KR101265292B1 - Preparation method of a far-infrared rays radiation solution and its articles - Google Patents

Abstract

PURPOSE: A manufacturing method of a far-infrared radiation solution and a far-infrared radiation article manufactured thereby are provided to effectively show the effects of released far-infrared radiation, anion generation, and vegetable-based material and to allow spraying on the surface of an object with high pressure and high temperature. CONSTITUTION: A manufacturing method of a far-infrared radiation solution comprises a first process of manufacturing a suspension of far-infrared radiation inorganic material by mixing for 2-50 days with a low speed stirrer while maintaining the inner temperature of mixing tank at 70-90°C after grounding the inorganic material into a particle size of 1500-3500 mesh and injecting the organic material and purified water at a volume ratio of 1:0.5-2 in the mixing tank; a second process of separating a fluid vegetable concentrate which is extracted for 1-4 days with a centrifuge while maintaining the inner temperature of a sludge thickener at 65-80°C after pulverizing dried vegetable material into a particle size of 150-300 mesh and injecting the vegetable material and purified water at a volume ratio of 1:0.5-2 in the sludge thicker; and a third process of stirring and aging for 10-50 days while maintaining the inner temperature of the mixing tank at 70-90°C after injecting the suspension of the far-infrared radiation inorganic material and the fluid vegetable concentrate at a volume ratio of 1: 0.5-2 in separate mixing tanks which are equipped with a high-speed agitator. [Reference numerals] (AA) First process: Manufacture mineral suspension of far-infrared radiation; (BB) Second process: Separate vegetable concentrate liquid; (CC) Third process: Manufacture a far-infrared radiation solution; (DD) Fourth process: Absorb the far-infrared radiation solution on the surface of an article; (EE) Fifth process: Cool the article

Description

Preparation method of far-infrared radiation solution and far-infrared radiation article manufactured therefrom {PREPARATION METHOD OF A FAR-INFRARED RAYS RADIATION SOLUTION AND ITS ARTICLES}

The present invention relates to a method for producing a far-infrared radiation solution, and to a far-infrared radiation article prepared therefrom, and more particularly, to a far-infrared radiation solution in which a far-infrared radiation inorganic suspension and a liquid vegetable concentrate are mixed, which are prepared at a high temperature and high pressure. By injecting into the surface pores and infiltrating into the surface pores, the product is not deformed or generated harmful substances such as heavy metals in the process of processing, and does not become discolored, and the effects of far infrared emission and anion generation, as well as deodorization, antibacterial, The present invention relates to a method for producing a far-infrared radiation solution that can be used in various applications such as functional plastic products or textile products, leather products, paper products, etc., having excellent health promotion functions, and far-infrared radiation articles produced therefrom.

As is well known, various gemstones that emit far infrared rays and negative ions are developed and processed to improve the health of the human body. Various crafts, building interior materials, beds, tiles, water filters, cooking utensils, storage containers, textile materials, warmers, shiatsu It has been used in many ways, such as old districts, to have beneficial effects on humans.

Among them, in bedding or clothing textile products, bacteria and microorganisms are multiplied by sweat and other organic substances such as fat and protein, which are secreted by the human body, and these bacteria and microorganisms break down organic matters and cause odor or contact with body. It can also cause skin diseases. In order to remedy these shortcomings, recent attempts have been made to give fiber products the advantages of minerals by adding natural special minerals to synthetic resins.

In addition, plastic containers made of resin compositions containing far-infrared radiation ceramics are known to have excellent deodorization and antibacterial properties, and are excellent in preserving the freshness of foods and vegetables, and are generally added or mixed to improve the functionality of synthetic resins. Powders include germanium, titanium oxide, mica, hornblende, elvan, loess, and charcoal.The above functional mineral particles are added by a master batch method or substituted with an antibacterial metal such as silver (Ag). Many methods of using ceramics such as dispersing inorganic zeolites have been developed.However, when injecting plastic containers, the properties of synthetic resins are greatly changed depending on the degree of grinding, mixing ratio, dispersibility, molding and cooling temperature of minerals. Product is not uniform and productivity decreases. Also, during melt spinning of synthetic fiber There is a problem of frequent trimming and discoloration of textile products, and dyeing fastness is poor in dyeing processing process, so there is a lot of problems in practical use due to poor dyeing.

For example, when manufacturing a plastic container using a conventional far-infrared radiation resin composition, a silicon oxide or a titanium oxide excellent in whiteness, which is relatively far-infrared radiation is powdered and mixed in a synthetic resin, wherein the particle size distribution is 4 ~ 10 When a small amount of far-infrared radiation ceramic powder in the range of micron (μm) is added to a synthetic resin, the plastic container is injection molded, and the effect of emitting far infrared rays is insignificant, and when the content of the ceramic powder is increased, dispersibility with the resin is poor. In particular, wear of the screw, cylinder, etc. of the compressor, resulting in a decrease in productivity, an increase in processing cost, etc., and also a problem in that the physical properties and surface glossiness of the plastic container are poor.

The conventional far-infrared radiation resin composition is only a measure of the value of far-infrared radiation emitted from the ceramic powder itself, and the value is not expressed as it is when applied to a small amount in a real plastic container, unlike the high far-infrared emissivity of the ceramics itself. The freshness preservation efficacy of vegetables did not show particularly good characteristics compared to general plastic containers. On the other hand, by excessively incorporating ceramic powder to increase the far-infrared emissivity, economic loss such as kneading caused by large mixing, device wear, surface defects of the product and deterioration of strength and durability were more likely to occur.

