KR0153116B1 - Detergent package employing water soluble packaging film - Google Patents
Detergent package employing water soluble packaging filmInfo
- Publication number
- KR0153116B1 KR0153116B1 KR1019950042426A KR19950042426A KR0153116B1 KR 0153116 B1 KR0153116 B1 KR 0153116B1 KR 1019950042426 A KR1019950042426 A KR 1019950042426A KR 19950042426 A KR19950042426 A KR 19950042426A KR 0153116 B1 KR0153116 B1 KR 0153116B1
- Authority
- KR
- South Korea
- Prior art keywords
- detergent
- powder
- film
- packaging
- quantitative
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 94
- 229920006280 packaging film Polymers 0.000 title 1
- 239000012785 packaging film Substances 0.000 title 1
- 238000009463 water soluble packaging Methods 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 24
- 238000004806 packaging method and process Methods 0.000 claims abstract description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 10
- 238000012856 packing Methods 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000005022 packaging material Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 8
- 238000007664 blowing Methods 0.000 abstract description 6
- 239000010408 film Substances 0.000 description 26
- 239000007788 liquid Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000004745 nonwoven fabric Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000012057 packaged powder Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000013097 stability assessment Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 중합도 500~3,000인 폴리비닐 알콜을 사용하여 10~60㎛의 두께로 제조한 필름으로 분말 또는 입상의 세제를 정량포장함으로써 제조된 것을 특징으로 하는 정량 포장형 세탁세제에 대한 것으로, 본 발명에 의한 정량포장형 세탁세제는 포장재로서 사용한 필름의 용해성 뛰어나, 세탁시 물에 곧 용해하여 버리므로, 세탁후 포장재의 재분리수거과정이 필요없을 뿐만 아니라, 세제의 정량사용을 가능하게 하므로, 환경적 측면에서 종래의 의류용세제에 비해 매우 유리하다. 또한, 분말세제의 계량 및 투입시에 발생하던 분말의 날림 현상이 방지되므로 우수한 사용감을 제공할 수 있다.The present invention relates to a quantitative packaging laundry detergent, which is prepared by quantitatively packing powder or granular detergent into a film prepared in a thickness of 10 to 60 μm using polyvinyl alcohol having a polymerization degree of 500 to 3,000. Quantitative packaging laundry detergent according to the invention is excellent in the solubility of the film used as a packaging material, so that it immediately dissolves in water during washing, not only does not require a re-collection process of the packaging material after washing, but also allows the quantitative use of detergent, In terms of environment, it is very advantageous compared to the conventional laundry detergent. In addition, it is possible to provide excellent feeling because the blowing of the powder generated during the metering and input of the powder detergent is prevented.
Description
본 발명은 물에 쉽게 용해되는 수용성 필름을 이용한 정량포장형 세탁세제에 관한 것으로, 보다 상세하게는 중합도 500~3,000인 폴리비닐알콜로 제조한 두께 10~60㎛의 필름을 이용항 정량포장형 세탁세제에 대한 것이다.The present invention relates to a quantitative packaging laundry detergent using a water-soluble film easily soluble in water, and more particularly, to a quantitative packaging laundry using a film having a thickness of 10 to 60 μm made of polyvinyl alcohol having a polymerization degree of 500 to 3,000. It's about detergents.
