KR101376082B1 - 산화 반응기 및 산화 방법 - Google Patents

산화 반응기 및 산화 방법 Download PDF

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Publication number
KR101376082B1
KR101376082B1 KR1020087016552A KR20087016552A KR101376082B1 KR 101376082 B1 KR101376082 B1 KR 101376082B1 KR 1020087016552 A KR1020087016552 A KR 1020087016552A KR 20087016552 A KR20087016552 A KR 20087016552A KR 101376082 B1 KR101376082 B1 KR 101376082B1
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membrane
reaction chamber
oxygen
gas
elements
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Expired - Fee Related
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Korean (ko)
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KR20080077667A (ko
Inventor
슈테펜 베르트
베른트 랑앙케
랄프 클라인슈미트
비외른 호팅
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티센크루프 우데 게엠베하
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/0271—Perovskites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/065—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0251—Physical processing only by making use of membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0043—Impurity removed
    • C01B2210/0046—Nitrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
KR1020087016552A 2005-12-14 2006-12-05 산화 반응기 및 산화 방법 Expired - Fee Related KR101376082B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005060171A DE102005060171A1 (de) 2005-12-14 2005-12-14 Oxidationsreaktor und Oxidationsverfahren
DE102005060171.5 2005-12-14
PCT/EP2006/011629 WO2007068369A1 (de) 2005-12-14 2006-12-05 Oxidationsreaktor und oxidationsverfahren

Publications (2)

Publication Number Publication Date
KR20080077667A KR20080077667A (ko) 2008-08-25
KR101376082B1 true KR101376082B1 (ko) 2014-03-19

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Application Number Title Priority Date Filing Date
KR1020087016552A Expired - Fee Related KR101376082B1 (ko) 2005-12-14 2006-12-05 산화 반응기 및 산화 방법

Country Status (13)

Country Link
US (1) US20090018373A1 (https=)
EP (1) EP1968738B1 (https=)
JP (1) JP5366556B2 (https=)
KR (1) KR101376082B1 (https=)
CN (1) CN101394924B (https=)
CA (1) CA2634263A1 (https=)
DE (1) DE102005060171A1 (https=)
DK (1) DK1968738T3 (https=)
EA (1) EA200870037A1 (https=)
EG (1) EG26485A (https=)
ES (1) ES2397966T3 (https=)
WO (1) WO2007068369A1 (https=)
ZA (1) ZA200805086B (https=)

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US7666449B2 (en) * 2001-06-20 2010-02-23 Metaproteomics, Llc Anti-inflammatory pharmaceutical compositions for reducing inflammation and the treatment or prevention of gastric toxicity
WO2009071463A2 (de) * 2007-12-03 2009-06-11 Basf Se Oxidative methankopplung via membranreaktor
DE102008013292A1 (de) 2008-03-07 2009-09-10 Borsig Process Heat Exchanger Gmbh Verfahren zum Regenerieren von Sauerstoff-leitenden keramischen Membranen sowie Reaktor
DE102009039920A1 (de) 2009-09-03 2011-03-10 Karl-Heinz Tetzlaff Verfahren und Vorrichtung zur Nutzung von Sauerstoff bei der Dampfreformierung von Biomasse
DE102009060489A1 (de) 2009-12-29 2011-06-30 Uhde GmbH, 44141 Vorrichtung und Verfahren zur Regelung der Sauerstoffpermeation durch nicht-poröse Sauerstoffanionen leitende keramische Membranen und deren Verwendung
JP2012091984A (ja) * 2010-10-28 2012-05-17 Mitsubishi Heavy Ind Ltd 高温シール材料、高温シール体、及び高温シール体を含む酸素透過モジュール
NL2006245C2 (en) * 2011-02-18 2012-08-21 Stichting Energie MEMBRANE REACTOR AND PROCESS FOR THE PRODUCTION OF A GASEOUS PRODUCT WITH SUCH REACTOR.
CN103826685A (zh) 2011-04-13 2014-05-28 迈克尔·科林 输气方法及装置
CN103130748B (zh) * 2011-11-29 2015-04-29 岳阳昌德化工实业有限公司 一种环己烯氧化的方法
EP2607301A1 (de) * 2011-12-20 2013-06-26 Karl-Heinz Tetzlaff Vorrichtung und Verfahren zur Erdgasreformierung
EP2935155B1 (en) 2012-12-19 2019-02-13 Praxair Technology Inc. Method for sealing an oxygen transport membrane assembly
WO2014107707A2 (en) * 2013-01-07 2014-07-10 Praxair Technology, Inc. High emissivity and high temperature diffusion barrier coatings for an oxygen transport membrane assembly
US9296671B2 (en) 2013-04-26 2016-03-29 Praxair Technology, Inc. Method and system for producing methanol using an integrated oxygen transport membrane based reforming system
US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
US9938145B2 (en) 2013-04-26 2018-04-10 Praxair Technology, Inc. Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system
US9212113B2 (en) 2013-04-26 2015-12-15 Praxair Technology, Inc. Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
EP3055054A2 (en) 2013-10-07 2016-08-17 Praxair Technology Inc. Ceramic oxygen transport membrane array reactor and reforming method
US10822234B2 (en) 2014-04-16 2020-11-03 Praxair Technology, Inc. Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC)
WO2016057164A1 (en) 2014-10-07 2016-04-14 Praxair Technology, Inc Composite oxygen ion transport membrane
US10441922B2 (en) 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
US10118823B2 (en) 2015-12-15 2018-11-06 Praxair Technology, Inc. Method of thermally-stabilizing an oxygen transport membrane-based reforming system
US9938146B2 (en) 2015-12-28 2018-04-10 Praxair Technology, Inc. High aspect ratio catalytic reactor and catalyst inserts therefor
CN109070014A (zh) 2016-04-01 2018-12-21 普莱克斯技术有限公司 含催化剂的氧气传送膜
JP6845102B2 (ja) * 2017-06-30 2021-03-17 日本特殊陶業株式会社 改質構造体および改質装置
US11136238B2 (en) 2018-05-21 2021-10-05 Praxair Technology, Inc. OTM syngas panel with gas heated reformer

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US20030218991A1 (en) 2002-05-24 2003-11-27 Besecker Charles J. Membrane systems containing an oxygen transport membrane and catalyst

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EP0962422A1 (en) * 1998-06-03 1999-12-08 Praxair Technology, Inc. Syngas reactor with ceramic membrane
US20030218991A1 (en) 2002-05-24 2003-11-27 Besecker Charles J. Membrane systems containing an oxygen transport membrane and catalyst

Also Published As

Publication number Publication date
JP5366556B2 (ja) 2013-12-11
DE102005060171A1 (de) 2007-06-21
EP1968738A1 (de) 2008-09-17
CN101394924A (zh) 2009-03-25
US20090018373A1 (en) 2009-01-15
CA2634263A1 (en) 2007-06-21
WO2007068369A1 (de) 2007-06-21
EG26485A (en) 2013-12-10
JP2009519195A (ja) 2009-05-14
KR20080077667A (ko) 2008-08-25
DK1968738T3 (da) 2013-01-28
EP1968738B1 (de) 2012-10-31
CN101394924B (zh) 2012-07-04
ES2397966T3 (es) 2013-03-12
EA200870037A1 (ru) 2009-12-30
ZA200805086B (en) 2009-03-25

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