KR102349949B1 - Composition for improving of shining effect - Google Patents

Abstract

The composition for enhancing gloss according to the present invention contains a functional ingredient having one or more amine or carboxyl reactive groups capable of covalent bonding with proteins of hair, scalp, skin, nails, leather or fibers, so that the protein and the functional ingredient are shared By forming a bond, it provides a semi-permanent gloss enhancement effect.

Description

Composition for improving of shining effect}

The present invention relates to a composition for enhancing the gloss of hair, skin, nails, leather or fibers.

The skin is a tissue covering the surface of the body, and consists of the epidermis, dermis, and subcutaneous fat layer, and skin appendages include sweat glands, sebaceous glands, hair, hands, and toenails. The epidermis, which constitutes the outermost layer of the skin, is derived from the ectoderm and is largely composed of an inner part composed of living cells called the Malphyoid layer and an outer part, which is a stratum corneum consisting of non-nucleated, flat, dry dead cells. The thickness of the face is 0.03 mm to 1 mm, hands and soles 0.16 mm to 0.8 mm, and the thinnest eyelid is about 0.1 mm. The epidermis is mainly stratified squamous keratinized epithelium, mainly composed of keratinocytes, and other melanocytes, Langerhans cells, and Merkel cells exist.

Keratinocytes are a major component of the epidermis and consist of four layers, the stratum corneum, granular layer, stratum corneum, and basal layer from the outer part of the epidermis.

Millions of new cells are formed in the epidermis every day, and they do not stay in one place and start to be pushed out to the outermost part of the epidermis. During this time, these cells gradually turn into hard keratin. The cells of the epidermis are first created in the basal layer, and their shape and function are also changed as they are gradually pushed out to the surface.

As the epidermis is keratinized, the shape gradually changes into the basal layer, the stratum corneum, the granular layer, and the stratum corneum, and these cells are all cells created in the process of forming keratin, so they are called keratinocytes.

The differentiation process in keratinocytes consists of 4 steps: 1) the division of basal cells, 2) the synthesis and maintenance process in apical cells, 3) the autolysis process in granule cells, and 4) the rebuilding process in keratinocytes. The stratum corneum is formed as the last stage of differentiation. This process is called keratinization.

The lifespan of keratinocytes is about 28 days, and although it varies slightly depending on the area, millions of them fall off every day, and millions of new cells are created and raised from the underlying layer. Aged keratinocytes continue to fall off from the skin surface of the human body, and in aged skin, it takes more time for the stratum corneum to fall, causing the stratum corneum to become thicker. Therefore, the decrease in the function of keratinocytes increases the number of dead cells and causes fine lines and rough skin.

The stratum corneum is the outermost hard and dry thin shell of keratinocytes, which forms the keratin, and is composed of 20 to 25 layers. The stratum corneum gets its name from the fact that it is made up of keratin, which is a hardened protein. The shape of the stratum corneum becomes flatter and elongated as it approaches the surface of the skin. Main ingredients include keratin protein (58%), lipids (11%), and natural moisturizing factor (NMF, 38%). The thickness varies depending on the part of the body, and the stratum corneum is very thick in parts such as the palms and soles of the feet, so it can withstand physical shocks, friction, or trauma in daily life. Although the stratum corneum is composed of dead cells without nuclei and a protein called keratin, it occupies the most important position in the protective function of the skin. This stratum corneum acts as an important defense barrier that prevents bacteria or external toxic substances from invading the body, and prevents moisture from escaping from the inside of the body. Keratin protein (58%), a major component of the keratin of the skin, is glycine, alanine, valine, leucine, isoleucine, threonine, serine, cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid, diiodotyrosine, lysine, It is composed of amino acids such as histidine, phenylalanine, tyrosine, tryptophan, proline, and oxyproline. In particular, keratin constituting the keratin of the skin is about 6.4 to 8.1% of aspartic acid, about 9.1 to 15.4% of glutamic acid, and about 3.1 to 6.9% of lysine. includes

In general, hair is a keratinized structure formed by invading the epithelium of the epidermis as an appendage of the mammalian skin, and corresponds to an appendage of the skin along with sweat and sebaceous glands. Hair includes all hairs covering the outside of the human body, such as hair, fluff, beard, armpit hair, and pubic hair, and in some cases, refers only to the hair on the scalp.

Hair is composed of keratin protein, the same as the main component of the stratum corneum of the skin, and keratin is largely divided into two types according to its origin. The keratin that makes up the stratum corneum of the skin is called soft keratin, and the keratin that makes up hair and nails is called hard keratin. This is due to the difference in the content of cysteine, one of the amino acids. Hard keratin has a high cysteine content and soft keratin has a low content. Therefore, hard keratin has strong resistance to external stimuli or invasion of chemicals.

Hair fibers have a thickness of about 50 to 100 μm, and are composed of a cuticle called a hair cortex and a cortex called a cortex, and sometimes have a medulla called a medulla in the middle part . All of these cells are dead cells, mostly filled with keratin protein.

About 65 to 95% of human hair is composed of keratin protein, and contains water, lipids (bound and unbound forms), pigments, and trace elements. Proteins are made by forming long chains of a mixture of about 20 to 50 amino acids, each of which is wound in a spiral or coil shape.

Among the numerous amino acids that make up human hair, cystine is one of the most important amino acids. Cystine is composed of two cysteines (thiols) present in different amino acid chains, and forms a disulfide bond, known as a very strong bond, that forms a bond between two sulfur atoms in a state of being close to each other. are doing In addition to disulfide bonds, hair contains very abundant peptide bonds. Also, the presence of many CO- and NH- groups causes hydrogen bonds between neighboring chain molecular groups. However, the physical properties of the hair appear due to the high cystine content, which is a very unique part of the cellular structure of human hair. The pigment that is related to the color of hair is melanin, which is mainly present in the form of granules in the cortex of human hair.

Most of the hair is protein, and the rest are melanin, lipids, trace elements, and moisture. The protein that makes up most of the amino acid composition of hair is keratin protein, which contains a lot of cysteine. Hair keratin is composed of about 18 kinds of amino acids, and in its composition, the content of cysteine is higher than that of human epidermis. In addition, the ratio of histidine, lysine, and arginine, which are basic amino acids, is 1:3:10, which is unique to hair keratin. Skin collagen is free of cysteine and is instead high in glycine, proline, and alanine. The melanin pigment, which determines the color of hair, is contained in hair at about 3% or less.

In addition to protein and melanin pigment, hair contains minerals and trace elements such as copper, zinc, iron, manganese, calcium, and magnesium, and it is known that inorganic components such as phosphorus, silicon, and the like exist.

