KR101878687B1

KR101878687B1 - Water dispersed type makeup cosmetic compositon

Info

Publication number: KR101878687B1
Application number: KR1020160155980A
Authority: KR
Inventors: 김기백; 지진구; 박명삼; 우영화; 김명성
Original assignee: 코스맥스 주식회사
Priority date: 2016-11-22
Filing date: 2016-11-22
Publication date: 2018-07-17
Also published as: KR20180057815A; WO2018097584A1

Abstract

The present invention relates to a water-dispersion type makeup cosmetic composition characterized by having a D-phase emulsion solubilized in water.
According to the present invention, an aqueous dispersion type makeup cosmetic composition in which oil and water are emulsified in D phase and then solubilized in water is remarkably excellent in moisturizing and polishing power as compared with the conventional water dispersion type cosmetic composition, This indicates a new feeling of use in the water dispersion type.

Description

Water dispersed type makeup cosmetic composition

The present invention relates to an aqueous dispersion type makeup cosmetic composition, and more specifically to a water dispersion type makeup cosmetic composition characterized by having a D-phase emulsion solubilized in water.

In general, a cosmetic composition of water dispersion type has a moist feeling due to the content of water. However, due to the evaporation of water, the moisture sensation disappears over time, resulting in a dry feeling, and there is a problem that the glossiness is reduced with evaporation of water. In order to solve these problems, the use of the thickening agent may increase the content of the thickening agent to some extent, but it has problems such as stickiness and heavy feeling, and there is no satisfactory improvement. In addition, although a method of using a polyol type to sustain the moisture sensitivity and luster of the water-based part is used, there is still a problem that the moisture and luster of the polyol are reduced over time due to the characteristics of the polyol, Also there is no satisfactory improvement in this.

The D phase emulsion refers to an emulsion prepared by the D phase emulsification method. Specifically, the oil is slowly added to the D phase composed of a surfactant, a polyol and a small amount of water to form a high viscosity transparent gel through the O / D form , Which is referred to as a low viscosity O / W emulsion having fine particles by adding water again.

D-phase emulsification has excellent stability compared to other emulsions and has a feature of being able to use a wide range of surfactants because of less influence of HLB and to develop a more stable formulation. In addition, it has the advantage that it is less susceptible to changes in temperature, temperature, and stability due to low temperature sensitivity. In addition, D-phase emulsification has an advantage that it can be applied to a solubilization type unlike other emulsification methods, and thus has an advantage that it can be applied to a hair dispersion-makeup cosmetic composition.

Accordingly, the present inventors have made intensive researches to overcome the problems of the prior art as described above. As a result, the present inventors have found that emulsions obtained through D phase emulsification are applied to a solubilization type aqueous dispersion formulation, Specifically, it was confirmed that an aqueous dispersion type formulation in which oil and water were emulsified in D phase and solubilized in water, was excellent in moisturizing and glossiness , Thereby completing the present invention.

Accordingly, a main object of the present invention is to provide an aqueous dispersion type makeup cosmetic composition in which a D-phase emulsion having excellent moisture resistance and glossiness is solubilized in water.

According to one aspect of the present invention, there is provided a water-dispersion type makeup cosmetic composition characterized by having a D-phase emulsion solubilized in water.

The conventional water dispersion type cosmetic composition has a property of imparting moisture due to the inclusion of water. However, there has been a problem in that the drying feeling is increased and the glossiness is reduced due to evaporation of water over time. Also, in order to solve the above-mentioned problems, a method of using a polyol to sustain moisture and luster has been used, but it has been difficult to solve the problems of moisture sensitivity and gloss reduction. In order to solve the above problems, the inventors of the present invention have invented an aqueous dispersion type makeup cosmetic composition in which a D-phase emulsion is solubilized in water.

In the present invention, the D-phase emulsion may be a combination of diphenyl dimethicone, glycerin, squalane, purified water, triethanolhexanone, polyglyceryl-10 myristate, disodium edetate, sodium citrate and citric acid Is used.

In the present invention, the water receiving portion includes purified water, a moisturizing agent, a thickening agent, and a pigment.

