KR20180117307A - Composition for improving of shining effect - Google Patents

Abstract

According to the present invention, a composition for increasing gloss effects contains a functional component having at least one amine or carboxyl-reactive group capable of covalently bonding with proteins on hair, scalp, skin, nail, leather, or fiber. By forming a covalent bond between the protein and the functional component, it is possible to increase semi-permanent gloss effects.

Description

{Composition for improving shining effect}

The present invention relates to a composition for enhancing the shine of hair, skin, nails, leather or fibers.

The skin is a tissue covering the surface of the body, consisting of epidermis, dermis and subcutaneous fat layer, and skin adherens include Hansoon, sebaceous gland, hair and hands and claws. The epidermis, which constitutes the outermost part of the skin, is composed of an inner part derived from ectoderm and composed of living cells called largely the epithelial layer, and an outer part composed of a stratum corneum composed of flattened, dry dead cells. The thickness of the face portion is 0.03 mm to 1 mm, the hands and soles are 0.16 mm to 0.8 mm, and the thinnest eyelid is 0.1 mm. The epidermis is mainly a middle layer flattened keratinized epithelium, mainly composed of keratinocytes, and melanocytes, Langerhans cells and Merkel cells.

The keratinocyte is a major constituent of the epidermis and consists of four strata from the outer part of the epidermis to the stratum corneum, the granular layer, the superficial layer and the basal layer. There is a transparent layer between the stratum corneum and the granular layer at the hands and soles.

Millions of new cells are formed every day in the epidermis, and they do not stay in one place but continue to push outward to the outermost of the epidermis. During this time, these cells become increasingly harder. Cells of the epidermis are first made in the basal layer and gradually come out to the surface, changing shape and function.

As the epidermis becomes keratinized, the shape gradually changes to the basal layer, the superficial layer, the granular layer, and the stratum corneum. These cells are called keratinized cells because they are cells formed during the process of forming keratin.

The differentiation process in keratinocytes is divided into four stages: 1) division of basal cells, 2) synthesis and maintenance of goblet cells, 3) autolysis of granule cells, and 4) reconstruction of keratinocytes , And the stratum corneum is formed as the last stage of differentiation. This process is called keratinization process.

The keratinocyte has a life span of about 28 days, which varies a little depending on the site, but millions of cells are removed every day and millions of new cells are generated from the lower layers. On the skin surface of the human body, the aging keratinocytes continue to fall off, and in the aged skin, it takes more time for the keratin layer to fall, and the stratum corneum becomes thicker. Therefore, degradation of keratinocyte cells leads to further increase of dead cells, causing fine lines and rough skin.

The stratum corneum is a part of the outermost keratinocyte that forms a hard, dry thin skin, keratin, 20 to 25 layers. The stratum corneum is a name given to the fact that the protein is made up of keratin, which is a hardened one. The shape of the stratum corneum becomes flat and elongated as it is closer to the surface of the skin. The main ingredients are keratin protein (58%), lipid (11%) and natural moisturizing factor (NMF, 38%). The thickness varies depending on the area of the body, and the areas such as the palms and soles are very thick, allowing them to withstand the physical impact, friction or trauma they experience in daily life. The stratum corneum, although composed of dead cells without nucleus and a protein called keratin, is the most important position in the protection of the skin. This stratum corneum protects bacteria and external toxins from entering the body from the outside, and serves as an important barrier to prevent moisture from escaping from inside the body. The keratin protein (58%), which is a major constituent of the skin keratin, is composed of glycine, alanine, valine, leucine, isoleucine, threonine, serine, cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid, Wherein the keratin constituting the skin keratin is composed of about 6.4 to 8.1% of aspartic acid, about 9.1 to 15.4% of glutamic acid, and about 3.1 to 6.9% of lysine < RTI ID = 0.0 & .

In general, hair is a mammalian skin attachment organ, and it is a keratinized structure formed by embryonic epidermal epithelium implanted into the skin, accompanied by sweat glands and sebaceous glands. Hair includes hair, fluffy hair, beard, armpit hair, and pubic hair covering the outside of the body, and in some cases, it refers to only the hair of the scalp.

Hair is composed of keratin proteins which are the main components of the skin stratum corneum. Keratin is divided into two types according to its origins. The keratin constituting the skin stratum corneum is called soft keratin, and the keratin constituting hair and nail is called hard keratin. This is due to differences in the content of cysteine, which is one of the amino acids. The hard keratin has a high cysteine content and the soft keratin has a low content. Thus, hard keratin is resistant to external stimuli or chemical attack.

Hair fibers have a thickness of about 50 to 100 μm and consist of a cuticle called follicle and a cortex called follicle and sometimes have a medulla called medulla in the middle . All these cells are dead cells and most of them are filled with keratin protein.

Human hair consists of about 60 to 95% of keratin proteins and contains water and lipids (bound and unconjugated forms), pigments and trace elements. Proteins are made by forming long chains of about 20 to 50 amino acid mixtures, and each chain is coiled in the form of helix or coil.

Of the many amino acid compositions that make up human hair, cystine is one of the most important amino acids. Cystine is formed by two cysteines (chiols) present in different amino acid chains and forms a disulfide bond known as a very strong bond that forms a bond between two sulfur atoms in close proximity to each other . In addition to disulfide bonds, hair contains a very abundant peptide bond. In addition, the presence of many CO- and NH- groups leads to hydrogen bonding between neighboring chain molecule groups. However, the high cystine content, a very unique part of the cellular structure of human hair, reveals the physical properties of the hair. The pigment that is related to the color of the hair is melanin, which is mainly present in granule form in the colctex part of human hair.

Most of the hair is protein, and the rest are melanin pigment, lipid, trace element, moisture. The protein that constitutes most of the amino acid composition of hair is a keratin protein which contains a lot of cysteine. Hair keratin is composed of about 18 kinds of amino acids, and its composition has a large content of cysteine in comparison with human epidermis. The ratio of basic amino acids histidine, lysine and arginine is 1: 3: 10, which is a unique ratio of hair keratin. Skin collagen does not have cysteine but instead has high glycine, proline, and alanine content. The melanin pigment that determines the color of the hair is contained in the hair by about 3% or less.

In addition to protein and melanin pigments, hair contains minerals and trace elements such as copper, zinc, iron, manganese, calcium, and magnesium. In addition, inorganic elements such as phosphorus and silicon are known to exist.

In addition to the peptide bonds between the amino acids inside the protein, the bonds existing in the hair also have intermolecular forces and binding forces between the respective protein molecules, and the hair maintains its properties and shape by this binding. The types of bonds are largely cysteine bonds, peptide bonds, and non-crosslinked salt bonds, hydrogen bonds, and hydrophobic interactions. Among them, cystine bond (Disulfide Bond; -CH ₂ -SS-CH ₂ -) is a side chain bond that is unseen in other fibers and is characteristic of keratin. to be. With this cystine bond, keratin shows strong physico-chemical properties.

The keratin protein (58%), a major constituent of such hair, is a glycine, alanine, valine, leucine, isoleucine, threonine, serine, cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid, diiodothyrosine, lysine, arginine, histidine Wherein the keratin constituting the hair contains about 3.9 to 7.7% of aspartic acid, about 13.6 to 14.2% of glutamic acid and about 1.9 to 3.1% of lysine. The hair follicle according to claim 1, wherein the hair follicle comprises an amino acid such as phenylalanine, tyrosine, tryptophan, proline or oxyproline. do.

Fibers are generally divided broadly into natural fibers and man-made fibers. Fibers obtained from animals in natural fibers are called animal fibers, and are also called protein fibers since they are proteins. Protein-based fibers are fibers obtained from animal hair and fibers obtained from cocoon, and fibers obtained from animal hair are obtained from flax obtained from hair of sheep, hair fibers obtained from goats, camels, rabbits, horses, cows and other animals .

Such protein-based fibers can be used in the same manner as hair, such as glycine, alanine, valine, leucine, isoleucine, threonine, serine, cystine, cystine, methionine, aspartic acid, asparagine, glutamic acid, diiodothyrosine, lysine, arginine, histidine, phenylalanine, Tryptophan, proline, and oxyproline. Of these protein fibers, wool (wool), which is most commonly used, is known to have a composition of amino acid similar to that of hair.