통상적인 의류용 세제는 액상 또는 입상(분말)형이 주류를 이루고 있다. 그러나, 액상 또는 입상(또는 분말)형 세제의 경우, 만족할만한 세척효과를 얻기 위해서는 세척시 계량용기를 사용하여 정량계량하여야 하므로 불편하였다. 특히, 액상세제의 경우, 계량용기로 계량하여 세탁기에 세제를 투입한 후에도 세제가 계량용기에 잔류하게 되므로 정량계량이 어려울 뿐 아니라, 계량시 용기외벽을 통하여 세제가 흘러내리는 등 사용상 불편한 문제점이 있다. 또한, 분말(또는 입상)세제의 경우, 제품의 제조시 겉보기 비중을 세밀하게 조절하는 것이 어렵기 때문에, 계량용기로 계량시 필요이상으로 과량계량되어 세제를 과도하게 사용하게 됨으로써 세제에 의한 환경오염을 증대시킬 우려가 있고, 정량 이하로 소량 계량시에는 원하는 세척력을 발휘하지 못해 사용자에게 만족을 줄 수가 없는 문제점이 있다. 또한, 계량 또는 투입과정에서 분말이 날려 세제가 호흡을 통하여 직접 체내에 흡입되어 인체에 좋지 않은 영향을 줄 뿐 아니라 사용감도 좋지 않다.Conventional clothing detergents are mainly liquid or granular (powder) type. However, in the case of a liquid or granular (or powder) type detergent, in order to obtain a satisfactory washing effect, it is inconvenient because it has to be quantitatively measured using a measuring container. Particularly, in the case of liquid detergent, since the detergent remains in the measuring container even after the detergent is put into the washing machine after weighing into the measuring container, it is difficult to quantitatively measure, and there is an inconvenience in use such as the detergent flowing down through the outer wall of the container during weighing. . In addition, in the case of powder (or granular) detergents, it is difficult to finely control the apparent specific gravity during the manufacture of the product, so that it is excessively weighed more than necessary when weighing with a measuring container and the detergent is excessively used, thereby causing environmental pollution. There is a fear to increase, when a small amount of less than the metering does not exhibit the desired washing power there is a problem that can not give the user satisfaction. In addition, the powder is blown during the metering or injecting process, the detergent is directly inhaled through the breathing body not only adversely affects the human body, but also does not feel good.
세제 공급업자들은, 상기와 같은 세제 개량에 따른 불편함과 세제의 분말 날림을 최소화 내지 방지하기 위해, 많은 연구를 실시하여 왔으나 만족한 만한 해결책을 찾지 못하고 있는 실정이다.Detergent suppliers have been conducting a lot of research to minimize or prevent the inconvenience caused by the above-described detergent improvement and powder blowing of the detergent, but the situation is not finding a satisfactory solution.
최근에 상기와 같은 문제점을 해결하기 위해 미국의 다국적 세제회사인 암웨이사는 부직포를 사용하여 일정량의 분말세제를 1회용으로 포장하여 세탁시 이를 일정수량 세탁기에 투입하여 세탁한 후 이 부직포를 다시 세탁물과 분리하여 수거하는 세제를 판매하고 있다. 그러나, 상기 부직포를 이용한 정량포장형 세탁세제는 계량에 따른 불편함 및 세제분말 가루가 날리는 문제는 어느 정도 해결할 수 있었으나, 세탁 후 부직포를 다시 분리 수거하여야 하는 불편함이 있을 뿐 아니라, 부직포 사이에 세제가 잔류하는 경 이 많아 헹굼과정이 길게 소요되는 문제점이 있어서 제품으로서 시장에서 각광받지 못하고 있는 실정이다.Recently, in order to solve the above problems, Amway, a multinational detergent company in the United States, uses a nonwoven fabric to pack a certain amount of powder detergent into a single use, and when washing it, puts it in a certain amount of washing machine and washes the nonwoven fabric again. We sell detergent that is collected separately. However, the quantitative packaging type laundry detergent using the nonwoven fabric was able to solve some of the inconvenience of weighing and the problem of blowing the detergent powder, but there was a inconvenience to separate and collect the nonwoven fabric again after washing, and between the nonwoven fabrics. Since many detergents remain, the rinsing process takes a long time, and as a product, it is not attracting attention in the market.
또한, 영국의 유니레버사는, 상기 암웨이사에서 제조한 정량포장형 세제의 단점인 부직포에의 세제 잔류형상을 개선하기 위해, 부직포의 봉합부분에 물에 쉽게 용해할 수 있는 고분자성 물질을 부착시켜 봉합한 정량포장형 세탁세제는, 세탁 후 부직포에의 세제 잔류 문제는 어느 정도 해결할 수 있었으나, 세탁후 세탁물과 부직포를 분리 수거 하여야 하는 불편함은 여전히 해결할 수 없어 시장에서 크게 부각되지 못하고 도태되어 사라져 버린 실정이다.In addition, Unilever in the United Kingdom, in order to improve the residual shape of the detergent on the nonwoven fabric, which is a disadvantage of the fixed-weight packaging detergent manufactured by Amway, by attaching a polymer material that can be easily dissolved in water to the suture of the nonwoven fabric A fixed amount laundry detergent was able to solve the problem of residual detergent in the nonwoven fabric after washing to some extent, but the inconvenience of separately collecting the laundry and the nonwoven fabric after washing could not be solved. It is true.