Looking at the prior art with respect to the present invention, Republic of Korea Patent Publication No. 10-0128110 (Registration Date: October 29, 1997) contains sodium silicate, sodium peroxide, potassium carbonate, sodium carbonate, purified white sugar and silver thiosulfate in an aqueous solution The weight ratio of sodium silicate based on sodium carbonate is 1: 10-18, sodium peroxide is 1: 0.1-0.5, potassium carbonate is 1: 5-10, refined white sugar is 1: 10-18 and silver thiosulfate It is known that the liquid far-infrared radiation composition is characterized by 1: 0.1-3.0, when the composition is impregnated or applied to a predetermined product, it can emit a large amount of far infrared rays, has excellent antibacterial properties and generates little static electricity. Although the fabric can be manufactured, the present invention has low adhesion to the fabric and its effectiveness is reduced due to washing, so it is difficult to expect the far-infrared radiation effect of long-term use. .

In addition, Republic of Korea Patent Publication No. 10-0290811 (Registration date: 2001.03.06), 93 to 97 parts by weight of homopolypropylene resin having a melt index of 8 to 15 g / 10min, 3 to 7 parts by weight of far-infrared radiation ceramics and molecular weight Far-infrared radiation resin composition is known which is composed of 90 parts by weight of vinylidene fluoride of 20,000 to 25,000 and 0.08 to 0.1 parts by weight of fluorocarbon-based elastomer consisting of 10 parts by weight of micro talc and 10 parts by weight of micro talc. Although a small amount of far-infrared radiation ceramics is contained in the synthetic resin, the workability is good and the surface glossiness and appearance can be maintained. However, as described above, the far-infrared radiation function is estimated to be insignificant.

And the Republic of Korea Patent Publication No. 10-0475506 (Registration date: 2005.02.28), after the fermentation (maturation) by mixing the powdered minerals and various herbal preparations, the optimum reaction conditions that can effectively grow the effective microorganisms A method for producing a liquid far infrared emitter and a powdered bio-ceramic having a maximum far infrared effect and a function by extracting the same is described, and the far-infrared ray extracted from the herbal medicine in Korean Patent Publication No. 10-0806289 (Registration Date: 2008.02.15) The discharge liquid and the clay are mixed and plastically processed to form a ceramic fired body, wherein the clay is added alone clay, black soil and red soil, or 80 to 90 wt% clay, 5 to 10 wt% clay, 5 to 10 wt% red clay. Although it discloses a far-infrared emitting ceramic fired body characterized in that, the above inventions all use the far-infrared ceramics themselves or include or coat in raw materials As used in the present invention, far-infrared and anion functions and vegetable raw materials inside the surface of an article, as well as advanced technologies for efficiently preparing a far-infrared radiation solution by mixing a far-infrared radiation inorganic suspension such as the present invention with a liquid vegetable concentrate. It is a situation that does not provide a treatment method for indicating a complex function.

Accordingly, the present inventors prepared a far-infrared radiation solution containing a mixture of inorganic suspension and liquid vegetable concentrate with excellent infrared radiation and anion generating function, which was sprayed at high temperature and high pressure on the surface of the article, and the far-infrared radiation material was infiltrated inside the pores. The far-infrared radiated article manufactured by strong adsorption has excellent far-infrared radiant function, and its effect is permanent as long as the life of the product, and it is eco-friendly with no material deformed, discolored or harmful substances such as heavy metals during the processing of the article. The present invention has been studied by studying a method for producing a far infrared ray emitting article.

For reference, far infrared rays are close to the energy curve that is most beneficial to the human body, and the central part of the human body maintains a body temperature of 35 ° C. or higher to maintain blood flow, thereby releasing fatigue by promoting metabolism. It is called 'vitamins' or 'oxygen kernels in the air', and various pollutants in the air, such as tobacco smoke, sulfur dioxide, nitrogen oxides, carbon monoxide, ozone and various organic substances, form cations. Anions are known to neutralize and precipitate these cations, thus keeping the air clean and fresh.

In addition, cations freeze the air by allowing bacteria, dust, pollen mold, and contaminated particles to float freely, while negative ions neutralize and remove them, and anions are typically atomic elements of air with negative charges. It neutralizes and removes harmful cations, clearing blood and promoting nerve stabilization, fatigue recovery, appetite and cell activation.

According to the known research results, the amount of negative ions normally required by the human body during the day is 700 / cm3, whereas in the city, the concentration of negative ions is 30 to 150 / cm3 and the concentration of cations is 1000 to 1500 / cm3. It is known to be about 3 cm 3. On the other hand, because forests contain a large amount of negative ions of 2000 ~ 2500 / cm3, the cations generated by the body when severely stressed or tired are neutralized in forests rich in negative ions. In addition, anion-rich air is known to be effective in eliminating headaches and suppressing free histamine, a neurohormone that causes respiratory diseases, and anions are effective in clearing blood, releasing fatigue, enhancing appetite, and increasing concentration and body immunity.

An object of the present invention is a far-infrared radiation-inorganic suspension obtained by pulverizing an inorganic raw material composed of purgatory, amethyst, volcanic ash, loess, sclerophysis, platinum, tourmaline, and germanium, and dried vegetable raw material composed of situational mushrooms, pine mushrooms, and koji It is to provide a method for producing a far-infrared radiation solution that can effectively exhibit the effect of far-infrared emission, anion generation and the effect of the vegetable raw material by mixing and aging the concentrated vegetable vegetable concentrated solution.