In addition to the peptide bond between amino acids in the protein, intermolecular force or binding force exists between each protein molecule, and the hair maintains its properties and shape by this bond. The types of bonds are largely cross-linked, such as cystine bonds and peptide bonds, and non-crosslinked salt bonds, hydrogen bonds, and hydrophobic interactions. Among them, the cystine bond (Disulfide Bond; -CH ₂ -SS-CH ₂ -) is specific to a protein containing sulfur (S), a side chain bond not seen in other fibers, and a bond characteristically seen in keratin to be. With this cystine bond, keratin exhibits strong physicochemical properties.

Keratin protein (58%), the main component of hair, is glycine, alanine, valine, leucine, isoleucine, threonine, serine, cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid, diiodotyrosine, lysine, arginine, histidine. , is composed of amino acids such as phenylalanine, tyrosine, tryptophan, proline, and oxyproline. In particular, keratin constituting hair contains about 3.9 to 7.7% of aspartic acid, about 13.6 to 14.2% of glutamic acid, and about 1.9 to 3.1% of lysine do.

Fibers are generally divided into natural fibers and man-made fibers. Among natural fibers, fibers obtained from animal bodies are called animal fibers, and since their chemical components are proteins, they are also called protein-based fibers. Protein-based fibers include fibers obtained from animal hair and cocoons. Fibers obtained from animal hair are wool fibers obtained from sheep hair and hair fibers obtained from goats, camels, rabbits, horses, cattle, and other animals. can be divided into

As with hair, glycine, alanine, valine, leucine, isoleucine, threonine, serine, cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid, diiodotyrosine, lysine, arginine, histidine, phenylalanine, tyrosine, It is composed of amino acids such as tryptophan, proline, and oxyproline, and wool (wool), which is most commonly used among these protein-based fibers, is known to have a composition similar to that of hair.

These protein-based fibers, hair, skin, nails, and leather are a kind of protein that is very strong under mild conditions such as water or neutral solvents, but combing, heat from a dryer, dyeing, perming, and physical friction in daily life It can be easily damaged by physical/chemical treatment and environmental stress, such as washing, sunlight, heat of ironing, adsorption of dirt, exposure to ultraviolet rays, exposure to high and low temperatures, seawater, and lime powder in swimming pools. As a result, damaged hair, skin, nails, and fibrous leather are eluted with internal and external proteins and become porous and rough, resulting in loss of softness and elasticity. may occur.

Therefore, treatment agents are used to improve the surface properties of substrates such as hair, skin, fibers, and leather to maintain a beautiful and healthy appearance. In particular, gloss, softness and smoothness are important representative surface properties to be improved.

As a representative example of a treatment agent for imparting shine, cosmetic preparations that can be used for hair, such as shampoo, conditioner, treatment, wax, spray, mousse, hair lotion, essence, hair cream, pack, mask, sheet, etc. In terms of skin, there are cosmetic preparations that can be used on the skin such as skin, lotion, essence, serum, cream, gel, foundation, powder, makeup base, point makeup, mask, patch, etc. Textile care agents that can be used for textiles, such as textile dyes, laundry detergents, treatment agents, post-treatment agents, laundry aids, partial stain removers, and sprays, may be mentioned. Also in the nail treatment agent, preparations which can be used for the hand and toenails, such as a brightening agent, a nutritional agent, and a strengthening agent, are mentioned. Also in leather products, preparations for leather treatment such as creams, lotions, essences, serums, gels, waxes, sprays, detergents, cleaners, partial decontamination agents, ointments, polishes, strips, and sheets can be mentioned.

In addition, in general, cosmetic means 'to clean the body, beautify it, increase attractiveness, change the appearance, or keep skin or hair healthy by applying, dispersing, or other similar methods to the body. It is defined as 'meaning a thing with a slight effect on the human body'. Such cosmetics include various functions to keep various parts of the human body healthy and beautiful, such as skin, hair, nails and toenails, and among them, gloss and gloss are one of the main functions of cosmetics.

Common raw materials constituting these cosmetic cosmetics include oil, wax, hydrocarbons, higher fatty acids, higher alcohols, ester oil, silicone oil, etc., anionic, cationic, amphoteric, nonionic surfactants, moisturizers, thickeners, and Contains high molecular weight compounds used as film forming agents, UV absorbers and blockers, antioxidants, sequestering agents, coloring materials including dyes and pigments, fragrances, and preservatives.

In addition, oils and fats, natural or synthetic fatty acids, fatty alcohols, alcohols, alkylglyceryl ethers, esters, hydrocarbons, silicones, fluorine compounds, polyalcohols, sugars, natural or synthetic polymers, waxes, Vitamins, hormones, amino acids, peptides, proteins, animal and plant extracts, mineral extracts and derivatives thereof and the like may be included.

However, most of the functional ingredients contained in these compositions impart an effect by simple adsorption. After treatment with the composition, the luster is continuously reduced due to various external environments occurring in daily life, and there is a disadvantage in that the effect disappears due to the loss of functional ingredients after washing.

For example, Patent Document 1 discloses a composition for hair washing that contains a high content of oil and polyol and at the same time contains a surfactant to provide softness and shine to the hair, and Patent Document 2 discloses a composition for hair washing by including a camellia extract Although a cosmetic composition that imparts shine has been disclosed, the oil or camellia extract, which is the main component for giving shine of the two compositions, is easily washed off by washing by simply adsorbing or hydrophobic bond to the hair, and the effect is long lasting. There is a problem with this falling.

Korean Patent Publication No. 2014-0141303 Korean Patent Publication No. 2013-0122070

SUMMARY OF THE INVENTION It is an object of the present invention to provide a gloss enhancing composition capable of imparting gloss to hair, scalp, skin, nails, leather or fibers.

Another object of the present invention is to provide a care product comprising the composition for enhancing gloss.

As a means for solving the above problems, the present invention

At least one selected from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine (Met), allantoin (Allantoin) and derivatives thereof functional ingredients; And it provides a composition for enhancing gloss comprising a reaction medium.

In addition, the present invention provides a care product comprising the composition.

The composition for enhancing gloss according to the present invention contains a functional ingredient having one or more amine or carboxyl reactive groups capable of covalent bonding with proteins of hair, scalp, skin, nails, leather or fibers, so that the protein and the functional ingredient are shared By forming a bond, it provides a semi-permanent gloss enhancement effect.

The present invention is from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine (Met), allantoin (Allantoin) and derivatives thereof one or more selected functional ingredients; And it relates to a composition for enhancing gloss comprising a reaction medium.

In the present invention, the 'composition for enhancing luster' refers to a functional component with excellent gloss-imparting properties and a component of hair, scalp, nail, skin, leather, or fiber protein. By modifying the surface, a gradual, semi-permanent effect can be obtained, thereby maximizing the effect of luster expression. In addition, it refers to a composition that allows to obtain ancillary effects such as improvement of color clarity, improvement of color clarity of dyed hair, improvement of hair gloss, and improvement of gloss of dyed hair.