한편, 본출원인은 폴리비닐알콜, 폴리비닐피롤리돈, 카복시메틸셀룰로오스, 에틸셀룰로오스, 메틸셀룰로오스, 하이드록시에틸셀룰로오스, 하이드록시프로필셀룰로오소, 하이드록시프로필메틸셀룰로오스, 폴리에틸렌옥사이드, 폴리아크릴산나트륨, 젤라틴, 카제인, 콜라겐을 1종 또는 2종이상 혼합된 수용성고분자필름으로 분말세제를 정량적으로 패키지하여 이루어진 정량형 패키지 세제를 제시한 바 있다(국내특허공개 제92-9971호). 그러나, 상기 정량형 패키지 세제는 수용성 고분자 필름에 대한 연구가 미비하여, 필름의 물에 대한 용해성 및 수분투과성이 만족스럽지 못하였다.The present applicant is polyvinyl alcohol, polyvinylpyrrolidone, carboxymethyl cellulose, ethyl cellulose, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, polyethylene oxide, sodium polyacrylate, A quantitative package detergent consisting of quantitatively packaged powder detergent with a water-soluble polymer film containing one or two or more kinds of gelatin, casein and collagen has been proposed (Domestic Patent Publication No. 92-9971). However, the quantitative package detergent has not been studied on the water-soluble polymer film, so that the water solubility and water permeability of the film was not satisfactory.
이와 같은 상황하에서, 본 발명자들은 세제 개량에 따른 불편함과 세제의 분말날림을 방지하고, 기조의 정량포장형 세탁세제의 문제점을 해결하고자 광범위하고도 철저하게 연구하여 오던 중, 물에 대한 용해성 및 수분투과성이 적절한 수용성 고분자인 폴리비닐 알콜을 이용하여 만든 필름으로 세제를 정량포장함으로써, 세탁후 세제 포장재의 분리 수거 과정이 필요없을 뿐만 아니라 세제의 정량사용을 가능케 하여 환경적으로도 유리한 정량포장형 세탁세제를 제공할 수 있음을 발견하고 본 발명을 완성하였다.Under such circumstances, the inventors of the present invention have been extensively and thoroughly researched to prevent inconveniences caused by the improvement of the detergent and the powder blowing of the detergent, and to solve the problems of the quantitatively packed laundry detergent, while the solubility in water and Quantitative packaging of detergent with a film made of polyvinyl alcohol, a water-soluble polymer with adequate water permeability, which eliminates the need for separate collection of detergent packaging materials after washing, and also enables the quantitative use of detergent. The present invention was found to be able to provide a laundry detergent and to complete the present invention.
따라서, 본 발명의 목적은, 세제 계량에 따른 불편함과 세제의 분말 날림을 방지할 수 있는 정량포장형 세탁세제를 제공하는 것이다.Accordingly, it is an object of the present invention to provide a fixed amount laundry detergent that can prevent the discomfort due to the measurement of detergent and powder blowing of the detergent.
본 발명의 또다른 목적은, 세탁 후 세제 포장재에 세제가 전혀 잔류하지 않고 세탁후 세탁물과 세제 포장재를 분리 수거할 필요가 없는 정량포장형 세탁세제를 제공하는 것이다.It is still another object of the present invention to provide a fixed amount laundry detergent which does not have any detergent remaining in the detergent packaging material after washing and does not need to separately collect the laundry and the detergent packaging material after washing.
이하, 본 발명을 보다 상세히 설명한다.Hereinafter, the present invention will be described in more detail.
세제의 정량포장에 사용될 수 있는 포장재는, 제품의 포장성, 저장 안전성 및 사용시 물에 대한 용해성의 관점에서 적합한 것이어야 한다.Packaging materials that can be used for quantitative packaging of detergents should be suitable in view of the product's packaging, storage safety and solubility in water in use.
본 발명의 정량포장형 세탁세제의 포장재로 사용되는 수용성 고분자 필름은 상기 세 가지 관점에서 적절한 중합도를 갖는 폴리비닐 알콜에 필름의 성형성을 용이하게 하는 여러가지 첨가제를 가하여 제조된 것이다.The water-soluble polymer film used as a packaging material for the quantitative packaging laundry detergent of the present invention is prepared by adding various additives to facilitate the moldability of the film to the polyvinyl alcohol having an appropriate degree of polymerization from the above three viewpoints.
