KR101128209B1 - 중합 반응을 위한 광개시제 시스템에서의 아릴술피네이트염 - Google Patents

중합 반응을 위한 광개시제 시스템에서의 아릴술피네이트염 Download PDF

Info

Publication number
KR101128209B1
KR101128209B1 KR1020067007987A KR20067007987A KR101128209B1 KR 101128209 B1 KR101128209 B1 KR 101128209B1 KR 1020067007987 A KR1020067007987 A KR 1020067007987A KR 20067007987 A KR20067007987 A KR 20067007987A KR 101128209 B1 KR101128209 B1 KR 101128209B1
Authority
KR
South Korea
Prior art keywords
substituted
delete delete
formula
alkyl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020067007987A
Other languages
English (en)
Korean (ko)
Other versions
KR20060116806A (ko
Inventor
라지딥 에스. 칼구트카르
미카엘 씨. 팔라조토
Original Assignee
쓰리엠 이노베이티브 프로퍼티즈 컴파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 쓰리엠 이노베이티브 프로퍼티즈 컴파니 filed Critical 쓰리엠 이노베이티브 프로퍼티즈 컴파니
Publication of KR20060116806A publication Critical patent/KR20060116806A/ko
Application granted granted Critical
Publication of KR101128209B1 publication Critical patent/KR101128209B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02Sulfinic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/20Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/30Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/60Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/62Photochemical radical initiators
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Inorganic Chemistry (AREA)
  • Biophysics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
KR1020067007987A 2003-09-26 2004-08-05 중합 반응을 위한 광개시제 시스템에서의 아릴술피네이트염 Expired - Fee Related KR101128209B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US50639603P 2003-09-26 2003-09-26
US60/506,396 2003-09-26
US10/847,523 US7064152B2 (en) 2003-09-26 2004-05-17 Arylsulfinate salts in photoinitiator systems for polymerization reactions
US10/847,523 2004-05-17
PCT/US2004/025258 WO2005035591A1 (en) 2003-09-26 2004-08-05 Arylsulfinate salts in photoinitiator systems for polymerization reactions

Publications (2)

Publication Number Publication Date
KR20060116806A KR20060116806A (ko) 2006-11-15
KR101128209B1 true KR101128209B1 (ko) 2012-03-23

Family

ID=34381232

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020067007987A Expired - Fee Related KR101128209B1 (ko) 2003-09-26 2004-08-05 중합 반응을 위한 광개시제 시스템에서의 아릴술피네이트염

Country Status (5)

Country Link
US (3) US7064152B2 (cg-RX-API-DMAC7.html)
EP (1) EP1668039B1 (cg-RX-API-DMAC7.html)
JP (1) JP4723499B2 (cg-RX-API-DMAC7.html)
KR (1) KR101128209B1 (cg-RX-API-DMAC7.html)
WO (1) WO2005035591A1 (cg-RX-API-DMAC7.html)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7250452B2 (en) * 2003-09-26 2007-07-31 3M Innovative Properties Company Dental compositions and methods with arylsulfinate salts
US7064152B2 (en) * 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions
US7030169B2 (en) * 2003-09-26 2006-04-18 3M Innovative Properties Company Arylsulfinate salts in initiator systems for polymeric reactions
US7026367B2 (en) * 2003-09-26 2006-04-11 3M Innovative Properties Company Photoiniators having triarylsulfonium and arylsulfinate ions
US7993807B2 (en) * 2004-04-28 2011-08-09 Hewlett-Packard Development Company, L.P. Compositions, systems, and methods for imaging
JP5211419B2 (ja) * 2005-07-29 2013-06-12 川崎化成工業株式会社 光重合開始剤、およびこれを含む光硬化性組成物
US8071953B2 (en) * 2008-04-29 2011-12-06 Redlen Technologies, Inc. ACF attachment for radiation detector
EP2288659B1 (en) * 2008-05-07 2011-11-09 3M Innovative Properties Company Antimicrobial nanoparticles
US20100166976A1 (en) * 2008-12-30 2010-07-01 Industrial Technology Research Institute Method of manufacturing core-shell nanostructure
EP2368919A1 (de) * 2010-03-25 2011-09-28 Universität des Saarlandes Nanopartikuläre Photoinitiatoren
US10597373B2 (en) * 2014-12-04 2020-03-24 Uop Llc Organo-1-oxa-4-azonium cyclohexane compounds
US9522896B2 (en) * 2014-12-04 2016-12-20 Uop Llc Organo-1-oxa-4-azonium cyclohexane compounds
EP3470048B1 (en) 2017-10-13 2021-11-10 Dentsply DeTrey GmbH Photocurable dental composition
US20240201584A1 (en) * 2021-03-30 2024-06-20 Digilens Inc. Photopolymers for Holographic Recording
CN114539197B (zh) * 2022-03-03 2023-05-30 浙江工业大学 一种3-位氟烷基取代色酮衍生物的合成方法
CN115747837A (zh) * 2022-11-07 2023-03-07 浙江师范大学 含七元环骨架的磺酰胺并多环类化合物的电化学合成方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2215474A1 (de) * 1972-03-29 1973-10-11 Canon Kk Diazophotographisches verfahren und material
US5486544A (en) 1989-07-12 1996-01-23 Kuraray Co., Ltd. Polymerizable composition

