KR20210002876A - method of making capsule detergent dissolved in water - Google Patents

method of making capsule detergent dissolved in water Download PDF

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Publication number
KR20210002876A
KR20210002876A KR1020190078694A KR20190078694A KR20210002876A KR 20210002876 A KR20210002876 A KR 20210002876A KR 1020190078694 A KR1020190078694 A KR 1020190078694A KR 20190078694 A KR20190078694 A KR 20190078694A KR 20210002876 A KR20210002876 A KR 20210002876A
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detergent
water
weight
laundry detergent
packaged
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KR1020190078694A
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Korean (ko)
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오동훈
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오동훈
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Priority to KR1020190078694A priority Critical patent/KR20210002876A/en
Publication of KR20210002876A publication Critical patent/KR20210002876A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0094Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

Abstract

The present invention relates to a detergent in which a laundry detergent packaged in quantity using polyvinyl alcohol as a water-soluble film has a gelatin sheet as an outer layer, and the laundry detergent is put in the contents. In addition, a bag of the detergent is put according to the laundry capacity without separate weighing, and the detergent melts the film in 90 seconds at 40°C and allows the laundry detergent packaged inside to be discharged. According to the present invention, since it enables the quantitative use of the detergent, excellent low-temperature storage stability and rinsing properties can be provided.

Description

물에 용해되는 캡슐세제 제조법{method of making capsule detergent dissolved in water}Method of making capsule detergent dissolved in water

본 발명은 세정 제제 분야에서 물에 쉽게 용해되는 수용성 필름을 이용한 세척 또는 세정 제제의 제조 방법에 관한 것으로 액상 세탁용 세제를 제조한 후 젤라틴 외피 시트지 수용성 필름에 1회 세탁에 필요한 양의 세제를 밀봉 포장하여 별도의 계량이 필요 없이 세탁물 용량에 맞추어 봉지째 투여하면 필름이 녹아 그 내부에 포장되었던 세탁용 세제가 배출되도록 하는 캡슐형 세탁 세제에 관한 것이다.The present invention relates to a method of manufacturing a washing or cleaning formulation using a water-soluble film that is easily soluble in water in the field of cleaning formulations. After preparing a liquid laundry detergent, the amount of detergent required for one washing is sealed in a water-soluble film on a gelatin-covered sheet paper. The present invention relates to a capsule-type laundry detergent that is packaged and administered in a bag according to the laundry volume without the need for separate weighing, so that the film melts and the laundry detergent packaged therein is discharged.

종래의 일반적인 세탁용 세제는 액상 또는 입상(분말)형이 대부분이다. 이들 세제를 사용하기 위해서는 세탁할 의류의 양 및 오염의 정도에 따라 필요한 세제량을 계량 스푼 또는 계량 컵을 이용하여 정량계량해야 하므로 불편하엿다.Conventional general laundry detergents are mostly liquid or granular (powder) types. In order to use these detergents, it is inconvenient because the amount of detergent required according to the amount of clothing to be washed and the degree of contamination must be quantitatively measured using a measuring spoon or measuring cup.

분말 세제는 세탁이 끝난 이후에도 세탁물 섬유 사이에 일정량 잔류하여 세탁물 건조시 또는 건조가 완료된 의류 세탁물을 착용하는 경우 피부에 지속적으로 좋지 않은 영향을 미치는 것으로 알려지고 있음을 고려할 때 여전히 환경 및 건강상의 문제점을 안고 있는 것이다.The powder detergent remains in a certain amount between the laundry fibers even after washing is finished, and it is still known to have a negative effect on the skin when the laundry is dried or when the dry clothes are worn. I am holding it.

분말 세제는 계량용기로 계량시 필요 이상으로 과량계량되어 세제를 과도하게 사용하게 됨으로써 세제에 의한 환경오염을증대시킬 우려가 있고, 정량 이하로 계량되는 경우 충분한 세척력을 발휘하지 못하는 문제점이 있고, 계량이나투입과정에서 분말이 날려 세제가 호흡을 통하여 직접 체내에 흡입되어 인체에 좋지 않은 영향을 주었다. When weighing in a weighing container, powder detergent is overweighed more than necessary, which leads to excessive use of detergent, which may increase environmental pollution caused by detergent, and if it is weighed below the amount, there is a problem that sufficient cleaning power cannot be exhibited. The powder was blown out during the injection process and the detergent was inhaled directly into the body through breathing, which adversely affects the human body.

