KR101773628B1 - 2,3,3,3-테트라플루오로프로펜을 제조하기 위한 촉매 및 방법 - Google Patents

2,3,3,3-테트라플루오로프로펜을 제조하기 위한 촉매 및 방법 Download PDF

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KR101773628B1
KR101773628B1 KR1020127000051A KR20127000051A KR101773628B1 KR 101773628 B1 KR101773628 B1 KR 101773628B1 KR 1020127000051 A KR1020127000051 A KR 1020127000051A KR 20127000051 A KR20127000051 A KR 20127000051A KR 101773628 B1 KR101773628 B1 KR 101773628B1
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catalyst
dehydrofluorination
hfc
tetrafluoropropene
alkali metal
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KR20120027452A (ko
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마리오 조셉 나파
앤드류 잭슨
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이 아이 듀폰 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/10—Alkenes with five carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/16—Alkadienes with four carbon atoms
    • C07C11/167—1, 3-Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/22—Aliphatic unsaturated hydrocarbons containing carbon-to-carbon triple bonds
    • C07C11/24—Acetylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/28—Aliphatic unsaturated hydrocarbons containing carbon-to-carbon double bonds and carbon-to-carbon triple bonds
    • C07C11/30—Butenyne
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/04—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/08—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020127000051A 2009-06-03 2010-06-03 2,3,3,3-테트라플루오로프로펜을 제조하기 위한 촉매 및 방법 Active KR101773628B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US18367409P 2009-06-03 2009-06-03
US61/183,674 2009-06-03
US25634109P 2009-10-30 2009-10-30
US61/256,341 2009-10-30
PCT/US2010/037179 WO2010141664A1 (en) 2009-06-03 2010-06-03 Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene

Publications (2)

Publication Number Publication Date
KR20120027452A KR20120027452A (ko) 2012-03-21
KR101773628B1 true KR101773628B1 (ko) 2017-09-12

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ID=43034102

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KR1020127000051A Active KR101773628B1 (ko) 2009-06-03 2010-06-03 2,3,3,3-테트라플루오로프로펜을 제조하기 위한 촉매 및 방법

Country Status (14)

Country Link
US (2) US7985884B2 (https=)
EP (1) EP2438033B1 (https=)
JP (1) JP5620478B2 (https=)
KR (1) KR101773628B1 (https=)
CN (1) CN102448921B (https=)
BR (1) BRPI1010128A2 (https=)
CA (1) CA2761722A1 (https=)
ES (1) ES2643322T3 (https=)
HU (1) HUE034982T2 (https=)
MX (1) MX2011012774A (https=)
PL (1) PL2438033T3 (https=)
RU (1) RU2011154374A (https=)
TW (1) TW201114727A (https=)
WO (1) WO2010141664A1 (https=)