Family Cites Families (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US587208A (en) * 1897-07-27 Clutch mechanism
US3573922A (en) * 1965-04-23 1971-04-06 Hughes Aircraft Co Photopolymerizable composition and process
US3531281A (en) 1966-10-03 1970-09-29 Hughes Aircraft Co Photopolymer fixation process
US3556794A (en) * 1966-10-03 1971-01-19 Hughes Aircraft Co Method of inhibiting photopolymerization and products therefor
US3607272A (en) * 1967-02-16 1971-09-21 Hughes Aircraft Co Photographic polymerization process and product
US3708296A (en) * 1968-08-20 1973-01-02 American Can Co Photopolymerization of epoxy monomers
US3627656A (en) * 1969-04-03 1971-12-14 Hughes Aircraft Co Catalyst systems for photo-chemical polymerization
US3627487A (en) * 1969-10-22 1971-12-14 Atomic Energy Commission Process for enriching carbon-13
US3623875A (en) * 1969-11-28 1971-11-30 Plastic Coating Corp Background coloration inhibition in diazosulfonate photoreproduction
US3808006A (en) * 1971-12-06 1974-04-30 Minnesota Mining & Mfg Photosensitive material containing a diaryliodium compound, a sensitizer and a color former
US3729313A (en) * 1971-12-06 1973-04-24 Minnesota Mining & Mfg Novel photosensitive systems comprising diaryliodonium compounds and their use
US3788858A (en) * 1972-10-02 1974-01-29 Hughes Aircraft Co Photopolymerization systems with tetrazolium salt
US3741769A (en) * 1972-10-24 1973-06-26 Minnesota Mining & Mfg Novel photosensitive polymerizable systems and their use
AU497960B2 (en) * 1974-04-11 1979-01-25 Minnesota Mining And Manufacturing Company Photopolymerizable compositions
GB1512981A (en) * 1974-05-02 1978-06-01 Gen Electric Curable epoxide compositions
US4250311A (en) * 1974-05-02 1981-02-10 General Electric Company P, As, and Sb hexafluoride onium salts as photoinitiators
US4069054A (en) * 1975-09-02 1978-01-17 Minnesota Mining And Manufacturing Company Photopolymerizable composition containing a sensitized aromatic sulfonium compound and a cationacally polymerizable monomer
GB1569021A (en) * 1976-03-17 1980-06-11 Kuraray Co Adhesive cementing agents containing partial phosphonic orphosphonic acid esters
US4216288A (en) * 1978-09-08 1980-08-05 General Electric Company Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents
US4455147A (en) * 1978-10-09 1984-06-19 I.W.S. Nominee Company, Limited Transfer printing
US4250053A (en) * 1979-05-21 1981-02-10 Minnesota Mining And Manufacturing Company Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems
US4257915A (en) * 1979-07-23 1981-03-24 E. I. Du Pont De Nemours And Company Photopolymer initiator system containing a semiconductor, a reducing agent and an oxidizing agent
US4695251A (en) * 1980-04-07 1987-09-22 Minnesota Mining And Manufacturing Company Orthodontic bracket adhesive and abrasive for removal thereof
US4366228A (en) * 1980-09-05 1982-12-28 Eastman Kodak Company Photopolymerizable compositions featuring novel co-initiators
AU7674481A (en) 1980-11-10 1982-05-20 Crosby Valve & Gage Company Valve monitoring device
US5304585A (en) * 1981-02-13 1994-04-19 Minnesota Mining And Manufacturing Dentin and enamel adhesive
US4356296A (en) * 1981-02-25 1982-10-26 The United States Of America As Represented By The Secretary Of The Navy Fluorinated diacrylic esters and polymers therefrom
US4539382A (en) * 1981-07-29 1985-09-03 Kuraray Co., Ltd. Adhesive composition
JPS59135272A (ja) * 1983-01-21 1984-08-03 Kuraray Co Ltd 接着剤
US4589572A (en) * 1983-06-20 1986-05-20 New Product Development, Inc. Dispensing mechanism
US4503169A (en) * 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
US4966934A (en) * 1984-11-29 1990-10-30 Dentsply Research & Development Corp. Biological compatible adhesive containing a phosphorous adhesion promoter and accelerator