본 발명자들은 본 발명의 목적에 적합한 정량포장형 세제를 제조하기 위한 수용성 필름의 조건을 연구한 결과, 항장력(抗張力, Tensile Strength)이 1.5~6.0kgf/mm2이며,신장도(Elongation)가 100~700%이고, 영 계수(Young's Modulus)값이 100~300kgf/mm2이며, 인열강도(Tear Strength)값이 20~80kgf/cm인 것이 적절하다는 것을 발견하였으며, 상기한 조건을 만족하는 필름을 제조하기 위해서는, 중합도가 500~3,000인 폴리비닐 알콜을 사용하여 10~60㎛ 두께의 필름으로 제조하여야 함을 알게 되었다.The present inventors have studied the conditions of the water-soluble film for producing a quantitative packaging detergent suitable for the purpose of the present invention, the tensile strength (Tensile Strength) is 1.5 ~ 6.0kgf / mm 2 , the elongation (Elongation) 100 It was found that it is appropriate to have a 700-%, Young's Modulus value of 100-300 kgf / mm 2 , and a tear strength value of 20-80 kgf / cm, and satisfy the above conditions. In order to prepare a, it was found that the polyvinyl alcohol having a degree of polymerization of 500 to 3,000 should be prepared into a film having a thickness of 10 to 60 μm.
본 발명에 의한 정량포장형 세제는, 세제의 제조 단계, 폴리비닐 알콜 및 필름 제조에 필요한 첨가제들을 제조될 수 있는데, 포장에 사용되는 세제의 제조방법은 통상의 의류용 세제를 제조하는 방법에 따라 제조하며, 세제의 조성역시 통상의 의류용세제의 그것과 동일하고 주로 다음과 같은 것을 함유한다.Quantitatively packaged detergent according to the present invention, the additives required for the manufacturing step of the detergent, polyvinyl alcohol and film production can be prepared, the manufacturing method of the detergent used for packaging according to the conventional method for manufacturing a detergent for clothes The composition of the detergent is also the same as that of the general laundry detergent and mainly contains the following.
세제의 조성물Composition of detergent
(1) 1종 이상의 계면활성물질 : 10~50중량%(1) at least one surfactant: 10 to 50% by weight
(2) 알카리금속 탄산염, 규산염 및 황산염 : 10~40중량%(2) Alkali metal carbonates, silicates and sulfates: 10-40 wt%
(3) 알루미노 규산나트륨(제오라이트) : 10~30중량%(3) Sodium alumino silicate (zeolite): 10-30 wt%
(4) 통상의 세제에 사용하는 각종첨가제 : 1~10중량%(4) Various additives for use in ordinary detergents: 1 to 10% by weight
또한, 본 발명에 의한 정량세제 포장용 필름의 제조방법은 특별히 한정되어 있는 것이 아니며, 중합도가 500~3,000인 폴리비닐 알콜을 사용하여 공지의 방법에 의해 10~60㎛ 두께의 필름으로 제조한다.In addition, the manufacturing method of the film for quantitative detergent packaging by this invention is not specifically limited, It manufactures into a film of 10-60 micrometers thickness by a well-known method using polyvinyl alcohol of 500-3,000 polymerization degree.
본 발명에 의한 정량포장형 세탁세제에서 낱게 포장되는 세제의 양은 10~100g 단위, 바람직하게는 20~60g 단위가 되도록 한다.The amount of the detergent packaged separately in the fixed amount laundry detergent according to the present invention is 10 to 100g units, preferably 20 to 60g units.
이하, 본발명을 실시예를 통해 보다 상세히 설명하지만 하기하는 실시예가 본 발명을 한정하는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples, but the following Examples are not intended to limit the present invention.
[참고예 1]Reference Example 1
[정량세제포장용 필름의 제조][Manufacture of Film for Packaging Detergent]
500~3000의 중합도를 갖는 폴리비닐 알콜에 적절한 소성제(다가알콜)를 적당량 혼합하여 두께 10~60㎛의 필름으로 제조하였다.An appropriate amount of a baking agent (polyalcohol) was mixed with a polyvinyl alcohol having a polymerization degree of 500 to 3000 to prepare a film having a thickness of 10 to 60 µm.
[참고예 2]Reference Example 2
[세제 조성물의 제조][Production of Detergent Composition]
A-1 성분이 함량이 60%가 되도록 분말세제 제조공정용 공정수를 가해 슬러리를 제조한 후, 통상의 분무건조탑을 이용 제품중 수분이 5% 이내가 되도록 건조하였다.After the slurry was prepared by adding the process water for the powder detergent manufacturing process so that the content of the A-1 component was 60%, the spray drying tower was dried so that the moisture in the product was within 5%.