Another object of the present invention is to modify the product processing process by injecting the far-infrared radiation solution prepared from the far-infrared radiation inorganic suspension and liquid vegetable concentrate at high temperature and high pressure on the surface of the article by infiltrating and adsorbing the far-infrared radiation material into the pores inside the material. Not only does it generate no harmful substances such as heavy metals, but also has the effect of far-infrared emission and negative ion generation, as well as deodorization, antibacterial and anti-static functions, and it is a new concept of environmentally friendly far-infrared radiation product that does not deteriorate or discolor during use. It is to provide a manufacturing method.

In the method for producing a far-infrared radiation solution of the present invention, after grinding the inorganic raw material composed of nephrite, amethyst, volcanic ash, loess, scleral rock, platinum, tourmaline, germanium to a particle size of 1500 to 3500 mesh (mesh), the inorganic First step of preparing a far-infrared radiation-inorganic suspension by adding raw materials and purified water to a mixing tank at a volume ratio of 1: 0.5 to 2 and mixing them with a low speed stirrer for 2 to 50 days while maintaining the internal temperature of the mixing tank at 70 to 90 ° C. ; After grinding the dried vegetable raw material composed of the situation mushroom, pine mushroom, kkujijak tree with a particle size of 150 ~ 300 mesh (mesh), the vegetable raw material and purified water are added to the concentration tank in a volume ratio of 1: 0.5 ~ 2, the concentration tank A second step of separating the liquid vegetable concentrate obtained by extraction for 1 to 4 days while maintaining the internal temperature at 65 to 80 ° C. with a centrifuge; Into a separate mixing tank equipped with a high speed stirrer, the far-infrared radiation inorganic suspension and the liquid vegetable concentrate were added at a volume ratio of 1: 0.5 to 2, and then maintained at an internal temperature of the mixing tank at 70 to 90 ° C for 10 to 50 days. It comprises a third step of aging with stirring, the mineral raw material is 15 to 20% by weight purgatory, 12 to 18% by weight amethyst, 7 to 13% by weight ash, 10 to 15% by weight ocher, 5 ~ 10 It is contained in the ratio of weight%, platinum 3-7% by weight, tourmaline 5-10% by weight, germanium 20-30% by weight, the dry vegetable raw material is 15 ~ 25% by weight mushroom, 45 ~ 55% by weight mushroom, Cudrania is characterized in that it is contained at a ratio of 25 to 35% by weight.

In addition, the method for producing a far-infrared radiation article, by spraying the far-infrared radiation solution on one or both sides of the article with a high-temperature, high-pressure steam injection nozzle of a temperature of 80 ~ 160 ℃, pressure 3 ~ 6 bar (bar), the far infrared radiation on the surface of the article A fourth step of adsorbing the solution and a fifth step of cooling the article, or putting the article in a sealed container (reactor), and then maintaining the inner temperature of the reactor at 80-160 ° C. And a fourth process of adsorbing a far-infrared radiation solution on the surface of the article by spraying with a high pressure steam injection nozzle of 6 bar and a fifth process of cooling the article, wherein the article is made of plastic, fiber, It is characterized in that it is made of any one or more materials selected from leather, paper.

In the fourth process, the adsorption treatment is performed with the far infrared radiation solution for 5 seconds to 5 minutes depending on the type and shape of the article, and after the fourth process, the far infrared radiation solution is recovered and reused.

The preparation method of the far-infrared radiation solution of the present invention is composed of far-infrared radiation-inorganic suspension and situation mushrooms, pine mushrooms, and zirconia, which are finely pulverized mineral raw materials composed of nephrite, amethyst, volcanic ash, loess, scleral rock, platinum, tourmaline and germanium. It is possible to spray high temperature and high pressure on the surface of the product by mixing and aging the liquid vegetable concentrate concentrated with the concentrated dry vegetable raw material, and it can be easily adsorbed inside the pores of the material to effectively release far infrared rays, generate negative ions, and enhance the efficacy of vegetable raw materials. There is an effect that can be exerted.

In addition, the method for producing a far-infrared radiation article of the present invention by spraying the far-infrared radiation solution mixed with a far-infrared radiation inorganic suspension and a liquid vegetable concentrate at a high temperature and high pressure on the surface of the article by infiltrating and adsorbing the far-infrared radiation substance inside the pores of the material Not only does there is no generation of harmful substances such as heavy metals or deformed during the treatment, but also the effects of far-infrared emission and anion generation, as well as excellent deodorization, antibacterial and antistatic properties, and do not alter or discolor during use. For products made of various kinds of materials such as sponge, fiber, leather, paper, etc., it has an excellent effect on quality improvement such as excellent processability, durability and durability.

1 is a flow chart sequentially showing a method of manufacturing a far infrared ray radiated article according to the present invention.
Figure 2 is a photograph of the thermal imaging camera before and after using the needle pad made of fibers treated with the far-infrared radiation solution according to the present invention.
Figure 3 is a photograph of the thermal imaging camera before and after using the shoe insole treated with the far-infrared radiation solution according to the present invention.
Figure 4 is an electron micrograph of the erythrocyte change experiment before and after using the needle pad made of fibers treated with the far-infrared radiation solution according to the present invention.