These protein-based fibers and hair, skin, nails, and leather are a very strong protein in mild conditions such as water or neutral solvents, but they can be caused by combing in daily life, heat of hair, dyeing, permanent, It can be easily damaged by physical / chemical treatments such as washing, sunshine, ironing heat, adsorption of pollution, exposure to ultraviolet rays, exposure to high and low temperatures, seawater, limestone in the pool, and environmental stress. As a result, damaged hair, skin, nails, and fiber leathers can be softened due to elution of inner and outer proteins, becoming rough and porous, and softness and elasticity may be deteriorated, frictional force may become difficult to be cleaned, shine and color become cloudy May occur.

Therefore, the treatment agent is used to improve the surface properties of the hair such as hair, skin, fiber and leather to maintain a beautiful and healthy appearance. In particular, gloss, softness and smoothness are important representative surface properties to be improved.

As a representative example of the treating agent for imparting luster, cosmetic preparations which can be used for hair such as shampoo, rinse, treatment, wax, spray, mousse, hair lotion, essence, hair cream, pack, There are cosmetic preparations which can be used on the skin such as skin, lotion, essence, serum, cream, gel, foundation, powder, makeup base, point makeup, mask, patch, A fiber care preparation that can be used for fibers such as a fiber dye, a laundry detergent, a treatment agent, a post-treatment agent, a laundry aid agent, a partial decontamination agent, and a spray. Also in the nail treatment agent, there can be mentioned a preparation which can be used for the hands and nails such as polishes, nutrients, and strengthening agents. Also in leather products, formulations for treating leather such as creams, lotions, essences, serums, gels, waxes, sprays, cleaners, cleaners, partial decontamination agents, ointment type, polishes, strips and sheets can be mentioned.

In general, cosmetics are also referred to as "cosmetics", which means "to clean, groom, charm, change appearance, or to apply healthy skin or hair to the body by applying, dispersing, And that the action on the human body is slight ". Such cosmetics include various functions for maintaining various parts of the human body such as skin, hair, nails and claws in a healthy and beautiful manner. Among them, glossiness and gloss are one of the main functions of cosmetics.

Common raw materials constituting such a lubricating cosmetic composition include oily materials such as oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, ester oils and silicone oils, anions, cationic, amphoteric and nonionic surfactants, moisturizers, Antioxidants, metal ion sequestrants, coloring materials including dyes and pigments, fragrances, preservatives, and the like.

In addition to the above, it is also possible to use as a component for providing a special performance, a preservative and a natural or synthetic fatty acid, a fatty alcohol, an alcohol, an alkyl glyceryl ether, an ester, a hydrocarbon, a silicone, a fluorine compound, a polyhydric alcohol, Vitamins, hormones, amino acids, peptides, proteins, plant and animal extracts, mineral extracts, derivatives thereof and the like.

However, most of the functional components contained in such a composition are imparted by simple adsorption. There is a disadvantage in that the gloss is continuously reduced due to various external environments occurring in everyday life after the composition treatment and the effect of disappearance of the functional ingredient is lost after cleaning.

For example, Patent Document 1 discloses a hair cleansing composition which contains a high amount of oil and polyol and simultaneously contains a surfactant to provide softness and luster to the hair. Patent Document 2 discloses a hair cleansing composition containing a camellia extract, However, the oil or camellia extract, which is the main ingredient for imparting the two composition glosses, is easily washed away by washing with a simple hydrophobic bond or simple adsorption to the hair, There is a falling problem.

Korea Patent Publication No. 2014-0141303 Korea Patent Publication No. 2013-0122070

It is an object of the present invention to provide a composition for glazing capable of imparting gloss to hair, scalp, skin, nails, leather or fiber.

It is another object of the present invention to provide a care product comprising the composition for shine-hardening.

As means for solving the above problems,

At least one member selected from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine Functional ingredients; And a reaction medium.

The present invention also provides a care product comprising the composition.

The composition for shine-strengthening according to the present invention contains a functional ingredient having at least one amine or carboxyl-reactive group capable of covalently bonding with proteins of hair, scalp, skin, nail, leather or fiber, By forming a bond, it provides a semi-permanent shine-strengthening effect.

The present invention relates to a pharmaceutical composition comprising a compound selected from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine One or more functional ingredients selected; And a reaction medium.

In the present invention, the term 'composition for improving glossiness' refers to a composition having a functional ingredient having excellent gloss-imparting properties and a carboxyl group and an amine group covalently bonded to a large amount of a carboxyl group and an amine group as constituents of hair, scalp, nail, skin, The surface is modified to obtain progressive and semi-permanent effects, thereby maximizing the effect of glossiness. It also means a composition capable of obtaining additional effects such as improvement of sharpness of hair color, improvement of color clarity of dyed hair, improvement of hair elasticity, improvement of the durability of hair dye.

The above-mentioned "composition for glaze strengthening" may include a composition for hair glaze strengthening, a composition for scalp glaze strengthening, a composition for skin glaze strengthening, a composition for nail glaze strengthening, a composition for leather glaze strengthening and / .

The composition for lubricity enhancement according to the present invention can be obtained by, for example, reacting a substrate composed of a protein with a functional ingredient through a reaction medium to react with a substrate composed of a protein and a functional ingredient to form a carboxyl group of the protein substrate and an amine group , The amino group of the protein substrate and the amino group of the carboxyl group of the functional ingredient and / or the protein substrate and the amine group of the functional ingredient are covalently bonded to maximize the gloss enhancement effect.

In the present invention, the term "substrate composed of protein" includes, but is not limited to, for example, hair, scalp, skin, nail, leather and fiber.

In the present invention, the term 'functional component' refers to a component having a single or at least one cyclic structure formed of carbon and nitrogen in the structure, and having at least one carboxyl group and an amine group at the same time, for example, tryptophane, histidine, tyrosine , Phenylalanine, arginine, cysteine, and methionine; And allantoin and derivatives thereof. ≪ Desc / Clms Page number 7 >

The functional ingredient may be used in an amount of 0.000001 to 30 parts by weight, for example, 0.001 to 15 parts by weight, 0.01 to 5 parts by weight, and 0.1 to 3 parts by weight based on 100 parts by weight of the total composition. If the content of the functional ingredient is less than 0.000001 parts by weight, there is a problem that the continuous gloss effect is hard to be exhibited. If the content exceeds 30 parts by weight, there may be a stability problem such that dissolution is impossible due to solubility of the functional ingredient or precipitation from the formulation.

In the present invention, the reaction medium material includes at least one selected from the group consisting of a carbodiimide compound, a dihydroxyquinoline compound, an aminium compound, and a phosphonium compound.

The carbodiimide-based compound may contain at least one methane diimine (-N = C = N-) in the molecule, and may be represented by the following formula (1)

[Chemical Formula 1]

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로 이루어진 군에서 선택된 하나 이상의 구조를 가지는 것으로, 반복 단위 양 말단에 이소시아네이트(*)기를 갖는 모노머이고, R은 수소; 또는 탄소수 1 내지 500의 직쇄, 분지쇄 또는 고리형의 탄화수소; 또는 벤젠 고리형의 탄화수소;를 나타내며, 상기 탄화수소 분자의 일부에 이중결합을 포함하거나; O, N, S, P 및 Si로 이루어진 군에서 선택된 하나 이상의 화합물이 치환된 형태이거나; 음이온, 양이온, 양쪽성 형태로 치환된 형태이거나; 또는 금속이온이 염 형태로 결합된 구조를 포함하고, m은 1 내지 100의 정수이다.In the above formula (1), A represents

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(*) Group at both terminals of the repeating unit, and R is hydrogen; A straight chain, branched chain or cyclic hydrocarbon having 1 to 500 carbon atoms; Or a benzene ring-type hydrocarbon, and the hydrocarbon molecule includes a double bond in a part of the molecule; At least one compound selected from the group consisting of O, N, S, P, and Si is substituted; Anion, cation, amphoteric form; Or a structure in which metal ions are bonded in the form of a salt, and m is an integer of 1 to 100.