The "composition for enhancing gloss" may include a composition for strengthening hair gloss, a composition for strengthening scalp gloss, a composition for enhancing skin gloss, a composition for enhancing nail gloss, a composition for enhancing skin gloss, and/or a composition for enhancing fiber gloss. .

The composition for enhancing gloss according to the present invention, for example, reacts a substrate composed of a protein with a functional component through a reaction medium to react the substrate composed of protein with a functional component, whereby the carboxyl group of the protein substrate and the amine group of the functional component , by covalently bonding the amine group of the protein substrate with the carboxyl group of the functional component and/or the amine group of the protein substrate with the amine group of the functional component, it is possible to semi-permanently maximize the gloss enhancing effect.

In the present invention, the term 'substrate composed of protein' includes, for example, hair, scalp, skin, nails, leather, and fibers, but is not limited thereto.

In the present invention, the term 'functional component' includes a single or at least one ring structure formed of carbon and nitrogen in the structure, and at the same time a component having at least one carboxyl group and an amine group, for example, tryptophan, histidine, tyrosine , amino acids including phenylalanine, arginine, cysteine and methionine; and one or more functional ingredients selected from the group consisting of allantoin and derivatives thereof.

The functional component may be used in an amount of 0.000001 to 30 parts by weight, for example, 0.001 to 15 parts by weight, 0.01 to 5 parts by weight, 0.1 to 3 parts by weight based on 100 parts by weight of the total composition. If the content of the functional ingredient is less than 0.000001 parts by weight, there is a problem that it is difficult to show a continuous shiny effect.

In the present invention, the reaction medium includes at least one selected from the group consisting of a carbodiimide-based compound, a dihydroxyquinoline-based compound, an aminium-based compound, and a phosphonium-based compound.

The carbodiimide-based compound is a compound including at least one methanediimine (-N=C=N-) in a molecule and may include a component represented by the following Chemical Formula 1:

[Formula 1]

상기 화학식 1에서, A는, 각각 독립적으로, 하기에 나열된 구조 중에서 선택된 하나 이상이며, 반복 단위 양 말단에 이소시아네이트(*)기를 갖는 모노머를 나타내며, 여기서 두 개의 A는 서로 같은 구조의 호모 폴리머(Homo Polymer) 또는 서로 다른 구조의 헤테로 폴리머(Hetero Polymer)이고,
R은, 각각 독립적으로, 수소; 또는 탄소수 1 내지 500의 직쇄 또는 분기쇄 또는 고리형의 탄화수소; 또는 벤젠 고리형의 탄화수소;를 나타내며, 상기 탄화수소 분자의 일부에 이중 결합을 포함하거나; O, N, S, P 및 Si로 이루어진 군에서 선택된 하나 이상의 화합물이 치환된 형태이거나; 음이온, 양이온, 양쪽성 형태로 치환된 형태이거나; 또는 금속이온이 염 형태로 결합된 구조를 포함하며, m은 1 내지 100의 정수이고,
m이 2 이상일 때, 각각의

는 서로 동일하거나 다르며,

In Formula 1, A is, each independently, at least one selected from the structures listed below, and represents a monomer having isocyanate (*) groups at both ends of the repeating unit, where two As are homopolymers having the same structure. Polymer) or a heteropolymer of a different structure,
R is, each independently, hydrogen; or a linear or branched or cyclic hydrocarbon having 1 to 500 carbon atoms; or a benzene cyclic hydrocarbon; and contains a double bond in a portion of the hydrocarbon molecule; at least one compound selected from the group consisting of O, N, S, P and Si is a substituted form; substituted with anionic, cation, or amphoteric forms; or a structure in which a metal ion is bonded in the form of a salt, m is an integer from 1 to 100,
When m is greater than or equal to 2, each

are the same or different from each other,

The * means a linking site.

The carbodiimide-based compound is 1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blockt (1,1'-methylene-bis) -(4-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked), 1,1'-methylene-bis-(4-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me -Ether-blocked (1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked), 1,1'-methylene-bis-(4-isocyane Itocycloheptane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (1,1'-methylene-bis-(4-isocyanatocycloheptane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked, 1, 1'-methylene-bis-(3-isocyanatocycloheptane)-, homopolymer, polyethylene glycol mono-Me-ether-block (1,1'-methylene-bis-(3-isocyanatocycloheptane)-, homopolymer , polyethylene glycol mono-Me-ether-blocked), 1,1'-methylene-bis-(3-isocyanatocyclopentane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (1,1 '-methylene-bis-(3-isocyanatocyclopentane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked), benzene, 1,3,-bis(1-isocyanato-1-methylethyl)-, homo Polymer, polyethylene glycol mono-meth-ether-block (Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono -Me-ether-blocked), 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide) and 1-ethyl-3-(3-dimethylamino Propyl) carbodiimide HCl (1-Ethyl-3- (3-dimethylaminopropyl) carbodiimide HCl) may include one or more selected from the group consisting of, but is not limited thereto.

In one embodiment, as a reaction medium, benzene, 1,3,-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-me-ether-block (Benzene, 1, 3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked) or 1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer , a carbodiimide-based compound of polyethylene glycol mono-Me-ether-blocked (1,1'-methylene-bis-( 3- isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked) may be used. .

The dihydroxyquinoline-based compound may be a compound represented by the following Chemical Formula 2:

[Formula 2]

In Formula 2, R ₁ is a water-soluble nonionic polymer; polymer resins in the form of beads and resins; and one selected from the group consisting of silica beads, R ₂ and R ₃ are each straight chain having 1 to 10 carbon atoms; or a branched saturated alkyl group; or an unsaturated alkyl group.

The water-soluble nonionic polymer has a molecular weight of less than 20,000 Da polyethylene glycol (PEG), polyvinyl alcohol (PVA), polyethylene oxide (PEO), polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP), It may be one or more polymers selected from the group consisting of polyisopropylacrylamide (PNIPPAm), cellulose derivatives, starch derivatives, dextran, and guar gum, but is not limited thereto. When the molecular weight of the water-soluble nonionic compound is 20,000 Da or more, there is a problem in that the ratio of the dihydroxyquinoline-based compound inducing covalent bonding is too small to exhibit a shiny effect.

The polymer resins in the form of beads and resins are styrene, ethylene, butadiene, acrylonitrile, methyl styrene, terephthalate, ethylene chloride, ether ketone, ether imide, ether sulfone, phthalamide, phenylene ether, and molecular weight less than 20,000 Da. It may be a polymer polymerized with one or more monomers selected from the group consisting of phenylene oxide, phenylene sulfide, sulfone, urethane, vinylidene fluoride and tetrafluoroethylene, but is not limited thereto.

