KR101841950B1 - Method for reducing unpleasant taste - Google Patents
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Abstract
인체에 유용한 기능성 성분 등 특유한 불쾌미 물질에 대해서, 그 불쾌미를 감소시키는 간단하고 저렴한 방법을 얻는 것을 과제로 한다. 갈락투론산 함유 수용성 다당류에 의해 분산된 글루텐 소재의 분산액 중에, 또는 함수 알코올류 혹은 당류 수용액에 의해 분산된 글루텐 소재의 분산액 중에, 불쾌미 물질을 혼합시켜 글루텐 소재 복합체로 함으로써 이들 불쾌미를 감소시킬 수 있다. 이에 따라 저렴한 조작을 함으로써, 불쾌미를 수반하는 다양한 기능성 성분 등을 맛에 영향을 주지 않고 섭취할 수 있게 된다.It is an object of the present invention to provide a simple and inexpensive method of reducing unpleasantness of a specific unpleasant substance such as a functional ingredient useful for the human body. It is possible to reduce unpleasantness by mixing glutinous material dispersed in a glutinous material dispersion dispersed with a galacturonic acid-containing water-soluble polysaccharide or in a glutinous material dispersion dispersed with a hydroalcoholic or saccharide aqueous solution to form a glutinous material composite . Accordingly, by performing inexpensive operations, various functional ingredients accompanied by unpleasantness can be ingested without affecting the taste.
Description
본 발명은, 불쾌미 물질(不快味 物質)이 가지는 불쾌미의 감소 방법에 관한 것이다. 상세하게는, 불쾌미 물질을, 글루텐 소재(gluten 素材)와, 물 또는 함수 알코올류(含水 alcohol類) 중으로 혼합시킴으로써, 입에 머금었을 때에 생기는 불쾌미를 감소시키는 방법에 관한 것이다.
The present invention relates to a method for reducing unpleasantness of an unpleasant substance (unpleasant substance). More particularly, the present invention relates to a method for reducing uncomfortable feeling caused by mixing an unpleasant substance into a gluten material (gluten material) and water or a hydroalcohol (hydroalcohol).
식품은 각각 복잡하고 고유한 맛을 가지고 있다. 식품의 기호성에 있어서, 쓴 맛, 떫은 맛이라는 맛은 빠뜨릴 수 없는 것이지만, 과도한 맛은 식품의 풍미의 조화를 현저하게 흐트러뜨려 불쾌미, 불쾌취(不快臭)가 된다. 일반적으로 식품의 쓴 맛 성분으로서 들 수 있는 배당체(配糖體)나 펩티드(peptide), 아미노산(amino acid)이라는 성분은, 대체로 인체에 유용한 생리기능을 구비하고 있어 적극적인 섭취가 요구되지만, 한편 그 불쾌미때문에 식품으로의 이용에 있어서는 기호상 문제가 되는 경우가 많다.Each food has a complex and unique taste. In the palatability of foods, the bitter taste and bitter taste are indispensable, but the excessive taste disturbs the harmony of the flavor of the food remarkably and becomes unpleasant and unpleasant odor. In general, components such as glycosides, peptides, and amino acids, which are generally considered to be bitter components of food, generally have a physiological function useful for the human body and require active ingestion. On the other hand, Because of the unpleasantness, it is often a symbolic problem in the use as food.
특히 대두 사포닌(大豆 saponin) 등의 배당체는, 항산화작용(抗酸化作用)이나 지질대사 개선작용(脂質代謝 改善作用), 당흡수 억제작용(糖吸收 抑制作用) 등도 보고되어 있어, 최근 주목받아 건강식품 등에 이용되고 있지만, 풍미상의 문제 때문에 다용(多用)할 수 없다고 하는 결점이 있었다.Particularly, glycosides such as soy saponin have been reported to have antioxidant activity, lipid metabolism improving action (lipid metabolism improving action), and glucose absorption inhibitory action (sugar absorption suppression action) Food and the like, but there is a drawback that it can not be used for a large amount because of the problem of flavor.
식품의 불쾌미를 감소시키는 방법으로서는, 예를 들면 효소처리나 미생물에 의한 발효처리 등으로 불쾌미 성분을 분해하는 방법(특허문헌1), 불쾌미를 구비하는 성분을 흡착 수지에 의해 제거하는 방법(특허문헌2) 등이 알려져 있지만, 분해나 제거에 의해 유익한 성분이 변화된다고 하는 폐해가 있다.As a method for reducing the unpleasantness of the food, a method of decomposing an unpleasant component by, for example, an enzyme treatment or a fermentation treatment with a microorganism (Patent Document 1), a method of removing a component having an unpleasant taste by an adsorption resin (Patent Document 2) and the like are known, but there is a problem that a beneficial component is changed by decomposition or removal.
또한 감미(甘味)를 구비하는 당류(糖類)나 당알코올(糖alcohol) 등을 사용해서 불쾌미를 감소시키는 방법(특허문헌3, 4, 5), 아미노산이나 쓴 맛 차폐 펩티드(遮蔽 peptide)를 사용해서 불쾌미를 감소시키는 방법(특허문헌6, 7, 비특허문헌1), 사이클로덱스트린(cyclodextrin)을 사용해서 두유의 불쾌미를 감소시키는 방법(특허문헌8) 등이 알려져 있지만, 당류나 아미노산, 펩티드 자체의 맛이 영향을 줄 가능성이 크다. 또한 사이클로덱스트린은, 포접공정(包接工程)이 번잡하고 사이클로덱스트린 자체의 가격이 고가이기 때문에, 쓴 맛 성분을 감소시키면서 일반의 식품에 이용하기에는 충분하게 만족할 수 있는 것은 아니었다.(Patent Documents 3, 4 and 5), a method of reducing uncomfortable feeling by using saccharides or sugar alcohols having sweetness (amino acids or a bitter taste shielding peptide) (Patent Literature 6 and 7, Non-Patent Literature 1), and a method of reducing unpleasantness of soybean milk using cyclodextrin (Patent Document 8). However, a method of reducing sugars and amino acids , The taste of the peptide itself is likely to affect the taste. Further, cyclodextrin was not satisfactory enough to be used for general food while decreasing bitter taste components because the inclusion step (inclusion step) was troublesome and the price of cyclodextrin itself was high.
글루텐은, 수중(水中)에서는 골격을 형성하고, 통상의 pH역(域)에서는 분산되기 어렵지만 pH4 이하의 산성이나 pH10 이상의 염기성 조건에서는 용해된다(비특허문헌2). 또한 글루텐에 펙틴(pectin)을 가함으로써(특허문헌9),혹은 수용성 대두 다당류(水溶性 大豆 多糖類)를 가함으로써(특허문헌10) 글루텐의 분산을 촉진하는 것이 개시되어 있다. 그러나 분산된 글루텐이 불쾌미 물질에 주는 효과에 대해서는 조금도 나타내지 않고 있다.
Gluten forms a skeleton in water (in water) and is difficult to disperse in a normal pH range, but dissolves in acidic conditions of pH 4 or less and basic conditions of pH 10 or more (Non-Patent Document 2). It is also disclosed that pectin is added to gluten (Patent Document 9), or water-soluble soy polysaccharide (water-soluble soybean polysaccharide) is added (Patent Document 10) to promote the dispersion of gluten. However, there is no indication of the effect of dispersed gluten on unpleasant substances.
예를 들면 인체에 유용한 기능성 성분 등에 있어서, 특유한 불쾌미를 구비하는 식용물질에 대해서, 그 불쾌미를 감소시키는 간단하고 저렴한 방법을 얻는 것을 과제로 하였다.