In the present invention, the content of the D phase emulsion is 0.01 to 10% by weight of diphenyl dimethicone, 1 to 20% by weight of glycerin, 0.01 to 7% by weight of squalane, 0.1 to 7% by weight of purified water 0.1 0.01 to 3% by weight of polyglyceryl-10-myristate, 0.001 to 0.1% by weight of disodium edetate, 0.001 to 0.1% by weight of sodium citrate, And 0.001 to 0.1% by weight of ric acid.

Specifically, the purified water may be 0.1 to 25% by weight based on the total weight of the D-phase emulsion composition. In addition to purified water, it may further include butylene glycol, glycerin, etc. which are widely used as cosmetics in cosmetics.

The diphenyl dimethicone of the present invention may be 0.01 to 10% by weight based on the total weight of the D-phase emulsion composition. When the content of diphenyl dimethicone is less than 0.01% by weight, the oil content is low and it is difficult to be regarded as a normal D-phase emulsion. When the content of diphenyl dimethicone is more than 10% by weight, the oil content is high and the stability of the emulsion may be lowered . Preferably, it is used in an amount of 10% by weight or less, more preferably 8% by weight or less, based on the total weight of the composition. Diphenyl Dimethicone It has low oily feeling and it can minimize moisture loss and maintain moist feeling. It also has excellent gloss. However, if the content of diphenyl dimethicone is excessively high, it may interfere with the formation of D phase emulsion.

The glycerin of the present invention may be from 1 to 20% by weight based on the total weight of the D-phase emulsion composition. When the content of glycerin is less than 1% by weight, the moisturizing effect tends to be poor and it is difficult to achieve the expected effect. When the content is more than 20% by weight, the tackiness is poor due to stickiness. The glycerin is a kind of polyol and is used as a raw material for improving the moisturizing feeling and glossiness. Compared to other polyol types, it has a high moisturizing effect and is recognized as a stable raw material. The content of glycerin is set in consideration of the feeling of non-stick feeling.

The squalane of the present invention may be 0.01 to 7% by weight based on the total weight of the D-phase emulsion composition. The squalane is a soft and less tacky raw material, and can enhance a feeling of rich feeling and smooth spreadability.

The triethanol hexane of the present invention may be present in an amount of 0.01 to 7% by weight based on the total weight of the D-phase emulsion composition. The triethoxyneine is a type of fatty acid obtained from glycerin and fatty acid, and is mainly used as a raw material for providing a moisturizing feeling.

The polyglyceryl-10 pre-state of the present invention may be from 0.01 to 3% by weight, based on the total weight of the D-phase emulsion composition. The polyglyceryl-10 myristate is a raw material used as a polyglycerol fatty acid ester (PGFE) solubilizer and emulsifier, and is also used as a solubilizer and emulsifier in the present invention. It is currently recommended as a PEG-free solubilizer.

The disodium idite of the present invention may be 0.001 to 0.1 wt.%, Based on the total weight of the D phase emulsion composition. The disulfomethane dithiene was used as a chelating agent as a raw material for enhancing emulsification stability.

The sodium citrate of the present invention may be 0.001 to 0.1 wt% based on the total weight of the D-phase emulsion composition. The sodium citrate was used as a pH regulator.

The citric acid of the present invention may be 0.001 to 0.1% by weight based on the total weight of the D-phase emulsion composition. The citric acid was used as a pH adjusting agent.

The content of the pigment of the present invention may be 0.01 to 5% by weight based on the total weight of the composition. The pigments may be used in combination with various pigments. For example, coloring pigments such as Red No. 102, Orange No. 205, Red No. 104, (1), Red No. 227, Yellow No. 4, Yellow No. 5, and Blue No. 1 may be used in combination. The kind of the pigment is not limited to the above-mentioned pigment but includes a water-soluble pigment soluble in water.

The makeup cosmetic composition of the present invention may contain a preservative, a moisturizing agent, a film-forming agent, a perfume, and the like, which are used in cosmetics of the present invention, within the range that does not impair the effects of the present invention.

In the present invention, the D-phase emulsion is contained in an amount of 0.5 to 20% by weight based on the total weight of the water-dispersion type makeup cosmetic composition. When the D-phase emulsion is used in an amount of 0.5% by weight or less, it is difficult to expect an improvement in moisturizing and luster feeling. When the D-phase emulsion is used in an amount of 20% by weight or more, oily feeling is severe and tackiness is accompanied.

In the present invention, the cosmetic composition is characterized by being excellent in moisturizing feeling, glossiness and stability.

