CN109305812A - Anion titanium crystalline substance sterilizes ecological brick - Google Patents

Anion titanium crystalline substance sterilizes ecological brick Download PDF

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Publication number
CN109305812A
CN109305812A CN201710614725.3A CN201710614725A CN109305812A CN 109305812 A CN109305812 A CN 109305812A CN 201710614725 A CN201710614725 A CN 201710614725A CN 109305812 A CN109305812 A CN 109305812A
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China
Prior art keywords
anion
raw material
crystalline substance
ecological brick
sterilization
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Pending
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CN201710614725.3A
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Chinese (zh)
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刘德旭
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Individual
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Priority to CN201710614725.3A priority Critical patent/CN109305812A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides the preparation method of anion titanium crystalline substance sterilization ecological brick, include following processing step: preparing ingredient, it is made of the raw material of following dosage ratio: rare earth 3%-10%, silver ion 0.1%-3%, titanium dioxide 20%-30%, parent glaze raw material 45%-60%, diatom ooze 0.5%-3%, zinc chloride 8%-15%, water 28%-35%.The product that the present invention produces not only stablize by surface effect and product quality situation, moreover it is possible to have the effects that purify air, sterilization, sterilize, eliminates the unusual smell, is anti-oxidant, anti-aging, bring the higher level health experience of client.

Description

Anion titanium crystalline substance sterilizes ecological brick
Technical field
The invention belongs to build floor field, and in particular to be anion titanium crystalline substance sterilization ecological brick.
Background technique
Traditional floor brick is repressed, firing, polishing, classification by raw materials such as clay, feldspars after certain proportion matches Enter warehouse after packaging to sell.The floor tile of the product produced through the technique in general sense can satisfy client's finishing Demand above cannot discharge anion, be unable to satisfy purification air, sterilization, sterilize, eliminate the unusual smell, is anti-oxidant, anti-aging, mentioning Rise the higher level health demands such as client health experience.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, on the basis of original glaze raw material, are guaranteeing not shadow Under the premise of sound glaze normal use combines the various physicochemical properties of glaze slip, three kinds of addition rare earth, silver ion, titanium dioxide etc. is new Ingredient, making the product produced, not only surface effect and new product quality condition are stablized, moreover it is possible to have purification air, sterilization, Sterilize, eliminate the unusual smell, is anti-oxidant, anti-aging the effects of, bring client it is higher level health experience.
The present invention is achieved by the following technical solutions, and anion titanium crystalline substance sterilizes the preparation method of ecological brick, includes Following processing step:
1), prepare ingredient, be made of the raw material of following dosage ratio: rare earth 3%-10%, silver ion 0.1%-3%, titanium dioxide 20%- 30%, parent glaze raw material 45%-60%, diatom ooze 0.5%-3%, zinc chloride 8%-15%, water 28%-35%；
2) after, uniformly deploying ingredient in proportion, ball milling is packed into the mud with certain fineness, mill puts mud into after grinding Pond carry out it is aging after, then pump after drying tower is dried to the powder with certain granules degree and grain mixture ratio, be transported to press vehicle Between be pressed, molding adobe enters the glazing ink-jet of glaze line after dry kiln is dry, after enter back into kiln through 1250 degree High temperature is fired into blank, and blank is packed and stored after being classified respectively using polish line polishing deburring.
The beneficial effects of the invention are that: guaranteeing that not influencing glaze normal use combines the various physicochemical properties of glaze slip Under the premise of, three kinds of new components such as addition rare earth, silver ion, titanium dioxide make the product produced not only surface effect and new production Quality situation is stablized, moreover it is possible to have the effects that purify air, sterilization, sterilize, eliminates the unusual smell, is anti-oxidant, anti-aging, bring client Higher level health experience.
Specific embodiment
Below with reference to specific embodiment, description is of the invention in further detail.
Embodiment one, anion titanium crystalline substance sterilize the preparation method of ecological brick, include following processing step:
1), prepare ingredient, be made of the raw material of following dosage ratio: rare earth 3%-10%, silver ion 0.1%-3%, titanium dioxide 20%- 30%, parent glaze raw material 45%-60%, diatom ooze 0.5%-3%, zinc chloride 8%-15%, water 28%-35%；
2) after, uniformly deploying ingredient in proportion, ball milling is packed into the mud with certain fineness, mill puts mud into after grinding Pond carry out it is aging after, then pump after drying tower is dried to the powder with certain granules degree and grain mixture ratio, be transported to press vehicle Between be pressed, molding adobe enters the glazing ink-jet of glaze line after dry kiln is dry, after enter back into kiln through 1250 degree High temperature is fired into blank, and blank is packed and stored after being classified respectively using polish line polishing deburring.
Rare earth, silver ion, titanium dioxide are added in original base composition of raw materials.The floor tile produced is because containing rare earth member Element, can the vertical anion, that is, negative oxygen ion of permanent stabilization release ecology, the interior of paving anion titanium crystalline substance brick, negative ion concentration reaches Several times to even more than natural forest are horizontal, your family is allowed to become a qualified forest oxygen bar, you can be allowed sufficient not Forest Bath is enjoyed at family out.It is crucial that the generation anion that anion titanium crystalline substance brick is able to continuously not electricity consumption, while Ozone is not generated, it is without any side effects to human body.Secondly as anion, which has, can neutralize in air haze particle institute band just Charge makes it easier to the effect of floc sedimentation sedimentation, can play the effect of purification air；The oxidisability of anion, can play point The effect for solving the volatile organic gas such as formaldehyde, keeps domestic environment safer；Anion also has the function of antibacterial, anti-mildew, very Just play the effect of protection whole family's health；Anion is also slow in stabilizing blood pressure, adjusting sleep, promotion children's brain development, treatment Venereal disease etc. has apparent effect.Third not only improves the strong of glaze paint because joined silver ion and titanium dioxide in formula Degree and Baidu, keep glaze paint not only wear-resisting, are the color development apparent nature of pattern under glaze paint while whiteness is high；The silver ion of addition Also have the function of Continuous sterilization, disinfection with titanium dioxide, increasingly meets the needs of modern client is for health.
Through detecting, after the polished refine of this product is stored for a long time, its anion radioactivity is detected, anion is put Penetrating property is between 20000-30000；Anion titanium crystalline substance brick has no any crackle by 5 heat stability testings of 180 degree, brick face, 5 degree of surface hardness Mohs or more, wear resistance level Four, brick face feels excellent thoroughly.
The above examples are only used to illustrate the technical scheme of the present invention and are not limiting, such as technical solution of the present invention is carried out Modification or equivalent replacement should all cover and want in right of the invention without departing from the objective and range of technical solution of the present invention It asks in range.