US4650913A (en) * 1984-11-29 1987-03-17 E. I. Du Pont De Nemours And Company Sulfinate-initiated addition of perfluorinated iodides to olefins
US4642126A (en) * 1985-02-11 1987-02-10 Norton Company Coated abrasives with rapidly curable adhesives and controllable curvature
DE3516257A1 (de) * 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
DE3516256A1 (de) * 1985-05-07 1986-11-13 Bayer Ag, 5090 Leverkusen (meth)-acrylsaeureester und ihre verwendung
US4665251A (en) * 1985-06-12 1987-05-12 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide
DE3670076D1 (de) * 1985-06-24 1990-05-10 Tokuyama Soda Kk Acrylatverbindung und diese enthaltende zusammensetzung.
US4652274A (en) * 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Coated abrasive product having radiation curable binder
DE3536076A1 (de) * 1985-10-09 1987-04-09 Muehlbauer Ernst Kg Polymerisierbare zementmischungen
AU590671B2 (en) 1986-02-28 1989-11-09 Minnesota Mining And Manufacturing Company One-part visible light-curable dentin and enamel adhesive
CA1323949C (en) * 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
DE3724838A1 (de) 1987-07-27 1989-02-09 Henkel Kgaa Verwendung von lichtinduziert vernetzbaren monomer-zusammensetzungen als dunkelhaertende klebstoffe
JPH0669928B2 (ja) * 1987-10-06 1994-09-07 宇部興産株式会社 光重合性歯科材料
US4908227A (en) * 1987-10-16 1990-03-13 Gaf Chemicals Corporation Divinyl epoxy ethers
US4959297A (en) * 1987-12-09 1990-09-25 Minnesota Mining And Manufacturing Company Ternary photoinitiator system for addition polymerization
AU618772B2 (en) * 1987-12-30 1992-01-09 Minnesota Mining And Manufacturing Company Photocurable ionomer cement systems
US4859572A (en) * 1988-05-02 1989-08-22 Eastman Kodak Company Dye sensitized photographic imaging system
JPH024891A (ja) * 1988-06-21 1990-01-09 Mitsubishi Rayon Co Ltd 歯科用接着剤組成物
US4871786A (en) * 1988-10-03 1989-10-03 Minnesota Mining And Manufacturing Company Organic fluoride sources
CA2000855A1 (en) * 1988-11-17 1990-05-17 Mohammad Z. Ali Triazine photoinitiators in a ternary system for addition polymerization
US4971892A (en) * 1988-11-23 1990-11-20 Minnesota Mining And Manufacturing Company High sensitivity photopolymerizable composition
US5076844A (en) * 1988-12-10 1991-12-31 Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology
US4954416A (en) 1988-12-21 1990-09-04 Minnesota Mining And Manufacturing Company Tethered sulfonium salt photoinitiators for free radical polymerization
US5105006A (en) * 1989-05-25 1992-04-14 The Dow Chemical Company Phosphonium salts
US5124417A (en) * 1990-02-12 1992-06-23 Minnesota Mining And Manufacturing Company Initiators for cationic polymerization
US5084586A (en) * 1990-02-12 1992-01-28 Minnesota Mining And Manufacturing Company Novel initiators for cationic polymerization
US5089374A (en) * 1990-08-20 1992-02-18 Eastman Kodak Company Novel bis-onium salts and the use thereof as photoinitiators
US5154762A (en) * 1991-05-31 1992-10-13 Minnesota Mining And Manufacturing Company Universal water-based medical and dental cement
US5256447A (en) * 1991-12-31 1993-10-26 Minnesota Mining And Manufacturing Company Adhesive composition and method
US5530038A (en) * 1993-08-02 1996-06-25 Sun Medical Co., Ltd. Primer composition and curable composition
US6312668B2 (en) * 1993-12-06 2001-11-06 3M Innovative Properties Company Optionally crosslinkable coatings, compositions and methods of use
US5888491A (en) * 1993-12-06 1999-03-30 Minnesota Mining And Manufacturing Company Optionally crosslinkable coatings, compositions and methods of use
JP3465753B2 (ja) 1993-12-28 2003-11-10 株式会社トクヤマ 歯科用組成物
US5501727A (en) * 1994-02-28 1996-03-26 Minnesota Mining And Manufacturing Company Color stability of dental compositions containing metal complexed ascorbic acid
DE69511822T2 (de) 1994-11-21 2000-05-25 Tokuyama Corp., Tokuya Dentalmasse und Kit