It is an object of the present invention to provide a simple and inexpensive method for reducing the unpleasantness of edible materials having peculiar unpleasantness in a functional ingredient useful for the human body, for example.
본 발명자는, 불쾌미 물질에 대하여, 갈락투론산 함유 수용성 다당류(galacturonic acid 含有水溶性多糖類)에 의해 수계에 분산된 글루텐 소재의 분산액, 또는 함수 알코올류 혹은 당류 수용액 중에 분산된 글루텐 소재의 분산액을 혼합 시킴으로써 그 불쾌미가 감소되는 것을 찾아내어, 본 발명을 완성시켰다.DISCLOSURE OF THE INVENTION The present inventors have found that a glutinous material dispersion dispersed in water by a water-soluble polysaccharide containing galacturonic acid (galacturonic acid-containing water-soluble polysaccharide) or a dispersion of glutinous material dispersed in a hydroalcoholic or saccharide aqueous solution And that the unpleasantness is reduced. Thus, the present invention has been completed.
즉 본 발명은,That is,
(1)불쾌미 물질에 대하여, 액중에 분산된 글루텐 소재를 혼합하는 것을 특징으로 하는 불쾌미 물질의 불쾌미의 감소 방법.(1) A method for reducing unpleasantness of unpleasant substances, which comprises mixing a gluten material dispersed in a liquid with an unpleasant substance.
(2)불쾌미 물질에 대하여, 갈락투론산 함유 수용성 다당류에 의해 수계에 분산된 글루텐 소재를 혼합하는 것을 특징으로 하는 (1)에 기재된 불쾌미 물질의 불쾌미의 감소 방법.(2) The method according to (1), wherein the glutinous material dispersed in the aqueous system is mixed with the galacturonic acid-containing water-soluble polysaccharide to the unpleasant microorganism.
(3)글루텐 소재중의 글루텐 단백질 고형분에 대하여, 갈락투론산 함유 수용성 다당류를 0.03~20중량% 사용하는 (2)에 기재된 불쾌미 물질의 불쾌미의 감소 방법.(3) A method for reducing the uncomfortable feeling of the unpleasant substance according to (2), wherein 0.03 to 20% by weight of the galacturonic acid-containing water-soluble polysaccharide is added to the gluten protein solid content in the gluten material.
(4)불쾌미 물질에 대하여, 함수 알코올류 혹은 당류 수용액에 분산된 글루텐 소재를 혼합하는 것을 특징으로 하는 (1)에 기재된 불쾌미 물질의 불쾌미의 감소 방법.(4) The method for reducing unpleasantness of unpleasant substances as set forth in (1), wherein glutinous material dispersed in a hydroalcoholic or aqueous sugar solution is mixed with the unpleasant substance.
(5)불쾌미 물질 1중량부에 대하여, 글루텐 소재를 글루텐 단백질 고형분으로서, 0.2~100중량부 사용하는 (1)에 기재된 불쾌미 물질의 불쾌미의 감소 방법.(5) A method for reducing the uncomfortable feeling of the unpleasant substance according to (1), wherein the gluten material is used in an amount of 0.2 to 100 parts by weight as a gluten protein solid content with respect to 1 part by weight of the unpleasant inorganic substance.
(6)불쾌미 물질이, 폴리페놀류(polyphenol類), 플라보노이드류(flavonoid類), 사포닌류, 알칼로이드류(alkaloid類), 쓴 맛 아미노산 또는 펩티드로부터 선택되는 1종 이상인 (1)에 기재된 불쾌미 물질의 불쾌미의 감소 방법.(6) The method according to (1), wherein the unpleasant substance is one or more selected from polyphenols, flavonoids, saponins, alkaloids, bitter amino acids or peptides A method for reducing unpleasantness of a substance.
(7)갈락투론산 함유 수용성 다당류에 의해 수계에 분산된 글루텐 소재의 분산액, 또는 함수 알코올류 혹은 당류 수용액 중에 분산된 글루텐 소재의 분산액과, 불쾌미 물질을 혼합하는 것을 특징으로 하는 글루텐 소재 복합체의 제조방법.(7) A gluten-containing composite material characterized by mixing a glutinous material dispersion dispersed in water with a water-soluble polysaccharide containing galacturonic acid, or a dispersion of glutinous material dispersed in a hydroalcoholic or aqueous sugar solution Gt;
(8)갈락투론산 함유 수용성 다당류에 의해 수계에 분산된 글루텐 소재의 분산액, 또는 함수 알코올류 혹은 당류 수용액 중에 분산된 글루텐 소재의 분산액과, 불쾌미 물질을 혼합함으로써 조제한 글루텐 소재 복합체.(8) A gluten material complex prepared by mixing a glutinous material dispersion dispersed in water with a water-soluble polysaccharide containing galacturonic acid, or a dispersion of glutinous material dispersed in a hydroalcohol or an aqueous solution of saccharides, and an unpleasant micro-material.
(9)(8)의 글루텐 소재 복합체를 포함한 음식품 또는 의약품.(9) A food or drink containing gluten material complex of (8).
이다.
to be.
본 발명에 의하면, 불쾌미를 지니는 여러가지 식용물질의 불쾌미를 감소시킬 수 있다. 이에 따라 저렴한 조작을 함으로써, 불쾌미를 수반하는 다양한 기능성 성분 등을 맛에 영향받지 않고 섭취할 수 있게 된다.
According to the present invention, it is possible to reduce the unpleasantness of various edible materials having unpleasantness. Accordingly, by performing inexpensive operation, various functional ingredients accompanied with unpleasant taste can be ingested without being affected by taste.
(불쾌미 물질)(Unpleasant substance)
본 발명에 있어서 불쾌미로는, 광의(廣義)로는 떫은 맛, 쓴 맛, 얼얼한 맛, 톡 쏘는 맛, 매운 맛, 또 이상한 맛, 이상한 냄새를 포함하는 것이며, 협의로는 떫은 맛, 쓴 맛이다. 불쾌미 물질로는, 상기한 불쾌미를 나타내는 물질로서, 식용물(可食物)이며, 사포닌류, 이소플라본류 등의 배당체나 아글리콘(aglycone), 탄닌(tannin), 카테킨(catechin) 등의 폴리페놀류, 카페인 등의 알칼로이드류, 및 펩티드, 쓴 맛 아미노산 등의 떫은 맛이나 쓴 맛 등의 불쾌미를 구비하는 성분을 포함하는 물질, 또 불쾌미를 나타내는 천연물이나 천연물로부터 추출된 조추출물(粗抽出物; crude extract) 등도 포함하는, 이들로부터 선택되는 1종 이상의 것이다. 한편 쓴 맛 아미노산에는, 페닐알라닌(phenylalanine), 히스티딘(histidine), 아르기닌(arginine), 이소류신(isoleucine), 발린(valine), 류신(leucine), 메티오닌(methionine), 트립토판(tryptophan)이 포함된다. 또한 불쾌미를 나타내는 천연물에는 그린 허브 분말(green herb粉末)이나 녹즙 등을 예시할 수 있고, 조추출물에는, 건강식품이라고 불리는 구아바잎 엑기스, 필발(Piper longum) 엑기스 등 각종 엑기스류나, 감초 엑기스 등의 한방약 성분이나 생약 등을 예시할 수 있다.In the present invention, the unpleasant maze includes a dark taste, a bitter taste, a pungent taste, a pungent taste, a pungent taste, a strange taste, and a strange smell in a broad sense. Examples of the unpleasant substances include edible materials such as glycosides such as saponins and isoflavones, aglycone, tannin, catechin, and the like, Alkaloids such as phenols, caffeine and the like, and substances containing unpleasant taste such as peel and bitter taste such as peptides and bitter amino acids, and crude extracts extracted from natural or natural products showing unpleasantness Crude extract, and the like. On the other hand, bitter amino acids include phenylalanine, histidine, arginine, isoleucine, valine, leucine, methionine, and tryptophan. Green herb powder and green juice can be exemplified as the natural products showing unpleasantness. The crude extract includes various extracts such as guava leaf extract, Piper longum extract and licorice extract, Herbal medicine ingredient and herbal medicine.
