleate salt.
b) 미생물 희석액 제조 단계b) preparing a microbial dilution
미생물 희석액은 수산화나트륨 8~10%, 구연산 10~15%, 미생물 원액 5~15%, 설탕 10~20% 및 물 45~55%를 상온에서 배합한 후, 10분간 교반하여 미생물 희석액을 제조한다.The microbial dilution solution is prepared by mixing 8~10% sodium hydroxide, 10~15% citric acid, 5~15% microbial stock solution, 10~20% sugar, and 45~55% water at room temperature, and then stirring for 10 minutes to prepare a microbial dilution solution. .
상기 미생물 희석액은 배합과정 중 발생되는 열로 인하여 온도가 약 40℃까지 올라간다.The temperature of the microbial diluent is raised to about 40°C due to the heat generated during the mixing process.
c) 원료 배합 단계c) step of mixing raw materials
상기 계면활성제 조성물 및 미생물 희석액을 7~8 : 2~3의 비율로 상온에서 배합한 후, 10분간 교반하여 세탁세제를 제조한다.After mixing the surfactant composition and the microbial dilution solution at a ratio of 7-8: 2-3 at room temperature, the mixture is stirred for 10 minutes to prepare a laundry detergent.
상기 계면활성제 조성액은 상기 미생물 희석액의 배합과정 중 발생되는 물과 열로 인하여 완전히 용해된다.The surfactant composition solution is completely dissolved due to water and heat generated during the mixing process of the microbial diluent.
d) 수용성 필름 포장 단계d) Water-soluble film packaging step
상기 c) 단계에서 제조한 세탁세제를 포장 기계를 이용하여 PVA film을 포함하는 수용성 필름 안에 포장하여 캡슐형 세탁세제를 제조한다.The laundry detergent prepared in step c) is packaged in a water-soluble film including a PVA film using a packaging machine to prepare a capsule-type laundry detergent.
상기 포장 기계로는 수직형 또는 수평형 삼면포장기를 사용할 수 있으며, 상기 PVA film의 두께는 55~75um으로, 75um가 가장 바람직하다.As the packaging machine, a vertical or horizontal three-sided packaging machine may be used, and the thickness of the PVA film is 55 ~ 75um, most preferably 75um.
전술된 바와 같이, 본 발명에 따라 제조된 캡슐형 세탁세제는 계면활성제 조성물 및 미생물 희석액을 배합하여 세탁세제를 제조하고 수용성 필름인 PVA film 안에 포장함으로써, 종래의 고착화된 캡슐세제의 제조방법을 개선하였다.As described above, the capsule-type laundry detergent prepared according to the present invention is prepared by mixing a surfactant composition and a microbial diluent to prepare a laundry detergent and packaged in a PVA film, which is a water-soluble film, thereby improving the manufacturing method of the conventional fixed capsule detergent. did
상기와 같이 명세서에 최적의 실시예가 개시되었다. 여기서 특정한 용어들이 사용되었으나, 이는 단지 본 발명을 설명하기 위한 목적에서 사용된 것이지 의미 한정이나 특허청구범위에 기재된 본 발명의 범위를 제한하기 위하여 사용된 것은 아니다. 그러므로, 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 이해할 것이다. 따라서, 본 발명의 진정한 기술적 보호범위는 첨부된 특허청구범위의 기술적 사상에 의해 정해져야 할 것이다.As described above, the optimal embodiment is disclosed in the specification. Although specific terms are used herein, they are used only for the purpose of describing the present invention and are not used to limit the meaning or the scope of the present invention described in the claims. Therefore, it will be understood by those skilled in the art that various modifications and equivalent other embodiments are possible therefrom. Accordingly, the true technical protection scope of the present invention should be defined by the technical spirit of the appended claims.
S100 : 캡슐형 세탁세제의 제조방법
S110 : 계면활성제 조성물 제조 단계
S120 : 미생물 희석액 제조 단계
S130 : 원료 배합 단계
S140 : 수용성 필름 포장 단계S100: Manufacturing method of capsule-type laundry detergent
S110: surfactant composition preparation step
S120: microbial dilution preparation step
S130: raw material mixing step
S140: Water-soluble film packaging step
Claims (5)
b) 수산화나트륨 8~10중량%, 구연산 10~15중량%, 미생물 원액 5~15중량%, 설탕 10~20중량% 및 물 45~55중량%를 포함하는 미생물 희석액을 제조하는 단계;
c) 상기 계면활성제 조성물 및 미생물 희석액을 7~8 : 2~3의 중량비율로 배합하여 세탁세제를 제조하는 단계; 및
d) 상기 c) 단계에서 제조한 세탁세제를 PVA film을 포함하는 수용성 필름 안에 포장하는 단계;
를 포함하는 것을 특징으로 하는 캡슐형 세탁세제의 제조방법.
a) an interface comprising 6 to 8% by weight of an antistatic agent, 45 to 55% by weight of polyoxyethylene alkyl ether, 8 to 12% by weight of sorbitan monooleate, 30 to 35% by weight of ethyl alcohol, and 0.5 to 1.5% by weight of fragrance preparing an active agent composition;
b) preparing a microbial dilution containing 8 to 10% by weight of sodium hydroxide, 10 to 15% by weight of citric acid, 5 to 15% by weight of a microbial stock solution, 10 to 20% by weight of sugar and 45 to 55% by weight of water;
c) preparing a laundry detergent by mixing the surfactant composition and the microbial diluent in a weight ratio of 7-8: 2-3; and
d) packaging the laundry detergent prepared in step c) in a water-soluble film including a PVA film;
A method for manufacturing a capsule-type laundry detergent comprising a.
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| JP2000219895A (en) * | 1998-11-25 | 2000-08-08 | Dow Corning Corp | Stable liquid breaching composition containing bis(organosilyl)peroxide |
| KR20130101026A (en) * | 2010-08-23 | 2013-09-12 | 더 선 프로덕츠 코포레이션 | Unit dose detergent compositions and methods of production and use thereof |
| KR102171856B1 (en) * | 2020-05-06 | 2020-10-30 | 주식회사 블루워시 | Powder type simple detergent using water-based film |
| KR20210002876A (en) | 2019-07-01 | 2021-01-11 | 오동훈 | method of making capsule detergent dissolved in water |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000219895A (en) * | 1998-11-25 | 2000-08-08 | Dow Corning Corp | Stable liquid breaching composition containing bis(organosilyl)peroxide |
| KR20130101026A (en) * | 2010-08-23 | 2013-09-12 | 더 선 프로덕츠 코포레이션 | Unit dose detergent compositions and methods of production and use thereof |
| KR20210002876A (en) | 2019-07-01 | 2021-01-11 | 오동훈 | method of making capsule detergent dissolved in water |
| KR102171856B1 (en) * | 2020-05-06 | 2020-10-30 | 주식회사 블루워시 | Powder type simple detergent using water-based film |
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