If the molecular weight of the polymer resin in the form of beads and resins is 20,000 Da or more, there is a problem in that the ratio of the dihydroxyquinoline-based compound that induces covalent bonding is too small to show a shiny effect.

The silica beads may have a diameter of 100 nm to 1 mm, for example, 100 nm to 100 µm, 1 µm to 100 µm, and 1 µm to 70 µm. If the diameter of the silica beads is smaller than 100 nm, it may cause safety problems on the skin surface, and if the diameter of the silica beads is larger than 1 mm, there is a problem in formulation and stabilization.

The reaction medium of the present invention is an aminium-based compound having a structure in which at least one of the hydrogens of an _{ammonium salt (NH 4} ⁺ ) or a phosphonium salt (PH ₄ ^{+ ) is substituted with an alkyl group or another organic group} Or it may include a phosphonium-based compound, but is not limited thereto.

The aminium compound is N-[(1H-benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethanaminium hexafluorophosphate N-oxide (N-[(1H-benzotriazol-1-yl) yl)(dimethylamino)methylene]-N-methylmethanaminium hexafluorophosphate N-oxide), N-[(1H-benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethanaminium hexafluoroborate (N -[(1H-benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethanaminium hexafluoroborate), 2-(3,4-(N-[(1H-benzotriazol-1-yl)(dimethylamino)methylene ]-N-methylmethanaminium hexafluorophosphate N-oxide (2-(3,4-(N-[(1H-benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethanaminium hexafluorophosphate N-oxide) , 2- (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-tetramethyluronium tetrafluoroborate (2- ( 3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl)-1,1,3,3-tetramethyluronium tetrafluoroborate), O-(3,4,-dihydro-4-oxo- 5-azabenzo-1,2,3-triazin-3-yl)-1,1,3,3-tetramethyluronium hexafluoroborate (O-(3,4,-dihydro-4-oxo- 5-azabenzo-1,2,3-triazin-3-yl)-1,1,3,3-tetramethyluronium hexafluoroborate), O-(3,4,-dihydro-4-oxo-5-azabenzo-1 ,2,3-triazin-3-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate (O-(3,4,-dihydro-4-oxo-5-azabenzo-1, 2,3-triazin-3-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate), 2-(2-oxo-1(2H)-pyridyl-1,1,3,3-tetramethyluronium tetrafluoroborate (2-(2-oxo-1(2H)-pyridyl-1,1; 3,3-tetramethyluronium tetrafluoroborate), 2-(2-oxo-1(2H)-pyridyl-1,1,3,3-tetramethyluronium tetrafluorophosphate (2-(2-oxo-1(2H) )-pyridyl-1,1,3,3-tetramethyluronium tetrafluorophosphate), 2-succinimido-1,1,3,3-tetramethyluronium tetrafluoroborate (2-succinimido-1,1,3,3 -tetramethyluronium tetrafluoroborate), 2-succinimido-1,1,3,3-tetramethyluronium tetrafluorophosphate (2-succinimido-1,1,3,3-tetramethyluronium tetrafluorophosphate), N,N,N ',N'-bis(tetramethylene-O-pentafluorophenyluronium tetrafluoroborate (N,N,N',N'-bis(tetramethylene-O-pentafluorophenyluronium tetrafluoroborate), N,N,N', N'-bis(tetramethylene-O-pentafluorophenyluronium hexafluorophosphate (N,N,N',N'-bis(tetramethylene-O-pentafluorophenyluronium hexafluorophosphate), N-[6-trifluoromethyl (1H-Benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethaminium tetrafluoroborate N-oxide (N-[6-trifluoromethyl(1H-benzotriazol-1-yl)(dimethylamino) methylene]-N-methylmethaminium tetrafluoroborate N-oxide), N-[6-trifluoromethyl(1H-benzotriazol-1-yl)(dimethylamino)methylene]-N-methylmethaminium hexafluorophosphate N -Oxide (N- [6-trifluoromethyl (1H-benzotriazol-1-yl) (dimethylamino )methylene]-N-methylmethaminium hexafluorophosphate N-oxide), N-[(dimethylamino)-1H-1,2,3-triazolo[4,5,b]pyridin-1-yl]methylene]-N-methyl Methanaminium hexafluorophosphate N-oxide (N-[(dimethylamino)-1H-1,2,3-triazolo[4,5,b]pyridin-1-yl]methylene]-N-methylmethanaminium hexafluorophosphate N-oxide ), N-[(dimethylamino)-1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene]-N-methylmethanaminium tetrafluoroborate N-oxide (N -[(dimethylamino)-1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene]-N-methylmethanaminium tetrafluoroborate N-oxide), N-[(dimethylamino)-1H-1, 2,3-triazolo[4,5-b]pyridin-1-ylmethylene]-N-methylmethanaminium hexafluorophosphate N-sulfide (N-[(dimethylamino)-1H-1,2,3- triazolo[4,5-b]pyridin-1-ylmethylene]-N-methylmethanaminium hexafluorophosphate N-sulfide), S-(1-oxido-1-pyridinyl)-1,1,3,3-tetramethylthiuro Nium hexafluorophosphate (S-(1-oxido-1-pyridinyl)-1,1,3,3-tetramethylthiouronium hexafluorophosphate), O-[cyano(ethoxycarbonyl)methyleneamino]-N,N,N ',N'-tetramethyluronium tetrafluoroborate (O-[cyano(ethoxycarbonyl)methyleneamino]-N,N,N',N'-tetramethyluronium tetrafluoroborate), O-[cyano(ethoxycarbonyl)methyleneamino] Amino]-N,N,N',N'-tetramethylthiuronium hexafluorophosphate (O-[cyano(ethoxycarbonyl)methyleneam ino]-N,N,N',N'-tetramethyluronium hexafluorophosphate, O-[(dicyanomethylidene)-amino]-1,1,3,3,-tetramethylthiuronium hexafluorophosphate (O- [(dicyanomethylidene)-amino]-1,1,3,3,-tetramethyluronium hexafluorophosphate, O-[(dimethoxycarbonylmethylidene)-amino]-1,1,3,3,-tetramethyluronium hexa Fluorophosphate (O-[(dimethoxycarbonylmethylidene)-amino]-1,1,3,3,-tetramethyluronium hexafluorophosphate), N-[(cyano(pyridin-2-yl)methylene aminooxy) (dimethylamino)methylene] -N-methylmethanaminium hexafluorophosphate (N-[(cyano(pyridin-2-yl)methylene aminooxy)(dimethylamino)methylene]-N-methylmethanaminium hexafluorophosphate), 2-(5-norbornene-2,3 -dicarboximido)-1,1,3,3-tetramethylthiuronium tetrafluoroborate (2-(5-norbornene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium tetrafluoroborate); 2-phthalimido-1,1,3,3-tetramethyluronium tetrafluoroborate (2-phthalimido-1,1,3,3-tetramethyluronium tetrafluoroborate, bis(tetramethylene)chloroformamidinium hexafluoro Phosphate (bis(tetramethylene)chloroformamidinium hexafluorophosphate), (1H-benzotriazol-1-yl) (1-pyrrolidinylmethylene) pyrrolidinium hexafluorophosphate N-oxide ((1H-benzotriazol-1-yl) ( 1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate N-oxide), 1-(1-pyrrolidinyl-1H-1,2,3-triazolo[4, 5-b]pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate N-oxide (1-(1-pyrrolidinyl-1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene) ) pyrrolidinium hexafluorophosphate N-oxide), O-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl)-1,1,3,3-bis(tetramethylene) Uranium hexafluorophosphate (O-(3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-yl)-1,1,3,3-bis(Tetramethylene)uranium hexafluorophosphate), O- (3,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl)-1,1,3,3-bis(tetramethylene) uranium hexafluorophosphate ( O-(3,4-Dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl)-1,1,3,3-bis(Tetramethylene) uranium hexafluorophosphate), N,N, N',N'-bis(tetramethylene)-O-pentafluoro phenyluronium hexafluorophosphate (N,N,N',N'-bis(tetra methylene)-O-pentafluoro phenyluronium hexafluorphosphate), N, N,N',N'-bis(tetramethylene)-S-pentafluorothiophenyluronium hexafluorophosphate (N,N,N',N'-bis(tetramethylene)-S-pentafluorothiophenyluronium