Hereinafter will be described in detail the operation of the configuration of the present invention, which is intended to illustrate the extent to which the invention can be easily carried out by those of ordinary skill in the art to which the present invention pertains, It does not mean that the technical spirit and scope are limited.

As shown in Figure 1, the far-infrared radiation article made of the far-infrared radiation solution according to the present invention comprises the first to fifth steps.

The first step is to finely pulverize the inorganic raw material composed of nephrite, amethyst, volcanic ash, loess, conglomerate rock, platinum, tourmaline, germanium to a particle size of 1500 to 3500 mesh (mesh), and then the inorganic raw material and purified water 1: Into the mixing tank at a volume ratio of 0.5 to 2, while maintaining the internal temperature of the mixing tank at 70 ~ 90 ℃ mixed with a low speed stirrer for 2 to 50 days to produce a far-infrared radiation inorganic suspension, the purgatory, amethyst, volcanic ash, Ocher and scleroderma are known to emit far-infrared rays. Therefore, it is considered that mixing and using them in an appropriate ratio is advantageous in terms of far-infrared emissivity and radiation energy intensity.

The far-infrared radiation inorganic raw material is primarily pulverized to 1500 ~ 3500 mesh (mesh) to remove foreign substances and harmful iron by magnets, etc. to prevent the color of the product or discoloration of dyes, etc. to improve the quality of the product, of course , The powder exhibits a weak alkalinity of about PH 7.2 ~ 7.8 to effectively enhance the effect on the human body and fresh food due to its inherent action as an environmentally friendly material that is not harmful to the human body at all. The content can be added or subtracted according to the purpose, but based on the total amount of the inorganic raw material, 15 to 20% by weight of jade, 12 to 18% by weight of amethyst, 7 to 13% by weight of volcanic ash, 10 to 15% by weight of loess, and cultured bedrock 5 It is most preferable to contain about 10% by weight in terms of appearance or far-infrared divergence effect and economical aspect of the final product.

The far-infrared radiation inorganic raw material may be pulverized to about 300 mesh or less when it is contained in synthetic resin, but in the present invention, the surface of the article is sprayed at high temperature and high pressure to infiltrate into the pores of the material and adsorb. Since it is intended to prepare a highly penetrating far-infrared radiation solution for use as, the inorganic raw material must be finely ground to a particle size of 1500 ~ 3500 mesh (mesh) size.

By the way, nephrite jade is said to have been brought to Europe by the Spanish in the 17th century when the Chinese jade was used to treat long-term diseases in China, and jade is the noblest gem of the East. Are roughly classified into two types of jadeite and jadeite, but in the mineralogical sense, jadeite is a kind of hornblende, while jadeite is a kind of alkali fluorite, and the two minerals have different chemical components and are distinguished by color and hardness. Jade used for health promotion and disease treatment is purgatory.

Amethyst contains more iron oxide (Fe ₂ O ₃ ) than any other variant of quartz, and experts say it is unique because of the iron or manganese or hydrocarbons it contains. Volcanic ash consists of crushed stone and glass fragments called tephra from volcanic eruptions, which are less than 4 mm in diameter at the time of their creation.

Loess has a melting point of 700 to 1000 ° C and maintains a solid state at a temperature of 200 to 300 ° C, which is a melting point of polyester or nylon resin, so that the far-infrared radiation effect can be semi-permanently maintained. Ocher powder is approximately 42.5% of silicon dioxide (SiO ₂ ), 4.05% of iron oxide (Fe ₂ O ₃ ), 36.6% of aluminum oxide (Al ₂ O ₃ ), 0.57% of calcium oxide (CaO), 0.69% of magnesium oxide (MgO), titanium oxide (TiO ₂ ) 0.23%, potassium oxide (K ₂ O) 0.41%, sodium oxide (Na ₂ O) 0.18%, loss of ignition 14.8% weight ratio, far-infrared radiation, heavy metal adsorption, antibacterial, volatile removal, It is known to exhibit effects such as deodorization.

Grannophyre is a type of quartz rock that has minerals and chemicals similar to granite but is formed by the solidification of rhyolite magma. Refers to the rock showing the anastomosis.

Also, platinum, tourmaline, and germanium are known to generate negative ions, and are manufactured by collecting particles having a strong negative charge, that is, generating a large number of negative ions. By increasing the specific surface area, not only the anion generation amount is increased but also the dispersibility of the far-infrared radiation solution is excellent. In particular, platinum has an excellent electrical conductivity to prevent static electricity of the final product. In order to maximize the function due to the increase in specific surface area and diffusivity, the inorganic raw material is absolutely required to be finely ground to a particle size of 1500 to 3500 mesh.

Platinum is a silver-white noble metal, soft, malleable, high melting point, strong corrosion resistance and chemical resistance. For example, the surface gloss does not change even when heated in the incandescent state in the air and easily melts in aqua regia, but does not melt well in simple acids. In the present invention, it is confirmed that the platinum material can sufficiently exhibit the negative ion dissipation function and the antistatic function by containing about 3 to 7% by weight of the inorganic raw material by using the property that platinum withstands the chemical action of high temperature and electric arc. Furthermore, compared to the case of using gold, silver, copper or other conductive metals, the product is not discolored and has excellent durability.