The carbodiimide-based compound may be selected from the group consisting of 1,1'-methylene-bis- (3-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Mee- - (4-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked, 1,1'-methylenebis- (4-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Me (3-isocyanatocyclohexane), homopolymer, polyethylene glycol mono-Me-ether-blocked, 1,1'-methylene-bis- 1-methylene-bis- (4-isocyanatocycloheptane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked, 1, (1-methylene-bis- (3-isocyanatocycloheptane) -, homopolymer, polyethylene glycol mono-Mee- , polyethylene glyco l-mono-Me-ether-blocked, 1,1'-methylene-bis- (3-isocyanatocyclopentane) -, homopolymer, polyethylene glycol mono-Me- methylene-bis- (3-isocyanatocyclopentane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked, benzene, 1,3 bis bis (1-isocyanato- Ethyl-3- (3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether- 3- (3-dimethylaminopropyl) carbodiimide and 1-ethyl-3- (3-dimethylaminopropyl) carbodiimide HCl (1-Ethyl- dimethylaminopropyl) carbodiimide HCl), but it is not limited thereto.

In one embodiment, the reaction medium is selected from the group consisting of benzene, 1,3, -bis (1-isocyanato-1-methylethyl) -, homopolymers, polyethylene glycol mono-ether- 3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked or 1,1'-methylene- , And polyethylene glycol mono-Me-ether-blocked (carbodiimide) compounds of 1,1'-methylene-bis- ( 3- isocyanatocyclohexane) -, homopolymer and polyethylene glycol mono-Me-ether- .

The dihydroxyquinoline-based compound may be a compound represented by the following Formula 2:

(2)

Wherein R ₁ is a water-soluble nonionic polymer; Polymeric resins in bead and resin form; And silica beads, and R ₂ and R ₃ are each a straight chain of 1 to 10 carbon atoms; Or branched saturated alkyl groups; Or an unsaturated alkyl group.

The water-soluble non-ionic polymer may be selected from the group consisting of polyethylene glycol (PEG), polyvinyl alcohol (PVA), polyethylene oxide (PEO), polyacrylonitrile (PAN), polyvinylpyrrolidone (PVP) But are not limited to, one or more polymers selected from the group consisting of polyisopropylacrylamide (PNIPPAm), cellulose derivatives, starch derivatives, dextran, and guar gum. If the molecular weight of the water-soluble nonionic system is 20,000 Da or more, the proportion of the dihydroxyquinoline-based compound which induces the covalent bond is too small to achieve a shiny effect.

The bead-shaped and resin-type polymer resin may be selected from the group consisting of styrene, ethylene, butadiene, acrylonitrile, methylstyrene, terephthalate, ethylene chloride, ether ketone, etherimide, ether sulfone, phthalamide, But are not limited to, polymers polymerized with one or more monomers selected from the group consisting of phenylene oxide, phenylene sulfide, sulfone, urethane, vinylidene fluoride and tetrafluoroethylene.

When the molecular weight of the bead-shaped and resin-type polymer resin is 20,000 Da or more, the proportion of the dihydroxyquinoline-based compound that induces the covalent bond is too small to achieve a shiny effect.

The silica beads may include those having a diameter of 100 nm to 1 mm, for example, 100 nm to 100 탆, 1 탆 to 100 탆, and 1 탆 to 70 탆. If the diameter of the silica beads is less than 100 nm, safety problems may occur on the surface of the skin. If the diameter of the silica beads is larger than 1 mm, there is a problem in formulation and stabilization.

The reaction mediator of the present invention is a reaction-mediating compound in which an aminium-based compound, which is a cationic compound having a structure in which at least one of hydrogen of an ammonium salt (NH ₄ ⁺ ) or a phosphonium salt (PH ₄ ⁺ ) is substituted with an alkyl group or another organic group Or a phosphonium-based compound.