hexafluorphosphate), 1 -(1-pyrrolidinyl-1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene)pyrrolidinium hexafluorophosphate N-sulfide (1-(1-pyrrolidinyl- 1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate N-sulfide), N,N,N',N'-bis(tetramethylene)-O-2-nitro phenyluronium hexafluorophosphate (N, N,N',N'-bis(tetramethylene)-O-2-nitrophenyluronium hexafluorophosphate), N,N,N',N'-bis(tetramethylene)-O-pentafluorophenyluronium hexafluorophosphate ( N,N,N',N'-bis(tetramethylene)-O-pentafluorophenyluronium hexafluorohosphate), O-(benzotriazol-1-yl)-1,1,3,3-bis(pentamethylene) hexafluorophosphate (O-(benzotriazol-1-yl)-1,1,3,3-bis(pentamethylene) hexafluorophosphate), O-(7-azabenzotriazol-1-yl)-1,1,3,3-bis (pentamethylene)-uronium hexafluorophosphate (O-(7-azabenzotriazol-1-yl)-1,1,3,3-bis(pentamethylene)-uronium hexafluorophosphate), 2- [2-oxo-1 ( 2H)-pyridyl]-1,1,3,3-bis(pentamethylene)uronium tetrafluoroborate (2-[2-oxo-1(2H)-pyridyl]-1,1,3,3- bis(pentamethylene) uronium tetrafluoroborate), 2-chloro-1,3-dimethylimidazolidinium hexafluorophosphate (2-chloro-1,3-dimethylimidazolidinium hexafluorophosphate), O-(benzotriazol-1-yl)- 1,3-dimethyl-1,3-dimethylene uronium hexafluorophosphate (O-(benzotriazol-1-yl)-1,3-dimethyl-1,3-dimethylene uronium hexafluorophosphate), O-(7-aza Benzotriazol-1-yl)-1,3-dimethyl-1,3-dimethylenuronium hexafluorophosphate (O-(7-azabenzotriazol-1-yl)-1,3-dimethyl-1,3- dimethyleneuronium hexafluorophosphate), 2-chloro-1,3-dimethylpyrimidinium hexafluorophosphate (2-chloro-1,3-dimethylpyrim) idinium hexafluorophosphate), O-(benzotriazol-1-yl)-1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate (O-(benzotriazol-1-yl)-1,3-dimethyl -1,3-trimethyleneuronium hexafluorophosphate), O-(7-azabenzotriazol-1-yl)-1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate (O-(7-azabenzotriazol- 1-yl)-1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate), (7-benzotriazol-yl)-1,1,3-trimethyl-1-hexafluorophosphate ((7-benzotriazol-yl) )-1,1,3-tri methyl-1-hexafluorophosphate), (7-azabenzotriazol-yl)-1,1,3-trimethyl-1-phenyluronium hexafluorophosphate ((7-azabenzotriazol- yl)-1,1,3-trimethyl-1-phenyluronium hexafluorophosphate), O-(1H-benzotriazol-1-yl)-1,1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate ( O-(1H-benzotriazol-1-yl)-1,1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate), O-(1H-1,2,3-triazolo[4,5-b]pyridin-yl )-1,1-dimethyl-3,3-tetramethyleneuronium hexafluorophosphate (O-(1H-1,2,3-triazolo[4,5-b]pyridin-yl)-1,1-dimethyl -3,3-tetramethyleneuronium hexafluorophosphate), O-(1H-benzotriazol-1-yl)-1,1-dimethyl-3,3-pentamethylene uronium hexafluorophosphate (O-(1H-benzotriazol-1 -yl)-1,1-dimethyl-3,3-pentamethylene uronium hexafluorophosphate), 6-chloro-1((dimethylamino)(morpholino)methylene)-1H-benzot Liazolium hexafluorophosphate-3 oxide (6-chloro-1((dimethylamino)(morpholino)methylene)-1H-benzo triazolium hexafluorophosphate-3 oxide), 3-((dimethylamino)-(morpholino)methylene) -1H-[1,2,3]triazolo[4,5-b]pyridinium hexafluorophosphate (3-((dimethylamino)-(morpholino)methylene)-1H-[1,2,3]triazolo[ 4,5-b]pyridinium hexafluorophosphate), 6-trifluoromethyl-1-((dimethylamino)-(morpholino)methylene)-1H-benzotriazolium hexafluorophosphate-3-oxide (6-trifluoromethyl -1-((dimethylamino)-(morpholino)methylene)-1H-benzotriazolium hexafluorophsphate-3-oxide), 1-((dimethylamino)-(morpholino)) oxypentafluorophenylmetheniminium hexafluorophosphate (1-((dimethylamino)-(morpholino)) oxypentafluorophenylmetheniminium hexafluorophosphate), 1-[(1-(cyano-2-ethoxy-2-oxoethylideneaminooxy)-dimethylamino morpholinomethylene)] methane Aminium hexafluorophosphate (1-[(1-(cyano-2-ethoxy-2-oxoethylideneaminooxy)-dimethylamino morpholinomethylene)] methanaminium hexafluorophosphate), 1-[(1- (dicyanomethyleneaminooxy) dimethylamino morphol nomethylene)] methanaminium hexafluorophosphate (1-[(1-(dicyanomethyleneaminooxy) dimethylamino morpholinomethylene)] methanaminium hexafluorophosphate), 1-[(1,3-diethoxy-1,3-dioxopropane-2- ylideneaminooxy) dimethylamino morpholinomethylene) ] methanaminium hexafluorophosphate (1-[(1,3-diethoxy-1,3-dioxopropan-2-ylideneaminooxy) dimethylaminomorpholinomethylene)] methanaminium hexafluorophosphate), N-[(cyano (pyridin-2-yl) methylene Aminooxy) (dimethylamino) methylene] -N-morpholinomethanaminium hexafluorophosphate (N-[(cyano(pyridin-2-yl)methyleneaminooxy) (dimethylamino)methylene]-N-morpholinomethanaminium hexafluorophosphate), 1 -[(1-(cyano-2-ethoxy-2-oxoethylideneaminooxy)dimethylaminopyrrolodino methylene)] methanaminium hexafluorophosphate (1-[(1-(cyano-2- ethoxy-2-oxoethylideneaminooxy)dimethylaminopyrrolodino methylene)]methanaminium hexafluorophosphate), 1-((dicyanomethyleneaminooxy) morpholinomethylene)pyrrolidinium hexafluorophosphate (1-((dicyanomethyleneaminooxy) morpholinomethylene)pyrrolidinium hexafluorophosphate), 1 -[(1,3-diethoxy-1,3-dioxopropan-2-yldenaminooxy)-dimethylamino-pyrrolodinomethylene]] methanaminium hexafluorophosphate (1-[(1,3- diethoxy-1,3-dioxopropan-2-yldeneaminooxy)-dimethylamino-pyrrolodinomethylene]] methanaminium hexafluorophosphate), 1-[(1-(cyano-2-ethoxy-2-oxoethylidene aminooxy)-dimethylamino- pyrrolodinomethylene)]methanaminium hexafluorophosphate (1-[(1-(cyano-2-ethoxy-2-oxoethylidene aminooxy)-dimethylamino-pyrrolodinomethylene)]methanaminium hexafluororphosphate), 1-((1-cyano-2-ethoxy-2-oxoethylideneaminooxy) (morpholino) methylene) pyrrolidinium hexafluorophosphate (1-((1-cyano-2 -ethoxy-2-oxoethylideneaminooxy)(morpholino)methylene)pyrrolidinium hexafluorophospahte), benzotriazol-1-yloxy-N,N-dimethyl-methanaminium hexachloroantimonate (benzotriazol-1-yloxy-N,N- dimethyl-methanaminium hexachloroantimonate), 5-(1H-benzotriazol-1-yloxy)-3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate (5-(1H-benzotriazol-1 -yloxy)-3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate), 5-(7-azabenzotriazol-1-yloxy)-3,4-dihydro-1-methyl-2H-pyrrole Lium hexachloroantimonate (5- (7-azabenzotriazol-1-yloxy) -3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate), 1- (1H-benzotriazol-1-yloxy) phenyl -Methylene pyrrolidinium hexachloroantimonate (1- (1H-benzotriazol-1-yloxy) phenyl-methylene pyrrolidinium hexachloroantimonate), 5- (pentafluorophenyloxy) -3,4-dihydro-1-methyl- 2H-pyrrolium hexachloroantimonate (5- (pentafluorophenyloxy)-3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonite), 5- (succinimidyloxy) -3,4-dihydro-1- Methyl-2H-pyrrolium hexachloroantimonate (5- (succinimidyloxy)-3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate), 5- (3',4'-dihydro-4'-oxo -1',2',3'-benzotriazine-3'-yl Oxy)-3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate (5-(3′,4′-dihydro-4′-oxo-1′,2′,3′-benzotriazin) It may be at least one selected from the group consisting of -3'-yloxy)-3,4-diydro-1-methyl-2H-pyrrolium hexachloroantimonate) and derivatives thereof, but is not limited thereto.

