KR101358405B1 - Functional detergent composition - Google Patents

Abstract

The present invention provides a functional detergent composition which comprises: 10-20 wt% of composition for emitting far infrared ray and blocking ultraviolet ray including pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, and yttrium oxide; 10-20 wt% of enzyme complex supplementation including protease, lipase, amylase, and cellulase; 5-15 wt% of sodium dodecyl sulfate; 20-30 wt% of sodium percarbonate; 10-20 wt% of sodium carbonate; 10-20 wt% of sodium citrate; 10-20 wt% of silicon dioxide; 3-7 wt% of tetraacetylethylenediamine (TAED); and 1-2 wt% of scent.

Description

Functional detergent composition {FUNCTIONAL DETERGENT COMPOSITION}

The present invention relates to a functional detergent composition, and more particularly, it is easy to remove various contaminants and stings, and of course, the flexibility of the fiber is particularly enhanced after washing, as well as far-infrared radiation, UV blocking function and oxidation. The present invention relates to a functional detergent composition that also provides a skin protection effect to prevent bacterial contamination even after drying after washing.

In general, detergents are used to wash the body in daily life or to clean dust, soot, etc. from various oils such as textile products, tableware, foods, metals, and so on. many.

In addition, the use can be classified into cosmetics, household, industrial detergents, etc., and the detergent forms that currently make up the mainstream of the detergent is powder or liquid form.

These powdery and liquid detergents are inconvenient because they have to be weighed each time they are used, and the use of quantitative liquids is difficult and spills because of the risk of spillage.

In addition, in the case of powdered detergents, detergent compositions such as those disclosed in Korean Patent Laid-Open Publication No. 1999-0039213 are disclosed, but powders may be scattered during the measurement thereof, which may cause discomfort to the user. In addition, there is a high risk of re-contamination by microorganisms in the drying process after washing, and there is a limit that does not meet the demand of the consumer for functional clothing, such as UV protection, skin protection effect.

Therefore, the present invention has been devised to solve the above problems, as well as easily remove various contaminants and stings, as well as the effect of particularly strengthening the flexibility of the fiber after washing, far infrared radiation, UV protection It is an object of the present invention to provide a functional detergent composition that provides anti-bacterial contamination to skin protection effect even after drying after washing by providing a function to anti-oxidation effect.

The technical problem of the present invention as described above is achieved by the following means.

(1) 10 to 20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, complex enzymes 10- including protease, lipase, amylase, and cellulase 20 wt%; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% Tetra Acetyl Ethylene Diamine (TAED); And 1 to 2 wt% of fragrance.

(2) In the above (1)

11% by weight of the composition for far-infrared emission and sunscreen containing the same amount of pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, and 15% by weight of a complex enzyme composed of the same amount of protease, lipase, amylase, and cellulase , Sodium dodecyl sulfate 10% by weight, sodium percarbonate 24% by weight, sodium carbonate 14% by weight, sodium citrate 15% by weight, silicon dioxide 15% by weight, TAED 5% by weight, and Downey flavor 1% by weight Functional detergent composition.

(3) In the above (1)

The detergent composition is a functional detergent composition, characterized in that it further comprises a propolis hot water extract.

(4) In the above (1)

The detergent composition is a functional detergent composition, characterized in that it further comprises a millennial hot water extract.

(5) In the above (1)

The detergent composition is a functional detergent composition, characterized in that it further comprises a Angelica Angelica hot water extract.

(6) In the above (1),

The detergent composition is a functional detergent composition, characterized in that it further comprises three hot water extracts.

(7) In the above (1),

The detergent composition is a functional detergent composition, characterized in that it further comprises a cheonnyeoncho hot water extract, Cangdong Angelica hot water extract and three water extract.

(8) As described in (1),

The detergent composition is a functional detergent composition, characterized in that it further comprises platinum nano.

As described above, according to the present invention, various contaminants and stings are easily removed, and the flexibility of the fiber after washing is particularly enhanced, and by providing far infrared radiation, UV blocking function or antioxidant effect. It provides a functional detergent composition that provides bacterial protection or skin protection even when dried after washing.

Hereinafter, the contents of the present invention will be described in more detail.

Functional detergent composition according to the present invention comprises 10-20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, protease, lipase, amylase, and cellulase 10 to 20% by weight of the complex enzyme; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% Tetra Acetyl Ethylene Diamine (TAED); And incense 1 to 2% by weight.

The pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide provides the activation of cellular tissues, the discharge of waste and toxic substances, the improvement of blood circulation, and the sterilization effect due to the far-infrared radiation effect, especially clothing It is effective in restoring flexibility. In addition, the composition is known to exert UV-blocking or oxidizing effect, and even by washing and drying clothes, it also provides an effect of preventing ultraviolet rays from penetrating into the skin or aging the skin.

The complex enzyme including protease, lipase, amylase, and cellulase can be effectively decomposed protein, fat, food starch or starch by adding 10 to 20% by weight.

