KR102038262B1 - 아크릴산 및 아크릴레이트 제조용 촉매 - Google Patents

아크릴산 및 아크릴레이트 제조용 촉매 Download PDF

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KR102038262B1
KR102038262B1 KR1020197020581A KR20197020581A KR102038262B1 KR 102038262 B1 KR102038262 B1 KR 102038262B1 KR 1020197020581 A KR1020197020581 A KR 1020197020581A KR 20197020581 A KR20197020581 A KR 20197020581A KR 102038262 B1 KR102038262 B1 KR 102038262B1
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catalyst composition
catalyst
titanium
oxide
weight
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Korean (ko)
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KR20190087653A (ko
Inventor
딕 나가키
하이코 바이너
조세피나 채프먼
마크 스케이츠
알렉산드라 록크
크레이그 피터슨
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셀라니즈 인터내셔날 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020197020581A 2011-05-11 2012-04-23 아크릴산 및 아크릴레이트 제조용 촉매 Expired - Fee Related KR102038262B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/105,558 US8642498B2 (en) 2011-05-11 2011-05-11 Catalysts for producing acrylic acids and acrylates
US13/105,558 2011-05-11
PCT/US2012/034624 WO2012154396A1 (en) 2011-05-11 2012-04-23 Catalysts for producing acrylic acids and acrylates

Related Parent Applications (1)

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KR1020137032729A Division KR20140028067A (ko) 2011-05-11 2012-04-23 아크릴산 및 아크릴레이트 제조용 촉매

Publications (2)

Publication Number Publication Date
KR20190087653A KR20190087653A (ko) 2019-07-24
KR102038262B1 true KR102038262B1 (ko) 2019-10-29

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KR1020197020581A Expired - Fee Related KR102038262B1 (ko) 2011-05-11 2012-04-23 아크릴산 및 아크릴레이트 제조용 촉매
KR1020137032729A Ceased KR20140028067A (ko) 2011-05-11 2012-04-23 아크릴산 및 아크릴레이트 제조용 촉매

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Country Status (10)

Country Link
US (1) US8642498B2 (enExample)
EP (1) EP2707136A1 (enExample)
JP (1) JP2014518759A (enExample)
KR (2) KR102038262B1 (enExample)
CN (1) CN103517760B (enExample)
AR (1) AR086032A1 (enExample)
BR (1) BR112013028888A2 (enExample)
MY (1) MY166460A (enExample)
TW (1) TW201247318A (enExample)
WO (1) WO2012154396A1 (enExample)

Families Citing this family (19)

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US8652988B2 (en) 2011-04-27 2014-02-18 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
US8642498B2 (en) * 2011-05-11 2014-02-04 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US8993801B2 (en) 2011-09-16 2015-03-31 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8765629B2 (en) * 2011-09-16 2014-07-01 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8883672B2 (en) 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US9573119B2 (en) 2011-09-16 2017-02-21 Eastman Chemical Company Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8802585B2 (en) * 2011-09-22 2014-08-12 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US8735314B2 (en) * 2011-09-29 2014-05-27 Celanese International Corporation Catalysts for producing acrylic acids and acrylates
US8669201B2 (en) * 2012-03-13 2014-03-11 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
WO2013137934A1 (en) * 2012-03-13 2013-09-19 Celanese International Corporation Catalyst for producing acrylic acids and acrylates
DK3721994T3 (da) * 2012-08-24 2023-01-23 Tronox Llc Katalysatorbærer omfattende titandioxid, molybdænoxid, phosphor og silicimdioxid
DE102015222198A1 (de) 2015-11-11 2017-05-11 Basf Se Oxidische Zusammensetzung
GB201616119D0 (en) 2016-09-22 2016-11-09 Johnson Matthey Davy Technologies Limited Process
GB201621975D0 (en) 2016-12-22 2017-02-08 Johnson Matthey Davy Technologies Ltd Process
GB201621985D0 (en) 2016-12-22 2017-02-08 Johnson Matthey Davy Technologies Ltd Process
CN107051576B (zh) * 2017-05-05 2020-01-10 北京华福工程有限公司 用于乙炔合成丙烯酸或丙烯酸酯的催化剂及其制备方法和用途
JP7209299B2 (ja) * 2019-03-07 2023-01-20 中国電力株式会社 脱硝触媒、及びその製造方法
CN114292186A (zh) * 2022-01-14 2022-04-08 万华化学集团股份有限公司 一种高纯度mma的制备方法
CN115888777B (zh) * 2022-10-27 2024-08-06 潍坊科技学院 一种增强型改性vpo催化剂及其制备方法和应用

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WO2013039715A1 (en) 2011-09-16 2013-03-21 Eastman Chemical Company PROCESS FOR PREPARING V-Ti-P CATALYSTS FOR SYNTHESIS OF 2,3-UNSATURATED CARBOXYLIC ACIDS
WO2013043385A2 (en) 2011-09-22 2013-03-28 Celanese International Corporation Catalysts for producing acrylic acids and acrylates

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US4276197A (en) 1979-12-19 1981-06-30 Atlantic Richfield Company Preparation of a titanium promoted VO(PO3)2 oxidation catalyst
JP2001354612A (ja) 2000-06-12 2001-12-25 Nippon Shokubai Co Ltd アクリル酸の製造方法
JP2004290924A (ja) 2003-03-28 2004-10-21 Sumitomo Chem Co Ltd 触媒繊維およびその製造方法
WO2013039715A1 (en) 2011-09-16 2013-03-21 Eastman Chemical Company PROCESS FOR PREPARING V-Ti-P CATALYSTS FOR SYNTHESIS OF 2,3-UNSATURATED CARBOXYLIC ACIDS
WO2013043385A2 (en) 2011-09-22 2013-03-28 Celanese International Corporation Catalysts for producing acrylic acids and acrylates

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CN103517760B (zh) 2016-03-16
TW201247318A (en) 2012-12-01
US20120289743A1 (en) 2012-11-15
BR112013028888A2 (pt) 2017-01-31
WO2012154396A1 (en) 2012-11-15
KR20190087653A (ko) 2019-07-24
CN103517760A (zh) 2014-01-15
KR20140028067A (ko) 2014-03-07
EP2707136A1 (en) 2014-03-19
US8642498B2 (en) 2014-02-04
JP2014518759A (ja) 2014-08-07
MY166460A (en) 2018-06-27
AR086032A1 (es) 2013-11-13

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