The phosphonium-based compound is benzotriazol-1-yloxytris (dimethylamino) phosphonium hexafluorophosphate (benzotriazol-1-yloxytris (dimethylamino) phosphonium hexafluorophosphate), bromotris (dimethylamino) phosphonium hexafluoro Phosphate (bromotris (dimethylamino)phosphonium hexafluorophosphate), chlorotri (pyrrolidino) phosphonium hexafluorophosphate (chlorotri (pyrrolidino) phosphonium hexafluorophosphate), bromotri (pyrrolidino) phosphonium hexafluorophosphate (bromotri (pyrrolidino) ) phosphonium hexafluorophosphate), chlorotris (dimethylamino) phosphonium hexafluorophosphate (chloro-tris (dimethylamino) phosphonium hexafluorophosphate), benzotriazol-1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate (benzotriazol) -1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate), [(7-azabenzotriazol-1-yl)oxy]tris-(dimethylamino)phosphonium hexafluorophosphate ([(7-azabenzotriazol-1-yl)oxy ]tris-(dimethylamino)phosphonium hexafluorophosphate), [(7-azabenzotriazol-1-yl)oxy]tris-(pyrrolidino)phosphonium hexafluorophosphate ([(7-azabenzotriazol-1-yl)oxy ]tris-(pyrrolidino)phosphonium hexaflurophosphate), O-[(cyano-(ethoxycarbonyl)methylidene)-amino]-yloxytrispyrrolidinophosphonium hexafluorophosphate (O-[(cyano-( ethoxycarbonyl)methyliden)-amino]- yloxytripyrrolidino phospho nium hexafluorophosphate), [(6-nitrobenzotriazol-yl)oxy]tris-(pyrrolidino)phosphonium hexafluorophosphate ([(6-nitrobenzotriazol-yl)oxy]tris-(pyrrolidino)phosphonium hexafluorophosphate), [(6-trifluoromethyl)benzotriazol-1-yl]-oxytris(pyrrolidino)phosphonium hexafluorophosphate ([[(6-trifluoromethyl)benzotriazol-1-yl]oxy-tris(pyrrolidino )phosphonium hexafluorophosphate), [4-nitro-6- (trifluoromethyl) benzotriazol-1-yl] oxy] tris (pyrrolidino) phosphonium hexafluorophosphate ([4-nitro-6- (trifluoromethyl) )benzotriazol-1-yl]oxy] tris(pyrrolidino) phosphonium hexafluorophosphate), (6-chloro-benzotriazol-1-yloxy) tris (pyrrolidino) phosphonium hexafluorophosphate ((6-chloro-benzotriazol -1-yloxy)tris (pyrrolidino)-phosphonium hexafluorophosphate), N',N',N',N'-bis(terramethylene)-O-pentafluorophenyluronium hexafluorophosphate (N',N ',N',N'-bis(tetramethylene)-O-pentafluoro phenyluronium hexafluorophosphate), (pyridyl-2-thio)tris (pyrrolidino)phosphonium hexafluorophosphate ((pyridyl-2-thio)tris ( pyrrolidino)-phosphonium hexafluorophosphate), [(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl)oxy]tris(pyrrolidino)phosphonium hexafluorophosphate ([ (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl)oxy]tris-(pyrrolidino)phosphonium hexafluoro phosphate), [(3,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl] tris (pyrrolidino) phosphonium hexafluorophosphate ([(3 ,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl] tris-(pyrrolidino) phosphonium hexafluorophosphate) and derivatives thereof may be at least one selected from the group consisting of, but limited thereto no.