In addition to the detergent composition according to the present invention, sodium percarbonate excellent in bleaching power, sodium carbonate, TAED, sodium carbonate, etc., which are useful for the catalyst of surfactant activity, are added, and citric acid is added to further enhance the softness of the garment.

In addition, in order to prevent spontaneous evaporation generated when adding the fragrance, the fragrance may be prevented from evaporating when the silicon dioxide is fine granulated and mixed with the fragrance.

Preferably, the pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, and yttrium oxide are each mixed in the same amount, or far-infrared emission, so as not to impair the flexibility and feel of the fabric while providing such an effect. It is mixed in the range of 10-20 weight% with respect to the total weight of a sunscreen composition.

As a result of the experiment according to the present invention, if the detergent composition is put into the laundry, various contaminants or stings are easily removed, and the flexibility of the fiber is particularly enhanced after washing, as well as far infrared radiation and ultraviolet ray blocking function. Providing anti-oxidation effect also provides bacterium to skin protection effect even after drying after washing.

In order to enhance the antimicrobial activity in the detergent composition according to the present invention, it is preferable to include platinum nano or propolis extract within the range of 0.1 to 5% by weight. Platinum nano is sufficient to select any one of the commercially available products (1000 ~ 2000 ppm solution), Propolis extract is a substance that enhances the skin protective activity in addition to the antimicrobial activity synergistic when added to the detergent composition according to the invention You can expect the effect. Platinum nano is particularly effective in deodorizing and deodorizing laundry.

In addition, the detergent composition according to the present invention, it is preferable to add at least one extract selected from hot spring extract, cheonnyeoncho hot water extract, and three hot water extract. Each of the extracts are cheap and easy to purchase, these extracts are excellent in antioxidant activity, soften the fibers and have an excellent deodorizing effect. The amount of each extract is preferably added in 1 to 5% by weight relative to the weight of the detergent composition.

The functional detergent composition according to the present invention is loaded into a water-soluble stick packaging container, it is preferable to directly put the water in the packaging container to wash the laundry.

To this end, the water-soluble stick packaging container according to the present invention can be dissolved quickly and completely in water at the temperature of the image, and the material itself is strong and flexible, non-sticky water-soluble film in high or low temperature, high humidity or dry storage conditions This is preferable and specifically, polyvinyl alcohol, polyethylene oxide, methyl cellulose, etc. are mentioned.

The thickness of the water-soluble film is preferably set to 0.01 to 0.1 mm in consideration of storage stability of the detergent composition to be charged therein and solubility during washing. When the thickness of the water-soluble film is less than 0.01 mm, the cleaning composition may be dissolved by moisture in the air during storage, and the storage stability is lowered. When the thickness of the water-soluble film exceeds 0.1 mm, the decomposability in water during washing is deteriorated.

The functional detergent composition of the present invention is preferably used individually packaged in units of the required amount for a single batch washing. Therefore, only a proper amount can be used during washing to prevent overuse of detergent, so it is economical, and can be directly administered to the washing tank together with the laundry during washing, so it is convenient to use and has excellent storage stability and transportability.

Hereinafter, the present invention will be described in more detail by the following examples and experimental examples. However, the following examples and experimental examples are illustrative of the present invention, and the content of the present invention is not limited by the following examples and experimental examples.

Example 1

11 wt% of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride and yttrium oxide in a stick-shaped packaging container made of 0.05 mm thick polyvinyl alcohol film, protease, 15% by weight of lipase, amylase, and cellulase in the same amount of enzyme, 5% by weight of sodium dodecyl sulfate, 24% by weight of sodium percarbonate, 14% by weight of sodium carbonate, 10% by weight of sodium citrate, 15% by weight of silicon dioxide, Disposable water-soluble stick detergent was prepared by charging 25 g of a detergent composition consisting of 5 wt% TAED and 1 wt% Downey flavor.

[Example 2]

A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that a polyethylene oxide film having a thickness of 0.05 mm was used and 10 parts by weight of propolis hot water extract was added to 100 parts by weight of the detergent composition.

[Example 3]

A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that a 0.05-mm-thick methyl cellulose film was added and 5 parts by weight of platinum nano-solution (1000 ppm) was added to 100 parts by weight of the detergent composition.

Example 4

In Example 3, a disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that 3 parts by weight of millennial hot water extract was added to 100 parts by weight of the detergent composition.

[Example 5]

A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1, except that 3 parts by weight of Angelica gigas hot water extract was added to 100 parts by weight of the detergent composition.

[Example 6]

A water-soluble disposable detergent was prepared under the same conditions as in Example 1 except that 3 parts by weight of three hot water extracts were added to 100 parts by weight of the detergent composition in Example 3.