Tourmaline is mainly produced as very rich and well-developed crystals in denatured limestone in contact with pegmatite and granitic magma, and accumulates in the debris deposits because of its resistance to weathering and is common in sedimentary rocks. In addition to being used as a gemstone as a minor mineral, piezoelectrics, that is, they are used in pressure devices by taking advantage of the property of generating electricity when applying mechanical force or changing shape when applying voltage.

In addition, germanium has a small ductility because the atomic arrangement of elemental crystals is the same as that of diamond carbon atoms, but it does not change at room temperature and oxidizes at 600 to 700 ° C. Corrosive only to 王水 and rarely react with corrosive aqueous solutions. In the present invention, it has been studied that it is preferable to contain 5-10 wt% of tourmaline and 20-30 wt% of germanium based on the total amount of the inorganic raw materials in order to enhance the effect of anions.

Next, the inorganic raw material and purified water are added to the mixing tank at a volume ratio of 1: 0.5 to 2, and mixed with a low speed stirrer for 2 to 50 days while maintaining the internal temperature of the mixing tank at 70 to 90 ° C. to produce a far-infrared radiation inorganic suspension. In order to mix the finely divided inorganic raw material with 1500 ~ 3500 mesh size in the purified water and to disperse evenly, it is necessary to keep the internal temperature of the mixing tank at a constant temperature in the range of 70 ~ 90 ℃, and also by mixing for a long time at low speed It is made of a far-infrared radiation inorganic suspension having good dispersibility and permeability.

In the second process simultaneously with the first process, the dried vegetable raw material composed of edible mushrooms, pine mushrooms, and custard trees is pulverized to a particle size of 150 to 300 mesh, and the vegetable raw material and purified water are 1: 0.5. It is added to the concentration tank at a volume ratio of ~ 2, the liquid vegetable concentrate is extracted for 1 to 4 days while maintaining the internal temperature of the concentration tank at 65 ~ 80 ℃ centrifuge, the vegetable raw material is 18 ~ 20 ℃ Firstly dry for about 7-9 hours in the shade maintained, and dry for 1.5-2.5 days in the sun at 26 ℃ or more. The drying conditions are not necessarily limited to these conditions for the purpose of powdering, it is most advantageous to maintain the active ingredient is the first drying in the shade at room temperature and the second drying in the sun. That is, it is preferable that the vegetable raw material is naturally dried to a moisture content of 15% or less, ground to an appropriate particle size, mixed with a certain ratio and extracted with purified water. The temperature of the concentrating tank is maintained at a temperature of about 65 to 80 ° C for more than 24 hours The active ingredient is dissolved out without being decomposed. By separating the same again using a centrifuge, the raw material can be used without wasting as much as possible.

The situation mushroom is a mycelium mushroom, which contains an enzyme that acts as an anticancer and antioxidant agent, and is known to have a great effect on enhancing anticancer effect and immunity and is cited as one of the Bulchocho in the oriental medicine. It has long been used for uterine bleeding and treatment of uterus, dysmenorrhea, intestinal bleeding, and gastrointestinal function. Recently, Japanese medicine has found that situational mushrooms contain high amounts of high-quality polysaccharides and proteins, and especially anti-cancer effects (especially digestive cancer). The study showed that it is effective in stomach cancer, esophageal cancer, duodenal cancer, colon cancer, rectal cancer and liver cancer.

Pine mushrooms are known to help stomach and intestinal function and promote circulation of energy, so that the hands and feet are numb and have no power, or the waist and knees are cold. Polysaccharides in pine mushrooms are known to have anti-cancer effects. However, they contain only 2% protein, 3.5% fat, 6.7% sugar, 0.8% fiber, 0.8% ash, other vitamin B2 and niacin, and a lot of ergosterol like other mushrooms.

Cudrania tricuspidata is a deciduous tree belonging to the Mulberry family, and it is said that it is effective to cure tinnitus symptoms in the ear when drinking with roots. Cudrania contains Gamma Amino Butyric Acid, which is good for lowering blood pressure, diuretic effect and promoting metabolism of brain cells, and Rutin, which is effective in preventing hemorrhagic diseases such as cerebral hemorrhage, and contains up to several times as much as general mulberry leaves or green tea. It is known to be excellent in preventing adult diseases such as diabetes and hypertension, and demand is increasing rapidly. Cucumber tree has a female and female fruit, and the fruit is open only to female trees. Stems, twigs, and berries contain rutin, aspartic acid, vitamins, and glutamine, which are good for relieving hangovers and restoring chronic fatigue, and are effective for children's growth, treatment of osteoporosis, skin care, and digestive function. It is also used to treat high blood pressure, diabetes, hyperlipidemia, arteriosclerosis, and various cardiovascular diseases. Since the Kudji mulberry tree can be used for various purposes for each root, stem, leaf, fruit, the present invention can be used alone or in combination of the roots, stems, leaves, and fruits of Cuji mulberry tree.

The above-mentioned dry vegetable raw materials were mixed in the proportion of 15 ~ 25% by weight of mushrooms, 45 ~ 55% by weight of mushrooms, 25 ~ 35% by weight of Kudji mulberry, and the best complementary and synergistic effects of each component were investigated. .