Claims (1)

1. the preparation method of anion titanium crystalline substance sterilization ecological brick, which is characterized in that include following processing step:
1), prepare ingredient, be made of the raw material of following dosage ratio: rare earth 3%-10%, silver ion 0.1%-3%, titanium dioxide 20%- 30%, parent glaze raw material 45%-60%, diatom ooze 0.5%-3%, zinc chloride 8%-15%, water 28%-35%；
2) after, uniformly deploying ingredient in proportion, ball milling is packed into the mud with certain fineness, mill puts mud into after grinding Pond carry out it is aging after, then pump after drying tower is dried to the powder with certain granules degree and grain mixture ratio, be transported to press vehicle Between be pressed, molding adobe enters the glazing ink-jet of glaze line after dry kiln is dry, after enter back into kiln through 1250 degree High temperature is fired into blank, and blank is packed and stored after being classified respectively using polish line polishing deburring.
CN201710614725.3A 2017-07-26 2017-07-26 Anion titanium crystalline substance sterilizes ecological brick Pending CN109305812A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710614725.3A CN109305812A (en) 2017-07-26 2017-07-26 Anion titanium crystalline substance sterilizes ecological brick

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710614725.3A CN109305812A (en) 2017-07-26 2017-07-26 Anion titanium crystalline substance sterilizes ecological brick

Publications (1)

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CN109305812A true CN109305812A (en) 2019-02-05

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CN201710614725.3A Pending CN109305812A (en) 2017-07-26 2017-07-26 Anion titanium crystalline substance sterilizes ecological brick

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111848223A (en) * 2020-07-22 2020-10-30 晋大纳米科技（厦门）有限公司 Highly-antibacterial functional glazed brick and preparation method thereof
CN111875255A (en) * 2020-07-27 2020-11-03 广东宏陶陶瓷有限公司 Healthy ecological ceramic tile and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382521A (en) * 2001-04-25 2002-12-04 中国科学院理化技术研究所 Nano composite metal-TiO2 particle and its preparing process and usage
CN1587186A (en) * 2004-09-03 2005-03-02 佛山欧神诺陶瓷有限公司 Method for producing health ceramic brick capable of releasing negative ion
CN102503340A (en) * 2011-11-11 2012-06-20 吉林省兰舍硅藻新材料有限公司 Decorative brick with diatomite as main component
CN103011785A (en) * 2012-12-21 2013-04-03 广东顺祥陶瓷有限公司 Daily refined porcelain with negative ion function and preparation method thereof
CN103253929A (en) * 2012-02-21 2013-08-21 李心红 Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382521A (en) * 2001-04-25 2002-12-04 中国科学院理化技术研究所 Nano composite metal-TiO2 particle and its preparing process and usage
CN1587186A (en) * 2004-09-03 2005-03-02 佛山欧神诺陶瓷有限公司 Method for producing health ceramic brick capable of releasing negative ion
CN102503340A (en) * 2011-11-11 2012-06-20 吉林省兰舍硅藻新材料有限公司 Decorative brick with diatomite as main component
CN103253929A (en) * 2012-02-21 2013-08-21 李心红 Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof
CN103011785A (en) * 2012-12-21 2013-04-03 广东顺祥陶瓷有限公司 Daily refined porcelain with negative ion function and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
伍卫东等: "《建设工程实用绿色建筑材料》", 30 June 2013, 中国环境出版社 *
林宗寿: "《无机非金属材料工学》", 31 December 2013, 武汉理工大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111848223A (en) * 2020-07-22 2020-10-30 晋大纳米科技（厦门）有限公司 Highly-antibacterial functional glazed brick and preparation method thereof
CN111875255A (en) * 2020-07-27 2020-11-03 广东宏陶陶瓷有限公司 Healthy ecological ceramic tile and preparation method thereof
CN111875255B (en) * 2020-07-27 2022-07-12 广东宏陶陶瓷有限公司 Healthy ecological ceramic tile and preparation method thereof

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