(글루텐 소재)(Gluten material)
본 발명에 있어서 글루텐 소재로는, 밀(小麥), 호밀, 쌀 등의 곡물 유래 단백질인 글루테닌(glutenin)과 글리아딘(gliadin)을 주성분으로 하는 글루텐 단백질을 포함하는 것이다. 부분 정제(粗精製)된 것이어도 정제된 것이어도, 웨트 글루텐(wet gluten)이어도 건조한 분말상(粉末狀)의 글루텐(활성 글루텐)이어도 사용할 수 있다. 또한 그 건조 방법에 있어서는 플래시 드라이(flash drying), 분무건조, 진공건조, 동결건조 등에 의해 조제할 수도 있다. 또한 글루텐 단백질을 함유하는 곡물, 예를 들면 밀로부터 조제된 밀가루(소맥분)도 사용할 수 있다. 글루텐 소재 중에 글루텐 단백질이 20중량% 이상 존재하는 것이 바람직하고, 50중량% 이상 존재하면 더 바람직하다.In the present invention, the gluten material includes gluten protein composed mainly of glutenin and gliadin, proteins derived from grain such as wheat, rye and rice. Partially purified (crude), purified or dried (wet gluten) powdery gluten (active gluten) may also be used. In addition, the drying method may be prepared by flash drying, spray drying, vacuum drying, freeze drying, or the like. It is also possible to use cereals containing gluten protein, for example flour (wheat flour) prepared from wheat. It is preferable that the gluten protein is present in the gluten material in an amount of 20 wt% or more, more preferably 50 wt% or more.
(갈락투론산 함유 수용성 다당류)(Water-soluble polysaccharide containing galacturonic acid)
본 발명에 있어서 갈락투론산 함유 수용성 다당류로는, 산성 다당류(酸性 多糖類)이며, 주로 우론산(uronic acid)이 갈락투론산인 것을 가리킨다. 구체적으로는 대두 유래의 수용성 대두 다당류 및 각종 펙틴, 예를 들면 비트(beet)나 감자 등의 근채류로부터 추출한 펙틴이나, 레몬이나 라임 등의 감귤류로부터 추출한 펙틴 등이 있다. 특히 수용성 대두 다당류를 사용했을 경우, 동(同) 수용액 또는 후술하는 글루텐 분산액이 저점도(低粘度)이며 바람직하다. 한편, 수용성 대두 다당류는, 비지로부터 약산성 하에서 100도를 넘는 온도에서 추출한, 갈락투론산을 주쇄(主鎖)로 가지는 수용성의 산성 다당류이다.In the present invention, the galacturonic acid-containing water-soluble polysaccharide is an acidic polysaccharide (acidic polysaccharide), and it mainly indicates that uronic acid is galacturonic acid. Specifically, there are water-soluble soybean polysaccharides derived from soybean and various pectin such as pectin extracted from root vegetables such as beet and potato, and pectin extracted from citrus such as lemon and lime. Particularly, when a water-soluble soy polysaccharide is used, the aqueous solution of copper or the gluten dispersion described below is preferably low viscosity (low viscosity). On the other hand, the water-soluble soy polysaccharide is a water-soluble acid polysaccharide having galacturonic acid as a main chain extracted at a temperature of more than 100 deg.
(함수 알코올류)(Functional alcohols)
본 발명에 있어서 함수 알코올류로는, 분자 중에 알코올성 수산기(水酸基)를 1기(基) 이상 구비하는 수용성 알코올류의, 함수물(含水物)의 것이다. 수용성 알코올류로서는, 메탄올, 에탄올, n-프로판올, iso-프로판올 등을 들 수 있다. 식용이 가능하며 이상한 냄새가 적은 것이 바람직하고, 에탄올이 가장 바람직하다.The functional alcohols in the present invention are water-soluble ones of water-soluble alcohols having at least one alcoholic hydroxyl group (hydroxyl group) in the molecule. Examples of the water-soluble alcohols include methanol, ethanol, n-propanol, and iso-propanol. It is preferably edible and has less unpleasant odor, and ethanol is most preferred.
(당류 수용액)(Aqueous solution of saccharide)
본 발명에 있어서, 당류로는, 에틸렌글리콜, 프로필렌글리콜, 글리세린(glycerin), 에리스리톨(erythritol), 소르비톨(sorbitol) 등의 당알코올류, 글루코오스(glucose), 프룩토오스(fructose), 갈락토오스(galactose), 아라비노스(arabinose), 수크로오스(sucrose), 말토오스(maltose), 락토오스당(lactose糖)의 소당류(少糖類)를 들 수 있다. 식용이 가능하며 이상한 냄새가 적은 것이 바람직하고, 글리세린, 맥아당(麥芽糖), 수크로오스가 가장 바람직하다.In the present invention, examples of the saccharides include sugar alcohols such as ethylene glycol, propylene glycol, glycerin, erythritol and sorbitol, glucose, fructose, galactose, ), Arabinose, sucrose, maltose, and lactose sugar (oligosaccharides). It is preferably edible and has less unpleasant odor, and glycerin, malt sugar and sucrose are most preferred.
이들 수용성 알코올류나 당류는, 액상의 형태로 되고, 그 중에 글루텐 소재가 균일한 슬러리 상태로 분산되는 것에 필요한 수분을 포함하는 것이 필요하다. 에탄올의 경우에 수분은 5~30중량% 정도가 바람직하고, 20도의 수크로오스의 수용액의 경우에 수분은 33~95중량% 정도가 바람직하다. 또한 복수의 알코올류나 당류를 동시에 사용할 수도 있다.These water-soluble alcohols and saccharides are in the form of a liquid, and it is necessary that they contain water necessary for dispersing the gluten material in a uniform slurry state. In the case of ethanol, the water content is preferably about 5 to 30% by weight, and in the case of an aqueous solution of sucrose at 20 캜, the water content is preferably about 33 to 95% by weight. A plurality of alcohols or saccharides may be used at the same time.
(글루텐 소재 분산액)(Gluten material dispersion)
본 발명에 있어서의 분산액으로는, 갈락투론산 함유 수용성 다당류를 사용하고, 수계(水系)에서 글루텐 소재를 균일한 슬러리 상태로 한 것, 또는 함수 알코올류 혹은 당류 수용액 중에 글루텐 소재를 균일한 슬러리 상태로 한 것이다. 이때에 각종 분산성 개량제를 병용하여도 좋다. 극단적으로 pH가 낮은 또는 높은 수계의 분산액은 독특한 풍미가 부여되기 때문에, pH5~9의 분산액이 바람직하다.As the dispersion in the present invention, it is possible to use a galacturonic acid-containing water-soluble polysaccharide, to make a gluten material into a uniform slurry state in an aqueous system, or to make a gluten material in a uniform slurry state in a hydroalcoholic or saccharide aqueous solution . At this time, various dispersant improving agents may be used in combination. A dispersion having a pH of from 5 to 9 is preferable because a dispersion of extremely low or high pH is imparted with a unique flavor.