According to the Experimental Example of the present invention, the moisture-dispersed type make-up cosmetic composition (Example) and the D-phase emulsion-free composition (Comparative Example 1-2) And gloss as well as the stability of the cosmetic composition are improved (see Experimental Examples 1 to 4 of the present invention). From these results, it can be seen that when the D-phase emulsion is solubilized in the water dispersion type cosmetic composition, it is possible to solve the drawback of the water dispersion type cosmetic composition, that is, the decrease in the feeling of moisture and luster.

In the present invention, the cosmetic composition may be used in formulations such as a liquid foundation, a concealer, a base, etc. Preferably, the cosmetic composition is composed of a lip makeup cosmetic composition for lip, specifically, a lipstick, a liquid loose, a lip balm and a lip gloss Lt; RTI ID = 0.0 > of: < / RTI >

The makeup cosmetic composition according to the present invention can be prepared by treating the above-mentioned components with a conventional method such as heating, mixing and stirring. Such a manufacturing process is obvious in view of the technical level of a person skilled in the art.

As described above, the cosmetic composition of the water dispersion type in which the D-phase emulsion is solubilized on the water surface imparts an oily feeling of flouring and a moist feeling without tackiness such as an emulsion type upon application and improves the gloss, It shows a new feeling that was not available.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a graph showing a comparison between the amount of skin moisture and the rate of change in Examples and Comparative Examples of the present invention. Fig.
Fig. 2 is a graph showing a comparison of the reflectance before and after coating of the embodiment of the present invention and the comparative example.

Hereinafter, the present invention will be described in more detail with reference to Examples. These embodiments are only for illustrating the present invention, and thus the scope of the present invention is not construed as being limited by these embodiments.

EXAMPLES AND COMPARATIVE EXAMPLES 1 TO 3 Preparation of Makeup Cosmetic Composition of Water Dispersion Type

Table 1 below shows raw materials for the D phase emulsion and raw materials for the aqueous formulation. The contents of the following Table 1 were prepared on the basis of% by weight.

Specifically, the D-phase emulsion in Table 1 was first prepared, and the water-based dispersion was prepared by sequentially dispersing and dissolving the aqueous feedstock in a separate container. Finally, the D-phase emulsion was added to the aqueous formulation And dispersed.

Specifically, the D-phase emulsion was prepared, and then the D-phase emulsion was added to the aqueous dispersion formulation.

The D-phase emulsion is prepared by mixing a small amount of purified water, glycerin, and polyglyceryl-10 myristate with stirring and heating (70 ° C), slowly mixing small amounts of diphenyl dimethicone, squalane and trihexylhexanone , And dispersion. In this case, OD Gel having a high viscosity is formed. After the dispersion is cooled to 30 ° C, purified water, a ginger extract, disodium dithiophosphate, sodium citrate, citric acid and rhizome flower extract are sequentially added and mixed in order to obtain a low viscosity O / W emulsion phase D phase emulsion can be completed.

In the case of water-dispersible formulations, the following purified water is added to an agitator, heated to 50 to 55 ° C, and then the raw materials in the table are added in turn and mixed. In the case of polyacrylate crosspolymer-6 and ammonium acryloyldimethyltaurate / Vpicopolymer when mixed, the powder may not be loosened when put in at once, so slowly add it in small amounts.

After the ingredients other than the fragrance are added, the mixture is put into the D phase and completely dispersed. When the D-phase emulsion is finally dispersed, the perfume is added and dispersed, followed by degassing (degassing) to remove the bubbles, thereby completing the formulation.

Raw material name Example Comparative Example 1 Comparative Example 2 Comparative Example 3

D phase emulsion raw material Diphenyl dimethicone 3.15 - - 31.3992 glycerin 2.554 - - 25.4583 Squalane 1.9 - - 18.9392 Purified water 0.706 - - 7.0374 Triethanolhexanone 1.1 - - 10.9648 Polyglyceryl-10 myristate 0.55 - - 5.4824 Gold Euphoria extract 0.005 - - 0.0498 Disodium iodide 0.01 - - 0.0997 Sodium citrate 0.01 - - 0.0997 Citric acid 0.01 - - 0.0997 Rhododendron flower extract 0.005 - - 0.0498