[Example 7]

In Example 3, a disposable water-soluble stick detergent was prepared under the same conditions as in Example 1, except that 1,000 parts by weight of hot water extract, Angelica gigas hot water extract, and three hot water extracts were added in an amount of 100 parts by weight of the detergent composition.

[Example 8]

A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that 10 parts by weight of propolis hot water extract was added to 100 parts by weight of the detergent composition.

Experimental Example 1 Washing Power

Artificially soiled clothes were used under a commercial centrifugal washer under 50 L of water, 1 stick detergent package of Examples 1 to 3, and 25 ° C of water temperature. It was then washed for 10 minutes and then rinsed twice for three minutes. The washing power was calculated and evaluated by the following equation according to the general method.

% Wash = ((Rw-Rs) / (RI-Rs)} × 100

RI is the reflectance of uncleaned clothing, Rw is the reflectance of washed clothing, and Rs is the reflectance of soiled clothing. Reflectance at 540 mn was measured using a multi-light spectrophotometer calorimeter. Comparative Example 1 is a conventional composition consisting of 35% by weight of sodium polyacrylate, 5% by weight of nonionic surfactant, 6% by weight of triethanolamine citrate salt, 5% by weight of propylene glycol, 0.4% by weight of alcalase, 48.6% by weight of water Detergent composition was used.

division Example 1 Example 2 Example 3 Comparative Example 1 Cleaning power ◎ ◎ ◎ △

* ◎: 40% or more washing power, ○: 32% or more washing power less than 40%, △: 20% or more washing power less than 32%, ×: cleaning power less than 20%

Experimental Example 2 Antimicrobial Activity

In order to determine the antimicrobial activity of the stick detergents of Examples 1 to 3, an antibacterial test for Escherichia coli ATCC 25922 and P. aeruginosa (Staphylococcus aureus ATCC 6538) was performed according to the disclosure method, and the results are shown in Table 2 below. .

division Experiment result Initial concentration
(CFU / 40p) Concentration after 1 hour
(CFU / 40p) Bacterial reduction rate
(%) Escherichia coli Example 1 225 2 99.1 Example 2 224 One 99.6 Example 3 227 One 99.6 Comparative Example 1 226 225 0.4 Pyogenic bacteria Example 1 354 2 99.4 Example 2 356 One 99.7 Example 3 356 One 99.7 Comparative Example 1 355 353 0.6

As a result of the experiment, it was determined that the stick detergent according to the embodiment of the present invention exhibited antibacterial activity due to the far infrared radiation effect.

Experimental Example 3 UV Protection

Artificially soiled clothes were cut into 10 절단 10cm size (test cloth), washed with a standard use amount (1g / 1L) in a washing machine standard course, and naturally dried, and then the UV blocking effect of the test cloth was measured as follows. In order to measure the UV blocking effect, the transmittance was measured after setting the measurement area (250-450 nm) using Perkin-Elmer (Lambda 15). When measuring the transmittance at a predetermined wavelength-350nm by transmitting ultraviolet rays to the test cloth with air as a control, the results are shown in Table 3 below.

division Example 1 Example 2 Example 3 Comparative Example 1 UV transmittance 27 24 24 52

As a result of the measurement, the disposable stick detergent according to the present embodiment compared to the general detergent of Comparative Example 1, the UV transmittance is reduced by about 48 to 52% it can be confirmed that the present invention has excellent UV blocking effect.

Experimental Example 4 Antioxidation

As a result of measuring the DPPH scavenging ability of the antioxidant effect in the detergent compositions of Examples 1 to 8, it was confirmed that the scavenging effect is excellent as shown in Table 4 below, it is expected to have a skin protection effect when applied to the laundry.

division % Scavenging power Example 1 42.7 ± 1.6 Example 2 43.5 ± 2.3 Example 3 44.1 ± 0.7 Example 4 48.3 ± 1.2 Example 5 49.8 ± 3.1 Example 6 49.4 ± 2.9 Example 7 53.5 ± 1.0 Example 8 46.5 ± 0.3

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the appended claims. It can be understood that

Claims (8)

10-20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, 10-20% by weight of a complex enzyme including protease, lipase, amylase, and cellulase ; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% tetraacetylethylenediamine (TAED); And 1 to 2 wt% of fragrance. The method of claim 1,
11% by weight of the composition for far-infrared emission and sunscreen containing the same amount of pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, and 15% by weight of a complex enzyme composed of the same amount of protease, lipase, amylase, and cellulase , 5% by weight sodium dodecyl sulfate, 24% by weight sodium percarbonate, 14% by weight sodium carbonate, 10% by weight sodium citrate, 15% by weight silicon dioxide, 5% by weight tetraacetylethylenediamine (TAED), and 1% by weight downey Functional detergent composition, characterized in that consisting of. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a propolis hot water extract. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a millennial hot water extract. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a Angelica Angelica hot water extract. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises three hot water extracts. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a cheonnyeoncho hot water extract, Cangdong Angelica hot water extract and three water extract. The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises platinum nano.