본 발명에 있어서 갈락투론산 함유 수용성 다당류의 분산액으로의 사용량은, 글루텐 소재중의 글루텐 단백질 고형분에 대하여 0.03중량%~20중량%의 첨가가 바람직하고, 0.1중량%~10중량%가 더 바람직하며, 0.5중량%~5중량%가 가장 바람직하다. 보통은 글루텐 소재의 조단백질(粗蛋白質) 함량을 글루텐 단백질 고형분으로 간주할 수 있다.In the present invention, the amount of the galacturonic acid-containing water-soluble polysaccharide to be used is preferably 0.03% by weight to 20% by weight, more preferably 0.1% by weight to 10% by weight, based on the solid content of gluten protein in the gluten material , And most preferably 0.5 wt% to 5 wt%. Normally, the crude protein content of gluten can be regarded as a gluten protein solid.
불쾌미 물질에 대한 글루텐 소재의 사용량에 대해서는, 불쾌미 성분을 포함하는 물질과 글루텐 단백질이 액중에 분산되어 불쾌미가 감소하는 조건이면 좋다. 불쾌미 물질의 순도 등 불쾌미의 정도에 의하지만, 예를 들면 펩티드나 정제 사포닌의 경우, 불쾌미 물질 1중량부에 대하여, 글루텐 소재를 글루텐 단백질 고형분으로서 0.2중량부~100중량부가 되도록 분산액에 혼합하는 것이 바람직하고, 0.5중량부~10중량부가 되는 것이 더 바람직하다. 정제도가 낮은 등 불쾌미가 약한 불쾌미 물질의 경우에는, 글루텐 단백질의 사용량은 적게 할 수 있다.Regarding the amount of the gluten material to be used with respect to the unpleasant substance, it is sufficient that the substance containing the unpleasant ingredient and the gluten protein are dispersed in the liquid to reduce the unpleasant taste. For example, in the case of peptides or purified saponins, 1 part by weight of the unpleasant substance is added to the dispersion such that the gluten content is 0.2 part by weight to 100 parts by weight as the gluten protein solid content, depending on the degree of unpleasantness, It is more preferable to mix them, and more preferably 0.5 parts by weight to 10 parts by weight. In the case of unpleasant unpleasant substances such as low refinement degree, the use amount of gluten protein can be reduced.
글루텐 소재는, 글루텐 단백질 고형분 1중량부에 대하여 3중량부~150중량부의 액에서 분산시키는 것이 바람직하고, 5중량부~100중량부가 더 바람직하다. 액량이 적으면 글루텐이 균일하게 분산되지 않아 원하는 효과가 얻어지지 않는 경우가 있고, 액량이 지나치게 많으면 용액이 희박하게 되어 실용성이 낮아진다.The gluten material is preferably dispersed in a liquid of 3 to 150 parts by weight based on 1 part by weight of the solid content of the gluten protein, more preferably 5 to 100 parts by weight. If the liquid amount is small, the gluten is not uniformly dispersed and the desired effect may not be obtained. When the liquid amount is too large, the solution becomes lean and the practicality is low.
(조제법·갈락투론산 함유 수용성 다당류)(Preparation method · Galacturonic acid-containing water-soluble polysaccharide)
본 발명에 있어서, 분산액의 조제 방법에 대해서는 여러가지 방법을 사용할 수 있다. 예를 들면 수중에서 괴상(塊狀)이 된 글루텐 소재에 대하여 갈락투론산 함유 수용성 다당류를 직접 첨가한 분산액이나, 미리 조제한 갈락투론산 함유 수용성 다당류 수용액에 글루텐 소재를 혼합한 분산액, 또는 갈락투론산 함유 수용성 다당류와 글루텐 소재의 혼합물에 물을 가한 분산액에, 불쾌미 물질을 첨가하더라도 좋다.In the present invention, various methods can be used for preparing the dispersion. For example, a dispersion prepared by directly adding a galacturonic acid-containing water-soluble polysaccharide to a massive gluten material in water or a dispersion in which a glutinous material is mixed with an aqueous solution of a previously prepared galacturonic acid-containing water-soluble polysaccharide or galacturonic acid Containing water-soluble polysaccharide and the gluten material may be added to the dispersion liquid in which water is added.
또는 불쾌미 물질을, 상기한 글루텐 소재를 용해시키는 물, 또는 갈락투론산 함유 수용성 다당류를 용해시키는 물에 미리 첨가하더라도 좋다. 갈락투론산 함유 수용성 다당류 건조물 및 글루텐 소재 건조물의 각각 또는 혼합물에 불쾌미 물질을 첨가한 뒤에 물을 가하여도 좋다.Or an unpleasant substance may be added in advance to water which dissolves the gluten material or galacturonic acid-containing water-soluble polysaccharide. Water may be added to each of the dried product of the water-soluble polysaccharide containing galacturonic acid and the dried product of the gluten material, or after the unpleasant micro-material is added.
또는 불쾌미 물질을 효과적으로 분산시키기 위해서, 글루텐 소재 첨가 전의 갈락투론산 함유 수용성 다당류와, 분체(粉體) 또는 수용액의 상태에서, 불쾌미 물질을 혼합해 둘 수도 있다.In order to effectively disperse the unpleasant microcrystalline material, the unpleasant microcrystalline material may be mixed with the galacturonic acid-containing water-soluble polysaccharide before the addition of the gluten material in the form of a powder or an aqueous solution.
(조제법·함수 알코올류)(Preparative method · Functional alcohols)
함수 알코올류를 사용하는 경우에는, 예를 들면 수중에서 괴상이 된 글루텐 소재에 대하여 알코올류나 함수 알코올류를 직접 첨가한 분산액이나, 함수 알코올류에 글루텐 소재를 혼합한 분산액, 또는 알코올류와 글루텐 소재의 혼합물에 물을 가한 분산액에, 불쾌미 물질을 첨가하더라도 좋다.In the case of using functional alcohols, it is possible to use, for example, a dispersion in which alcohol or hydroalcohol is directly added to a gluten material which has been agglomerated in water, a dispersion in which hydrous alcohols are mixed with a gluten material or a dispersion in which alcohols and gluten materials May be added to the dispersion liquid in which water is added.
또는 불쾌미 물질을 알코올류에 혼합하는 물에 미리 첨가하더라도 좋다.Or an unpleasant substance may be previously added to water mixed with an alcohol.
또는 불쾌미 물질을 효과적으로 분산시키기 위해서, 글루텐 소재 첨가 전의 함수 알코올류에 불쾌미 물질을 혼합해 둘 수도 있다.In order to effectively disperse the unpleasant substance, the unpleasant substance may be mixed with the functional alcohol before the gluten material is added.
(조제법·당류 수용액)(Preparation method · aqueous solution of sugar)
당류 수용액을 사용하는 경우에는, 예를 들면 수중에서 괴상이 된 글루텐 소재에 대하여 당류나 당류 수용액을 직접 첨가한 분산액이나, 당류 수용액에 글루텐 소재를 혼합한 분산액, 또는 당류와 글루텐 소재의 혼합물에 물을 가한 분산액에, 불쾌미 물질을 첨가하더라도 좋다.In the case of using a saccharide aqueous solution, for example, a dispersion in which a saccharide or an aqueous solution of a saccharide is directly added to a gluten material which has become massive in water, a dispersion in which a saccharide material is mixed with an aqueous solution of saccharides, An unpleasant substance may be added to the dispersion.