In the third step, the far-infrared radiation inorganic suspension and the liquid vegetable concentrate are added to a separate mixing tank equipped with a high speed stirrer at a volume ratio of 1: 0.5 to 2, and the internal temperature of the mixing tank is maintained at 70 to 90 ° C. Aging with stirring for 10 to 50 days to prepare a far-infrared spinning solution, which is suitable for the preparation of the far-infrared spinning inorganic suspension prepared by the first process and the vegetable concentrate prepared by the second process in a separate mixing tank equipped with a high-speed stirrer In addition to the uniform mixing at the ratio, the mycelium contained in the vegetable raw material is sufficiently fermented under a good temperature for fermentation and evenly adsorbed to the inorganic raw material particles so that the far-infrared radiation solution produced is not only an infrared ray emitting function but also an anion generating function and a mycelium. Effectively promotes health-promoting functions caused by substances produced in plants Thereby tanael.

Due to the above process, the present invention does not require a separate molding process or a firing process as compared to using a general ceramic fired body, and is capable of maintaining unchanged for a long time in terms of efficacy. And while maintaining the internal temperature of the mixing tank at 70 ~ 90 ℃ while stirring at low speed within 10 days or more than 50 days is suitable for aging, if too short or long aging may cause problems when spraying using a high pressure spray nozzle. .

The fourth step is to spray the far-infrared radiation solution on one or both sides of the article with a high-temperature, high-pressure steam spray nozzle at a temperature of 80 to 160 ° C. and a pressure of 3 to 6 bar to adsorb the far-infrared radiation solution to the surface of the article. If the temperature of the product due to the far-infrared radiation solution is 80 ~ 160 ℃, the plastic and fiber products made of synthetic resin are heated to the glass transition temperature or below the melting point, so that voids occur without deforming the product. As a result, the far-infrared radiation solution is uniformly infiltrated and adsorbed into the gap to be processed regardless of the external shape of the product. For example, by controlling the temperature of the steam and the injection amount of the far-infrared radiation solution appropriately according to the components of the plastic material, it is possible to prevent the appearance or color change of the product.

Also, if the temperature is maintained at 80 ~ 160 ℃, the pores are generated by heating the surface temperature of the material such as leather, natural fiber, and paper, so that the far-infrared radiation solution is uniformly infiltrated and adsorbed. At high temperatures, the external deformation or internal deterioration of the product is concerned, and at temperatures lower than 80 ° C., the far-infrared radiant is coated only on the surface of the product, and the far-infrared radiant is difficult to infiltrate into the inner pores of the material, thereby reducing the sustainability of the effect.

In addition, the conditions for adsorbing the far-infrared radiation solution on the surface of the article in the fourth step is to put the object to be treated in a sealed container (reactor), and then to maintain the internal temperature of the reactor at 80 ~ 160 ℃ 3 Even spraying with a high pressure steam injection nozzle of ~ 6 bar (bar) was found to show an equivalent result in the effect of adsorbing the far-infrared radiation solution on the surface of the article.

Plastic products, textile products, and leather products manufactured as described above have the effect of washing the product using scrubbers, such as hot water or detergents, due to the infiltration, adsorption, and fixation of the far-infrared radiation material between the tissues or molecular pores constituting the material. It does not degrade.

In addition, the fourth process has been studied to exhibit a sufficient effect by treatment with the far-infrared radiation solution for 5 seconds to 5 minutes depending on the type of the article, that is, the component, thickness and shape of the synthetic resin, etc., the far-infrared radiation solution It is obvious that it is economically advantageous to recover and purify or dilute with purified water after the process and then reflux and reuse it in the third process.

Finally, the fifth step is to cool the article, which is more closely adhered to by the far-infrared radiation material inside the surface tissue of the product even by natural cooling, so that far-infrared rays are emitted from the inside and / or outside of the product. Therefore, the food can be kept fresh for a long time even at room temperature or low temperature, as well as deodorizing effect in the refrigerator can be expected.

In the above method, the far-infrared radiation solution is vaporized and used, so that the active ingredient is uniformly infiltrated and adsorbed into the surface molecular tissues of articles such as plastic containers and sponges, yarns, fabrics, nonwoven fabrics, leathers, and papers even in a small amount. It can maximize the function and sustainability of food, human body or the surrounding atmosphere by the effect of negative ions, and it also has a huge production cost reduction effect.

As described above, the present invention has been completed through numerous experiments. Hereinafter, the present invention will be described through preferred embodiments to be easily understood and implemented by those skilled in the art.

Finely pulverized the mineral raw material composed of nephrite, amethyst, volcanic ash, loess, conglomerate rock, platinum, tourmaline, and germanium at a particle size of 1500 to 3500 mesh, and weighed 17% by weight of pulverized jade and 15% by weight of amethyst. 10% by weight of volcanic ash, 13% by weight of ocher, 7% by weight of condylodium, 5% by weight of platinum, 8% by weight of tourmaline, and 25% by weight of germanium were added to the mixing tank, and then poured 1.5 times the volume of purified water compared to the inorganic raw material and mixed. The far-infrared spinning inorganic suspension was prepared by mixing with a low speed stirrer for 10 days while maintaining the temperature of the bath at about 80 ° C. Next, the dried vegetable raw material composed of the situation mushroom, matsutake mushroom, kkujijak tree is pulverized to a particle size of 150 ~ 300 mesh (mesh), 20% by weight of crushed mushrooms, 50% by weight matsutake mushroom, 30 wt. After the ratio was added, the same volume of purified water as the vegetable raw material was poured and extracted for 2 days while maintaining the temperature of the concentration tank at about 75 ℃ to separate the liquid vegetable concentrate from the centrifuge. The far-infrared spinning inorganic suspension and liquid vegetable concentrate were added to the same mixing tank equipped with a high speed stirrer at the same volume ratio, and then the inner temperature of the mixing tank was maintained at about 80 ° C. and aged for 20 days, followed by ripening while stirring. Was prepared.