상기 문제점을 해결하기 위해 부직포를 사용하여 일정량의 분말세제를 1회용 포장하여 사용하는 부직포세제가 개발되었으나 세탁 후 세탁물과 부직포를 분리 수거하여야 하는 불편함은 여전하였다.In order to solve the above problem, a nonwoven detergent was developed that uses a nonwoven fabric to pack a certain amount of powder detergent for a single use. However, the inconvenience of separating the laundry and the nonwoven fabric after washing has remained.

또한, 액상 세제의 경우, 계량용기로 계량하여 세탁기에 세제를 투입한 후에도 세제가 계량용기에 잔류하게 되므로 정량계량이어려울 뿐 아니라, 계량시 용기 외벽을 통하여 세제가 흘러내리는 등 사용상 불편한 문제점이 있다. In addition, in the case of liquid detergent, since the detergent remains in the measuring container even after the detergent is added to the washing machine after weighing in the measuring container, it is difficult to quantitate, and there are problems in use, such as the detergent flowing down through the outer wall of the container during weighing. .

기존의 세제들은 분말형 세제의 경우 장기 보관시 수분 및 기타 구성 성분들간의 상호작용으로 물성 및 내용변질과 같은 문제를 가지고 있다. Existing detergents have problems such as deterioration of properties and contents due to the interaction between moisture and other constituents during long-term storage in powdered detergents.

본 발명의 목적은, 세제 계량에 따른 불편함과 세제의 분말 날림을 방지할 수 있는 정량 포장형 세탁용액상 세제를 제공하고, 분말 세제에 비하여 수용해성이 좋아 세탁 후 의류 등에 잔류율이 낮은 액상 세제를 1회 세탁에 필요한 양의 세제를 수용성 필름으로 포장하여 과량의 세제를 사용하는 것을 방지하고, 세제 계량의 불편함을 최소화하는 것이다. An object of the present invention is to provide a quantitatively packaged laundry liquid detergent capable of preventing discomfort due to detergent metering and powder flying of the detergent, and a liquid that has a low residual rate in clothes after washing with good water solubility compared to powder detergent. It is to prevent the use of an excessive amount of detergent by wrapping the amount of detergent required for washing one time with a water-soluble film, and to minimize the inconvenience of weighing detergent.

본 발명에서는 캡슐의 내용물로 고상, 액상 및 반죽상 거의 모든 유형을 넣을 수 있다. 그래서 완성된 처방의 성분을 넣을 수 있을 뿐만 아니라 장기안정성 측면에서 격리되는 것이 좋은 효소, 표백제 등을 캡슐을 통하여 격리함으로서 그 물질들의 성능 유지를 도모할 수 있다. 처방상의 문제로 그 이상의 함량으로 적용하기가 불가능하였던 액상성분을 별개의 캡슐에 캡슐화함으로서 문제를 해결할 수 있으며, 또한 젤라틴, 탄성화제, 물의 비율을 변화시켜 캡슐의 표면 물성, 즉 탄성화도를 변화시킴으로서 캡슐이 수용액에서 용해되는 시간을 조절함에 의한 시간 지연(time-releasing) 효과를 부여할 수있다.In the present invention, almost all types of solid, liquid and pasty can be put as the contents of the capsule. So, not only can the ingredients of the completed prescription be put, but also enzymes, bleach, etc., which are good to be isolated in terms of long-term stability, can be isolated through capsules to maintain the performance of the substances. The problem can be solved by encapsulating a liquid component in a separate capsule, which was impossible to apply in a higher amount due to a prescription problem, and by changing the ratio of gelatin, elasticity agent, and water to change the surface properties of the capsule, that is, the degree of elasticity. It is possible to give a time-releasing effect by controlling the time that the capsule is dissolved in the aqueous solution.