또는 불쾌미 물질을 당류에 혼합하는 물에 미리 첨가하더라도 좋고, 당류 및 글루텐 소재 건조물의 각각 또는 혼합물에 불쾌미 물질을 첨가한 뒤에 물을 가하더라도 좋다.Alternatively, the unpleasant microorganism may be added in advance to the water to be mixed with the saccharide, or water may be added after the unpleasant microorganism is added to each of the saccharides and the dried product of the gluten material.
또는 불쾌미 물질을 효과적으로 분산시키기 위해서, 글루텐 소재 첨가 전의 당류 수용액에 불쾌미 물질을 혼합해 둘 수도 있다.In order to effectively disperse the unpleasant substance, an unpleasant substance may be mixed in the aqueous saccharide solution before the gluten material is added.
불쾌미 물질의 성상(性狀)에 따라 분산시키기 어려운 경우에는, 다른 분산제 등을 병용해서 사용하는 것도 가능하다. 또한 교반력(攪拌力)이 강한 고속분산 교반기 등의 사용도 가능하다.In the case where it is difficult to disperse depending on the nature of the unpleasant substance, other dispersant or the like may be used in combination. It is also possible to use a high-speed dispersion stirrer with strong agitation force.
분산액을 건조해도 본 발명의 불쾌미 감소의 효과는 유지된다. 건조 방법에 대해서는 일반적인 식품의 건조 방법이면 이용할 수 있다. 예를 들면 동결건조, 분무건조, 진공건조 등을 들 수 있다. 한편, 불쾌미 물질과 갈락투론산 함유 수용성 다당류와 글루텐 소재를, 또는 불쾌미 물질과 알코올류 혹은 당류와 글루텐 소재를, 건조상태인 채로 단순하게 혼합하면 본 발명의 효과를 얻을 수 없다.Even if the dispersion is dried, the effect of the unpleasant reduction of the present invention is maintained. The drying method can be used as long as it is a general food drying method. For example, freeze drying, spray drying, vacuum drying and the like. On the other hand, the effect of the present invention can not be obtained by simply mixing an unpleasant substance, a galacturonic acid-containing water-soluble polysaccharide and a gluten material, or an unpleasant substance, an alcohol, a saccharide and a gluten material in a dry state.
(글루텐 소재 복합체)(Gluten material complex)
이상과 같이 조제된, 불쾌미 물질 특히 다양한 생리기능을 수반하는 불쾌미 물질과 분산된 글루텐 소재와의 혼합물은, 글루텐 소재 복합체로서 음식품이나 의약품 분야에서 여러가지 용도로 이용할 수 있다. 즉 불쾌미 성분, 갈락투론산 함유 수용성 다당류, 글루텐 소재를 혼합한 글루텐 소재 복합체를, 또는 불쾌미 물질, 알코올류 혹은 당류, 글루텐 소재를, 수용액이나 분산액 또는 그 건조물로 조제하거나, 또는 이들을 펠렛(pellet)이나 타블렛(tablet), 겔, 졸 등으로 가공하거나, 또는 다양한 식품이나 음료에 토핑 하거나 첨가 혼합하거나 할 수도 있다. 건조물을 물이나 음료에 재용해해서 섭취하는 것도 좋다.Mixtures of unpleasant substances, particularly unpleasant substances accompanied by various physiological functions, and dispersed gluten materials, prepared as described above, can be used for various purposes in the field of foods and pharmaceuticals as a gluten material complex. A glutinous material complex containing a discomfort ingredient, a galacturonic acid-containing water-soluble polysaccharide and a gluten material, or an unpleasant substance, an alcohol, a saccharide or a gluten material is prepared from an aqueous solution, a dispersion or a dried material thereof, pellets, tablets, gels, sols or the like, or topped or mixed with various foods or beverages. It is good to eat the dried material by reusing it in water or drink.
구체적인 예로서는, 녹즙 등 불쾌미를 구비하는 음료에 글루텐 소재와 갈락투론산 함유 수용성 다당류를 혼합해 균일하게 분산시킴으로써, 이들의 불쾌미를 감소시킬 수 있다. 또는 사포닌이나 이소플라본 등 불쾌미를 가지는 다양한 기능성 소재에 대해서 그 불쾌미를 감소시킨 것을 시판 음료에 적하(滴下)하여 섭취할 수도 있다.As a specific example, the dissatisfaction may be reduced by mixing the gluten material and the galacturonic acid-containing water-soluble polysaccharide in a beverage having unpleasant taste such as green juice and uniformly dispersing it. Or a variety of functional materials having unpleasantness such as saponin and isoflavone may be ingested by dropping them in a commercial drink.
본 발명에 있어서, 불쾌미 물질과 함께 혼합되는 것 외의 소재에 대해서는, 특히 본 발명의 목적에 크게 영향을 주는 것이 아니면 그 종류는 묻지 않는다. 예를 들면 일반적으로 식품에 이용되는 성분으로서, 당질, 아미노산, 유기산, 무기산 등을 들 수 있지만, 그것에 한하지 않고 적당하게 혼합할 수 있다.In the present invention, materials other than those mixed together with the unpleasant inorganic material are not particularly limited unless they greatly affect the purpose of the present invention. For example, saccharides, amino acids, organic acids, inorganic acids and the like are generally used as ingredients for foods, but they can be suitably mixed without being limited thereto.
실시예Example
이하에 실시예를 기재한다.Examples will be described below.
○글루텐종의 검토(갈락투론산 함유 수용성 다당류의 검토)○ Examination of gluten species (Examination of water-soluble polysaccharide containing galacturonic acid)
(실시예1)(Example 1)
프리즈 드라이 활성 글루텐(freeze dry 活性 gluten)(북국푸드(주)제(製) 바이탈글루텐 : 조단백질 함량 74중량%(as-is)) 10g에 수용성 대두 다당류(후지세이유(주)제 소야파이브-S)를 0.1g(에 대해 글루텐 1.4중량%) 가하고 혼합하여 글루텐 혼합물로 하였다. 비이커에 70g의 물을 넣고 마그네틱 스터러(magnetic stirrer)로 교반한 것에 글루텐 혼합물을 투입하고, 1분간 혼합해 분산액을 만들었다. 또한 고순도 대두 사포닌(후지세이유(주) 소이헬스SA)을 5g 가하고 1분간 혼합하고 분산시켜 글루텐 소재 복합체로 하였다. 조제한 글루텐 소재 복합체 분산액을 동결건조하여 분말품(粉末品)을 얻어서 실시예1로 하였다.10 g of freeze dry active gluten (Vital Gluten: crude protein content 74 wt% (as-is), manufactured by Northern Food Co., Ltd.) was added to 100 g of a water-soluble soy polysaccharide (Soya Five- S) (1.4 wt.% Of gluten) was added and mixed to prepare a gluten mixture. 70 g of water was put into a beaker, and the mixture was stirred with a magnetic stirrer. The gluten mixture was added and mixed for 1 minute to prepare a dispersion. Further, 5 g of high-purity soybean saponin (Soichi Health SA, Fujisuyu Co., Ltd.) was added and mixed for 1 minute and dispersed to obtain a gluten material composite. The prepared glutinic material composite dispersion was freeze-dried to obtain a powdery product (powdery product), thereby obtaining Example 1.
