ES2397966T3 - Reactor de oxidación y procedimiento de oxidación - Google Patents
Reactor de oxidación y procedimiento de oxidación Download PDFInfo
- Publication number
- ES2397966T3 ES2397966T3 ES06829277T ES06829277T ES2397966T3 ES 2397966 T3 ES2397966 T3 ES 2397966T3 ES 06829277 T ES06829277 T ES 06829277T ES 06829277 T ES06829277 T ES 06829277T ES 2397966 T3 ES2397966 T3 ES 2397966T3
- Authority
- ES
- Spain
- Prior art keywords
- oxygen
- membrane
- elements
- oxidation
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/0271—Perovskites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
- B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/065—Feeding reactive fluids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0251—Physical processing only by making use of membranes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0046—Nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005060171A DE102005060171A1 (de) | 2005-12-14 | 2005-12-14 | Oxidationsreaktor und Oxidationsverfahren |
| DE102005060171 | 2005-12-14 | ||
| PCT/EP2006/011629 WO2007068369A1 (de) | 2005-12-14 | 2006-12-05 | Oxidationsreaktor und oxidationsverfahren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2397966T3 true ES2397966T3 (es) | 2013-03-12 |
Family
ID=37907494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06829277T Active ES2397966T3 (es) | 2005-12-14 | 2006-12-05 | Reactor de oxidación y procedimiento de oxidación |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20090018373A1 (https=) |
| EP (1) | EP1968738B1 (https=) |
| JP (1) | JP5366556B2 (https=) |
| KR (1) | KR101376082B1 (https=) |
| CN (1) | CN101394924B (https=) |
| CA (1) | CA2634263A1 (https=) |
| DE (1) | DE102005060171A1 (https=) |
| DK (1) | DK1968738T3 (https=) |
| EA (1) | EA200870037A1 (https=) |
| EG (1) | EG26485A (https=) |
| ES (1) | ES2397966T3 (https=) |
| WO (1) | WO2007068369A1 (https=) |
| ZA (1) | ZA200805086B (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7666449B2 (en) * | 2001-06-20 | 2010-02-23 | Metaproteomics, Llc | Anti-inflammatory pharmaceutical compositions for reducing inflammation and the treatment or prevention of gastric toxicity |
| WO2009071463A2 (de) * | 2007-12-03 | 2009-06-11 | Basf Se | Oxidative methankopplung via membranreaktor |
| DE102008013292A1 (de) | 2008-03-07 | 2009-09-10 | Borsig Process Heat Exchanger Gmbh | Verfahren zum Regenerieren von Sauerstoff-leitenden keramischen Membranen sowie Reaktor |
| DE102009039920A1 (de) | 2009-09-03 | 2011-03-10 | Karl-Heinz Tetzlaff | Verfahren und Vorrichtung zur Nutzung von Sauerstoff bei der Dampfreformierung von Biomasse |
| DE102009060489A1 (de) | 2009-12-29 | 2011-06-30 | Uhde GmbH, 44141 | Vorrichtung und Verfahren zur Regelung der Sauerstoffpermeation durch nicht-poröse Sauerstoffanionen leitende keramische Membranen und deren Verwendung |
| JP2012091984A (ja) * | 2010-10-28 | 2012-05-17 | Mitsubishi Heavy Ind Ltd | 高温シール材料、高温シール体、及び高温シール体を含む酸素透過モジュール |
| NL2006245C2 (en) * | 2011-02-18 | 2012-08-21 | Stichting Energie | MEMBRANE REACTOR AND PROCESS FOR THE PRODUCTION OF A GASEOUS PRODUCT WITH SUCH REACTOR. |
| CN103826685A (zh) | 2011-04-13 | 2014-05-28 | 迈克尔·科林 | 输气方法及装置 |
| CN103130748B (zh) * | 2011-11-29 | 2015-04-29 | 岳阳昌德化工实业有限公司 | 一种环己烯氧化的方法 |
| EP2607301A1 (de) * | 2011-12-20 | 2013-06-26 | Karl-Heinz Tetzlaff | Vorrichtung und Verfahren zur Erdgasreformierung |
| EP2935155B1 (en) | 2012-12-19 | 2019-02-13 | Praxair Technology Inc. | Method for sealing an oxygen transport membrane assembly |
| WO2014107707A2 (en) * | 2013-01-07 | 2014-07-10 | Praxair Technology, Inc. | High emissivity and high temperature diffusion barrier coatings for an oxygen transport membrane assembly |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| EP3055054A2 (en) | 2013-10-07 | 2016-08-17 | Praxair Technology Inc. | Ceramic oxygen transport membrane array reactor and reforming method |
| US10822234B2 (en) | 2014-04-16 | 2020-11-03 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC) |
| WO2016057164A1 (en) | 2014-10-07 | 2016-04-14 | Praxair Technology, Inc | Composite oxygen ion transport membrane |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| CN109070014A (zh) | 2016-04-01 | 2018-12-21 | 普莱克斯技术有限公司 | 含催化剂的氧气传送膜 |
| JP6845102B2 (ja) * | 2017-06-30 | 2021-03-17 | 日本特殊陶業株式会社 | 改質構造体および改質装置 |