더욱 구체적으로, 캡슐에는 캡슐의 표면 성질에 따라 경질캡슐과 연질캡슐로 나누어진다. 분말상이나 과립상의 물질은경질캡슐이 적합하지만, 액상이나 반죽상의 물질들은 경질캡슐보다 캡슐표면을 좀 더 탄성화시키고 구상 또는 난형으로 피포, 성형한 연질캡슐이 적합하다. 우선 경질캡슐은 젤라틴으로 만들어진 몸체와 캡으로 구성되고, 그 몸체와 캡에 탄성을 주기 위하여 간혹 글리세린, 아라비아 고무, 한천 등을 쓸 수 있으며, 내용물의 구별 및 보존을 위하여 착색제, 차광제 등이 첨가될 수 있다. 그리고 연질캡슐은 젤라틴에 글리세린, D-솔비톨 등의 다가 알코올을 가소제로 하여 탄력을 준 캡슐이다. 캡슐의 성분들은 수용액상에서 쉽게 팽윤되고 용해가 이루어져야 한다.캡슐의 외피를 이루는 젤라틴 시트를 제조하기 위하여 젤라틴:물:탄성화제를 (1:2.8:0.2) 내지 (1:0.5:1.5)의 중량비로 혼합한 액으로부터 시트가 제조된다.More specifically, capsules are divided into hard capsules and soft capsules according to the surface properties of the capsule. Hard capsules are suitable for powdery or granular materials, but soft capsules that are coated or molded in a spherical or oval shape with a more elasticity of the capsule surface than hard capsules are suitable for liquid or paste materials. First, hard capsules are composed of a body and cap made of gelatin, and sometimes glycerin, gum arabic, agar, etc. can be used to give elasticity to the body and cap, and colorants and light-shielding agents are added to distinguish and preserve the contents. Can be. And soft capsules are capsules that give elasticity to gelatin by using polyhydric alcohols such as glycerin and D-sorbitol as plasticizers. The components of the capsule must be easily swelled and dissolved in an aqueous solution. In order to prepare a gelatin sheet forming the outer shell of the capsule, a gelatin:water:elastic agent is used in a weight ratio of (1:2.8:0.2) to (1:0.5:1.5). A sheet is produced from the mixed liquid.

적절한 함량에 의하여 제조된 젤라틴 시트에 포함된 수분은 내용물에 영향은 아주 미비하거나 주지 않는다. 그리고 제조된 캡슐에 세제의 성분들을 한 개의 캡슐에 넣거나 혹은 성분의 성질에 따라 나누어서 두 개 이상의 캡슐에 넣어서 포장함으로서 내용물상의 장기 안정성을 향상시킬 뿐만 아니라 사용상의 계량과 분말이 날림현상이나 액상의 흘림/누수현상으로 인한 불편함을 제거함으로서 소비자의 사용 환경을 쾌적하게 한다.The moisture contained in the gelatin sheet prepared by the appropriate content has little or no effect on the contents. In addition, the long-term stability of the contents is improved by putting the ingredients of the detergent into one capsule or dividing the ingredients of the detergent into two or more capsules according to the nature of the ingredients, and not only improving the long-term stability of the contents, but also the measurement of use and the phenomenon of powder flying or liquid spillage. / By removing the inconvenience caused by the leak phenomenon, it makes the consumer's use environment comfortable.