(실시예2)(Example 2)
실시예1에 있어서, 가수량을 160g으로 하는 것 외에는 같은 조건으로 하였다.The same conditions as in Example 1 were used except that the amount of water was 160 g.
(실시예3~5)(Examples 3 to 5)
실시예2에 있어서 활성 글루텐을, 플래시 드라이 글루텐(A-글루G), 알칼리 분산성 스프레이 드라이 글루텐(A-글루K), 산분산성 스프레이 드라이 글루텐(A-글루SS)(이상, 글리코영양식품(주)제 : 조단백질 함량 74중량%(as-is))으로 하여, 각각 실시예3, 실시예4, 실시예5로 하였다.The active gluten was obtained in the same manner as in Example 2 except that the active gluten was replaced with a mixture of flash dry gluten (A-Glue G), alkaline dispersible spray dry gluten (A-Glue K), acid dispersible spray dry gluten (A- , Crude protein content: 74% by weight (as-is)) was used as Example 3, Example 4 and Example 5, respectively.
(실시예6)(Example 6)
실시예2에 있어서, 활성 글루텐 10g을 박력분(닛신제분(주)제 바이올렛 : 조단백질 함량 8중량%(as-is)) 50g으로 하는 것 외에는 같은 조건으로 하였다.The same conditions as in Example 2 were used except that 10 g of active gluten was replaced with 50 g of a pulp (Violet: crude protein content: 8 wt% (as-is) produced by Nissin Chemical Industry Co., Ltd.).
(실시예7)(Example 7)
실시예2에 있어서, 활성 글루텐 10g을 강력분(니혼제분(주)제 이글 : 조단백질 함량 12중량%(as-is)) 50g으로 하는 것 외에는 같은 조건으로 하였다.The same conditions as in Example 2 were used except that 10 g of active gluten was replaced with 50 g of high-strength powder (eagle made by Nippon Budokan Co., Ltd.: crude protein content 12 wt% (as-is)).
(비교예1)(Comparative Example 1)
실시예2에 있어서, 활성 글루텐을 분말상 분리 대두 단백(후지세이유(주)제 후지프로-E)으로 치환하는 것 외에는 같은 조건으로 하였다.The same conditions as in Example 2 were used except that active gluten was replaced with powdered soybean protein (Fujipro-E made by Fujisai Co., Ltd.).
○평가방법○ Evaluation method
각 조건으로 얻어진 글루텐 소재 복합체 분말품을 0.2g씩 먹고 관능평가를 하였다. 또한 수분산(水分散)시키지 않고 동(同) 배합으로 분체 혼합한 분말품을 컨트롤로 하여, 그 평가점과의 차이 1.0 이상을 합격으로 하였다.The glutinous composite powder obtained under each condition was eaten in 0.2 g portions and sensory evaluation was carried out. Also, powdery materials obtained by mixing powders in the same manner without water dispersion were controlled, and a difference of 1.0 or more from the evaluation point was determined as acceptable.
(g)Addition amount
(g)
(g)Quantity of water
(g)
고순도 대두 사포닌 5g 사용, 수용성 대두 다당류 0.1g 사용
Use 5 g of high purity soybean saponin, use 0.1 g of water-soluble soy polysaccharide
표2에 나타나 있는 바와 같이, 글루텐과 불쾌미 물질을 수중에서 분산시킨 글루텐 소재 복합체의 건조물은, 글루텐과 불쾌미 물질을 분체로 혼합했을 때보다 분명하게 불쾌미를 감소시키고 있었다. 또한 단백질로서 분말상 분리 대두 단백을 사용한 경우에는, 불쾌미 감소 효과는 얻어지지 않았다.As shown in Table 2, the dried product of the glutinous material complex in which the gluten and the unpleasant micro-material were dispersed in water was obviously less unpleasant than when the gluten and the unpleasant micro-material were mixed in the powder. In addition, when powdered soy protein was used as a protein, the discomfort reduction effect was not obtained.
○각종 불쾌미 물질의 검토○ Review of various unpleasant substances
(실시예8~9)(Examples 8 to 9)
실시예3에 있어서, 고순도 대두 사포닌을 대두 펩티드(후지세이유(주)제 하이뉴토D1 및 하이뉴토DC-6)로 하는 것 외에는 같은 조건으로 하여 각각 실시예8, 실시예9로 하였다. 평가는 실시예1과 동일하게 하였다.The same conditions as in Example 3 were used in Example 8 and Example 9, respectively, except that high-purity soybean saponin was used as a soybean peptide (Hi-Neuto D1 and Hi-Neuto DC-6 manufactured by Fuji Seiyu Co., Ltd.). The evaluation was made in the same manner as in Example 1.
(실시예10~11)(Examples 10 to 11)
실시예3에 있어서, 고순도 대두 사포닌을 구아바잎 엑기스 분말(피에이치에스사제 구아바잎 엑기스말-s) 1g 및 5g으로 하는 것 외에는 같은 조건으로 하여 각각 실시예10, 실시예11로 하였다. 한편, 구아바잎 엑기스는 탄닌에 유래하는 불쾌미를 가진다.The same conditions as in Example 3 were used, except that 1 g of high-purity soybean saponin and 1 g and 5 g of guava leaf extract powder (guava leaves extract-s from PACS Co., Ltd.) were used respectively as Example 10 and Example 11. On the other hand, guava leaf extract has an unpleasant taste derived from tannin.
(실시예12~13)(Examples 12 to 13)
실시예3에 있어서, 고순도 대두 사포닌을 카테킨(태양화학(주)제 산페논90S) 1g 및 5g으로 하는 것 외에는 같은 조건으로 하여 각각 실시예12, 실시예13으로 하였다.Example 12 and Example 13 were used in Example 3, except that 1 g and 5 g of high purity soybean saponin were replaced with catechin (Sanfenon 90S, manufactured by Sekisui Chemical Co., Ltd.).
(실시예14~15)(Examples 14 to 15)
실시예3에 있어서, 고순도 대두 사포닌을 필발 엑기스(환선제약(주)제 필발 엑기스 파우더MF) 1g 및 5g으로 하는 것 외에는 같은 조건으로 하여 각각 실시예14, 실시예15으로 하였다. 한편, 필발 엑기스는 피페린(piperine)(알칼로이드)에 유래하며 매운 맛을 동반하는 불쾌미를 가진다.Example 14 and Example 15 were used in Example 3, except that 1 g of high purity soybean saponin and 5 g of a pale yellow extract (excretion powder MF of Pigon Pharmaceutical Co., Ltd.) were used. On the other hand, Lilium extract is derived from piperine (alkaloid) and has an unpleasant taste accompanied by spicy taste.
(실시예16)(Example 16)
실시예3에 있어서, 고순도 대두 사포닌을 그린 허브 분말(대양향료(주)제 그린허브 파우더) 1g으로 하는 것 외에는 같은 조건으로 하였다. 한편, 그린 허브는 풋내나는 특유한 불쾌미를 가진다.
In the same manner as in Example 3 except that 1 g of a high-purity soybean saponin was used as a green herb powder (Green Herb Powder made by Ocean Perfume Co., Ltd.). On the other hand, the green herb has a peculiar unpleasant beauty.