건조분말(A-1) 83중량%에 비이온 계면활성제 4중량%를 혼합하여 조립기를 이용하여 겉보기비중이 750~800g/ℓ가 되도록 조립한 후 제오라이트를 혼합하여 입자 표면을 개질하고 효소 및 향을 첨가하여 세제를 제조하였다.After mixing 83% by weight of dry powder (A-1) with 4% by weight of nonionic surfactant, use a granulator to assemble the apparent specific gravity to 750 ~ 800g / l, and then mix the zeolite to modify the surface of the particles, enzymes and flavors. Was added to prepare a detergent.
[실시예 1~12 및 비교예 1~14][Examples 1-12 and Comparative Examples 1-14]
상기 표에서 나타난 중합도의 폴리비닐 알콜을 사용하여 각각의 두께의 필름으로 제조한 후, 참고예 2에서 제조한 세제 30g씩을 낱개 포장하였다.After using the polyvinyl alcohol of the degree of polymerization shown in the table to prepare a film of each thickness, 30g each of the detergent prepared in Reference Example 2 was individually packed.
[시험예 1][Test Example 1]
[세제의 사용성 평가][Ease of use evaluation of detergent]
상기 실시예 1~12 및 비교예 1~14에서 제조된 정량포장된 세제의 사용성을 다음과 같은 방법으로 평가하였다.The usability of the packaged detergent prepared in Examples 1 to 12 and Comparative Examples 1 to 14 was evaluated by the following method.
가정에서 매일 세탁을 행하는 주부 100명을 대상으로 기존에 사용하는 의류용 분말 세탁세제와 액체 세탁세제를 비교대상세제로 선정하여 실시예 1~12 및 비교예 1~14의 정량포장형 세탁세제의 사용성을 다음과 같이 점수로 평가하게 하여 그 평균값을 계산하고 그 결과를 하기의 표에 나타내었다.For 100 housewives who wash daily at home, the powder laundry detergent and the liquid laundry detergent for clothes were used as comparative detergents, and the quantitative packaging laundry detergents of Examples 1 to 12 and Comparative Examples 1 to 14 were used. The usability was evaluated by the score as follows and the average value was calculated and the results are shown in the following table.
5점 : 기존의 분말세제 및 액체세제보다 사용성이 현저하게 편리한 경우5 points: When the usability is significantly more convenient than conventional powder and liquid detergents.
4점 : 다소 편리한 경우 3점 : 동일한 경우4 points: Somewhat convenient 3 points: Same case
2점 : 다소 불편한 경우 1점 : 매우 불편한 경우2 points: Somewhat uncomfortable 1 point: Very uncomfortable
따라서, 본 발명에 의한 정량포장형 세탁세제는 사용감에 있어서, 기존의 의류용 분말 세탁세제와 액체 세탁세제에 비해 훨씬 우수함을 알 수 있다.Therefore, it can be seen that the quantitative packaging laundry detergent according to the present invention is much superior to the conventional laundry powder laundry detergent and liquid laundry detergent in terms of use.
[실험예 2]Experimental Example 2
[필름의 용해성 평가][Solubility Evaluation of Film]
상기 실시예 1~12 및 비교예 1~14에서 제조된 정량포장된 세제의 필름의 용해성을 다음과 같은 방법으로 평가하였으며, 그 결과는 하기의 표에 나타내었다.The solubility of the films of the quantitatively packed detergents prepared in Examples 1 to 12 and Comparative Examples 1 to 14 were evaluated by the following method, and the results are shown in the following table.
(가) 1ℓ 비이커에 800cc의 이온교환수를 채운다(20℃).(A) Fill 1 liter beaker with 800 cc of ion-exchanged water (20 ℃).
(나) 4cm×4cm 크기로 절단한 필름을 매단다.(B) Hang the film cut into 4cm × 4cm size.
(다) 마그네틱바를 600㎖선까지 수류가 생길 수 있는 속도로 회전시킨다.(C) Rotate the magnetic bar at a speed that can generate water flow up to 600ml.
(라) 필름이 용해되어 육안으로 관찰되지 않는 시점까지 소요되는 시간을 측정한다.(D) Measure the time taken until the film is dissolved and not visually observed.