Aquatic raw materials Purified water 64.98 87.38 74.98 - Butylene glycol 5 5 5 - glycerin 5 5 5 - Dipropylene glycol 5 - 5 - Dimethicone 4 - 4 - Polyacrylate Crosspolymer-6 2.5 - 2.5 - Ammonium acryloyldimethyltaurate / Vpicopolymer 1.5 - 1.5 - Phenoxyethanol 0.72 0.5 0.72 - lecithin 0.4 - 0.4 - Ethylhexyl Glycerin 0.08 - 0.08 - Methylparaben - 0.3 - - Carbomer - 0.7 - - &Lt; tb > ______________________________________ < tb > ______________________________________ < tb > - - - - PIGGY-60 Hydrogenated Castor Oil 0.4 - 0.4 - Pigment 0.32 0.32 0.32 0.32 Pentyleneglycol - - - - Tromethamine - 0.7 - - Spices 0.1 0.1 0.1 -

In the case of Comparative Examples 1 and 2, the formulation of the conventional water dispersion formulation was used. In Comparative Examples 1 and 2, other thickening agents were used.

In the case of Comparative Examples 1 and 2, it is the prescription of the conventional water dispersion formulations. In Comparative Example 1, the other thickener of the carbomer type which is most widely used in the water dispersion formulations is used. In Comparative Example 2, the same amount and the same amount were applied as in the Examples.

In the case of Comparative Example 3, only the D phase raw material itself was used without solubilizing the D phase raw material in the aqueous formulation, and only the pigment was added. The manufacturing process of the comparative examples is the same as the embodiment.

After preparing the examples and comparative examples 1 to 3 as described above, their formulations were compared.

As a result, in the case of Comparative Example 1, water evaporation was very rapid, and a feeling of dryness was felt to be severe, and the gloss reduction after the lapse of time was confirmed very quickly.

In the case of Comparative Example 2, although the initial moisture sensitivity was high, the water evaporation rapidly proceeded, and the shining power was also rapidly decreased as the water evaporated.

In the case of Comparative Example 3 using only the D phase emulsion, the feeling of adhesion was very poor due to oily rubbing property, pigment dispersion did not occur, and dye bleeding phenomenon was very strongly observed. It is considered impossible for commercialization using the D-phase emulsion itself.

Due to these problems, it was considered that it would be difficult to commercialize. In Comparative Example 3, additional tests other than hardness and pH measurement were excluded.

Test Example 1: Hardness and pH measurement

The pH and the viscosity were comparatively evaluated using the above-described Examples and Comparative Examples 1 to 3. Specifically, each sample was stored in a constant temperature bath at 25 ° C for 24 hours, and the viscosity was measured using a Brookfield LVT viscometer (brookfield viscometer) at a No. 64 PIN 12RPM. Using a pH meter (Bench pH meter HI 4221) The pH was measured. The measurement results are shown in Table 2.

Example Comparative Example 1 Comparative Example 2 Comparative Example 3 pH 7.05 6.89 6.98 7.31 Viscosity 19000 16000 18000 5000

As a result, as shown in Table 2, the viscosity of the composition of the examples of the present invention and the compositions of Comparative Examples 1 and 2 were not significantly different.

In addition, the pH value is a factor affecting the formulation stability and repellency, and the pH portion is similar to 7.05 in the embodiment, and the comparative examples 1 and 2 are similar to about 7.0.

On the other hand, Comparative Example 3 had a low viscosity and a slightly higher pH than Examples and Comparative Examples 1 and 2.

Test Example 2: Evaluation of moisture

A Corneometer CM825 (CK electronic, Germany) instrument was used to evaluate the moisture resistance of the above Examples and Comparative Examples 1 and 2.

The evaluation method was applied to five healthy adult women (average age: 26.2 years) and the moisture was measured after application. The results are shown in the graph (FIG. 1). Specifically, in the measurement of the moisture resistance, the moisture content of the martini coat of the test area (22 cm ² ) was measured, and 20 μl of the product was applied to the test site and absorbed. After 30 minutes, 2 hours, 4 hours, and 8 hours after skin moisture were measured three times, respectively.

The results of the measurements were obtained by calculating the skin moisture content and the rate of change using the average value of the three measurements, and then compared with the non-attrition value. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a graph comparing skin moisture change rates in Examples of the present invention and Comparative Example. Fig.