US5607663A (en) * 1994-12-01 1997-03-04 Minnesota Mining And Manufacturing Company Hydrocarbyl containing coatings, compositions and methods of use
US5662887A (en) * 1994-12-01 1997-09-02 Minnesota Mining And Manufacturing Company Fluorocarbon containing coatings, compositions and methods of use
JPH0934110A (ja) 1995-07-17 1997-02-07 Konica Corp 光重合性組成物、ラジカル発生方法、平版印刷版作成用感光材料及びそれを用いた平版印刷版の作成方法
US6017860A (en) 1996-04-15 2000-01-25 Stepan Company Cleaning, conditioning and styling hair care compositions
US5998495A (en) * 1997-04-11 1999-12-07 3M Innovative Properties Company Ternary photoinitiator system for curing of epoxy/polyol resin compositions
JP3536895B2 (ja) * 1997-12-18 2004-06-14 株式会社トクヤマ 重合触媒
US6030606A (en) * 1998-06-22 2000-02-29 3M Innovative Properties Company Dental restoratives comprising Bis-EMA6
US6331080B1 (en) * 1998-07-15 2001-12-18 3M Innovative Properties Company Optical fiber connector using colored photocurable adhesive
US6204302B1 (en) * 1998-11-20 2001-03-20 Bisco, Inc. Photosensitizers for free radical polymerization initiation resins and method of making the same
DE19860364C2 (de) * 1998-12-24 2001-12-13 3M Espe Ag Polymerisierbare Dentalmassen auf der Basis von zur Aushärtung befähigten Siloxanverbindungen, deren Verwendung und Herstellung
DE19860361A1 (de) * 1998-12-24 2000-06-29 Espe Dental Ag Vernetzbare Monomere auf Cyclosiloxanbasis, deren Herstellung und deren Verwendung in polymerisierbaren Massen
ES2209846T3 (es) * 1999-03-31 2004-07-01 Kuraray Co., Ltd. Compuestos organofosforados para composiciones dentales polimerizables.
TWI284540B (en) 1999-05-13 2007-08-01 Kuraray Co Bonding composition suitable to tooth tissue
DE19934407A1 (de) 1999-07-22 2001-01-25 Espe Dental Ag Hydrolysierbare und polymerisierbare Silane mit geringer Viskosität und deren Verwendung
US6387981B1 (en) * 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
US6572693B1 (en) * 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
EP1227781B9 (en) 1999-10-28 2006-03-08 3M Innovative Properties Company Dental materials with nano-sized silica particles
US6444725B1 (en) * 2000-01-21 2002-09-03 3M Innovative Properties Company Color-changing dental compositions
DE10026432A1 (de) * 2000-05-29 2002-02-14 3M Espe Ag Präpolymere (Meth)acrylate mit polycyclischen oder aromatischen Segmenten
US6528555B1 (en) * 2000-10-12 2003-03-04 3M Innovative Properties Company Adhesive for use in the oral environment having color-changing capabilities
DE10124028B4 (de) 2001-05-16 2010-02-18 3M Espe Ag Selbstadhäsive Dentalmaterialien
JP2002341519A (ja) 2001-05-17 2002-11-27 Fuji Photo Film Co Ltd 感熱性組成物及びそれを用いた平版印刷版原版
US6759177B2 (en) * 2001-05-17 2004-07-06 Fuji Photo Film Co., Ltd. Photosensitive composition and planographic printing plate precursor
JP4759170B2 (ja) 2001-06-28 2011-08-31 株式会社クラレ 歯科用組成物キット
US6906074B2 (en) 2002-02-22 2005-06-14 Nippon Zoki Pharmaceutical Co., Ltd. 2-phenylpiperazine derivatives
EP1400851A3 (en) * 2002-09-11 2006-09-06 Fuji Photo Film Co., Ltd. Polymerizable composition and planographic printing plate precursor using the same
US6777460B2 (en) * 2002-12-23 2004-08-17 3M Innovative Properties Company Curing agents for cationically curable compositions
US7030169B2 (en) 2003-09-26 2006-04-18 3M Innovative Properties Company Arylsulfinate salts in initiator systems for polymeric reactions
US7250452B2 (en) * 2003-09-26 2007-07-31 3M Innovative Properties Company Dental compositions and methods with arylsulfinate salts
US7026367B2 (en) 2003-09-26 2006-04-11 3M Innovative Properties Company Photoiniators having triarylsulfonium and arylsulfinate ions
US7064152B2 (en) 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2215474A1 (de) * 1972-03-29 1973-10-11 Canon Kk Diazophotographisches verfahren und material
US5486544A (en) 1989-07-12 1996-01-23 Kuraray Co., Ltd. Polymerizable composition