[실험예 3]Experimental Example 3
[저장 안정성 평가][Storage Stability Assessment]
상기 실시예 1~12 및 비교예 1~14에서 제조된 정량포장된 세제를 40℃ 상대 습도 80%를 갖는 항온항습실에 통상의 세제와 동일하게 외부포장을 하고 3개월간 보관하면서 안정도를 육안으로 관찰하여 다음과 같이 점수로 평가하고 그 평균값을 하기의 표에 나타내었다.The quantitatively packaged detergents prepared in Examples 1 to 12 and Comparative Examples 1 to 14 were externally packaged in a constant temperature and humidity chamber having a relative humidity of 80% at 40 ° C. and stored for 3 months, and visually observed for stability. It was evaluated by the score as follows and the average value is shown in the following table.
3점 : 기존의 분말세제 및 액체세제보다 저장 안정성이 우수한 경우3 points: When storage stability is better than conventional powder and liquid detergents.
2점 : 기존의 분말세제 및 액체세제와 동일한 수준인 경우2 points: When it is the same level as the conventional powder detergent and liquid detergent
1점 : 기존의 분말 세제 및 액체 세제보다 저장 안정성이 나쁜 경우1 point: When storage stability is worse than conventional powder detergent and liquid detergent
상기 실험예 1~3의 결과에서 알 수 있는 바와 같이, 본 발명에 의한, 중합도 500~3,000인 폴리비닐알콜로 제조한 두께 10~60㎛의 필름을 이용한 정량포장형 세탁세제는 세제의 사용성, 필름의 용해도 및 세제의 저장 안전성 면에서 모두 만족스러운 효과를 갖는 반면, 중합도가 500미만인 폴리비닐알콜을 사용하거나 필름의 두께가 10㎛미만인 경우에는 세제의 저장안정성 및 사용감 측면에서 좋지 못하며, 중합도가 3,000이 넘는 폴리비닐알콜을 사용하거나 필름의 두께가 60㎛를 넘는 경우에는 필름의 용해도가 좋지 못함을 알 수 있다.As can be seen from the results of Experimental Examples 1 to 3, the fixed-quantity type laundry detergent using a film having a thickness of 10 to 60 μm made of polyvinyl alcohol having a polymerization degree of 500 to 3,000 according to the present invention is used for detergents, While both have a satisfactory effect in terms of solubility of the film and storage stability of the detergent, when polyvinyl alcohol having a polymerization degree of less than 500 or a thickness of the film is less than 10 μm, it is not good in terms of storage stability and feel of the detergent. It can be seen that the solubility of the film is not good when using more than 3,000 polyvinyl alcohol or when the thickness of the film exceeds 60㎛.
본 발명에 의한 정량포장형 분말세제는 포장재로서 사용한 필름의 용해성이 뛰어나, 세탁시 물에 곧 용해하여 버리므로, 세탁후 포장재의 분리수거과정이 필요없을 뿐만 아니라, 세제의 정량사용을 가능하게 하므로, 환경적 측면에서 종래의 의류용세제에 비해 매우 유리하며, 분말세제의 계량 및 투입시에 발생하던 분말의 날림 현상이 방지되므로 우수한 사용감을 제공할 수 있다.Quantitative packaging powder detergent according to the present invention is excellent in the solubility of the film used as a packaging material, because it immediately dissolves in water during washing, not only does not require a separate collection process of the packaging material after washing, it also enables the quantitative use of detergent In terms of environment, it is very advantageous compared to the conventional laundry detergent, and can prevent the blowing of the powder generated during the weighing and input of the powder detergent, thereby providing an excellent feeling of use.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950042426A KR0153116B1 (en) | 1995-11-21 | 1995-11-21 | Detergent package employing water soluble packaging film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019950042426A KR0153116B1 (en) | 1995-11-21 | 1995-11-21 | Detergent package employing water soluble packaging film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970027282A KR970027282A (en) | 1997-06-24 |
| KR0153116B1 true KR0153116B1 (en) | 1998-11-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950042426A KR0153116B1 (en) | 1995-11-21 | 1995-11-21 | Detergent package employing water soluble packaging film |
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| Country | Link |
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| KR (1) | KR0153116B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102171856B1 (en) | 2020-05-06 | 2020-10-30 | 주식회사 블루워시 | Powder type simple detergent using water-based film |
-
1995
- 1995-11-21 KR KR1019950042426A patent/KR0153116B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102171856B1 (en) | 2020-05-06 | 2020-10-30 | 주식회사 블루워시 | Powder type simple detergent using water-based film |
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| Publication number | Publication date |
|---|---|
| KR970027282A (en) | 1997-06-24 |
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