KR100791202B1 - 카르보닐화를 위한 촉매계 및 카르보닐화 방법 - Google Patents

카르보닐화를 위한 촉매계 및 카르보닐화 방법 Download PDF

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Publication number
KR100791202B1
KR100791202B1 KR1020037004408A KR20037004408A KR100791202B1 KR 100791202 B1 KR100791202 B1 KR 100791202B1 KR 1020037004408 A KR1020037004408 A KR 1020037004408A KR 20037004408 A KR20037004408 A KR 20037004408A KR 100791202 B1 KR100791202 B1 KR 100791202B1
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South Korea
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carbonylation
catalyst system
palladium
reaction
radicals
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KR20030040501A (ko
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마르틴 쉐퍼
미하엘 슬라니
에드가 젤러
미하엘 뢰퍼
미하엘 슐쯔
귄터 그림
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바스프 악티엔게젤샤프트
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020037004408A 2000-09-29 2001-09-25 카르보닐화를 위한 촉매계 및 카르보닐화 방법 Expired - Fee Related KR100791202B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10048874.9 2000-09-29
DE10048874A DE10048874A1 (de) 2000-09-29 2000-09-29 Katalysatorsystem und Verfahren zur Carbonylierung
PCT/EP2001/011052 WO2002026382A1 (de) 2000-09-29 2001-09-25 Katalysatorsystem und verfahren zur carbonylierung

Publications (2)

Publication Number Publication Date
KR20030040501A KR20030040501A (ko) 2003-05-22
KR100791202B1 true KR100791202B1 (ko) 2008-01-02

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ID=7658496

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KR1020037004408A Expired - Fee Related KR100791202B1 (ko) 2000-09-29 2001-09-25 카르보닐화를 위한 촉매계 및 카르보닐화 방법

Country Status (11)

Country Link
US (1) US6916954B2 (OSRAM)
EP (1) EP1330309B1 (OSRAM)
JP (1) JP2004509741A (OSRAM)
KR (1) KR100791202B1 (OSRAM)
CN (1) CN1207099C (OSRAM)
AT (1) ATE322339T1 (OSRAM)
AU (1) AU2002210515A1 (OSRAM)
DE (2) DE10048874A1 (OSRAM)
ES (1) ES2261484T3 (OSRAM)
MY (1) MY137590A (OSRAM)
WO (1) WO2002026382A1 (OSRAM)

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GB9918229D0 (en) * 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
GB0228018D0 (en) * 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
JP4773722B2 (ja) * 2002-09-13 2011-09-14 和光純薬工業株式会社 パラジウム触媒組成物
WO2005003070A1 (en) * 2003-07-03 2005-01-13 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
KR20100038476A (ko) * 2004-11-16 2010-04-14 벨로시스, 인코포레이티드 마이크로채널 기술을 사용하는 다중상 반응 과정
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
CA2626107C (en) * 2005-11-17 2016-06-21 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
MX2009005568A (es) 2006-12-02 2009-06-05 Lucite Int Uk Ltd Nuevos ligandos de carbonilacion y su uso en la carbonilacion de compuestos etilenicamente insaturados.
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
WO2009144197A1 (de) * 2008-05-27 2009-12-03 Basf Se Verfahren zur herstellung von aromatischen und heteroaromatischen carbonsäuren, carbonsäureestern und carbonsäureamiden
GB0812297D0 (en) 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
GB0921876D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
GB0921875D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
GB201122054D0 (en) 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
CN107739309B (zh) * 2017-10-30 2020-08-28 中国成达工程有限公司 一种钯催化乙炔的双羰基化制备方法
CN109364996B (zh) * 2018-10-22 2020-11-03 厦门大学 一种双齿磷配体配位的金属催化剂及其催化制备3-羟基丙酸酯的方法
CN114685276B (zh) * 2020-12-30 2024-04-16 上海浦景化工技术股份有限公司 一种乙烯羰基化制备丙酸酯类产品的方法
US20250368598A1 (en) * 2022-06-24 2025-12-04 Shrabanti Bhattacharya Catalytic carboxycarbonylation of alkenes to form anhydrides
CN115870002B (zh) * 2022-12-12 2025-06-03 万华化学集团股份有限公司 一种不饱和烯烃甲氧羰基化的催化剂及方法