Also Published As

Publication number Publication date
US20050070624A1 (en) 2005-03-31
JP2007506835A (ja) 2007-03-22
EP1668039B1 (en) 2012-12-05
US20070249749A1 (en) 2007-10-25
WO2005035591A1 (en) 2005-04-21
US7732633B2 (en) 2010-06-08
US7541389B2 (en) 2009-06-02
US20090203904A1 (en) 2009-08-13
KR20060116806A (ko) 2006-11-15
JP4723499B2 (ja) 2011-07-13
US7064152B2 (en) 2006-06-20
EP1668039A1 (en) 2006-06-14

Similar Documents

Publication Publication Date Title
US7732633B2 (en) Arylsulfinate salts in photoinitiator systems for polymerization reactions
KR101128189B1 (ko) 중합 반응을 위한 개시제 시스템에서의 아릴술피네이트 염
US7026367B2 (en) Photoiniators having triarylsulfonium and arylsulfinate ions
EP1431315B1 (en) Photopolymerization initiator and photopolymerizable composition
Bouzrati-Zerelli et al. A novel photoinitiating system producing germyl radicals for the polymerization of representative methacrylate resins: Camphorquinone/R3GeH/iodonium salt
Garra et al. Radical cations in versatile high performance initiating systems for thermal, redox, and photopolymerizations
He et al. Penta-Methine Cyanine IRTs: Enabling NIR or Visible Photoinduced Polymerization of Acrylate and Thiol–Ene for Preparation of Polychromatic and Color-Changing Polymers
CN113099718B (zh) 咪唑𬭩/硫醇聚合引发体系
CN100475856C (zh) 聚合反应用的光引发剂体系中的芳基亚磺酸盐
Podemska et al. Diazobenzo [a] fluorene derivatives as visible photosensitizers for cationic polymerization
Świeży et al. New Efficient D‐π‐A and A‐π‐A Structured Type I Radical Photoinitiators for Additive Manufacturing Nanomaterials Preparation
JPH0559110A (ja) 光重合開始剤
Balcerak-Woźniak et al. Dual role of novel highly efficient radical generators for UV/LED-activated polymerization processes

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20150224

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20160218

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20170220

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

FPAY Annual fee payment

Payment date: 20180219

Year of fee payment: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20190313

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20190313