The reaction medium may be used in an amount of 0.000001 to 10 parts by weight, 0.001 to 7 parts by weight, 0.01 to 5 parts by weight, and 0.05 to 3 parts by weight based on 100 parts by weight of the total composition. If the content of the reaction medium is less than 0.000001 parts by weight, there is a problem that a continuous surface modification effect is difficult to appear. By reacting with functional ingredients in a non-reacting state, there is a problem that it does not help to improve the durability of luster, but may act as a lost ingredient.

In the reaction, the reaction is possible under the conditions of pH 2 to pH 12, more preferably, the reaction is preferably performed at pH 3 to pH 10, and most preferably in a weakly acidic aqueous solution of pH 4.5 to pH 7. This can increase the reaction efficiency the most. The reaction is completed within 1 to 30 minutes.

The composition may be applied, spread, diluted, or used in a manner similar to these.

In one embodiment, using a carbodiimide-based compound as a reaction medium, the reaction between the carboxyl group and the amine group of the functional component on the surface of the protein substrate is shown in Scheme 1 below, with the amine group on the surface of the protein substrate and the functional The reaction between the carboxyl groups of the components is schematized in Scheme 2 below.

[Scheme 1]

[Scheme 2]

As shown in Schemes 1 and 2, the amino acids combined with hair, scalp, skin, nails, leather, and/or fibers do not come off easily even during general washing with shampoo, detergent, soap, etc. , retain structures attached to the skin, nails, leather and/or fibers.

The composition for enhancing luster according to the present invention may further include a component capable of increasing the luster enhancing effect incidentally in addition to the functional ingredients and reaction medium. For example, fatty acids such as palmitic acid, stearic acid, lauric acid, and myristic acid, fatty alcohols, straight-chain and branched long-chain alkyl quaternary ammonium salts Formulation can be facilitated when mixed with cationized surfactants such as cationized surfactants, cationized polymers such as cationized cellulose, cationized guar, and cationized polyvinylpyrrolidone, and silicone. In addition, for formulation into cosmetic formulations, solvents, surfactants, thickeners, stabilizers, preservatives, colorants, pH adjusters, metal ion sequestrants, colorants, pearlizing agents, appearance improving agents, pigments, powder particles, etc. For cosmetic formulation Ingredients may be included incidentally. Components for the formulation may be used in an amount of 40 to 99 parts by weight based on 100 parts by weight of the total composition.

The composition for enhancing luster according to the present invention may include a luster enhancing functional ingredient having a functional group and used in the formulation of the composition for enhancing luster. For hair, pre-shampoo products, shampoo, rinse treatment, wax, spray, mousse, hair lotion, essence, hair cream, pack, mask, sheet, tablet, patch, strip, ointment type, It can include all cosmetic preparations that can be used for hair such as permanent hair dye, temporary hair dye, and perm, and for the skin, skin, lotion, essence, serum, cream, gel, foundation, powder, makeup base, point makeup, mask , patches, and other cosmetic preparations that can be used on the skin It may include all available textile care agents. For leather products, cream, lotion, essence, serum, gel, wax, spray, cleaner, cleaner, partial decontamination agent, ointment type, temporary hair dye, permanent hair dye, polish, strip, sheet, etc. may be, but is not limited thereto.

In order to increase the effect of the functional ingredients in the composition for shine according to the present invention, 2-basic acid ester oils such as dioctyl succinate, dioctyl adipate, and diethyl sebacate, polyols, polyethylene glycol, propylene glycol, hexylene glycol, Butanediol and isomers thereof, glycerol, benzyl alcohol, ethoxydiglycol and derivatives thereof can be used. The above-mentioned solvents increase the permeability of hair and skin and are used as solvents of poorly soluble substances.

Advantages and features of the present invention, and methods for achieving them, will become apparent with reference to the embodiments described below in detail. However, the present invention is not limited to the embodiments disclosed below, but will be implemented in various different forms, only to ensure that the disclosure of the present invention is complete, and to those of ordinary skill in the art to which the present invention pertains. It is provided to fully indicate the category of

Example 1 to 10 and comparative example 1 to 4

Shampoo compositions for enhancing hair gloss of Examples 1 to 10 and Comparative Examples 1 to 4 were prepared with the composition and content shown in Table 1 below. After washing the hair thoroughly with the prepared shampoo composition, prepare a towel-dried hair tress of about 3 g, and measure the initial gloss using SAMBA (Bossa Nova Index), and 0.3 g of the prepared composition The gloss after shampooing 30 times and SLES (Sodium Lauryl Ether Sulfate) 15% solution were washed 3 times and dried. Measuring instrument: SAMBA Hair System (Bossa Nova Technology, USA).

(weight%) Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Polyquaternium-10 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 EDTA 4Na 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Sodium Lauryl Ether(2mole) Sulfate(30%) 35 35 35 35 35 35 35 35 35 35 35 35 35 35 Cocamidopropyl Betaine (30%) 15 15 15 15 15 15 15 15 15 15 15 15 15 15 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 0.5 Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 0.5 1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One 0.5 pH adjuster appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 1 compare
Example 2 compare
Example 3 compare
Example 4 practice
Example 1 practice
Example 2 practice
Example 3 practice
Example 4 practice
Example 5 practice
Example 6 practice
Example 7 practice
Example 8 practice
Example 9 practice
Example 10 Early 18.6 18.5 18.6 18.3 18.5 18.4 18.6 18.5 18.4 18.6 18.5 18.5 18.3 18.6 After 30 shampoos 16.7 16.3 16.7 16.6 19.2 19 19.3 19.6 19.4 19.8 19.8 19.6 21.3 21.5 After washing 3 times of SLES 15.3 15.5 15.5 15.3 18.4 18.6 18.5 18.6 18.9 18.9 18.8 19 20.6 20.7

As shown in Table 2, the experimental results of Examples 1 to 10 and Comparative Examples 1 to 4, compared to the compositions of Comparative Examples 1 to 4 containing only the amino acid component without including the reaction mediating component, the reaction mediating component Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 1-4, 10) or 1,1'-methylene-bis-(3-isocyanatocyclohexane )-, homopolymer, and polyethylene glycol mono-Me-ether-blocked (Examples 5 to 9) were found to have excellent gloss lasting effects by shine and washing after shampoo use.

