KR101682254B1 - 가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법 - Google Patents

가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법 Download PDF

Info

Publication number
KR101682254B1
KR101682254B1 KR1020117005699A KR20117005699A KR101682254B1 KR 101682254 B1 KR101682254 B1 KR 101682254B1 KR 1020117005699 A KR1020117005699 A KR 1020117005699A KR 20117005699 A KR20117005699 A KR 20117005699A KR 101682254 B1 KR101682254 B1 KR 101682254B1
Authority
KR
South Korea
Prior art keywords
particles
silica
solution
pore
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020117005699A
Other languages
English (en)
Korean (ko)
Other versions
KR20110073443A (ko
Inventor
브라이언 티. 홀란드
사스차 웰츠
Original Assignee
날코 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 날코 컴퍼니 filed Critical 날코 컴퍼니
Publication of KR20110073443A publication Critical patent/KR20110073443A/ko
Application granted granted Critical
Publication of KR101682254B1 publication Critical patent/KR101682254B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/126—Preparation of silica of undetermined type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C01B33/142—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Silicon Compounds (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
KR1020117005699A 2008-09-12 2009-09-11 가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법 Active KR101682254B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/209,790 2008-09-12
US12/209,790 US8790608B2 (en) 2008-09-12 2008-09-12 Siliceous materials having tunable porosity and surface morphology and methods of synthesizing same
PCT/US2009/056659 WO2010030878A2 (en) 2008-09-12 2009-09-11 Siliceous materials having tunable porosity and surface morphology and methods of synthesizing same

Publications (2)

Publication Number Publication Date
KR20110073443A KR20110073443A (ko) 2011-06-29
KR101682254B1 true KR101682254B1 (ko) 2016-12-02

Family

ID=41572620

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020117005699A Active KR101682254B1 (ko) 2008-09-12 2009-09-11 가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법

Country Status (8)

Country Link
US (1) US8790608B2 (https=)
EP (1) EP2346782A2 (https=)
JP (1) JP5615281B2 (https=)
KR (1) KR101682254B1 (https=)
CN (1) CN102186772B (https=)
MY (1) MY155398A (https=)
TW (1) TWI527758B (https=)
WO (1) WO2010030878A2 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10227238B2 (en) * 2006-04-04 2019-03-12 Ecolab Usa Inc. Production and use of polysilicate particulate materials
US8764974B2 (en) 2010-04-16 2014-07-01 Nalco Company Processing aids to improve the bitumen recovery and froth quality in oil sands extraction processes
US10087081B2 (en) 2013-03-08 2018-10-02 Ecolab Usa Inc. Process for producing high solids colloidal silica
US10926241B2 (en) 2014-06-12 2021-02-23 Arizona Board Of Regents On Behalf Of Arizona State University Carbon dioxide adsorbents
EP3325590B1 (en) 2015-07-18 2020-09-30 Ecolab USA Inc. Chemical additives to improve oil separation in stillage process operations
CN105251446B (zh) * 2015-11-11 2018-02-02 中国电建集团中南勘测设计研究院有限公司 一种地下水复合重金属污染修复材料
CN105329906B (zh) * 2015-11-30 2017-06-23 中海油天津化工研究设计院有限公司 一种丙烯腈催化剂用硅溶胶的制备方法
WO2018136695A1 (en) 2017-01-20 2018-07-26 Seo Dong Kyun Aluminosilicate nanorods
CN106823850B (zh) * 2017-03-08 2019-05-24 常州大学 一种桥架有机硅膜孔径的调控方法
JP7034435B2 (ja) * 2017-11-29 2022-03-14 東洋製罐グループホールディングス株式会社 複合体及びその製造方法。
KR102252313B1 (ko) * 2019-01-23 2021-05-14 청주대학교 산학협력단 중공의 다공성 실리카 나노구 및 그 제조방법
US12006439B2 (en) * 2019-03-27 2024-06-11 Canon Kabushiki Kaisha Optical member, optical device and coating liquid
CN120137436B (zh) * 2025-04-22 2025-11-11 中国科学院宁波材料技术与工程研究所 一种硅钛复合防雾涂层及其制备方法与应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680013B1 (en) 1999-04-15 2004-01-20 Regents Of The University Of Minnesota Synthesis of macroporous structures