The internal temperature of the airtight container (reactor) was maintained at about 100 ° C., a polyester textile was added, and the far-infrared radiation solution prepared in Example 1 was sprayed with a 4 bar high pressure steam spray nozzle for 10 seconds. The far-infrared spinning polyester fabric was prepared by spraying to adsorb and cool the far-infrared spinning solution on the surface of the fabric.

The temperature of the airtight container (reactor) was maintained at about 120 ° C., a shoe insole made of polyurethane foam was added thereto, and the far-infrared spinning solution prepared in Example 1 was sprayed with a high pressure steam spray nozzle of 5 bar for 1 minute. Was prepared by adsorbing and cooling the far-infrared spinning solution on the surface of the shoe insole.

For the plastic bucket made of high density polyethylene (HDPE), the far-infrared radiation solution prepared in Example 1 was sprayed for 2 minutes with a high-temperature, high-pressure steam spray nozzle at a temperature of 80 ° C. and a pressure of 3.5 bar, and the far-infrared rays were irradiated on the surface of the plastic bucket. The spinning solution was adsorbed and cooled to prepare a far-infrared spinning plastic bucket.

≪ Comparative Example 1 &

Comparative Example 1 prepared a general polyester fabric that was not treated with a far infrared spinning solution.

<Experimental Example 1>

As a result of requesting to Korea Fashion Industry Institute (1561-4 Bongmu-dong, Dong-gu, Daegu) to investigate the objective physical properties of the polyester fabrics according to Example 2 and Comparative Example 1, the test analysis report on the thermal insulation test It is shown in [Table 1], and the evaluation results of the temperature change according to the time required after the close contact with the thermal imaging camera is shown in [Table 2] below.

Test Items
Test result
Test Methods
Warmth
(%) CLO
(Comfort) Thermal conductivity
(W / ㎡ ℃) Example 2 23.7 0.18 35.05 KS K 0560
Comparative Example 1 19.2 0.14 47.45

<Experimental Example 2>

The far-infrared emissivity and the radiant energy of the polyester fabric according to Example 2, the shoe insole made of the polyurethane foam according to Example 3, and the plastic bucket according to Example 4, respectively, were established by the Korea Far Infrared Association. The results of the measurement based on 174-12 Seokchon-dong, Songpa-gu, are shown in [Table 3] below. Actually, it reaches 0.884 ~ 0.893, and the radiant energy (W / ㎡㎛, 37 ℃) reaches 3.44 × 10 ² . Could confirm.

Test Items Emissivity
(5 ~ 20㎛) Radiant energy
(W / m 2 μm, 37 ° C) Test Methods Example 2 0.884 3.41 × 10 ²
KFIA-FI-1005
Example 3 0.892 3.44 × 10 ² Example 4 0.893 3.44 × 10 ²

In addition, the far-infrared radiation solution of the polyester fabric according to Example 2, a shoe insole made of a polyurethane foam according to Example 3, and a plastic bucket according to Example 4 were measured several times using a contact type anion meter. The concentration of anion emitted from the article treated with the average of 300 ~ 700 / cm 3 was found to be sufficient to implement the object and effect of the present invention.

As described above, the far-infrared radiated article prepared by the manufacturing method of the present invention prepares a far-infrared radiated solution in which a far-infrared radiated inorganic suspension and a liquid vegetable concentrate are mixed, and sprays it on the surface of the article at high temperature and high pressure to infiltrate inside the pores. As a result, as well as the effects of far-infrared emission and anion generation, as well as deodorization, antibacterial, anti-static, and health promotion functions, various plastic products such as food storage containers, sponges, cushioning materials, nonwoven fabrics, and textile products such as yarns, fabrics, and mats When used in leather, paper products, etc., it does not damage the unique color of the product and generates no harmful substances. Also, it exhibits remarkably differentiated quality compared to existing products such as excellent processability and UV blocking effect.

Therefore, the far-infrared radiation solution prepared as described above and the treated article thereof can be substituted, modified, and changed in various ways by those skilled in the art without departing from the technical spirit of the present invention, and thus are environmentally friendly for various functional products. Phosphorus material can be used in various applications and forms.

Claims (10)