The aminium-based compound is a compound represented by the following general formula (1): N - [(1H-benzotriazol-1-yl) (dimethylamino) methylene] -N- methylmethanaminiumhexafluorophosphate N- yl) (dimethylamino) methylene] -N-methylmethanaminium hexafluorophosphate N-oxide, N - [(1H-benzotriazol- - [(1H-benzotriazol-1-yl) (dimethylamino) methylene] -N-methylmethanaminium hexafluoroborate), 2- ] -N-methylmethanaminium hexafluorophosphate N-oxide (2- (3,4- (N - [(1H-benzotriazol- , 2- (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-tetramethyluronium tetrafluoroborate (2- 3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-tetramethyluronium tetrafluoroborate), O- (3,4, 5-A Triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluoroborate (O- (3,4-dihydro-4-oxo- 5- azabenzo-1,2,3-triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluoroborate), O- (3,4-dihydro-4-oxo- 3-yl) -1,1,3,3-tetramethyluronium hexafluorophosphate (O- (3,4-dihydro-4-oxo-5-azabenzo- 3-triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluorophosphate, 2- (2-oxo-1 (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluoro (2-oxo-1 (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluoroborate), 2- (2- (2-oxo-1 (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluorophosphate), 2-succinimidyl-1,1,3,3-tetramethyluronium tetrafluorophosphate 2-succinimido-1,1,3,3-tetramethyluronium tetrafluoroborate), 2-succinimido-1,1,3,3-tetramethyluronium tetrafluoro Tetramethyluronium tetrafluorophosphate, N, N, N ', N'-bis (tetramethylene-O-pentafluorophenyluronium tetrafluoroborate (N, N N, N ', N'-bis (tetramethylene-O-pentafluorophenyluronium tetrafluoroborate), N, N'-bis (tetramethylene-O-pentafluorophenyluronium hexafluorophosphate), N- [6-trifluoromethyl (1H-benzotriazol- 1-yl) (dimethylamino) methylene] -N- methylmethaminium tetrafluoro (Dimethylamino) methylene] -N-methylmethaminium tetrafluoroborate N-oxide, N- [6-trifluoromethyl (1H-benzotriazol- 1-yl) (dimethylamino) methylene] -N-methylmethaminium hexafluorophosphate N-oxide (N- methylmethaminium hexafluorophosphate N-oxid e), N - [(dimethylamino) -1H-1,2,3-triazolo [4,5, b] pyridin- 1 -yl] methylene] -N- methylmethanaminium hexafluorophosphate N- N-methylmethanaminium hexafluorophosphate N-oxide, N - [(dimethylamino) -1H-1,2,3-triazolo [4,5, b] pyridin- 1H-1,2,3-triazolo [4,5-b] pyridin-1-ylmethylene] -N-methylmethanaminium tetrafluoroborate N-oxide (N - [(dimethylamino) 2,3-triazolo [4,5-b] pyridin-1-ylmethylene] -N-methylmethanaminium tetrafluoroborate N-oxide), N - [(dimethylamino) -1H-1,2,3-triazolo [ -b] pyridin-1-ylmethylene] -N-methylmethanaminium hexafluorophosphate N-sulfide (N - [(dimethylamino) -1H-1,2,3-triazolo [ 1-ylmethylene] -N-methylmethanaminium hexafluorophosphate N-sulfide, S- (1-oxydo-1-pyridinyl) -1,1,3,3-tetramethylthiuorium hexafluorophosphate (S- -oxido-1-pyridinyl) -1,1,3,3-tetramethylthiouronium hexafluorophospha N, N ', N'-tetramethyluronium tetrafluoroborate (O- [cyano (ethoxycarbonyl) methyleneamino] -N, N , N ', N'-tetramethyluronium tetrafluoroborate), O- [cyano (ethoxycarbonyl) methyleneamino] -N, N, N', N'-tetramethylthuronium hexafluorophosphate N, N ', N'-tetramethyluronium hexafluorophosphate, O - [(dicyanomethylidene) -amino] -1,1,3,3, - tetramethylthauronium hexafluorophosphate (O - [(dicyanomethylidene) -amino] -1,1,3,3, -tetramethyluronium hexafluorophosphate, O - [(dimethoxycarbonylmethylidene) -amino] -1,1,3,3, (Dimethoxycarbonylmethylidene) -amino] -1,1,3,3-tetramethyluronium hexafluorophosphate), N - [(cyano (pyridin-2- yl) methyleneaminooxy) (dimethylamino ) Methylene] -N-methylmethanaminium hexafluorophosphate (N - [(cyano (py ridin-2-yl) methylene aminooxy) (dimethylamino) methylene] -N-methylmethanaminium hexafluorophosphate), 2- (5-norbornene-2,3-dicarboximido) -1,1,3,3- 2- (5-norbornene-2,3-dicarboximido) -1,1,3,3-tetramethyluronium tetrafluoroborate), 2- phthalimido-1,1,3,3-tetramethyluronium Tetramethyluronium tetrafluoroborate, bis (tetramethylene) chloroformamidinium hexafluorophosphate, 2-phthalimido-1,1,3,3-tetramethyluronium tetrafluoroborate, bis (tetramethylene) chloroformamidinium hexafluorophosphate, (1-pyrrolidinylmethylene) pyrrolidinium hexafluorophosphate N-oxide), 1- (1-pyrrolidinylmethylene) pyrrolidinium hexafluorophosphate N-oxide, 1H-1,2, 3-triazolo [4,5-b] pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate N-oxide (1- 3-triazolo [4,5-b] pyridin-1-ylmethyl] (pyrrolidinium hexafluorophosphate N-oxide), O- (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3- (3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate), O - (3,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazine-3- yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate (3,4-Dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate), N, N , N ', N'-bis (tetramethylene) -O-pentafluorophenyluronium hexafluorophosphate (N, N', N'- , N, N ', N'-bis (tetramethylene) -S-pentafluorothiophenyluronium hexafluorophosphate), N, N' 1- (1-pyrrolidinyl-1H-1,2,3-triazolo [4,5-b ] Pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate (1-pyrrolidinyl-1H-1,2,3-triazolo [4,5- b] pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate N, N ', N'-bis (tetramethylene) -O-2-nitrophenyluronium hexafluorophosphate -2-nitrophenyluronium hexafluorophosphate, N, N, N'-bis (tetramethylene) -O-pentafluorophenyluronium hexafluorophosphate, O-pentafluorophenyluronium hexafluorohosphate), O- (benzotriazol-1-yl) -1,1,3,3-bis (pentamethylene) hexafluorophosphate , 3,3-bis (pentamethylene) hexafluorophosphate, O- (7-azabenzotriazol-1-yl) -1,1,3,3-bis (pentamethylene) -ouronium hexafluorophosphate (2-oxo-1 (2H) -pyridyl] -1,1,3,3-bis (pentamethylene) -uronium hexafluorophosphate) - bis (pentamethylene) uranium Tetrafluoroborate (2- [2-oxo-1 (2H) -pyridyl] -1,1,3,3-bis (pentamethylene) uronium tetrafluoroborate), 2-chloro-1,3-dimethylimidazolidinium hexa (2-chloro- 1,3-dimethylimidazolidinium hexafluorophosphate), O- (benzotriazol-1-yl) -1,3-dimethyl-1,3-dimethylen uronium hexafluorophosphate benzotriazol-1-yl) -1,3-dimethyl-1,3-dimethylene uronium hexafluorophosphate), O- (7-azabenzotriazol- 1-yl-1,3-dimethyl-1,3-dimethyleneuronium hexafluorophosphate), 2-chloro-1,3-dimethylpyrimidinium hexafluorophosphate (2-chloro-1,3-dimethylpyrimidinium hexafluorophosphate) -chloro-1,3-dimethylpyrimidinium hexafluorophosphate, O- (benzotriazol-1-yl) -1,3-dimethyl-1,3-trimethylene uronium hexafluorophosphate ) -1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate, O- (7-azabenzotriazol-1-yl) (7-azabenzotriazol-1-yl) -1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate), (7-benzotriazol- (7-benzotriazol-yl) -1,1,3-tri methyl-1-hexafluorophosphate), (7-azabenzotriazol- , 1, 3-trimethyl-1-phenyluronium hexafluorophosphate), O- (1H-benzotriazol- 1,1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate (O- (1H-benzotriazol-1-yl) -1,1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate), O - (1H-1,2,3-triazolo [4,5-b] pyridin-1-yl) - 1,1- dimethyl-3,3-tetramethyleneuronium hexafluorophosphate (O- 2,3-triazolo [4,5-b] pyridin-yl) -1,1-dimethyl-3,3-tetramethyleneuronium hexafluorophosphate, O- (1H-benzotriazol- -3,3-pentamethylene uronium hexafluoro Benzoquinolin-1-yl) -1,1-dimethyl-3,3-pentamethylene uronium hexafluorophosphate), 6-chloro-1 ((dimethylamino) (morpholino) methylene) 3 - ((dimethylamino) - (morpholino) methylene) -1H-benzo triazolium hexafluorophosphate-3 oxide, -1H- [1,2,3] triazolo [4,5-b] pyridinium hexafluorophosphate (3 - ((dimethylamino) - (morpholino) methylene) -1H- [1,2,3] triazolo [ 4,5-b] pyridinium hexafluorophosphate, 6-trifluoromethyl-1 - ((dimethylamino) - (morpholino) methylene) -1H-benzotriazolium hexafluorophosphate- 1 - ((dimethylamino) - (morpholino) methylene) -1H-benzotriazolium hexafluorophosphate-3-oxide), 1 - ((dimethylamino) - (morpholino)) oxypentafluorophenylmetheniminium hexafluorophosphate (1 - ((dimethylamino) - (morpholino)) oxype (1 - [(1-cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylaminomorpholinomethylene)] methanaminium hexafluorophosphate - (cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylamino morpholinomethylene)] methanaminium hexafluorophosphate), 1 - [(1- (dicyanomethyleneaminooxy) dimethylaminomorpholinomethylene)] methanaminium hexafluorophosphate 1 - [(1-dicyanomethyleneaminooxy) dimethylamino morpholinomethylene]] methanaminium hexafluorophosphate), 1 - [(1,3-diethoxy-1,3-dioxopropane-2-ylideneaminooxy) dimethylamino morpholinomethylene) 2-ylideneaminooxy)] methanaminium hexafluorophosphate), N - [(cyano (pyridin-2-yl) methylene) Aminooxy) (dimethylamino) methylene] -N-morpholinomethanaminium hexafluoro 1 - [(1- (cyano-2-ethoxy-2-oxoethylidene) methylene] amino] methylene] -N-morpholinomethanaminium hexafluorophosphate) 2-ethoxy-2-oxoethylideneaminooxy) dimethylaminopyrrolodino methylene]] methanaminium hexafluorophosphate), 1 - ((dicyano (Dicyanomethyleneaminooxy) morpholinomethylene) pyrrolidinium hexafluorophosphate), 1 - [(1,3-diethoxy-1,3-dioxopropane-2- (1 - [(1,3-diethoxy-1,3-dioxopropan-2-yldeneaminooxy) -dimethylamino-pyrrolodinomethylene]] methanaminium hexafluorophosphate ), 1 - [(1- (cyano-2-ethoxy-2-oxoethylideneminooxy) -dimethylamino- (1-cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylamino-pyrrolodinomethylene)] methanaminium hexafluorophosphate), 1- 2-ethoxy-2-oxoethylideneaminooxy) (morpholino) methylene) pyrrolidinium hexafluorophosphate (1-cyano- pyrrolidinium hexafluorophosphate, benzotriazole-1-yloxy-N, N-dimethyl-methanaminium hexachloroantimonate, 5- (1H-benzo (1H-benzotriazol-1-yloxy) -3,4-dihydro-1-methyl-2H- methyl-2H-pyrrolium hexachloroantimonate), 5- (7-azabenzotriazol-1-yloxy) -3,4-dihydro- azabenzotriazol-1-yloxy) -3,4-dihydro-1-methyl-2H-pyrrole hexachlor 1- (1H-benzotriazol-1-yloxy) phenyl-methylene pyrrolidinium hexachloroantimonate), 5- ( (Pentafluorophenyloxy) -3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonite), 5- (succinimidyloxy) -3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate (5- (succinimidyloxy) -3,4-dihydro- ), 5- (3 ', 4'-dihydro-4'-oxo-1', 2 ', 3'- benzotriazin-3'-yloxy) -3,4- dihydro- 2H-pyrrole hexachloroantimonate (5- (3 ', 4'-dihydro-4'-oxo-1', 2'3'-benzotriazin-3'-yloxy) -3,4- -methyl-2H-pyrrolium hexachloroantimonate) and derivatives thereof, but is not limited thereto.