| US11136238B2 (en) | 2018-05-21 | 2021-10-05 | Praxair Technology, Inc. | OTM syngas panel with gas heated reformer |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2081170C (en) * | 1992-10-22 | 2002-12-24 | Alaa-Eldin Moustafa Adris | Fluidized bed reaction system for steam/hydrocarbon gas reforming to produce hydrogen |
| AU706663B2 (en) * | 1994-09-23 | 1999-06-17 | Standard Oil Company, The | Oxygen permeable mixed conductor membranes |
| US5573737A (en) * | 1994-09-27 | 1996-11-12 | The United States Of America As Represented By The United States Department Of Energy | Functionally gradient material for membrane reactors to convert methane gas into value-added products |
| US5681373A (en) * | 1995-03-13 | 1997-10-28 | Air Products And Chemicals, Inc. | Planar solid-state membrane module |
| EP0743088A3 (en) * | 1995-05-18 | 1997-05-07 | Praxair Technology Inc | Method and device for separating gases with an electrolytic membrane and under pressure drop |
| US5820655A (en) * | 1997-04-29 | 1998-10-13 | Praxair Technology, Inc. | Solid Electrolyte ionic conductor reactor design |
| US6077323A (en) * | 1997-06-06 | 2000-06-20 | Air Products And Chemicals, Inc. | Synthesis gas production by ion transport membranes |
| US6106591A (en) * | 1997-06-23 | 2000-08-22 | Praxair Technology, Inc. | Process for reducing carbon production in solid electrolyte ionic conductor systems |
| US6200541B1 (en) * | 1997-10-28 | 2001-03-13 | Bp Amoco Corporation | Composite materials for membrane reactors |
| US5935533A (en) * | 1997-10-28 | 1999-08-10 | Bp Amoco Corporation | Membrane reactor hollow tube module with ceramic/metal interfacial zone |
| US6139810A (en) * | 1998-06-03 | 2000-10-31 | Praxair Technology, Inc. | Tube and shell reactor with oxygen selective ion transport ceramic reaction tubes |
| ES2218012T3 (es) * | 1999-03-05 | 2004-11-16 | Haldor Topsoe A/S | Procedimiento para reformado catalitico autotermico con vapor. |
| JP2001097789A (ja) * | 1999-10-01 | 2001-04-10 | Nippon Steel Corp | セラミック複合材料 |
| JP2002085946A (ja) * | 2000-09-20 | 2002-03-26 | Teikoku Oil Co Ltd | セラミックス膜式反応器およびこれを用いる低圧水素製造方法 |
| US6695983B2 (en) * | 2001-04-24 | 2004-02-24 | Praxair Technology, Inc. | Syngas production method utilizing an oxygen transport membrane |
| US20030039601A1 (en) * | 2001-08-10 | 2003-02-27 | Halvorson Thomas Gilbert | Oxygen ion transport membrane apparatus and process for use in syngas production |
| JP3914416B2 (ja) * | 2001-11-06 | 2007-05-16 | 帝国石油株式会社 | 膜式反応器 |
| JP2003346859A (ja) * | 2002-05-23 | 2003-12-05 | Nissan Motor Co Ltd | 一酸化炭素除去装置 |
| US7125528B2 (en) | 2002-05-24 | 2006-10-24 | Bp Corporation North America Inc. | Membrane systems containing an oxygen transport membrane and catalyst |
| FR2859115B1 (fr) * | 2003-08-28 | 2005-10-28 | Centre Nat Rech Scient | Membranes de conduction electronique et oxygene ionique comprenant une couche d'oxyde mixte de vanadium et de magnesium |
-
2005
- 2005-12-14 DE DE102005060171A patent/DE102005060171A1/de not_active Withdrawn
-
2006
- 2006-12-05 WO PCT/EP2006/011629 patent/WO2007068369A1/de not_active Ceased
- 2006-12-05 US US12/097,020 patent/US20090018373A1/en not_active Abandoned
- 2006-12-05 EA EA200870037A patent/EA200870037A1/ru unknown
- 2006-12-05 JP JP2008544812A patent/JP5366556B2/ja not_active Expired - Fee Related
- 2006-12-05 KR KR1020087016552A patent/KR101376082B1/ko not_active Expired - Fee Related
- 2006-12-05 CA CA002634263A patent/CA2634263A1/en not_active Abandoned
- 2006-12-05 DK DK06829277.0T patent/DK1968738T3/da active
- 2006-12-05 CN CN2006800528590A patent/CN101394924B/zh not_active Expired - Fee Related
- 2006-12-05 EP EP06829277A patent/EP1968738B1/de not_active Not-in-force
- 2006-12-05 ES ES06829277T patent/ES2397966T3/es active Active
-
2008
- 2008-06-11 EG EG2008060972A patent/EG26485A/en active
- 2008-06-11 ZA ZA200805086A patent/ZA200805086B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP5366556B2 (ja) | 2013-12-11 |
| DE102005060171A1 (de) | 2007-06-21 |
| EP1968738A1 (de) | 2008-09-17 |
| CN101394924A (zh) | 2009-03-25 |
| US20090018373A1 (en) | 2009-01-15 |
| CA2634263A1 (en) | 2007-06-21 |
| WO2007068369A1 (de) | 2007-06-21 |
| EG26485A (en) | 2013-12-10 |
| JP2009519195A (ja) | 2009-05-14 |
| KR101376082B1 (ko) | 2014-03-19 |
| KR20080077667A (ko) | 2008-08-25 |
| DK1968738T3 (da) | 2013-01-28 |
| EP1968738B1 (de) | 2012-10-31 |
| CN101394924B (zh) | 2012-07-04 |
| EA200870037A1 (ru) | 2009-12-30 |
| ZA200805086B (en) | 2009-03-25 |
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