(g)Addition amount
(g)
플래시 드라이 글루텐 10g 사용, 가수량(加水量) 160g
Use of flash dry gluten 10g, amount of water (amount of water) 160g
이상에서, 펩티드, 사포닌, 카테킨, 탄닌 등을 포함하는 여러가지 불쾌미 물질에 대해서 이들을 글루텐과 함께 수중에서 분산시킨 글루텐 소재 복합체는, 처리에 의해 불쾌미가 감소되는 것을 확인할 수 있었다.As described above, it has been confirmed that the glutinous material complexes in which glutinous and glutinous materials are dispersed in various kinds of unpleasant substances including peptides, saponins, catechins, and tannins are reduced in unpleasantness by the treatment.
○단백질종의 검토○ Review of Protein Species
(실시예17)(Example 17)
컵에 녹즙 분말((주)삼공당한방 녹즙 100%) 3g, A-글루G를 1g, 수용성 대두 다당류(후지세이유(주)제 소야파이브-S)를 0.01g 가하고, 물 100g을 넣어 약 숟가락으로 1분간 교반 혼합하여 녹즙액을 얻었다. 표1의 기준에 따라 관능평가를 하였다. 한편, 녹즙 분말은 풋내나는 특유한 불쾌미를 가진다.Add 0.01 g of water-soluble soy polysaccharide (Soya Five-S made by Fuji Seiyu Co., Ltd.), add 3 g of green juice powder (100% The mixture was stirred with a spoon for 1 minute to obtain green juice. Sensory evaluation was carried out according to the criteria shown in Table 1. On the other hand, the green juice powder has a peculiar unpleasant feeling.
(실시예18)(Example 18)
실시예17에 있어서, A-글루G를 3g으로 하는 것 외에는 같은 조건으로 하였다.The same conditions as in Example 17 were used except that 3 g of A-Glue G was used.
(비교예2)(Comparative Example 2)
컵에 녹즙 분말(동(同)) 3g, 물 100g을 넣어 약 숟가락으로 1분간 교반 혼합하여 녹즙액을 얻었다.3 g of green juice powder (copper) and 100 g of water were put in a cup, and the mixture was stirred for about 1 minute with a spoon to obtain a green juice.
(비교예3)(Comparative Example 3)
컵에 녹즙 분말(동(同)) 3g, 우유 100g을 넣어 약 숟가락으로 1분간 교반 혼합하여 녹즙액을 얻었다.3 g of green juice powder (copper) and 100 g of milk were put in a cup, and the mixture was stirred with a spoon for about 1 minute to obtain a green juice.
(비교예4)(Comparative Example 4)
컵에 녹즙 분말(동(同)) 3g, 분말상 분리 대두 단백(후지세이유(주) 후지프로-E)을 3g 가하고, 물 100g을 넣어 약 숟가락으로 1분간 교반 혼합하여 녹즙액을 얻었다.
3 g of green juice powder (copper) and 3 g of powdery separated soybean protein (Fujisuiyu Co., Ltd. Fuji Pro-E) were added to the cup, and 100 g of water was added thereto and mixed with stirring for about 1 minute with a spoon to obtain a green juice.
(g)Addition amount
(g)
(g)Quantity of water
(g)
evaluation
녹즙 분말 3g 사용Using green juice powder 3g
**수용성 대두 다당류 0.01g 사용
** Use 0.01 g of water-soluble soy polysaccharide
이상에 의하여 여러가지의 단백질 중에서도 글루텐 단백질만 본 발명의 효과가 얻어지는 것을 확인할 수 있었다.
Thus, it was confirmed that among the various proteins, only the gluten protein can obtain the effect of the present invention.
홍차에의 응용Application to tea
(실시예19)(Example 19)
활성 글루텐(글리코영양식품(주)제 바이탈글루텐 : 조단백질 함량 74중량%(as-is)) 10g에 수용성 대두 다당류(후지세이유(주)제 소야파이브-S)를 0.1g(에 대해 글루텐 1.4중량%) 가해 혼합하여, 글루텐 혼합물로 하였다. 비이커에 160g의 물을 넣고 마그네틱 스터러로 교반한 것에 혼합한 글루텐 혼합물을 넣고 1분간 교반 혼합하여, 글루텐 분산액을 만들었다. 또한 고순도 대두 사포닌(후지세이유(주) 소이헬스SA)을 5g 가하고 1분간 혼합하여 분산물을 조제해 글루텐 소재 복합체로 하였다. 얻어진 글루텐 소재 복합체 분산액을 홍차 50g에 3.5g 적하해서(홍차 중의 소이헬스SA의 함량 약 100mg) 홍차용액을 만들었다. 표1의 기준에 따라 관능평가를 하였다.To 10 g of activated gluten (vital gluten: 74% by weight as crude protein content, manufactured by Glyco Nutrition Food Co., Ltd.) was added 0.1 g of water-soluble soy polysaccharide (Soya Five-S made by Fuji Seiyu Co., Ltd.) Weight%) were mixed and mixed to prepare a gluten mixture. 160 g of water was placed in a beaker, and the mixture was stirred with a magnetic stirrer. The mixture was mixed with stirring for 1 minute to prepare a gluten dispersion. Further, 5 g of high purity soybean saponin (Soil Health SA, Fuji Seiyu Co., Ltd.) was added and mixed for 1 minute to prepare a dispersion to obtain a gluten material composite. 3.5 g of the resulting glutinic material composite dispersion was added dropwise to 50 g of black tea (about 100 mg of Soi Health SA in black tea) to prepare a black tea solution. Sensory evaluation was carried out according to the criteria shown in Table 1.
(비교예5)(Comparative Example 5)
실시예19와 같은 홍차 50g에 고순도 대두 사포닌 2.9% 용액을 3.5g 적하해서(홍차 중의 소이헬스SA 함량 약 100mg) 홍차용액을 만들었다.
3.5 g of a 2.9% solution of high purity soybean saponin was added dropwise to 50 g of the black tea as in Example 19 (about 100 mg of Soithealth SA content in black tea) to prepare a black tea solution.
(g)Addition amount
(g)
(g)Quantity of water
(g)
evaluation
고순도 대두 사포닌 5g 사용Using high purity soybean saponin 5g
**수용성 대두 다당류 0.1g 사용
** Use 0.1 g of water-soluble soy polysaccharide
홍차에 사포닌류를 가한 것만에서는(비교예5) 떫은 맛이 잔존했지만, 사포닌류와 함께 분산된 글루텐 소재 복합체를 가하면 떫은 맛은 크게 개선되었다.Only when saponins were added to black tea (Comparative Example 5), a slight taste remained, but when the gluten mixture was dispersed with saponins, the taste was greatly improved.
○타블렛에의 응용○ Application to tablet
(실시예20)(Example 20)
실시예2에서 조제한 글루텐 소재 복합체 분말품 9g을 말티톨(maltitol)(임원상사(주)제 분말 마빗트50M), 유당 과립(乳糖 顆粒)(후로인트산업(주)제) 44g, 수크로오스지방산에스테르(제일공업제약(주)제 DK에스테르F-20W) 3g과 함께 혼합하고, 타정기(打錠機)로 타블렛을 만들었다. 표1의 기준에 따라 관능평가를 하였다.9 g of the glutinous material composite powder prepared in Example 2 was mixed with 44 g of maltitol (Powder Mabbit 50M manufactured by Imagine Chemical Co., Ltd.), lactose granule (lactose granule) (manufactured by Furoind Industries Ltd.), sucrose fatty acid ester And 3 g of DK Ester F-20W manufactured by Cheil Industries, Ltd.), and tablet was made with a tableting machine. Sensory evaluation was carried out according to the criteria shown in Table 1.