As a result, as can be seen from FIG. 1, the moisture resistance of the three groups was improved compared to the non-moisture group, and the moisturizing power of the examples was the highest. Compared to Comparative Example 1, and about 1.5 times higher than Comparative Example 2, respectively. It was found that the skin moisturizing ability was maintained up to 8 hours. In Comparative Examples 1 and 2, there was no significant difference from the non-irritating group after about 2 hours,

That is, it was confirmed that the moisturizing power was good in the order of Examples of the moisture-holding test result> Example> Comparative Example 2> Comparative Example 1, and it was confirmed that the embodiment of the present invention using the D-phase emulsion was superior not only in moisture resistance, .

Test Example 3: Glossiness evaluation

Micro-TRI-gloss (BYK Gardner, Germany) instrument was used to evaluate the glossiness of the makeup cosmetic compositions of the above Examples and Comparative Examples 2.

In the case of Comparative Example 1, the incrementing agent and the incrementing agent were differently used in Examples and Comparative Example 2, and in the case of Carbomer, which is an increment agent applied to Comparative Example 1, the glossiness was generally lowered, Therefore, they were excluded from the glossiness evaluation.

For the test, artificial leather was used. The glossiness of the artificial leather test area (48 cm ² ) was measured three times before applying the product, and the product was applied to the test area by 120 쨉 l.

The measured results were compared with the before and after values at 20 ° reflectance at 70 ° C or higher and 85 ° C reflectance at 10 ° C or below based on the measured reflectance at 60 ° C. 2 is a graph comparing the reflectance before and after coating of the embodiment of the present invention and Comparative Example 2. Fig.

As a result of the glossiness test, the glossiness of the example was excellent as shown in the graph 2. It has a glossiness improved by about 2.6 times as compared with that before coating, and is about twice as improved as that of Comparative Example 2.

That is, it was confirmed that the example of the present invention to which the D-phase emulsion was applied had a better glossiness as compared with Comparative Example 2.

Test Example 4: Stability evaluation

In the Examples and Comparative Examples 1 and 2, the stability of the makeup cosmetic composition was evaluated.

The temperature was kept for 14 days in a thermostatic chamber according to the temperature shown in Table 4, and the appearance change was visually observed. The results are shown in Table 3.

Example Comparative Example 1 Comparative Example 2 25 ℃ ○ ○ ○ 37 ℃ ○ ○ ○ 45 ° C ○ △ ○ cycle ○ △ ○

As a result, as shown in Table 3, it was confirmed that the stability of the example of the present invention and the comparative example 2 were stable under various conditions as a whole.

The embodiments described above are merely illustrative of the present invention and are used for the purpose of describing the present invention only and not for limiting the scope of the present invention described in the claims or the claims. Therefore, those skilled in the art will appreciate that various modifications and equivalent embodiments are possible without departing from the scope of the present invention.

Claims

Dispersed type make-up cosmetic composition comprising a water-dispersed aqueous phase-containing cosmetic composition, wherein the D-phase emulsion is solubilized on the aqueous phase.

The method of claim 1, wherein the D phase emulsion is selected from the group consisting of diphenyl dimethicone, glycerin, squalane, purified water, triethanolhexanoin, polyglyceryl-10 myristate, disodium iditate, sodium citrate and citric acid Wherein the water-dispersible type make-up cosmetic composition is used in combination.

The water-dispersed make-up cosmetic composition according to claim 1, wherein the water-receiving part comprises purified water, a moisturizer, a thickening agent, and a pigment.

The emulsion according to claim 2, wherein the D-phase emulsion comprises 0.01 to 10% by weight of diphenyl dimethicone, 1 to 20% by weight of glycerin, 0.01 to 7% by weight of squalane, 0.1 to 25% 0.01 to 7 wt% of ethylhexanone, and 0.01 to 3 wt% of polyglyceryl-10-myristate.

The makeup cosmetic composition according to claim 1, wherein the D-phase emulsion is contained in an amount of 5 to 20% by weight based on the total weight of the makeup cosmetic composition.

The makeup cosmetic composition according to claim 1, wherein the cosmetic composition is excellent in a moisturizing feeling, glossiness and stability.

The cosmetic composition of claim 1, wherein the cosmetic composition is selected from the group consisting of lipstick, liquid loose, lip balm, and lip gloss.