The phosphonium-based compound may be at least one selected from the group consisting of benzotriazol-1-yloxytris (dimethylamino) phosphonium hexafluorophosphate, benzotriazol-1-yloxytris (dimethylamino) phosphonium hexafluorophosphate, bromotris (dimethylamino) phosphonium hexafluoro (Bromotri (dimethylamino) phosphonium hexafluorophosphate), chlorotri (pyrrolidino) phosphonium hexafluorophosphate, bromotri (pyrrolidino) phosphonium hexafluorophosphate, bromotri ) phosphonium hexafluorophosphate, chloro-tris (dimethylamino) phosphonium hexafluorophosphate, benzotriazol-1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate -1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate), [(7-azabenzotriazol- (Dimethylamino) phosphonium hexafluorophosphate), [(7-azabenzotriazol-1-yl) oxy] [(7-azabenzotriazol-1-yl) oxy] tris- (pyrrolidino) phosphonium hexaflurophosphate), O - [(cyano- (ethoxycarbonyl) Methylidene) -amino] -yloxytrispyrrolidinophosphonium hexafluorophosphate (O - [(cyano- (ethoxycarbonyl) methyliden) -amino] -yloxytripyrrolidino phosphonium hexafluorophosphate), [ (6-nitrobenzotriazol-yl) oxy] tris- (pyrrolidino) phosphonium hexafluorophosphate), [(6-trifluoromethyl) benzotriazole- -Yl] -oxytris (pyrrolidino) phosphonium hexafluorophosphate ([[(6-trifluoromethyl) benzotriazol-1-yl] oxy-tris (pyrrolidino) phosphonium hexafluorophosphate), [4-nitro-6- (trifluoromethyl) benzotriazol-1-yl] oxy] (6-chloro- benzothiazol-1-yloxy) tris (pyrrolidino) phosphonium hexafluorophosphate, benzotriazol-1-yloxy) tris (pyrrolidino) -phosphonium hexafluorophosphate), N ', N', N ', N'-bis (terrhymethylene )- O-pentafluorophenyluronium hexafluorophosphate (Pyridyl-2-thio) tris (pyrrolidino) phosphonium hexafluorophosphate, N, (pyrrolidino) -phosphonium hexafluorophosphate), [(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3- yl) oxy] tris (pyrrolidino) phosphonium hexafluorophosphate [(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) oxy] tris- (pyrrolidino) phosphonium hexafluorophosphate, Triazin-3-yl] tris (pyrrolidino) phosphonium hexafluorophosphate ([(3,4-dihydro-4-oxo-5-azabenzo-1,2,3 -triazin-3-yl] tris- (pyrrolidino) phosphonium hexafluorophosphate) and derivatives thereof, but is not limited thereto.

The reaction medium may be used in an amount of 0.000001 to 10 parts by weight, 0.001 to 7 parts by weight, 0.01 to 5 parts by weight and 0.05 to 3 parts by weight based on 100 parts by weight of the total composition. If the content of the reaction mediator is less than 0.000001 parts by weight, there is a problem that the effect of continuous surface modification is hardly exhibited. If the amount exceeds 10 parts by weight, a reaction medium excessively present at a reaction site existing in a protein- There is a problem in that it can act as a lost component rather than improving the persistence of gloss imparting by reacting with the functional ingredient in the unreacted state.

In the reaction, the reaction can be carried out at a pH of from 2 to 12, more preferably at a pH of from 3 to 10, and most preferably at a pH of from 4 to 7 in a weakly acidic aqueous solution Which can increase the reaction efficiency most. The reaction is completed within 1 minute to 30 minutes.

The composition may be applied by application, dispersion, dilution, or the like.

In one embodiment, a reaction between a carboxyl group on the surface of a substrate composed of a protein and an amine group of a functional ingredient using a carbodiimide-based compound as a reaction mediator is shown in the following reaction formula 1 in which the amine group on the surface of the protein- The reaction between the carboxyl groups of the components is schematized in Scheme 2 below.

[Reaction Scheme 1]

[Reaction Scheme 2]

As can be seen from the above Schemes 1 and 2, the amino acids combined with hair, scalp, skin, nails, leather and / or fibers do not easily come off during general washing due to shampoo, detergent, soap, , The skin, the nails, the leather and / or the structure attached to the fibers.

The composition for glaze-reinforcing according to the present invention may further comprise, in addition to the functional component and the reaction medium, an ingredient capable of additionally enhancing the gloss-enhancing effect. Examples thereof include fatty acids such as palmitic acid, stearic acid, lauric acid and myristic acid, fatty alcohols, long-chain alkyl quaternary ammonium salts of straight chain and branched chain Or a cationic polymer such as cationic polyvinylpyrrolidone, silicone, etc., can be easily formulated. [0154] In addition, when the cationic surfactant is used in combination with the cationic surfactant, cationic cellulose, cationic guar, cationic polyvinylpyrrolidone, In order to formulate cosmetics such as solvents, surfactants, thickeners, stabilizers, preservatives, coloring agents, pH adjusters, metal ion sequestering agents, coloring agents, pearlizing agents, external appearance improvers, pigments and powder particles, Components may be incidentally included. The ingredients for the formulation may be used in an amount of 40 to 99 parts by weight based on 100 parts by weight of the total composition.

The composition for glaze-reinforcing according to the present invention can be used in the formulation of a composition for glaze-strengthening including a gloss-enhancing functional component having a functional group. Hair, lotion, essence, hair cream, pack, mask, sheet, tablet, patch, strip, ointment type, shampoo, shampoo, shampoo, rinse treatment, wax, spray, A lotion, essence, serum, cream, gel, foundation, powder, make-up base, point make-up, mask, The present invention can also be applied to a textile such as a fabric softener, a fiber dye, a laundry detergent, a treatment agent, a post-treatment agent, a laundry auxiliary agent, a partial decontamination agent, a spray, etc. And may include all of the fiber care agents that may be used. Leather products also include all formulations for leather processing such as creams, lotions, essences, serums, gels, waxes, sprays, cleansers, cleaners, partial decontamination agents, ointment types, temporary hair dyes, permanent hair dyes, polishes, But is not limited thereto.

In order to increase the effect of the functional ingredient in the composition for shine according to the present invention, it is possible to use a 2-base acid ester oil such as dioctyl succinate, dioctyl adipate, diethyl sebacate and the like, a polyol, polyethylene glycol, propylene glycol, hexylene glycol, Butanediol and their isomers, glycerol, benzyl alcohol, ethoxydiglycol and derivatives thereof. The above-mentioned solvents increase the permeability of hair and skin, and are used as a solvent of a poorly soluble substance.

Advantages and features of the present invention, and methods of accomplishing the same, will be apparent from and elucidated with reference to the embodiments described hereinafter in detail. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. To provide a complete description of the category.

Example  1 to 10 and Comparative Example  1 to 4

The hair shine enhancing shampoo compositions of Examples 1 to 10 and Comparative Examples 1 to 4 were prepared by the compositions and contents shown in Table 1 below. After washing the hair with the prepared shampoo composition, a hair tress of about 3 g which was dried with a towel was prepared and each initial gloss was measured using SAMBA (Bossa Nova Index), and 0.3 g The shine after shampooing 30 times and the 15% solution of SLES (Sodium Lauryl Ether Sulfate) were washed three times, and the shine after drying was measured to evaluate the shine lasting effect by cleaning. Measurement instrument: SAMBA Hair System (Bossa Nova Technology, USA).

(weight%) Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Polyquaternium-10 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 EDTA 4Na 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Sodium Lauryl Ether (2 mole) Sulfate (30%) 35 35 35 35 35 35 35 35 35 35 35 35 35 35 Cocamidopropyl Betaine (30%) 15 15 15 15 15 15 15 15 15 15 15 15 15 15 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 0.5 Benzene, 1,3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 0.5 1,1'-methylene-bis- (3-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One 0.5 pH adjuster Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 1 compare
Example 2 compare
Example 3 compare
Example 4 practice
Example 1 practice
Example 2 practice
Example 3 practice
Example 4 practice
Example 5 practice
Example 6 practice
Example 7 practice
Example 8 practice
Example 9 practice
Example 10 Early 18.6 18.5 18.6 18.3 18.5 18.4 18.6 18.5 18.4 18.6 18.5 18.5 18.3 18.6 30 times after shampooing 16.7 16.3 16.7 16.6 19.2 19 19.3 19.6 19.4 19.8 19.8 19.6 21.3 21.5 SLES After 3 rinses 15.3 15.5 15.5 15.3 18.4 18.6 18.5 18.6 18.9 18.9 18.8 19 20.6 20.7

As shown in Table 2, the results of the experiments of Examples 1 to 10 and Comparative Examples 1 to 4 show that, compared with the compositions of Comparative Examples 1 to 4 containing no amino acid components but no reaction medium components, 1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 1 to 4, 10) or 1,1'-methylene- bis- (3-isocyanatocyclohexane ), homopolymer, and polyethylene glycol mono-Me-ether-blocked (Examples 5 to 9), it was confirmed that the shine lasting effect by shine and washing was excellent.

