KR100921196B1 - 식물에서의 에틸렌 반응 억제방법 - Google Patents

식물에서의 에틸렌 반응 억제방법 Download PDF

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KR100921196B1
KR100921196B1 KR1020037002434A KR20037002434A KR100921196B1 KR 100921196 B1 KR100921196 B1 KR 100921196B1 KR 1020037002434 A KR1020037002434 A KR 1020037002434A KR 20037002434 A KR20037002434 A KR 20037002434A KR 100921196 B1 KR100921196 B1 KR 100921196B1
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mmol
added
cyclopropene
water
separated
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KR1020037002434A
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KR20030076561A (ko
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제콥슨리차드마틴
켈리마르타진
웨메이어피오나리네트
에반스카렌앤더슨
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롬 앤드 하스 캄파니
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    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/82—Benzo [b] furans; Hydrogenated benzo [b] furans with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
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    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
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AU2002254251A1 (en) * 2001-02-26 2002-09-12 North Carolina State University A method to inhibit ethylene responses in plants
US7041625B2 (en) 2003-08-21 2006-05-09 Rohm And Haas Company Method to inhibit ethylene responses in plants
UA85690C2 (ru) * 2003-11-07 2009-02-25 Басф Акциенгезелльшафт Смесь для применения в сельском хозяйстве, содержащая стробилурин и модулятор этилена, способ обработки и борьбы с инфекциями в бобовых культурах
EP1609359A3 (en) * 2004-06-24 2011-10-05 Rohm and Haas Company A method for treating plants or plant parts
AU2005242218A1 (en) * 2005-01-14 2006-08-03 Rohm And Haas Company Plant growth regulation
US20070117720A1 (en) * 2005-11-18 2007-05-24 Jacobson Richard M Compositions with cyclopropenes
US8093430B2 (en) * 2007-06-22 2012-01-10 North Carolina State University Methods of inhibiting ethylene responses in plants using cyclopropene amine compounds
IL184729A0 (en) * 2007-07-19 2008-01-20 Yissum Res Dev Co Compositions and methods for blocking ethylene response in plants using 3-cyclopropyl-1-enyl-propanoic acid salt
KR101429554B1 (ko) 2010-04-22 2014-08-14 (주)이룸바이오테크놀러지 시클로프로펜 화합물 및 이를 농작물에 부가하는 방법
CN103524434B (zh) * 2013-09-29 2015-08-12 北京大学 植物乙烯合成途径的小分子抑制剂吡嗪酰胺及其应用
US20180325106A1 (en) * 2015-11-03 2018-11-15 Curtin University Of Technology Method of retarding an ethylene response
CN106478507A (zh) * 2016-09-28 2017-03-08 重庆大学 一种2‑（1,3,5‑三芳基‑1‑h‑吡唑‑4‑基）丙二腈的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5518988A (en) 1994-06-03 1996-05-21 North Carolina State University Method of counteracting an ethylene response in plants
WO2001037663A2 (en) * 1999-11-23 2001-05-31 North Carolina State University Blocking an ethylene response in plants using cyclopropene derivatives

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8407195D0 (en) * 1984-03-20 1984-04-26 Cadbury Schweppes Plc Microbial desaturase enzyme inhibitors
DE3523862A1 (de) * 1985-07-04 1987-01-08 Basf Ag Mittel zur regulierung des pflanzenwachstums
US5123951A (en) * 1986-03-31 1992-06-23 Rhone-Poulenc Nederland B.V. Synergistic plant growth regulator compositions
US5100462A (en) 1991-04-01 1992-03-31 North Carolina State University Method of counteracting ethylene response by treating plants with diazocyclopentadiene and derivatives thereof
US5395958A (en) * 1992-09-30 1995-03-07 Mitsubishi Kasei Corporation Cyclopropene derivatives
US6017849A (en) * 1998-08-20 2000-01-25 Biotechnologies For Horticulture, Inc. Synthesis methods, complexes and delivery methods for the safe and convenient storage, transport and application of compounds for inhibiting the ethylene response in plants
US6194350B1 (en) * 1999-11-23 2001-02-27 North Carolina State University Methods of blocking ethylene response in plants using cyclopropene derivatives

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5518988A (en) 1994-06-03 1996-05-21 North Carolina State University Method of counteracting an ethylene response in plants
WO2001037663A2 (en) * 1999-11-23 2001-05-31 North Carolina State University Blocking an ethylene response in plants using cyclopropene derivatives

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