(비교예6)(Comparative Example 6)
수분산시키지 않고 같은 배합으로 분체 혼합한 분말품을 컨트롤로 하고, 실시예2와 같은 배합을 수분산시키지 않고 같은 배합으로 분체 혼합한 분말 혼합품 9g을 사용하여 실시예20과 마찬가지로 타블렛을 만들어 평가했다.
A tablet was prepared and evaluated in the same manner as in Example 20 by using 9 g of a powder mixture obtained by mixing powders in the same blend without water dispersion as a control and powder mixing the same blend as in Example 2 without water dispersion did.
글루텐 및 고순도 대두 사포닌에 당류와 유화제(乳化劑)를 단순하게 혼합한 비교예6에 비하여, 글루텐과 사포닌을 수중에서 분산시킨 글루텐 소재 복합체인 실시예20은, 불쾌미가 크게 감소했다.
Compared with Comparative Example 6 in which saccharides and high purity soybean saponin were simply mixed with saccharides and emulsifiers, Example 20, which is a gluten material complex in which gluten and saponin were dispersed in water, showed a significant reduction in unpleasant taste.
○함수 에탄올에 의한 검토○ Review by Functional Ethanol
(실시예21)(Example 21)
프리즈 드라이 활성 글루텐(북국푸드(주)제 바이탈 글루텐) 10g에 70용량% 에탄올을 70g 가하고 비이커 내에서 마그네틱 스터러로 1분간 혼합해 분산액을 만들었다. 또한 고순도 대두 사포닌(후지세이유(주) 소이헬스SA)을 5g 가하여 1분간 혼합하고 분산시켰다. 조제한 분산액을 건조시켜 분말품을 얻어서 실시예21로 하였다. 평가 방법은 실시예1~7과 마찬가지로 표1의 기준에 따라 관능평가를 하였다.
70 g of 70% by volume ethanol was added to 10 g of freeze-dried active gluten (Vital Gluten manufactured by Northern Food Co., Ltd.), and the mixture was mixed in a beaker with a magnetic stirrer for 1 minute to prepare a dispersion. Further, 5 g of high purity soybean saponin (manufactured by Fuji Seiyu Co., Ltd.) was added and mixed for 1 minute and dispersed. The thus-prepared dispersion was dried to obtain a powdery product, to give Example 21. The evaluation method was the same as in Examples 1 to 7, and the sensory evaluation was carried out according to the criteria shown in Table 1.
(실시예22)(Example 22)
○당류 수용액에 의한 검토○ Examination by sugar water solution
실시예21에 있어서, 70용량% 에탄올을 70중량% 글리세린 용액으로 하는 것 외에는 같은 조건으로 하여 혼합액을 얻었다. 얻어진 분산액을 홍차 50g에 1.8g 적하해서(홍차 중의 소이헬스SA의 함량 약 100mg) 홍차용액을 만들었다.A mixed solution was obtained in the same manner as in Example 21 except that 70% by volume of ethanol was replaced by 70% by weight of glycerin solution. 1.8 g of the obtained dispersion was added dropwise to 50 g of black tea (about 100 mg of Soi Health SA in black tea) to prepare a black tea solution.
(비교예7)(Comparative Example 7)
실시예21과 마찬가지로 하고 글루텐을 첨가하지 않고 분산액을 얻었다. 얻어진 분산액을 홍차 50g에 1.5g 적하해서(홍차 중의 소이헬스SA의 함량 약 100mg) 홍차용액을 만들었다.The procedure of Example 21 was repeated to obtain a dispersion without adding gluten. The resulting dispersion was dropped into 50 g of black tea (about 100 mg of Soi Health SA in black tea) to make a black tea solution.
(실시예23)(Example 23)
실시예21에 있어서, 70용량% 에탄올을 65중량% 수크로오스 용액으로 하는 것 외에는 같은 조건으로 하여 혼합액을 얻었다. 얻어진 분산액을 홍차 50g에 1.8g 적하해서(홍차 중의 소이헬스SA의 함량 약 100mg) 홍차용액을 만들었다.A mixed solution was obtained in the same manner as in Example 21 except that 70% by volume ethanol was used as a 65% sucrose solution. 1.8 g of the obtained dispersion was added dropwise to 50 g of black tea (about 100 mg of Soi Health SA in black tea) to prepare a black tea solution.
(비교예8)(Comparative Example 8)
실시예23과 마찬가지로 하고 글루텐을 첨가하지 않고 분산액을 얻었다. 얻어진 분산액을 홍차 50g에 1.5g 적하해서(홍차 중의 소이헬스SA의 함량 약 100mg) 홍차용액을 만들었다.
The procedure of Example 23 was repeated to obtain a dispersion without adding gluten. The resulting dispersion was dropped into 50 g of black tea (about 100 mg of Soi Health SA in black tea) to make a black tea solution.
표7, 8에 나타나 있는 바와 같이, 글루텐과 불쾌미 물질을 액 중에서 분산시킨 분산액, 또는 그것을 건조시킨 건조물은, 글루텐과 불쾌미 물질을 분체로 혼합했을 때나 단독의 분산액보다도 분명하게 불쾌미가 감소하고 있었다.As shown in Tables 7 and 8, the dispersion liquid in which the gluten and the unpleasant micro-material are dispersed in the liquid, or the dried material in which the glutin and the unpleasant micro-substance are dispersed in the liquid, there was.
Claims (9)
특징으로 하는 불쾌미 물질의 불쾌미의 감소 방법.
By a non-offensive material (不快味物質) containing, galacturonic acid go against the water-soluble polysaccharide (galacturonic acid含有水溶性多糖類) to blend in the liquid a gluten material dispersed in an aqueous (水系)
A method for reducing unpleasantness of an unpleasant substance.
글루텐 소재중의 글루텐 단백질 고형분에 대하여, 갈락투론산 함유 수용성 다당류를 0.03~20중량% 사용하는 것을
특징으로 하는 불쾌미 물질의 불쾌미의 감소 방법.
The method according to claim 1,
0.03 to 20 wt% of galacturonic acid-containing water-soluble polysaccharide is used for the gluten protein solid in the gluten material
A method for reducing unpleasantness of an unpleasant substance.
불쾌미 물질 1중량부에 대하여, 글루텐 소재를 글루텐 단백질 고형분으로서 0.2~100중량부 사용하는 것을
특징으로 하는 불쾌미 물질의 불쾌미의 감소 방법.
The method according to claim 1,
It is preferable that 0.2 to 100 parts by weight of a gluten material is used as the gluten protein solid content relative to 1 part by weight of the unpleasant microcrystalline material
A method for reducing unpleasantness of an unpleasant substance.
불쾌미 물질이, 폴리페놀류(polyphenol類), 플라보노이드류(flavonoid類), 사포닌류(saponin類), 알칼로이드류(alkaloid類), 쓴 맛 아미노산 또는 펩티드(peptide)로부터 선택되는 1종 이상인 것을
특징으로 하는 불쾌미 물질의 불쾌미의 감소 방법.
The method according to claim 1,
The unpleasant substance is at least one selected from polyphenols, flavonoids, saponins, alkaloids, bitter amino acids and peptides.
A method for reducing unpleasantness of an unpleasant substance.
Wherein a glutinous material dispersion dispersed in water by a galacturonic acid-containing water-soluble polysaccharide and an unpleasant micro material are mixed in a liquid .
A gluten material complex prepared by mixing a dispersion of a gluten material dispersed in water with a galacturonic acid-containing water-soluble polysaccharide and an unpleasant micro material in a liquid .
A food or drink comprising the gluten material complex of claim 6.
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