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EP2099082B1 (en) * 2008-03-05 2014-05-07 NGK Spark Plug Co., Ltd. Piezoceramic material, piezoelectric element and non-resonance knock sensor
US9724684B2 (en) 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US8884082B2 (en) 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
US8884083B2 (en) 2011-02-21 2014-11-11 E. I. Du Pont De Nemours And Company Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
GB201207666D0 (en) 2012-05-02 2012-06-13 Mexichem Amanco Holding Sa Process
CN107032947A (zh) 2012-06-06 2017-08-11 科慕埃弗西有限公司 用于降低氟代烯烃中RfCCX杂质的方法
WO2014152325A1 (en) 2013-03-15 2014-09-25 E.I. Du Pont De Nemours And Company Process for the reduction of alkyne impurities in fluoroolefins
US9187386B2 (en) * 2013-05-23 2015-11-17 The Chemours Company Fc, Llc Catalytic process of making 1,3,3,3-tetrafluoropropene
GB2519572B (en) 2013-10-25 2015-12-30 Mexichem Amanco Holding Sa Process for isomerising (hydro)(halo)fluoroalkenes
WO2016025288A1 (en) 2014-08-14 2016-02-18 The Chemours Company Fc, Llc Process for the production of e-1,3,3,3-tetrafluoropropene (hfc-1234ze) by dehydrofluorinatiokl
JP6328589B2 (ja) * 2015-05-29 2018-05-23 ダイキン工業株式会社 含フッ素オレフィンの製造方法
MX2018001489A (es) * 2015-08-07 2018-04-24 Chemours Co Fc Llc Isomerizacion catalitica de z-1,1,14,4,4,-hexafluoro-2-buteno a e-1,1,1,4,4,4-hexafluoro-2-buteno.
JP6624126B2 (ja) * 2017-03-13 2019-12-25 ダイキン工業株式会社 含フッ素オレフィンの製造方法
US11209196B2 (en) 2018-10-26 2021-12-28 The Chemours Company Fc, Llc HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions
BR112021022059A2 (pt) 2018-10-26 2021-12-28 Chemours Co Fc Llc Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante
EP3870562B1 (en) 2018-10-26 2026-01-28 The Chemours Company FC, LLC Hfo-1234ze and hfo-1234yf compositions and processes for producing and using the compositions
CN121002142A (zh) 2023-04-06 2025-11-21 科慕埃弗西有限公司 包含z-1,3,3,3-四氟丙烯的制冷剂组合物、其制备方法及其用途
CN116143583B (zh) * 2023-04-19 2023-07-07 山东澳帆新材料有限公司 一种2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯的联产制备方法
WO2025096370A2 (en) 2023-10-30 2025-05-08 The Chemours Company Fc, Llc Compositions comprising 1,3,3,3-tetrafluoropropene, methods of making same, and uses thereof
TW202535813A (zh) 2023-10-30 2025-09-16 美商科慕Ｆｃ有限責任公司 包含１，３，３，３－四氟丙烯的組成物、其製備方法、及其用途
WO2025160054A2 (en) 2024-01-22 2025-07-31 The Chemours Company Fc, Llc Synthesis of 1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene
CN121181396B (zh) * 2025-11-25 2026-02-03 山东联创聚合物有限公司 含氟烯烃的制备方法及其所使用的装置

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WO2009003157A1 (en) * 2007-06-27 2008-12-31 Arkema Inc. Two step process for the manufacture of hydrofluoroolefins

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US5036036A (en) 1989-06-13 1991-07-30 E. I. Du Pont De Nemours And Company Chromium oxide catalyst composition
JP3981409B2 (ja) * 1995-06-08 2007-09-26 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー 酸化クロムの処理及びフッ化ビニルの触媒的製造
JP4378779B2 (ja) 1998-07-17 2009-12-09 ダイキン工業株式会社 含フッ素エタンの製造方法
US7897823B2 (en) 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US7423188B2 (en) 2005-11-01 2008-09-09 E. I. Du Pont De Nemours And Company Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7476771B2 (en) 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
JP5143011B2 (ja) * 2005-11-03 2013-02-13 ハネウェル・インターナショナル・インコーポレーテッド フッ素化有機化合物の製造方法
US7560602B2 (en) * 2005-11-03 2009-07-14 Honeywell International Inc. Process for manufacture of fluorinated olefins
JP5393454B2 (ja) 2006-06-27 2014-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー １，２，３，３，３−ペンタフルオロプロペンの製造方法
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US7982073B2 (en) * 2006-07-13 2011-07-19 E. I. Du Pont De Nemours And Company Catalytic production processes for making tetrafluoropropenes and pentafluoropropenes
KR102884920B1 (ko) 2008-05-07 2025-11-12 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물

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Also Published As

Publication number Publication date
PL2438033T3 (pl) 2017-11-30
US8227649B2 (en) 2012-07-24
US20100312025A1 (en) 2010-12-09
CN102448921B (zh) 2014-04-23
KR20120027452A (ko) 2012-03-21
ES2643322T3 (es) 2017-11-22
US20110282112A1 (en) 2011-11-17
CA2761722A1 (en) 2010-12-09
JP5620478B2 (ja) 2014-11-05
JP2012528878A (ja) 2012-11-15
CN102448921A (zh) 2012-05-09
TW201114727A (en) 2011-05-01
BRPI1010128A2 (pt) 2016-03-15
RU2011154374A (ru) 2013-07-20
HUE034982T2 (en) 2018-05-02
US7985884B2 (en) 2011-07-26
EP2438033A1 (en) 2012-04-11
MX2011012774A (es) 2012-01-20
WO2010141664A1 (en) 2010-12-09
EP2438033B1 (en) 2017-07-26

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