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2892797A (en) * 1956-02-17 1959-06-30 Du Pont Process for modifying the properties of a silica sol and product thereof
US2913419A (en) * 1956-04-18 1959-11-17 Du Pont Chemical process and composition
US2974108A (en) * 1957-01-14 1961-03-07 Du Pont Aluminosilicate aquasols and their preparation
US3442795A (en) * 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
US3745126A (en) * 1971-04-22 1973-07-10 Du Pont Stable positively charged alumina coated silica sols
US3864142A (en) * 1971-04-26 1975-02-04 Nalco Chemical Co Metal oxide sols
US4287086A (en) * 1975-05-02 1981-09-01 Nl Industries, Inc. Viscous organic systems containing an organophilic clay gellant without an organic dispersant therefor
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4451388A (en) * 1981-11-02 1984-05-29 Nalco Chemical Company Preparation of aluminum oxide coated silica sols using ultrafiltration
FR2567505B1 (fr) * 1984-07-11 1986-11-21 Rhone Poulenc Chim Base Silice a prise d'huile elevee et a structure primaire controlee et procede pour son obtention
JPS61158810A (ja) * 1984-12-28 1986-07-18 Shokubai Kasei Kogyo Kk 高純度シリカゾルの製造法
US5221497A (en) * 1988-03-16 1993-06-22 Nissan Chemical Industries, Ltd. Elongated-shaped silica sol and method for preparing the same
ATE207036T1 (de) * 1992-12-16 2001-11-15 Chevron Usa Inc Herstellung von aluminosilikatzeolithen
JP3517913B2 (ja) * 1993-10-15 2004-04-12 日産化学工業株式会社 細長い形状のシリカゾルの製造法
JP2908253B2 (ja) * 1994-09-26 1999-06-21 日本化学工業株式会社 水和珪酸とその製造方法
DE19648798C2 (de) * 1996-11-26 1998-11-19 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
US5968473A (en) * 1998-12-18 1999-10-19 Uop Llc Stannosilicate molecular sieves
US6191323B1 (en) * 2000-04-25 2001-02-20 Uop Llc Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta
JP2002173314A (ja) * 2000-11-30 2002-06-21 Watanabe Shoko:Kk 高純度コロイダルシリカ及び高純度合成石英粉の製造方法
JP4976613B2 (ja) * 2000-12-08 2012-07-18 水澤化学工業株式会社 シリカゾルの製造方法
JP2003253154A (ja) * 2001-12-25 2003-09-10 Asahi Kasei Corp 無機多孔性微粒子
US6916514B2 (en) * 2003-07-18 2005-07-12 Eastman Kodak Company Cationic shelled particle
JP4041892B2 (ja) * 2003-10-03 2008-02-06 独立行政法人物質・材料研究機構 多孔質ガラス微小粒子およびその製造方法
US20070034116A1 (en) * 2005-08-10 2007-02-15 Mac Donald Dennis L Silica sols with controlled minimum particle size and preparation thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680013B1 (en) 1999-04-15 2004-01-20 Regents Of The University Of Minnesota Synthesis of macroporous structures

Also Published As

Publication number Publication date
US20100068519A1 (en) 2010-03-18
TWI527758B (zh) 2016-04-01
WO2010030878A2 (en) 2010-03-18
US8790608B2 (en) 2014-07-29
JP2012501958A (ja) 2012-01-26
EP2346782A2 (en) 2011-07-27
CN102186772A (zh) 2011-09-14
JP5615281B2 (ja) 2014-10-29
CN102186772B (zh) 2015-07-22
TW201010942A (en) 2010-03-16
KR20110073443A (ko) 2011-06-29
MY155398A (en) 2015-10-15
WO2010030878A3 (en) 2010-05-06

Similar Documents

Publication Publication Date Title
KR101682254B1 (ko) 가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법
Sierra et al. Synthesis of mesoporous silica with tunable pore size from sodium silicate solutions and a polyethylene oxide surfactant
Huang et al. Lanthanum-doped ordered mesoporous hollow silica spheres as novel adsorbents for efficient phosphate removal
Cui et al. Nonionic triblock copolymer synthesis of SBA-15 above the isoelectric point of silica (pH= 2–5)
JP5389660B2 (ja) 高金属性ケイ質組成物及び同一物を生成する方法
Misran et al. Nonsurfactant route of fatty alcohols decomposition for templating of mesoporous silica
Meléndez-Ortiz et al. Synthesis of spherical SBA-15 mesoporous silica. Influence of reaction conditions on the structural order and stability
Qiao et al. Control of ordered structure and morphology of large-pore periodic mesoporous organosilicas by inorganic salt
US20110257006A1 (en) Method for preparing a structured porous material comprising nanoparticles of metal 0 imbedded in the walls thereof
WO2012110995A1 (en) Silica core-shell microparticles
US9764315B2 (en) Method for preparation of a group 4 metal silicate and use thereof
Mazinani et al. Synthesis and photocatalytic performance of hollow sphere particles of SiO2-TiO2 composite of mesocellular foam walls
Hanrahan et al. Synthesis and swelling of large pore diameter mesoporous silica spheres
Lee et al. Preparation of NaCl-incorporated plugged mesoporous silica using a cost-effective precursor and applications to the hydrodechlorination of chlorinated hydrocarbons
WO2006060623A2 (en) Mesoporous inorganic oxide spheres and method of making same
Newalkar et al. Synthesis and characterization of PSU-1, a novel cage-like mesoporous silica
Aranda et al. Total oxidation of naphthalene using mesoporous CeO2 catalysts synthesized by nanocasting from two dimensional SBA-15 and three dimensional KIT-6 and MCM-48 silica templates
Isobe et al. Micropore to macropore structure-designed silicas with regulated condensation of silicic acid nanoparticles
Nowak Textural and structural properties of niobium-containing micro-, meso-and macroporous molecular sieves
Niu et al. Chelating template-induced encapsulation of NiO cluster in mesoporous silica via anionic surfactant-templated route
JP5167482B2 (ja) 複合多孔体及びその製造方法
Lin et al. New insights into the mesophase transformation of ethane-bridged PMOs by the influence of different counterions under basic conditions
Martynyuk et al. Nanostructures constituted by unusually small silica nanoparticles modified with metal oxides as support for ultra-small gold nanoparticles
Carta et al. Iron–cobalt nanocrystalline alloy supported on a cubic mesostructured silica matrix: FeCo/SBA-16 porous nanocomposites
Rose Photocatalytically Active Aerogels–Development and Characterization of (Semi-) Crystalline Titania

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20110311

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20140801

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20151012

Patent event code: PE09021S01D

E90F Notification of reason for final refusal
PE0902 Notice of grounds for rejection

Comment text: Final Notice of Reason for Refusal

Patent event date: 20160414

Patent event code: PE09021S02D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20160901

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20161128

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20161128

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20201028

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20211027

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 20221017

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20231017

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 20241016

Start annual number: 9

End annual number: 9