After pulverizing the mineral raw material composed of nephrite, amethyst, volcanic ash, loess, conglomerate rock, platinum, tourmaline, and germanium to a particle size of 1500 to 3500 mesh, the inorganic raw material and purified water were 1: 0.5-2. A first step of preparing a far-infrared radiation-inorganic suspension by mixing into a mixing tank at a ratio and mixing with a low speed stirrer for 2 to 50 days while maintaining the internal temperature of the mixing tank at 70 to 90 ° C;
After grinding the dried vegetable raw material composed of the situation mushroom, pine mushroom, kkujijak tree with a particle size of 150 ~ 300 mesh (mesh), the vegetable raw material and purified water are added to the concentration tank in a volume ratio of 1: 0.5 ~ 2, the concentration tank A second step of separating the liquid vegetable concentrate obtained by extraction for 1 to 4 days while maintaining the internal temperature at 65 to 80 ° C. with a centrifuge;
Into a separate mixing tank equipped with a high speed stirrer, the far-infrared radiation inorganic suspension and the liquid vegetable concentrate were added at a volume ratio of 1: 0.5 to 2, and then maintained at an internal temperature of the mixing tank at 70 to 90 ° C for 10 to 50 days. A third step of aging with stirring;
Method for producing a far-infrared radiation solution comprising a. The method of claim 1,
Inorganic raw materials used in the first step is 15 to 20% by weight of purgatory, 12 to 18% by weight of amethyst, 7 to 13% by weight of volcanic ash, 10 to 15% by weight of ocher, 5 to 10% by weight of stools, platinum 3 to 7 A method for producing a far-infrared radiation solution, characterized in that it is contained at a weight%, tourmaline 5 to 10% by weight, germanium 20 to 30% by weight. The method of claim 1,
The dry vegetable raw material used in the second step is a 15 to 25% by weight of mushrooms, 45 to 55% by weight of mushrooms, 25 to 35% by weight of Cudrania mulberry method for producing a far-infrared radiation solution. After pulverizing the mineral raw material composed of nephrite, amethyst, volcanic ash, loess, conglomerate rock, platinum, tourmaline, and germanium to a particle size of 1500 to 3500 mesh, the inorganic raw material and purified water were 1: 0.5-2. A first step of preparing a far-infrared radiation-inorganic suspension by mixing into a mixing tank at a ratio and mixing with a low speed stirrer for 2 to 50 days while maintaining the internal temperature of the mixing tank at 70 to 90 ° C;
After grinding the dried vegetable raw material composed of the situation mushroom, pine mushroom, kkujijak tree with a particle size of 150 ~ 300 mesh (mesh), the vegetable raw material and purified water are added to the concentration tank in a volume ratio of 1: 0.5 ~ 2, the concentration tank A second step of separating the liquid vegetable concentrate obtained by extraction for 1 to 4 days while maintaining the internal temperature at 65 to 80 ° C. with a centrifuge;
Into a separate mixing tank equipped with a high speed stirrer, the far-infrared radiation inorganic suspension and the liquid vegetable concentrate were added at a volume ratio of 1: 0.5 to 2, and then maintained at an internal temperature of the mixing tank at 70 to 90 ° C for 10 to 50 days. A third step of producing a far-infrared radiation solution by aging with stirring;
A fourth step of spraying the far-infrared radiation solution on one or both sides of the article with a high-temperature, high-pressure steam injection nozzle having a temperature of 80 to 160 ° C. and a pressure of 3 to 6 bar to adsorb the far-infrared radiation solution on the surface of the article;
A fifth step of cooling the article;
Method for producing a far-infrared radiation article comprising a. After pulverizing the mineral raw material composed of nephrite, amethyst, volcanic ash, loess, conglomerate rock, platinum, tourmaline, and germanium to a particle size of 1500 to 3500 mesh, the inorganic raw material and purified water were 1: 0.5-2. A first step of preparing a far-infrared radiation-inorganic suspension by mixing into a mixing tank at a ratio and mixing with a low speed stirrer for 2 to 50 days while maintaining the internal temperature of the mixing tank at 70 to 90 ° C;
After grinding the dried vegetable raw material composed of the situation mushroom, pine mushroom, kkujijak tree with a particle size of 150 ~ 300 mesh (mesh), the vegetable raw material and purified water are added to the concentration tank in a volume ratio of 1: 0.5 ~ 2, the concentration tank A second step of separating the liquid vegetable concentrate obtained by extraction for 1 to 4 days while maintaining the internal temperature at 65 to 80 ° C. with a centrifuge;
Into a separate mixing tank equipped with a high speed stirrer, the far-infrared radiation inorganic suspension and the liquid vegetable concentrate were added at a volume ratio of 1: 0.5 to 2, and then maintained at an internal temperature of the mixing tank at 70 to 90 ° C for 10 to 50 days. A third step of producing a far-infrared radiation solution by aging with stirring;
After placing the article in an airtight container (reactor), the far-infrared radiation solution was sprayed with a high-pressure steam injection nozzle of 3 to 6 bar while maintaining the internal temperature of the reactor at 80 to 160 ° C. 4th step of adsorbing;
A fifth step of cooling the article;
Method for producing a far-infrared radiation article comprising a. The method according to claim 4 or 5,
The article is a method of producing a far-infrared radiation article, characterized in that made of at least one material selected from plastics, fibers, leather, paper. The method according to claim 4 or 5,
Inorganic raw materials used in the first step is 15 to 20% by weight of purgatory, 12 to 18% by weight of amethyst, 7 to 13% by weight of volcanic ash, 10 to 15% by weight of ocher, 5 to 10% by weight of stools, platinum 3 to 7 A method for producing a far-infrared radiated article, characterized in that it is contained in a proportion of 5% by weight, tourmaline 5-10% by weight, and germanium 20-30% by weight. The method according to claim 4 or 5,
The dry vegetable raw material used in the second step is 15 to 25% by weight of mushrooms, 45 to 55% by weight of pine mushrooms, 25 to 35% by weight of kkujijak tree manufacturing method of the far-infrared radiation article. The method according to claim 4 or 5,
The fourth step is a method for producing a far-infrared radiation article, characterized in that for adsorbing the far-infrared radiation solution for 5 seconds to 5 minutes depending on the type and shape of the article. The method according to claim 4 or 5,
The far-infrared radiation solution is a method for producing a far-infrared radiation article, characterized in that the recovery and reuse after the fourth step.

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