Example 11 to 20 and comparative example 5 to 8

The body shampoo compositions for enhancing gloss of Examples 11 to 20 and Comparative Examples 5 to 8 were prepared with the composition and content shown in Table 3 below, and after each composition was used for 10 consumers for 20 days, The skin luster was compared with the initial luster state before use, and was evaluated by sensory evaluation on a 5-point scale (5: very good, 4: slightly superior, 3: no difference, 2: no effect, 1: very ineffective). .

(weight%) Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Example 11 Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Polyquaternium-7 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 EDTA 4Na 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Lauric Acid 3 3 3 3 3 3 3 3 3 3 3 3 35 Myristic acid 4 4 4 4 4 4 4 4 4 4 4 4 15 Sodium Lauryl Ether(2mole) Sulfate(30%) 20 20 20 20 20 20 20 20 20 20 20 20 0.9 Cocamidopropyl Betaine (30%) 15 15 15 15 15 15 15 15 15 15 15 15 0.5 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.5 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One pH adjuster appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 5 compare
Example 6 compare
Example 7 compare
Example 8 practice
Example 11 practice
Example 12 practice
Example 13 practice
Example 14 practice
Example 15 practice
Example 16 practice
Example 17 practice
Example 18 practice
Example 19 2.3 2.5 2.2 2.2 3.8 3.8 3.9 3.8 4 3.9 3.9 4.1 4.4

As shown in Table 4, the experimental results of Examples 11 to 20 and Comparative Examples 5 to 8, compared to the compositions of Comparative Examples 5 to 8 containing only the amino acid component without the reaction mediating component, the reaction mediating component Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 11 to 14, 20) or 1,1'-methylene-bis-(3-isocyanatocyclohexane )-, homopolymer, and polyethylene glycol mono-Me-ether-blocked (Examples 15 to 19) were confirmed to have excellent skin gloss improvement effects after body shampoo use.

Example 21 to 30 and comparative example 9 to 12

Liquid detergent compositions for fibers of Examples 21 to 30 and Comparative Examples 9 to 12 were prepared with the compositions and contents shown in Table 5 below. For the prepared composition, the initial gloss was measured using SAMBA (Bossa Nova Index) using silk fabric with a length of 20 cm and a width of 5 cm, and after shampooing and washing 3 times using 0.3 g of the prepared composition, the gloss and SLES (Sodium Lauryl Ether Sulfate) After washing once with a 15% solution and drying, the gloss was measured, and the gloss lasting effect by washing was compared by device evaluation. Measuring instrument: SAMBA Hair System (Bossa Nova Technology, USA).

(weight%) Comparative Example 9 Comparative Example 10 Comparative Example 11 Comparative Example 12 Example 21 Example 22 Example 23 Example 24 Example 25 Example 26 Example 27 Example 28 Example 29 Example 30 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Lauryl Sulfate 20 20 20 20 20 20 20 20 20 20 20 20 20 20 Laurylalcohol Ethoxylate (12 moles) 7 7 7 7 7 7 7 7 7 7 7 7 7 7 Lauric Acid 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Sodium triphosphate 10 10 10 10 10 10 10 10 10 10 10 10 10 10 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 0.5 Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 0.5 1,1'-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One 0.5 pH adjuster appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount appropriate amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 9 compare
Example 10 compare
Example 11 compare
Example 12 practice
Example 21 practice
Example 22 practice
Example 23 practice
Example 24 practice
Example 25 practice
Example 26 practice
Example 27 practice
Example 28 practice
Example 29 practice
Example 30 Early 4.5 4.5 4.6 4.5 4.4 4.5 4.5 4.5 4.6 4.6 4.4 4.5 4.5 4.6 After washing 3 times 1.6 1.5 1.6 1.7 3.5 3.6 3.6 3.7 3.5 3.7 3.8 3.4 4.4 4.5 After 1 wash of SLES 1.3 1.1 1.3 1.3 3.2 3.3 3.2 3.3 3.3 3.4 3.4 3.2 3.8 3.8

As shown in the results of Table 6, the experimental results of Examples 21 to 30 and Comparative Examples 9 to 12, compared to the compositions of Comparative Examples 5 to 8 containing only the amino acid component without including the reaction mediating component, the reaction mediating component Phosphorus Benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 11-14, 20) or 1,1'-methylene-bis-( In the case of including 3-isocyanatocyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 15-19), the gloss reduction effect by washing silk fibers after using the textile detergent was remarkably improved, and It was confirmed that the gloss lasting effect was also excellent.

Claims (15)

At least one functional ingredient selected from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine (Met) and allantoin (Allantoin); and
As a reaction medium, a composition for enhancing gloss comprising a carbodiimide-based compound represented by the following formula (1):
[Formula 1]

In Formula 1, A is, each independently, at least one selected from the structures listed below, and represents a monomer having isocyanate (*) groups at both ends of the repeating unit, where two As are homopolymers having the same structure. Polymer) or a heteropolymer of a different structure,
R is, each independently, hydrogen; or a linear or branched or cyclic hydrocarbon having 1 to 500 carbon atoms; or a benzene cyclic hydrocarbon; and contains a double bond in a portion of the hydrocarbon molecule; at least one compound selected from the group consisting of O, N, S, P and Si is a substituted form; substituted with anionic, cation, or amphoteric forms; or a structure in which a metal ion is bonded in the form of a salt, m is an integer from 1 to 100,
When m is greater than or equal to 2, each

are the same or different from each other,

The * means a linking site. delete The method of claim 1,
A composition for enhancing gloss, wherein the carbodiimide-based compound is a compound including at least one N=C=N structure in a molecule. delete delete delete delete delete delete delete delete The method of claim 1,
The composition is a composition for enhancing gloss that gives gloss to hair, scalp, skin, nails, leather or fibers. The method of claim 1,
The functional component is a gloss enhancement composition comprising 0.000001 to 30 parts by weight based on 100 parts by weight of the total composition. The method of claim 1,
The reaction medium is a gloss enhancement composition comprising 0.001 to 20 parts by weight based on 100 parts by weight of the total composition. A care product comprising the composition for enhancing gloss of claim 1 .