수용성 고분자 필름에 포장할 수 있도록 액상 세탁용 세제 조성물을 제조한다. 수용성 필름에 포장할 액상 세제 조성물은 함수율이 낮아야 하므로 자연스럽게 세제의 주성분인 계면활성제의 함량이 60~70중량% 정도로 높아지기 때문에 고농축 세제이다. 이와 같이, 계면활성제의 조성비가 다른 세제류에 비해 배 이상 높기 때문에 세탁시 발생하는 거품을 소포제만으로 제어하는데 상당한 어려움이 있다. 따라서 본 발명의 세제 조성물은 각종 계면활성제들의 특성을 고려하여 거품 발생을 최소화하도록 조성비를 조절하였으며, 계면활성제에 가용제를 22~25중량% 넣고, 점도조절제 0.5중량%, 각A liquid laundry detergent composition is prepared so as to be packaged in a water-soluble polymer film. The liquid detergent composition to be packaged in a water-soluble film is a highly concentrated detergent because the water content should be low, and the content of the surfactant, which is the main component of the detergent, naturally increases to about 60 to 70% by weight. As described above, since the composition ratio of the surfactant is more than twice that of other detergents, it is difficult to control the foam generated during washing with only the antifoaming agent. Therefore, in the detergent composition of the present invention, the composition ratio was adjusted to minimize the occurrence of bubbles in consideration of the characteristics of various surfactants, 22 to 25% by weight of a soluble agent was added to the surfactant, and 0.5% by weight of a viscosity modifier, each

종 조제 2~3중량%를 넣어 액상 세제 조성물을 구성하였다. 이와 같이 구성된 액상 세제를 수용성 고분자 필름에포장하면 안정된 포장팩을 형성할 수 있으며 시간에 따라서 내구성도 1년 이상 오랫동안 유지됨을 확인할 수 있었다. 그리고, 유연 효과, 항균 효과를 발휘하기 위해서 에틸렌글리콜류, 키토산 등의 첨가제를 부가할 수있다. 항균기능이 있는 키토산은 액상 세제의 성상에 영향이 미치지 않도록 미량 첨가하였으며, 키토산의 경우양이온성을 띠므로 침전물이 발생하여 미량 추가함(0.1~0.5중량%)과 동시에 착화합물 형성을 막기 위해 EDTA를첨가하여 침전을 방지하고 골고루 분산시켰다.2 to 3% by weight of the seed preparation was added to constitute a liquid detergent composition. When the liquid detergent configured as described above is packaged in a water-soluble polymer film, a stable packaging pack can be formed, and it can be confirmed that durability is maintained for a long time for at least one year depending on time. Further, additives such as ethylene glycols and chitosan can be added in order to exert a softening effect and an antibacterial effect. Chitosan, which has antibacterial function, was added in a small amount so as not to affect the properties of the liquid detergent.Since chitosan has a cationic property, a precipitate is generated and a small amount is added (0.1 to 0.5% by weight) and EDTA is used to prevent the formation of complex compounds. It was added to prevent precipitation and was evenly dispersed.

본 발명에 따라 제조된 캡슐형 세탁용 세제는 종래의 분말, 액체, 반죽(paste)형의 세제와는 다른 개념의 세제로 캡슐에 세제성분들을 계량하여 포장함에 의하여 계량이 편하고 내용물의 변질을 현저히 줄일 수 있으며 또한 사용상의 편리를 제공한다The capsule-type laundry detergent manufactured according to the present invention is a detergent of a concept different from the conventional powder, liquid, and paste-type detergents. By measuring and packaging the detergent ingredients in the capsule, it is easy to measure and significantly reduces the deterioration of the contents. It can reduce and also provide convenience in use.

젤라틴 수용성 필름으로 포장된 액상 세제 조성물은 수용성 고분자 필름에 포장할 수있으며 포장 안정성이 높아졌고 거품 발생 억제력이 우수하다. 또한, 수용성 폴리비닐알콜 필름으로 포장된 제품은 세탁시 세탁물과 함께 세탁 중에 물에 녹아 물과 함께 쉽게 용해되는 강점이 있어 잔류세제 문제가 없다. 그러므로 본 발명은 소비자들에게 사용의 편리성을 제공함과 동시에 잔류 세제의 걱정이 없는 세제를 제공한다. 저온 보관시에도 혼탁해지거나 겔링되지 않으며, 우수한 헹굼성을 나타낸다.The liquid detergent composition packaged with a gelatin water-soluble film can be packaged in a water-soluble polymer film, has improved packaging stability, and has excellent anti-foaming power. In addition, the product packaged with a water-soluble polyvinyl alcohol film has the advantage of being dissolved in water during washing with the laundry and dissolving easily with water, so there is no problem of residual detergent. Therefore, the present invention provides a detergent that does not worry about residual detergent while providing convenience to consumers. It does not become cloudy or gelled even when stored at low temperatures, and exhibits excellent rinse performance.