Example  11 to 20 and Comparative Example  5 to 8

The shampoo compositions for shine-strengthening of Examples 11 to 20 and Comparative Examples 5 to 8 were prepared by the compositions and contents shown in Table 3 below. Each composition was used for 10 days for ten consumers, The shine condition of the skin was compared with the initial glare condition before use to evaluate the sensory qualities of the 5 point scale (5: very good, 4: slightly excellent, 3: no difference, 2: no effect, 1: .

(weight%) Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Example 11 Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Polyquaternium-7 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 EDTA 4Na 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Lauric Acid 3 3 3 3 3 3 3 3 3 3 3 3 35 Myristic acid 4 4 4 4 4 4 4 4 4 4 4 4 15 Sodium Lauryl Ether (2 mole) Sulfate (30%) 20 20 20 20 20 20 20 20 20 20 20 20 0.9 Cocamidopropyl Betaine (30%) 15 15 15 15 15 15 15 15 15 15 15 15 0.5 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.5 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 Benzene, 1,3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 1,1'-methylene-bis- (3-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One pH adjuster Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 5 compare
Example 6 compare
Example 7 compare
Example 8 practice
Example 11 practice
Example 12 practice
Example 13 practice
Example 14 practice
Example 15 practice
Example 16 practice
Example 17 practice
Example 18 practice
Example 19 2.3 2.5 2.2 2.2 3.8 3.8 3.9 3.8 4 3.9 3.9 4.1 4.4

As shown in Table 4, the results of the experiments of Examples 11 to 20 and Comparative Examples 5 to 8 show that compared with the compositions of Comparative Examples 5 to 8 containing no amino acid components but no reaction medium components, 1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 11 to 14, 20) or 1,1'-methylene- bis- (3-isocyanatocyclohexane ) -, homopolymer, and polyethylene glycol mono-Me-ether-blocked (Examples 15 to 19) were included.

Example  21 to 30 and Comparative Example  9-12

The liquid detergent compositions for fibers of Examples 21 to 30 and Comparative Examples 9 to 12 were prepared by the compositions and contents shown in Table 5 below. Each of the prepared compositions was measured by SAMBA (Bossa Nova Index) using a silk fabric having a length of 20 cm and a width of 5 cm. After the shampooing and washing after 3 times of shampooing and washing, (Sodium Lauryl Ether Sulfate) 15% solution, and measured the gloss after drying. Measurement instrument: SAMBA Hair System (Bossa Nova Technology, USA).

(weight%) Comparative Example 9 Comparative Example 10 Comparative Example 11 Comparative Example 12 Example 21 Example 22 Example 23 Example 24 Example 25 Example 26 Example 27 Example 28 Example 29 Example 30 Water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 Lauryl Sulfate 20 20 20 20 20 20 20 20 20 20 20 20 20 20 Laurylalcohol Ethoxylate (12 moles) 7 7 7 7 7 7 7 7 7 7 7 7 7 7 Lauric Acid 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Sodiumtriphosphate 10 10 10 10 10 10 10 10 10 10 10 10 10 10 incense 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Triptophan 0.5 - - - 0.5 - - - 0.5 - - - 0.5 0.5 Histidine - 0.5 - - - 0.5 - - - 0.5 - - 0.5 0.5 Phenylalanine - - 0.5 - - - 0.5 - - - 0.5 - 0.5 0.5 Tyrosine - - - 0.5 - - - 0.5 - - - 0.5 0.5 0.5 Benzene, 1,3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - One One One One - - - - - 0.5 1,1'-methylene-bis- (3-isocyanatocyclohexane) -, homopolymer, polyethylene glycol mono-Me-ether-blocked - - - - - - - - One One One One One 0.5 pH adjuster Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Sum 100 100 100 100 100 100 100 100 100 100 100 100 100 100

compare
Example 9 compare
Example 10 compare
Example 11 compare
Example 12 practice
Example 21 practice
Example 22 practice
Example 23 practice
Example 24 practice
Example 25 practice
Example 26 practice
Example 27 practice
Example 28 practice
Example 29 practice
Yes 30 Early 4.5 4.5 4.6 4.5 4.4 4.5 4.5 4.5 4.6 4.6 4.4 4.5 4.5 4.6 After 3 washing 1.6 1.5 1.6 1.7 3.5 3.6 3.6 3.7 3.5 3.7 3.8 3.4 4.4 4.5 After SLES 1 rinse 1.3 1.1 1.3 1.3 3.2 3.3 3.2 3.3 3.3 3.4 3.4 3.2 3.8 3.8

As shown in the results of Table 6 above, the results of the experiments of Examples 21 to 30 and Comparative Examples 9 to 12 show that, compared to the compositions of Comparative Examples 5 to 8 containing no amino acid components but no reaction medium components, Benzene, 1,3-bis (1-isocyanato-1-methylethyl) -, homopolymer, polyethylene glycol mono-Me-ether-blocked (Examples 11 to 14, 20) or 1,1'- 3-isocyanatocyclohexane), homopolymer and polyethylene glycol mono-Me-ether-blocked (Examples 15 to 19), the effect of washing the silk fibers after washing with the textile fabric was remarkably improved, And it was confirmed that the effect of lasting gloss was also excellent.

Claims (15)

At least one member selected from the group consisting of tryptophan (Trp), histidine (His), tyrosine (Tyr), phenylalanine (Phe), arginine (Arg), cysteine (Cys), methionine Functional ingredients; And a reaction medium. The method according to claim 1,
The reaction medium is at least one selected from the group consisting of a carbodiimide compound, a dihydroxyquinoline compound, an aminium compound, and a phosphonium compound. 3. The method of claim 2,
Wherein the carbodiimide compound is a compound containing at least one N = C = N structure in the molecule. 3. The method of claim 2,
Wherein the carbodiimide compound is a compound represented by the following formula (1): < EMI ID =
[Chemical Formula 1]

In the above formula (1), A represents

,

,

,

,

,

,

,

,

,

,

,

,

,

,

,

,

,

,

,

And

, Wherein R is a hydrogen atom or a monovalent hydrocarbon group having one or more structures selected from the group consisting of hydrogen, A straight chain, branched chain or cyclic hydrocarbon having 1 to 500 carbon atoms; Or a benzene ring-type hydrocarbon, and the hydrocarbon molecule includes a double bond in a part of the molecule; At least one compound selected from the group consisting of O, N, S, P, and Si is substituted; Anion, cation, amphoteric form; Or a structure in which metal ions are bonded in the form of a salt, and m is an integer of 1 to 100. 3. The method of claim 2,
Wherein the dihydroxyquinoline-based compound is a compound represented by the following formula (2): < EMI ID =
(2)