Citations (2)

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EP0008407A1 (de) * 1978-08-17 1980-03-05 Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG Polymere Hydrierkatalysatoren, Verfahren zur Herstellung dieser Katalysatoren und ihre Verwendung für katalytische Hydrierungen
EP0441446A1 (en) * 1990-02-05 1991-08-14 Shell Internationale Researchmaatschappij B.V. Carbonylation catalyst system

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US3168553A (en) * 1961-08-25 1965-02-02 Shell Oil Co Reactions of olefins with carbon monoxide
GB1051627A (OSRAM) * 1961-12-29
DE2227546C3 (de) * 1972-06-07 1979-04-05 Basf Ag, 6700 Ludwigshafen Verwendung von oxalkylierten PoIyalkylenpolyaminen zur SchneUentwässening von Rohölen
US3997472A (en) * 1974-11-11 1976-12-14 Polymeric Enzymes, Inc. Novel catalyst systems and methods of preparation
GB1517662A (en) * 1976-03-12 1978-07-12 California Inst Of Techn Photochemical preparation of catalysts for addition reactions of olefines
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8701966D0 (en) 1987-01-29 1987-03-04 Shell Int Research Carbonylation process
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
DE3727704A1 (de) 1987-08-19 1989-03-02 Heyl Chem Pharm Verwendung polymerer loeslicher hydrierkatalysatoren zur positionsselektiven hydrierung von fetten und oelen
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DE69204691T2 (de) 1991-01-15 1996-04-11 Shell Int Research Verfahren zur Karbonylierung von Olefin.
KR100230139B1 (ko) 1991-02-15 1999-11-15 오노 알버어스 카르보닐화 촉매 시스템
EP0577204B1 (en) 1992-06-29 1996-10-09 Shell Internationale Researchmaatschappij B.V. Preparation of alkanedioic derivatives
EP0577205B1 (en) 1992-06-29 1997-10-08 Shell Internationale Researchmaatschappij B.V. Carbonylation of conjugated dienes
US5436356A (en) 1993-02-09 1995-07-25 Shell Oil Company Carbonylation process
DE4435688A1 (de) * 1994-10-06 1996-04-11 Basf Ag Verfahren zur Herstellung von Oligoaminen oder Polyaminen
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GB9918229D0 (en) * 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
EP0008407A1 (de) * 1978-08-17 1980-03-05 Heyl Chemisch-pharmazeutische Fabrik GmbH & Co. KG Polymere Hydrierkatalysatoren, Verfahren zur Herstellung dieser Katalysatoren und ihre Verwendung für katalytische Hydrierungen
EP0441446A1 (en) * 1990-02-05 1991-08-14 Shell Internationale Researchmaatschappij B.V. Carbonylation catalyst system

Also Published As

Publication number Publication date
ATE322339T1 (de) 2006-04-15
DE50109455D1 (de) 2006-05-18
ES2261484T3 (es) 2006-11-16
KR20030040501A (ko) 2003-05-22
WO2002026382A1 (de) 2002-04-04
US20030191339A1 (en) 2003-10-09
US6916954B2 (en) 2005-07-12
DE10048874A1 (de) 2002-04-11
JP2004509741A (ja) 2004-04-02
CN1466489A (zh) 2004-01-07
CN1207099C (zh) 2005-06-22
EP1330309B1 (de) 2006-04-05
MY137590A (en) 2009-02-27
AU2002210515A1 (en) 2002-04-08
EP1330309A1 (de) 2003-07-30

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