KR100637963B1 - 파라-크실렌의 제조방법 - Google Patents

파라-크실렌의 제조방법 Download PDF

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Publication number
KR100637963B1
KR100637963B1 KR1020017002362A KR20017002362A KR100637963B1 KR 100637963 B1 KR100637963 B1 KR 100637963B1 KR 1020017002362 A KR1020017002362 A KR 1020017002362A KR 20017002362 A KR20017002362 A KR 20017002362A KR 100637963 B1 KR100637963 B1 KR 100637963B1
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South Korea
Prior art keywords
xylene
stream
para
feedstock
isomerization
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Expired - Fee Related
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KR1020017002362A
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English (en)
Korean (ko)
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KR20010072935A (ko
Inventor
아비찬다니지반사히브
벡제프리스코트
브라운스티븐해럴드
시미니로날드조셉
쿼크셀마
존슨아이비돈
리구라스디미트리스콘스탄틴
스턴데이비드로렌스
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엑손모빌 오일 코포레이션
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Priority claimed from US09/139,463 external-priority patent/US5977420A/en
Priority claimed from US09/139,465 external-priority patent/US5998688A/en
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Publication of KR20010072935A publication Critical patent/KR20010072935A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/18—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020017002362A 1998-08-25 1999-08-12 파라-크실렌의 제조방법 Expired - Fee Related KR100637963B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/139,463 US5977420A (en) 1998-08-25 1998-08-25 Dual-loop xylene isomerization process
US09/139,465 1998-08-25
US09/139,463 1998-08-25
US09/139,465 US5998688A (en) 1998-08-25 1998-08-25 Xylene isomerization process using toluene co-feed

Publications (2)

Publication Number Publication Date
KR20010072935A KR20010072935A (ko) 2001-07-31
KR100637963B1 true KR100637963B1 (ko) 2006-10-23

Family

ID=26837245

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KR1020017002362A Expired - Fee Related KR100637963B1 (ko) 1998-08-25 1999-08-12 파라-크실렌의 제조방법

Country Status (13)

Country Link
EP (1) EP1109761B1 (enExample)
JP (1) JP4808313B2 (enExample)
KR (1) KR100637963B1 (enExample)
CN (1) CN1177783C (enExample)
AR (1) AR020266A1 (enExample)
AT (1) ATE239683T1 (enExample)
AU (1) AU5558699A (enExample)
BR (1) BR9913240A (enExample)
CA (1) CA2341603A1 (enExample)
DE (1) DE69907694T2 (enExample)
ES (1) ES2198945T3 (enExample)
TW (1) TW518316B (enExample)
WO (1) WO2000010944A1 (enExample)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007127049A2 (en) * 2006-04-25 2007-11-08 Exxonmobil Chemical Patents Inc. Process for producing para-xylene
US7553998B2 (en) * 2006-06-21 2009-06-30 Uop Llc Energy-efficient process for para-xylene production
CN102199066B (zh) * 2010-03-25 2014-05-28 中国石油化工股份有限公司 一种烷基芳烃异构化方法
KR101947247B1 (ko) * 2010-10-29 2019-02-12 엑손모빌 케미칼 패턴츠 인코포레이티드 파라자일렌의 제조 방법
SG189199A1 (en) * 2010-10-29 2013-05-31 Exxonmobil Chem Patents Inc Process for the production of purified xylene isomers
US9309170B2 (en) * 2011-11-14 2016-04-12 Uop Llc Aromatics isomerization using a dual-catalyst system
JP6290180B2 (ja) 2012-04-19 2018-03-07 サウジ アラビアン オイル カンパニー キシレン生成を最大化するための複合重質リフォメートの脱アルキル化−トランスアルキル化法
US20150251973A1 (en) * 2012-10-09 2015-09-10 Exxonmobil Chemical Patents Inc. Purge Streams in Paraxylene Production
EP2925710A4 (en) 2012-11-30 2016-05-11 Exxonmobil Chem Patents Inc ENERGY-EFFICIENT METHOD OF XYLENE MANUFACTURE
US9309169B2 (en) 2012-11-30 2016-04-12 Exxonmobil Chemical Patents Inc. Process for the production of purified xylene isomers
US9809509B2 (en) 2015-12-15 2017-11-07 Exxonmobil Chemical Patents Inc. Process for xylenes isomerization
WO2017105617A1 (en) * 2015-12-15 2017-06-22 Exxonmobil Chemical Patents Inc. Process for xylenes isomerization
US10173950B2 (en) * 2017-01-04 2019-01-08 Saudi Arabian Oil Company Integrated process for the production of benzene and xylenes from heavy aromatics
US10252958B2 (en) 2017-05-26 2019-04-09 Saudi Arabian Oil Company Process for xylene production with energy optimization
US10464868B2 (en) 2017-05-26 2019-11-05 Saudi Arabian Oil Company Process for maximizing production of xylenes from heavy reformate without purge
US10035742B1 (en) 2017-05-26 2018-07-31 Saudi Arabian Oil Company Process for maximizing xylenes production from heavy aromatics for use therein
US10894755B2 (en) 2018-10-15 2021-01-19 Saudi Arabian Oil Company Integrated process for optimum production of para-xylene
US10696609B2 (en) 2018-10-15 2020-06-30 Saudi Arabian Oil Company Integrated process for maximizing production of para-xylene from full reformate
US10501389B1 (en) 2018-10-25 2019-12-10 Saudi Arabian Oil Company Process and system for the production of para-xylene and benzene from streams rich in C6 to C12+ aromatics
KR20210126101A (ko) 2019-03-29 2021-10-19 엑손모빌 케미칼 패턴츠 인코포레이티드 방향족 탄화수소 전환용 mel형 제올라이트, 상기 제올라이트의 제조 방법, 및 상기 제올라이트를 포함하는 촉매 조성물
CN113646287B (zh) 2019-03-29 2025-04-25 埃克森美孚化学专利公司 新型沸石、所述沸石的制备方法及所述沸石用于转化芳族烃的用途
WO2021015900A1 (en) * 2019-07-19 2021-01-28 Exxonmobil Chemical Patents Inc. Isomerization processes for converting aromatic hydrocarbons comprising alkyl-demethylation
EP3978461A1 (en) * 2020-09-30 2022-04-06 Sulzer Management AG A process and apparatus for preparing a purified styrene composition using a divided-wall column and a crystallization unit