본 발명은 수용성 필름 포장 액체세제 조성물에 관한 것으로, 상기 액체세제 조성물은 인체 유해성이 의심되는물질인 에탄올아민류 성분을 사용하지 않고, 비이온 계면활성제를 주성분으로 사용하여 안전성이 우수하며, 지방산염 및/또는 소포제 첨가 없이도 헹굼성이 우수하고, 저온 보관 시 혼탁해지거나 겔링되지 않는 우수한 안정성을 제공할 수 있다.The present invention relates to a liquid detergent composition for packaging a water-soluble film, wherein the liquid detergent composition does not use ethanolamine components, which are substances suspected of harm to the human body, but uses a nonionic surfactant as a main component, and has excellent safety, / Or without the addition of an antifoaming agent, it has excellent rinsing properties and can provide excellent stability that does not become cloudy or gelled when stored at low temperatures.

본 발명의 수용성 필름으로 포장된 액체세제 조성물은 비이온 계면활성제 40 내지 70 중량% 비이온 계면활성제 5 내지 35 중량% 알킬렌글리콜 10 내지 20 중량%; 및 물 2 내지 10 중량%를 포함하며, 수용성 필름으로 포장되는 것을 특징으로 한다.The liquid detergent composition packaged with the water-soluble film of the present invention comprises 40 to 70% by weight of nonionic surfactant and 5 to 35% by weight of nonionic surfactant 10 to 20% by weight of alkylene glycol; And it contains 2 to 10% by weight of water, characterized in that the packaged in a water-soluble film.

상기 비이온 계면활성제는 상기 액체세제 조성물의 헹굼성을 향상시키기 위해 포함되는 것으로, 상기 액체세제 조성물의 전체 중량에 대해 40 내지 70 중량%로 포함하는 것이 바람직하다. 더욱바람직하게는 50 내지 65 중량%이며, 상기 함량이 40 중량% 미만으로 포함되면 헹굼성을 향상시키는 효과가 미미하고, 70 중량%를 초과하여 포함되면 상 안정성이 저하되어 저온 보관 시 혼탁해 지거나 겔링되는 현상이 발생할 수 있다. The nonionic surfactant is included to improve the rinsability of the liquid detergent composition, and is preferably contained in an amount of 40 to 70% by weight based on the total weight of the liquid detergent composition. More preferably, it is 50 to 65% by weight, and when the content is less than 40% by weight, the effect of improving the rinsing property is insignificant, and when it is included in more than 70% by weight, the phase stability is lowered, resulting in turbidity when stored at low temperatures. Gelling may occur.

비이온 계면활성제는 상기 액체세제 조성물의 상 안정성을 향상시키기 위해 포함되는 것으로, 상기 액체세제 조성물의 전체 중량에 대해 5 내지 35 중량%로 포함하는 것이 바람직하다. 더욱 바람직하게는 10 내지 25 중량%이며, 상기 함량이 5 중량% 미만이면 상 안정성이 저하되어 저온 보관 시 혼탁해지거나 겔링되는 현상이 발생할 수 있으며, 35 중량%를 초과하여 포함되면 세탁 중 발생된 기포가 쉽게 터지지않아 헹굼성이 불량해 질 수 있다.The nonionic surfactant is included to improve the phase stability of the liquid detergent composition, and is preferably included in an amount of 5 to 35% by weight based on the total weight of the liquid detergent composition. More preferably, it is 10 to 25% by weight, and if the content is less than 5% by weight, phase stability may be lowered, resulting in cloudiness or gelling during low temperature storage, and if it is contained in excess of 35% by weight, it may occur during washing. Air bubbles do not burst easily, resulting in poor rinse performance.