Wherein R ₁ is a water-soluble nonionic polymer; Polymeric resins in bead and resin form; And silica beads, and R ₂ and R ₃ are each a straight chain of 1 to 10 carbon atoms; Or branched saturated alkyl groups; Or an unsaturated alkyl group. 6. The method of claim 5,
The water-soluble non-ionic polymer may be selected from the group consisting of polyethylene glycol (PEG), polyvinyl alcohol (PVA), polyethylene oxide (PEO), polyacrylonitrile (PAN), polyvinylpyrrolidone Wherein the composition is at least one polymer selected from the group consisting of isopropyl acrylamide (PNIPPAm), cellulose derivatives, starch derivatives, dextran and guar gum. 6. The method of claim 5,
The polymeric resin in bead or resin form can be selected from styrene, ethylene, butadiene, acrylonitrile, methylstyrene, terephthalate, ethylene chloride, ether ketone, etherimide, ether sulfone, phthalamide, phenylene ether, Wherein the polymer is a polymer polymerized with at least one monomer selected from the group consisting of phenylene, phenylene sulfide, sulfone, urethane, vinylidene fluoride and tetrafluoroethylene. 6. The method of claim 5,
The silica bead has a diameter of 100 nm to 1 mm. 3. The method of claim 2,
The aminium-based compound can be prepared by reacting N - [(1H-benzotriazol-1-yl) (dimethylamino) methylene] -N- methylmethanaminium hexafluorophosphate N- (dimethylamino) methylene] -N-methylmethanaminium hexafluorophosphate N-oxide, N - [(1H-benzotriazol- [(1H-benzotriazol-1-yl) (dimethylamino) methylene] -N-methylmethanaminium hexafluoroborate, 2- (3,4- N-methylmethanaminium hexafluorophosphate (N-oxide), N-methylmethanaminium hexafluorophosphate (N-oxide), N- 2- (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-tetramethyluronium tetrafluoroborate (2- 4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-tetramethyluronium tetrafluoroborate), O- (3,4 dihydro- - Azaben Triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluoroborate (O- (3,4-dihydro-4-oxo- 1,2,3-triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluoroborate), O- (3,4 dihydro-4-oxo-5-azabenzo-1,2,3 3-yl) -1,1,3,3-tetramethyluronium hexafluorophosphate (O- (3,4-dihydro-4-oxo-5-azabenzo- triazin-3-yl) -1,1,3,3-tetramethyluronium hexafluorophosphate), 2- (2-oxo-1 (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluoroborate (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluoroborate, 2- (2-oxo-1 Tetramethyluronium tetrafluorophosphate, 2- (2-oxo-1 (2H) -pyridyl-1,1,3,3-tetramethyluronium tetrafluorophosphate) 2-succinimido-1,1,3,3-tetramethyluronium tetrafluoroborate), 2-succinimido-1,1,3,3-tetramethyluronium tetrafluorophosphate N, N ', N'-bis (tetramethylene-O-pentafluorophenyluronium tetrafluoroborate (N, N, N, N'-bis (tetramethylene-O-pentafluorophenyluronium tetrafluoroborate), N, N, N ' , N'-bis (tetramethylene-O-pentafluorophenyluronium hexafluorophosphate), N- [6-trifluoromethyl (1H-benzotriazol- 1-yl) (dimethylamino) methylene] -N- methylmethaminium tetrafluoro A method for preparing a compound of formula (I) wherein the compound is a compound selected from the group consisting of N- [6-trifluoromethyl (1H-benzotriazol-1-yl) (dimethylamino) methylene] -N-methylmethaminium tetrafluoroborate N-oxide, 1-yl) (dimethylamino) methylene] -N-methylmethaminium (N-methylmethylammonium) hexafluorophosphate hexafluorophosphate N-oxide), N - [( (Dimethylamino) -1H-1,2,3-triazolo [4,5, b] pyridin-1-yl] methylene] -N- methylmethanaminium hexafluorophosphate N- -1H-1,2,3-triazolo [4,5, b] pyridin-1-yl] methylene] -N-methylmethanaminium hexafluorophosphate N-oxide), N - [(dimethylamino) -Triazolo [4,5-b] pyridin-1-ylmethylene] -N-methylmethanaminium tetrafluoroborate N-oxide (N - [(dimethylamino) -1H-1,2,3-triazolo [ , 5-b] pyridin-1-ylmethylene] -N-methylmethanaminium tetrafluoroborate N-oxide), N - [(dimethylamino) -1H-1,2,3- triazolo [4,5- b] pyridin- Ylmethylene] -N-methylmethanaminium hexafluorophosphate N-sulfide (N - [(dimethylamino) -1H-1,2,3-triazolo [4,5- b] pyridin- methylmethanaminium hexafluorophosphate N-sulfide, S- (1-oxido-1-pyridinyl) -1,1,3,3-tetramethylthiuramonium hexafluorophosphate (S- -1,1,3,3-tetramethylthiouronium hexafluorophosphate), O- [ N, N ', N', N'-tetramethyluronium tetrafluoroborate (O- [cyano (ethoxycarbonyl) methyleneamino] -tetramethyluronium tetrafluoroborate, O- [cyano (ethoxycarbonyl) methyleneamino] -N, N, N ', N'-tetramethylthiuramonium hexafluorophosphate N, N, N ', N'-tetramethyluronium hexafluorophosphate, O - [(dicyanomethylidene) - amino] -1,1,3,3, - tetramethylthionium hexafluorophosphate ) -amino] -1,1,3,3, -tetramethyluronium hexafluorophosphate, O - [(dimethoxycarbonylmethylidene) -amino] -1,1,3,3, - tetramethylthiuronium hexafluorophosphate (O - [(dimethoxycarbonylmethylidene) -amino] -1,1,3,3, -tetramethyluronium hexafluorophosphate, N - [(cyano (pyridin- 2- yl) methyleneaminooxy) Methylmethanaminium hexafluorophosphate (N - [(cyano (pyridin-2- methyleneaminooxy) methylene] -N-methylmethanaminium hexafluorophosphate), 2- (5-norbornene-2,3-dicarboximido) -1,1,3,3-tetramethylthiuronium tetrafluoro (5-norbornene-2,3-dicarboximido) -1,1,3,3-tetramethyluronium tetrafluoroborate), 2- phthalimido-1,1,3,3-tetramethyluronium tetrafluoroborate (2-phthalimido-1,1,3,3-tetramethyluronium tetrafluoroborate, bis (tetramethylene) chloroformamidinium hexafluorophosphate), (1H-benzotriazol- 1-pyrrolidinylmethylene) pyrrolidinium hexafluorophosphate N-oxide), 1- (1-pyrrolidinyl-1H-benzotriazol- 1,2,3-triazolo [4,5-b] pyridin-1-ylmethylene) pyrrolidinium hexafluorophosphate N-oxide (1- 4,5-b] pyridin-1-ylmethylene ) pyrrolidinium hexafluorophosphate N-oxide, O- (3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-bis (tetramethylene) (3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate), O- (3,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazine-3-yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate (3,4-Dihydro-4-oxo-5-azabenzo-1,2,3-triazin-3-yl) -1,1,3,3-bis (tetramethylene) uranium hexafluorophosphate) N ', N'-bis (tetramethylene) -O-pentafluorophenyluronium hexafluorophosphate (N, N', N'- N, N ', N'-bis (tetramethylene) -S-pentafluorothiophenyluronium hexafluorophosphate), 1, - (1-pyrrolidinyl-1H-1,2,3-triazolo [4,5-b] -1-ylmethylene) pyrrolidinium hexafluorophosphate N- (1-pyrrolidinyl-1H-1,2,3-triazolo [4,5-b] pyridin- N, N ', N'-bis (tetramethylene) -O-2-nitrophenyluronium hexafluorophosphate (N, -nitrophenyluronium hexafluorophosphate, N, N, N ', N'-bis (tetramethylene) -O-pentafluorophenyluronium hexafluorophosphate, pentafluorophenyluronium hexafluorohosphate, O- (benzotriazol-1-yl) -1,1,3,3-bis (pentamethylene) hexafluorophosphate , 3-bis (pentamethylene) hexafluorophosphate, O- (7-azabenzotriazol-1-yl) -1,1,3,3-bis (pentamethylene) -ouronium hexafluorophosphate 2-oxo-1 (2H) -pyridyl] -1,1,3,3-bis (pentamethylene) (Pentamethylene) uranium tetra Fluoroborate (2- [2-oxo-1 (2H) -pyridyl] -1,1,3,3-bis (pentamethylene) uronium tetrafluoroborate), 2-chloro-1,3-dimethylimidazolidinium hexafluor (2-chloro-1,3-dimethylimidazolidinium hexafluorophosphate), O- (benzotriazol-1-yl) -1,3-dimethyl-1,3-dimethylenuronium hexafluorophosphate -1-yl) -1,3-dimethyl-1,3-dimethylene uronium hexafluorophosphate, O- (7-azabenzotriazol-1-yl) -1,3-dimethyl- 1-yl-1,3-dimethyl-1,3-dimethyleneuronium hexafluorophosphate), 2-chloro-1,3-dimethylpyrimidinium hexafluorophosphate (2- 1,3-dimethylpyrimidinium hexafluorophosphate, O- (benzotriazol-1-yl) -1,3-dimethyl-1,3-trimethylen uronium hexafluorophosphate, -1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate), O- (7-azabenzotriazol-1-yl) -1,3-dimethyl- (7-azabenzotriazol-1-yl) -1,3-dimethyl-1,3-trimethyleneuronium hexafluorophosphate), (7-benzotriazol- 3-trimethyl-1-hexafluorophosphate, (7-azabenzotriazol-yl) -1,1,3- (7-azabenzotriazol-yl) -1,1,3-trimethyl-1-phenyluronium hexafluorophosphate), O- (1H-benzotriazol- 1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate (O- (1H-benzotriazol-1-yl) , 2,3-triazolo [4,5-b] pyridin-yl) -1,1-dimethyl-3,3-tetramethylene uronium hexafluorophosphate (O- (1H-1,2,3-triazolo [4,5-b] pyridin-yl) -1,1-dimethyl-3,3-tetramethyleneuronium hexafluorophosphate), O- (1H-benzotriazol- Pentamethylene uronium hexafluorophosphate Benzotriazol-1-yl) -1,1-dimethyl-3,3-pentamethylene uronium hexafluorophosphate), 6-chloro-1 ((dimethylamino) (morpholino) methylene) 3 - ((dimethylamino) - (morpholino) methylene) -1H-benzo triazolium hexafluorophosphate-3 oxide, -1H- [1,2,3] triazolo [4,5-b] pyridinium hexafluorophosphate (3 - ((dimethylamino) - (morpholino) methylene) -1H- [1,2,3] triazolo [ 4,5-b] pyridinium hexafluorophosphate, 6-trifluoromethyl-1 - ((dimethylamino) - (morpholino) methylene) -1H-benzotriazolium hexafluorophosphate- 1 - ((dimethylamino) - (morpholino) methylene) -1H-benzotriazolium hexafluorophosphate-3-oxide), 1 - ((dimethylamino) - (morpholino)) oxypentafluorophenylmetheniminium hexafluorophosphate (1 - ((dimethylamino) - (morpholino)) oxypentafluor (1 - [(1-cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylaminomorpholinomethylene)] methanaminium hexafluorophosphate - (cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylamino morpholinomethylene)] methanaminium hexafluorophosphate), 1 - [(1- (dicyanomethyleneaminooxy) dimethylaminomorpholinomethylene)] methanaminium hexafluorophosphate 1 - [(1-dicyanomethyleneaminooxy) dimethylamino morpholinomethylene]] methanaminium hexafluorophosphate), 1 - [(1,3-diethoxy-1,3-dioxopropane-2-ylideneaminooxy) dimethylamino morpholinomethylene) 2-ylideneaminooxy)] methanaminium hexafluorophosphate), N - [(cyano (pyridin-2-yl) methylene) Aminooxy) (dimethylamino) methylene] -N-morpholinomethanaminium hexafluoro (1-cyano-2-ethoxy-2-oxoethylidene) methyleneamino] methylene] -N-morpholinomethanaminium hexafluorophosphate), 1 - [ 2-ethoxy-2-oxoethylideneaminooxy) dimethylaminopyrrolodino methylene]] methanaminium hexafluorophosphate), 1 - ((dicyano (Dicyanomethyleneaminooxy) morpholinomethylene) pyrrolidinium hexafluorophosphate), 1 - [(1,3-diethoxy-1,3-dioxopropane-2- (1 - [(1,3-diethoxy-1,3-dioxopropan-2-yldeneaminooxy) -dimethylamino-pyrrolodinomethylene]] methanaminium hexafluorophosphate ), 1 - [(1- (cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylamino-pyrrolodi (1-cyano-2-ethoxy-2-oxoethylideneaminooxy) -dimethylamino-pyrrolodinomethylene)] methanaminium hexafluorophosphate), 1 - 2-ethoxy-2-oxoethylideneaminooxy) (morpholino) methylene) pyrrolidinium (1-cyano-2- hexafluorophosphate, benzotriazol-1-yloxy-N, N-dimethyl-methanaminium hexachloroantimonate, 5- (1H-benzotriazole- 1-yloxy) -3,4-dihydro-1-methyl-2H-pyrrole hexachloroantimonate (5- (1H-benzotriazol- -2H-pyrrolium hexachloroantimonate), 5- (7-azabenzotriazol-1-yloxy) -3,4-dihydro-1-methyl-2H-pyrrole hexachloroantimonate -1-yloxy) -3,4-dihydro-1-methyl-2H-pyrrole hexachloroantimon ate and 1- (1H-benzotriazol-1-yloxy) phenyl-methylenepyrrolidinium hexachloroantimonate (1- (1H-benzotriazol-1-yloxy) phenyl-methylene pyrrolidinium hexachloroantimonate) (Pentafluorophenyloxy) -3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonite), 5- (succinimidyloxy) -3,4-dihydro-1-methyl-2H-pyrrolium hexachloroantimonate (5- (succinimidyloxy) -3,4-dihydro- ), 5- (3 ', 4'-dihydro-4'-oxo-1', 2 ', 3'- benzotriazin-3'-yloxy) -3,4- dihydro- 2H-pyrrole hexachloroantimonate (5- (3 ', 4'-dihydro-4'-oxo-1', 2'3'-benzotriazin-3'-yloxy) -3,4- -methyl-2H-pyrrolium hexachloroantimonate) and derivatives thereof. 3. The method of claim 2,
The phosphonium-based compound is a compound containing at least one phosphonium salts structure in the molecule. 3. The method of claim 2,
The phosphonium compounds include benzotriazol-1-yloxytris (dimethylamino) phosphonium hexafluorophosphate, bromotris (dimethylamino) phosphonium hexafluorophosphate (dimethylamino) phosphonium hexafluorophosphate, (bromotris (dimethylamino) phosphonium hexafluorophosphate), chlorotri (pyrrolidino) phosphonium hexafluorophosphate, bromotri (pyrrolidino) phosphonium hexafluorophosphate, phosphonium hexafluorophosphate, chloro-tris (dimethylamino) phosphonium hexafluorophosphate, benzotriazol-1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate, 1-yloxytris (pyrrolidino) phosphonium hexafluorophosphate), [(7-azabenzotriazol-1-yl) oxy [(7-azabenzotriazol-1-yl) oxy] tris- (dimethylamino) phosphonium hexafluorophosphate), [(7-azabenzotriazol- [(7-azabenzotriazol-1-yl) oxy] tris- (pyrrolidino) phosphonium hexaflurophosphate), O - [(cyano- (ethoxycarbonyl) methylidene ) - amino] -yloxytrispyrrolidinophosphonium hexafluorophosphate (O - [(cyano- (ethoxycarbonyl) methyliden) -amino] -yloxytripyrrolidino phosphonium hexafluorophosphate), [(6-nitrobenzotriazol- (6-nitrobenzotriazol-yl) oxy] tris- (pyrrolidino) phosphonium hexafluorophosphate), [(6-trifluoromethyl) benzotriazol- ] - oxytris (pyrrolidino) phosphonium hexafluorophosphate ([[(6-trifluoromethyl) benzotriazol-1-yl] oxy- ino phosphonium hexafluorophosphate, [4-nitro-6- (trifluoromethyl) benzotriazol-1-yl] oxy] tris (pyrrolidino) phosphonium hexafluorophosphate, (6-chloro- benzothiazol-1-yloxy) tris (pyrrolidino) phosphonium hexafluorophosphate, benzotriazol-1-yloxy) tris (pyrrolidino) -phosphonium hexafluorophosphate), N ', N', N ', N'-bis (terrhymethylene )- O-pentafluorophenyluronium hexafluorophosphate (Pyridyl-2-thio) tris (pyrrolidino) phosphonium hexafluorophosphate, N, (pyrrolidino) -phosphonium hexafluorophosphate), [(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3- yl) oxy] tris (pyrrolidino) phosphonium hexafluorophosphate [(3,4-d 4-oxo-1,2,3-benzotriazin-3-yl) oxy] tris- (pyrrolidino) phosphonium hexafluorophosphate), [ 3-yl] tris (pyrrolidino) phosphonium hexafluorophosphate ([(3,4-dihydro-4-oxo-5-azabenzo-1,2,3-triazin- ] tris- (pyrrolidino) phosphonium hexafluorophosphate) and derivatives thereof. The method according to claim 1,
Wherein the composition imparts radiance to hair, scalp, skin, nail, leather or fiber. The method according to claim 1,
Wherein the functional component comprises 0.000001 to 30 parts by weight based on 100 parts by weight of the total composition. The method according to claim 1,
Wherein the reaction medium material comprises 0.001 to 20 parts by weight based on 100 parts by weight of the total composition. A care product comprising the gloss enhancing composition of claim 1.