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3948758A (en) * 1974-06-17 1976-04-06 Mobil Oil Corporation Production of alkyl aromatic hydrocarbons
KR810000478B1 (ko) * 1978-01-11 1981-05-20 에드워드 에이취. 밸랜스 P-크실렌의 제조방법

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101595A (en) * 1977-05-02 1978-07-18 Mobil Oil Corporation Conversion of ethyl benzene to para xylene
US4159282A (en) * 1978-06-09 1979-06-26 Mobil Oil Corporation Xylene isomerization
JPS63196528A (ja) * 1985-09-13 1988-08-15 ユ−オ−ピ−　インコ−ポレイテツド 異性化／トランスアルキル化兼用帯域を用いたキシレンの製造法
JPS6456628A (en) * 1987-08-25 1989-03-03 Toray Industries Production of p-xylene
JPH08245436A (ja) * 1995-03-09 1996-09-24 Toray Ind Inc ｐ−キシレンの製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3948758A (en) * 1974-06-17 1976-04-06 Mobil Oil Corporation Production of alkyl aromatic hydrocarbons
KR810000478B1 (ko) * 1978-01-11 1981-05-20 에드워드 에이취. 밸랜스 P-크실렌의 제조방법

Also Published As

Publication number Publication date
JP4808313B2 (ja) 2011-11-02
CN1177783C (zh) 2004-12-01
WO2000010944A1 (en) 2000-03-02
AU5558699A (en) 2000-03-14
KR20010072935A (ko) 2001-07-31
CN1319078A (zh) 2001-10-24
CA2341603A1 (en) 2000-03-02
ATE239683T1 (de) 2003-05-15
DE69907694T2 (de) 2004-01-29
ES2198945T3 (es) 2004-02-01
BR9913240A (pt) 2001-05-15
DE69907694D1 (de) 2003-06-12
AR020266A1 (es) 2002-05-02
TW518316B (en) 2003-01-21
EP1109761A1 (en) 2001-06-27
JP2002523385A (ja) 2002-07-30
EP1109761A4 (en) 2001-11-07
EP1109761B1 (en) 2003-05-07

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