캡슐화된 유효성분이 포함된 액체세제 조성물은, 수용성 필름으로 포장하여 캡슐화하고 이를 액체세제 조성물 내에 투입함으로써 상기 유효성분을 제외한 나머지 성분과 유효성분의 접촉을 차단할 수 있으며, 이는 상기 유효성분을 안정하게 보관하는데 탁월한 효과를 나타낸다. The liquid detergent composition containing the encapsulated active ingredient can be encapsulated by packaging with a water-soluble film, and then introduced into the liquid detergent composition to block contact between the active ingredient and the remaining ingredients other than the active ingredient, which stably stores the active ingredient. It has an excellent effect.

본 발명에 따른 액체세제 조성물은 본 발명에 따른 액체세제 조성물은 (a) 유효성분과 (b) 보조성분을 포함하는 액체세제 조성물에 있어서, 상기 (a) 유효성분은 수용성 폴리머 필름으로 포장되어 캡슐화되고, 된 것을 특징으로 하며, 상기 (b) 보조성분은 상기 보조성분의 총 중량에 대하여 계면활성제 70 내지 85 중량%, 알킬렌글리콜 10 내지 20 중량%, 및 물 1 내지 10 중량%를 포함하는 것을 특징으로 한다.In the liquid detergent composition according to the present invention, the liquid detergent composition according to the present invention comprises (a) an active ingredient and (b) an auxiliary ingredient, wherein the (a) the active ingredient is packaged with a water-soluble polymer film and encapsulated. , Wherein the (b) auxiliary component comprises 70 to 85% by weight of a surfactant, 10 to 20% by weight of alkylene glycol, and 1 to 10% by weight of water based on the total weight of the auxiliary ingredient. It is characterized.

유효성분은 상기 액체세제 조성물에 포함되는 것으로 유효성분의 함량 및 구체적인 종류는 특별히 한정되지 않고, 세탁세제 조성물에 유효한 기능을 나타내기 위해 통상적으로 사용되는 함량 및 성분을 사용할 수있다. 구체적인 성분으로는, 계면활성제, 효소, 소포제, 표백제, 유연제, 이염방지제, 탈색방지제, pH조절제,킬레이트제, 향료 및 색소 중에서 선택된 1종 이상을 포함할 수 있으며, 이는 액체상, 겔상, 분말상 및 고체상으로 이루어진 군으로부터 1종의 형태일 수 있다.The active ingredient is included in the liquid detergent composition, and the content and specific types of the active ingredient are not particularly limited, and contents and ingredients commonly used to show effective functions in the laundry detergent composition may be used. Specific ingredients may include one or more selected from surfactants, enzymes, antifoaming agents, bleaching agents, softening agents, anti-decoloring agents, decolorizing agents, pH adjusting agents, chelating agents, fragrances, and pigments, which are in liquid, gel, powder and solid forms. It may be in one type from the group consisting of.

물은 상기 보조성분 총 중량에 대해 1 내지 10 중량%를 포함하는 것이 바람직하며, 상기 함량이 10 중량%를 초과할 경우에는 수용성 필름이 용해되어 수용성 필름으로 포장된 유효성분이 액체세제 조성물 내로 유출될 가능성이 있어 바람직하지 않다.Water preferably contains 1 to 10% by weight based on the total weight of the auxiliary ingredients, and when the content exceeds 10% by weight, the water-soluble film is dissolved and the active ingredient packaged in the water-soluble film is spilled into the liquid detergent composition. This is not desirable because of the possibility.

본 발명에 따른 액체세제 조성물은 상기 수용성 폴리머 필름으로 포장된 (a) 유효성분과 (b) 보조성분을 함께 수용성 폴리머 필름으로 재포장하여 2중 이상의 다중 캡슐 형태로 구성할 수 있으며, 이는 소비자가 상기 다중 캡슐 형태로 구성된 캡슐을 하나만 사용하더라도 1회 세탁에 필요한 보조성분과 유효성분을 동시에 사용할 수 있도록 하는데 효과적이다.The liquid detergent composition according to the present invention can be configured in the form of two or more multiple capsules by repackaging the (a) active ingredient and (b) auxiliary ingredients together with a water-soluble polymer film, packaged with the water-soluble polymer film, Even if only one capsule is used in the form of multiple capsules, it is effective to simultaneously use auxiliary ingredients and active ingredients necessary for one wash.

Claims (1)

청구항 1
비이온성 고급 천연알콜계 계면활성제 23-25중량%, 음이온성 직쇄 알킬벤젠계 계면활성제 25-33중량%, 음이온성알파올레핀계 계면활성제 13-15중량%, 에틸렌글리콜 22-25중량%, 지방산염 9-10중량%로 구성된 것을 특징으로하는, 수용성 고분자 필름 포장용 액상 세탁용 세제.
청구항 2
제1항에 있어서, 상기 조성으로부터 축합반응에 의하여 생성된 함수율은 7중량% 미만인 것을 특징으로 하는, 수용성 고분자 필름 포장용 액상 세탁용 세제.
청구항 3
제1항에 있어서, 상기 세제의 pH는 7-9인 것을 특징으로 하는, 수용성 고분자 필름 포장용 액상 세탁용 세제.
청구항 4
제1항에 있어서, 상기 세제의 점도는 포장 가능한 350~500cps 범위의 값을 갖는 것을 특징으로 하는, 수용성 고분자 필름 포장용 액상 세탁용 세제.
청구항 5
제1항에 있어서, 상기 세제에는 점도조절제, 효소, 향 및 키토산으로 이루어진 그룹 중에서 선택된 한 가지 이상이 부가되는 것을 특징으로 하는, 수용성 고분자 필름 포장용 액상 세탁용 세제.
청구항 6
제1항 내지 제5항 중 어느 한 항의 액상 세탁용 세제를 함유하고, 60-80㎛ 두께의 수용성 폴리비닐알콜 필름에포장된 것을 특징으로 하는, 수용성 고분자 필름에 포장된 액상 세탁용 세제.
Claim 1
Nonionic high-quality natural alcohol-based surfactant 23-25% by weight, anionic linear alkylbenzene-based surfactant 25-33% by weight, anionic alphaolefin-based surfactant 13-15% by weight, ethylene glycol 22-25% by weight, fat Liquid laundry detergent for packaging a water-soluble polymer film, characterized in that consisting of 9-10% by weight of acid salt.
Claim 2
The liquid laundry detergent for packaging a water-soluble polymer film according to claim 1, wherein the moisture content generated by the condensation reaction from the composition is less than 7% by weight.
Claim 3
The liquid laundry detergent according to claim 1, wherein the detergent has a pH of 7-9.
Claim 4
The liquid laundry detergent for packaging a water-soluble polymer film according to claim 1, wherein the viscosity of the detergent has a value ranging from 350 to 500 cps that can be packaged.
Claim 5
The liquid laundry detergent for packaging a water-soluble polymer film according to claim 1, wherein at least one selected from the group consisting of a viscosity modifier, an enzyme, a fragrance, and chitosan is added to the detergent.
Claim 6
A liquid laundry detergent packaged in a water-soluble polymer film, characterized in that it contains the liquid laundry detergent of any one of claims 1 to 5, and is packaged in a water-soluble polyvinyl alcohol film having a thickness of 60-80 μm.
KR1020190078694A 2019-07-01 2019-07-01 method of making capsule detergent dissolved in water KR20210002876A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102401324B1 (en) 2021-11-25 2022-05-25 최제범 Manufacturing method of capsule-type laundry detergent
WO2022149923A1 (en) 2021-01-08 2022-07-14 주식회사 엘지에너지솔루션 Battery pack and vehicle comprising same
KR102588828B1 (en) 2023-05-08 2023-10-16 주식회사 자우버 Washing capsule for laundry

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022149923A1 (en) 2021-01-08 2022-07-14 주식회사 엘지에너지솔루션 Battery pack and vehicle comprising same
KR102401324B1 (en) 2021-11-25 2022-05-25 최제범 Manufacturing method of capsule-type laundry detergent
KR102588828B1 (en) 2023-05-08 2023-10-16 주식회사 자우버 Washing capsule for laundry

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